Physical Sciences and Mathematics Commons^™

Design, Synthesis, And Characterization Of Complex Chalcogenides For Energy Storage And Energy Conversion Applications, Srikanth Balijapelly

Doctoral Dissertations

"Through this investigation, complex chalcogenides with the combination of main group metals, transition metals, and rare earth metals have been synthesized using the building block approach and their structure-property relationships are evaluated. The main emphasis of research is on rationally designing new materials for applications in sodium and lithium ion conducting solid electrolytes, cathodes, thermoelectrics, and nonlinear optics. Along with the experimental studies, theoretical calculations are also employed to better understand the physicochemical properties of the synthesized compounds.

The first part of the research will discuss designing alkali ion containing complex chalcogenides using the building block approach. This investigation resulted …

Extracting Social Network Model Parameters From Social Science Literature, Isaac Batts

Theses and Dissertations--Computer Science

When looking at computer modeling of social situations, much of the social science literature does not include ready-to-use statistics or parameters to be included in a social model. I explore studies related to speaking about racism (and other forms of bias), and interventions designed to diminish the occurrence of biased behavior, and use those readings to synthesize plausible parameters for a social computer model.

Scene Understanding And Spatial Analysis Using Scene Graph Enhanced By Hall's Proxemics Zones In Smart Homes, Debaleen Das Spandan

MSU Graduate Theses

Voice-controlled smart assistants have received widespread popularity. It plays a pivotal role in smart homes by providing a natural and convenient interface for interacting with smart devices. However, these assistants are unable to serve persons with physical disabilities and speech impairments. Therefore, non-verbal communication methods, such as eye tracking, gesture recognition, and context awareness can complement and overcome some of these limitations to enhance user experience in smart homes. To address this issue, I am investigating non-verbal communication methods to make smart home technology more accessible and intuitive. In this research, I focus on proxemics, i.e., the study of distance …

Photoluminescence Of Beryllium-Related Defects In Gallium Nitride, Mykhailo Vorobiov, Mykhailo Vorobiov

Theses and Dissertations

This study explores the potential of beryllium (Be) as an alternative dopant to magnesium (Mg) for achieving higher hole concentrations in gallium nitride (GaN). Despite Mg prominence as an acceptor in optoelectronic and high-power devices, its deep acceptor level at 0.22 eV above the valence band limits its effectiveness. By examining Be, this research aims to pave the way to overcoming these limitations and extend the findings to aluminum nitride and aluminum gallium nitride (AlGaN) alloy. Key contributions of this work include. i)Identification of three Be-related luminescence bands in GaN through photoluminescence spectroscopy, improving the understanding needed for further material …

Edge Colored And Edge Ordered Graphs, Per Gustin Wagenius

Graduate College Dissertations and Theses

In this work, the current state of the field of edge-colored graphs is surveyed. Anew concept of unshrinkable edge colorings is introduced which is useful for rainbow subgraph problems and interesting in its own right. This concept is analyzed in some depth. Building upon the linear edge ordering described in a recent work from Gerbner, Methuku, Nagy, Pálvölgyi, Tardos, and Vizer, edge-ordering graphs with the cyclic group is introduced and some results are given on this and a related counting problem.

Managing Inventory With A Database, David Bartlett

Williams Honors College, Honors Research Projects

Large commercial companies often use warehouses to store and organize their product inventory. However, manually keeping track of inventory through physical means can be a tedious process and is at risk for a variety of potential issues. It is very easy for records to be inaccurate or duplicated, especially if large reorganizations are undertaken, as this can cause issues such as duplicate product ID numbers. Therefore, it was decided that an inventory management system utilizing a SQL database should be created. The system needed to have capabilities including allowing the entry of product information, the ability to search database records …

Utilizing Suas-Based Remote Sensing For Sustainable Outdoor Recreational Trail Design And Monitoring, Isaac C. Kinder

Graduate Theses, Dissertations, and Problem Reports

This study utilizes sUAS-based remote sensing and hydrologic models to analyze and predict locations susceptible to water-based trail erosion. Erosion is frequently cited as the most significant environmental impact of trails and often requires costly design and management considerations. A professionally designed trail totaling 4 km in length was segmented based on presence or absence of water-based erosion for analyses and then flown with sUAS technology. Three Logistic regression (LR) models were generated utilizing several hydrologic terrain models of varying resolutions to determine the effects of spatial resolution on the models’ predictive accuracies. Receiver operator characteristics, kappa, and overall accuracy …

Educators’ Beliefs About Using Academic Acceleration With Gifted Math Students And Others: Barriers And Opportunities, Jason Gorgia

Theses, Dissertations and Capstones

This study examined the perceptions of educators (i.e., math teachers, administrators, and others) for insight into the absence of acceleration as a common pedagogical strategy in mathematics, despite longstanding research supporting the practice for students gifted in math and the interest frequently articulated by policymakers and educators in boosting American K-12 students’ math achievement. Educators from 48 states responded to scale-based and open-ended questions about math acceleration through an online survey where 713 of 818 respondents were teachers, balanced almost evenly among elementary, middle, and high schools, and among urban, suburban, and rural settings. The responses of teachers and non-teaching …

Environmental Impact Assessment Of The Horseshoe Bend Trail Reconstruction, Ian Caldwell, Kathleen Castleberry, Julia Grams, Sascha Knight, Emily Panteleeff

College of the Environment Graduate and Undergraduate Publications

This is an Environmental Impact Assessment (EIA) on the proposed action of constructing a new section of the Horseshoe Bend Trail along the State Route 542 corridor to Mt. Baker in Whatcom County, Washington. The construction of a new section of trail will renew access to the popular trail, which was washed out in 2021. Impacts to elements of the natural and built environment are examined, with emphasis on riparian and water quality impacts. The proposed action, alternative action, and no action are all considered, along with positives, negatives, and no impacts of each.

Assisted Regeneration Of Threatened Whitebark Pine After Wildfires In North Cascades National Park, Dylan Braund, Clara Magsarili, Ben Molenhouse, Bridget Miller, Zalan Szanyi

College of the Environment Graduate and Undergraduate Publications

This assessment evaluates the environmental effects of seeding whitebark pine seed caches in two burn sites located within the North Cascades National Park Service Complex (NOCA) in Washington State. The goal of these efforts would be to reestablish stands of whitebark pines lost to wildfire.

Environmental Impact Assessment Of Mcglinn-Goat Island Jetty, Sydney Freeman, Sarah Granard, Joey Lane, Ava O’Neill, Malia Thatcher

College of the Environment Graduate and Undergraduate Publications

This environmental impact assessment examines the potential effects of two major fish restoration actions regarding the McGlinn-Goat Island Jetty and the no-action alternative. The goals of these actions are to improve fish passage to/from the N. Fork Skagit River and the Swinomish Channel, important migratory habitat for many salmonid species. This report also investigates potential sedimentation issues arising from alterations to the jetty infrastructure and the potentially deleterious effect of such alterations on maintenance of the Swinomish Channel as a navigable marine passage. This report focuses on analyzing the effects on earth, plants and animals, water, and Transportation. This assessment …

Environmental Impact Assessment Of The Abc Recycling Metal Shredder, Amanda Hogue, Ellysen Mcfarland, Julian Medina-Schroeder, Nico Fotes, Anna Newberry

College of the Environment Graduate and Undergraduate Publications

The purpose of this Environmental Impact Assessment (EIA) is to determine the likely effects of ABC Recycling’s proposed metal shredder facility on the natural and built environment. This assessment summarizes negative and positive effects associated with both the proposed and alternative actions. Where appropriate, this assessment provides additional mitigation measures that could be applied to either the proposed or alternative actions. The impacts of ABC Recycling’s proposed action to build a metal shredder facility were investigated with emphasis on the adverse effects on air and water quality, soil and geological conditions, plant and animal habitat, energy and natural resources, and …

Environmental Impact Assessment For Reforestation Of Douglas Fir After The 2023 Sourdough Mountain Fire, Samantha Burgh, Brandon Lankford, Spencer Natario, Mikaela Silva, Maggie Strecker

College of the Environment Graduate and Undergraduate Publications

This Environmental Impact Assessment was conducted on account of the extensive damage to site conditions at Sourdough Mountain. The proposed areas of action would focus on National Park lands, within the parameters of Sourdough, that withstood severe, extensive degradation as a result of a wildfire outbreak in Summer of 2023. Deforestation throughout the Skagit basin, with particular focus surrounding Sourdough Mountain, was investigated in relation to critical assessments and analyses of natural and built environmental factors throughout the mountain.

Poster, Performed: Understanding Public Opinions Of Authorship In Generative Artificial Intelligence Models Via Analogy, Wylie Z. Kasai

Dartmouth College Master’s Theses

Over the last decade, generative artificial intelligence models have advanced significantly and provided the public with several tools to create new works of art. However, the true authorship of these works has been debated due to their training on web-scraped data. Serving as an analogy to these larger models, Poster, Performed is an interactive artificial intelligence exhibition project that uses image assets submitted by the public to create poster compositions with custom image processing algorithms. During the course of a four-day exhibition, visitors were asked to identify the exhibition’s primary artist from five options: (1) participants who submitted image assets, …

Fire Severity Mediates Marten And Fisher Occurrence: Impacts Of The Dixie Fire On A Carnivore Community, Christopher James Collier

Cal Poly Humboldt theses and projects

The consumption of an astounding one million acres resulted from California’s largest single fire to date, the 2021 Dixie Fire. The social and economic losses associated with the fire were immediately apparent, but the effects on wildlife remained unknown. While previous research has suggested mixed or low severity fire may be beneficial to certain wildlife species, the responses to megafires are poorly understood for many carnivores. To better understand these responses to severe fire, I used a random sampling design stratified by burn severity to survey in and around the Dixie Fire footprint using baited camera stations. This allowed me …

Building Detailed And Accurate Whole-Plant Concepts: A Morphometrics-Informed Reconstruction Of A Zosterophyll From The Lower Devonian Of Wyoming, Samar R. El-Abdallah

Cal Poly Humboldt theses and projects

The fragmentary state of plant fossils and the modular organization of plants make whole-plant reconstructions of fossil species desirable and feasible. Such reconstructions are key for integrating fossil species in systematic studies. The ca. 410 Ma Beartooth Butte Formation of Wyoming (USA) hosts the only rich Early Devonian plant assemblages in western North America, which fills a major gap in the phytogeography of this interval. I construct a whole-plant concept for a new zosterophyll from the Beartooth Butte Formation based on a detailed morphometric study. More than 600 fragments of the new zosterophyll were observed and 200 of those were …

Factors Associated With Acoustic Bat Presence During Spring Emergence In The Appalachian Mountains Of Western Virginia, Emily Kirk Pody

Theses, Dissertations and Capstones

Studies of threats that bats face during hibernation have increased in response to white-nose syndrome (WNS), a fungal disease that has ravaged North American bat populations. However, impacts of WNS on bat ecology during spring emergence, when bats are potentially recovering from infection and allocating resources for reproduction, is relatively understudied. As more bat species become listed at the federal and state level, the need to understand the factors associated with spring emergence is critical for improving conservation guidelines and habitat management practices. Acoustic monitoring is an efficient method for monitoring bat presence for prolonged periods of time, giving biologists …

The Measure Of Efficiency And Effectiveness When Using Artificial Intelligence (Ai) In Radiology, Jordan Watts

Theses, Dissertations and Capstones

Introduction: The use of artificial intelligence in radiology has helped radiologists identify patterns and abnormalities in medical images to diagnose and treat patients. Deep learning and machine learning algorithms have been used to assist physicians in detecting features that are not noticeable to the human eye. The FDA has approved almost 400 AI algorithms for radiology and estimated that the market for AI in medical imaging would grow from $21.48 billion in 2018 to $264.85 billion in 2028.

Purpose of the Study: The purpose of this research was to evaluate the use of artificial intelligence in radiology to determine its …

Assessment Of Potential Impacts Of Climate Change On Hydrology And Water Resource Availability In The Passaic River Basin, New Jersey, Felix Oteng Mensah

Theses, Dissertations and Culminating Projects

Streamflow dynamics in a basin is known to be a major driver of available water resources. In the context of climate change, it is expected that global warming will accelerate the global hydrologic cycle, which will drive more intense floods and droughts leading to changes in streamflow and water resource availability. Most researchers agree that the amount and intensity of precipitation have a direct impact on runoff. Yet, there is no consensus as to how warming can affect streamflow. Evapotranspiration (ET) plays a crucial role here. However, there is a shortage of real-world observations on it. And yet, ET is …

Natural Language Generation From Large-Scale Open-Domain Knowledge Graphs, Xiao Shi

Computer Science and Engineering Dissertations

This dissertation delves into the realm of natural language generation (NLG) from expansive open-domain knowledge graphs, aiming to bridge the gap between existing methods primarily tested on limited datasets and the demands of real-world large-scale, diverse graph structures. Prior works in NLG often relied on small-scale or restricted datasets, neglecting the complexities of broader knowledge graphs. To address this, we introduce a new dataset called GraphNarrative, designed to encompass a wide range of graph structures and enhance the realism of NLG tasks.

The core contribution of this research lies in devising a novel approach to mitigating information hallucination, a common …

When Brain Meets Artificial Intelligence, Lu Zhang

Computer Science and Engineering Dissertations

When we review the history of development of artificial intelligence (AI), we will find that brain science plays a pivotal role in fostering breakthroughs in AI, such as artificial neural networks (ANNs). Today, AI has made remarkable strides, particularly with the emergence of large language models (LLMs), surpassing expectations and achieving human-level performance in certain tasks. Nonetheless, an insurmountable gap remains between AI and human intelligence. It is urgent to establish a bridge between brain science and AI, promoting their mutual enhancement and collaborations. This involve establishing connections from brain science to AI (brain-inspired AI), and reversely, from AI to …

Amination Of 2-Bromo-6-Methylaminopyridine, Matthew H. Elterman

Honors College Theses

Extended metal atom chains (EMACs) represent molecular structures comprising a linear arrangement of metal ions, accompanied by supporting ligands. These compounds possess intriguing properties, yet remain understudied, drawing interest from diverse fields such as physics. However, synthesizing these multimetallic complexes poses significant challenges due to their intricate nature and specificity. Bridging ligands like silyl aminopyridine (SAP) and dipyridyl amine (DAP) have been utilized successfully to support EMACs, with SAP's application in this context being limited to a single published case, highlighting the urgent need for stabilization. This project aims to address this challenge through the synthesis of a novel scaffolded …

Using Pose Estimation Software To Predict Actions In Sabre Fencing, Micah Edwin Peters Ii

Honors College Theses

Fencing is a combat sport that uses three different swords: epee, foil, and sabre. Due to its fast-paced nature and employment of right of way, sabre fencing is often considered the most difficult of the three to learn. Computer vision and pose estimation software can be used to lower the barrier of entry to sabre fencing by identifying the different actions in sabre fencing. This project focuses on using open-source software to design a program that can identify the sabre parries as well as the main sabre movements. This program could be used to help newer fencers and spectators better …

Synthesis Of Chiral Amino Acids Via Direct Amination Of Diazo Ester With A Rhodium-Based Catalyst, Steven J. Boyles

Honors College Theses

Amino acids are critical molecules within living organisms as they are the building blocks of proteins. In organisms, proteins serve as regulators of necessary processes, structural components in tissue, hormones, and neurotransmitters. Amino acid therapy is an emerging treatment in the medical field used to treat symptoms of diseases such as Alzheimer’s disease, Parkinson’s disease, and multiple sclerosis. Amino acid therapies have also shown promising effects when it comes to treating mood disorders and weight management. In order to increase the number of amino acids available and increase the potential treatments for other ailments, there is a drive to increase …

Counting Conjugates Of Colored Compositions, Jesus Omar Sistos Barron

Honors College Theses

The properties of n-color compositions have been studied parallel to those of regular compositions. The conjugate of a composition as defined by MacMahon, however, does not translate well to n-color compositions, and there is currently no established analogous concept. We propose a conjugation rule for cyclic n-color compositions. We also count the number of self-conjugates under these rules and establish a couple of connections between these and regular compositions.

Investigating The Relationship Between Inherited Geologic Framework And Saltwater Intrusion On St. Catherines Island, Georgia, Juliet Talaber, Jacque Kelly, Robert Vance

Honors College Theses

Since the late 1800s, the oldest cities on the Georgia coast have been withdrawing water from the confined Floridan Aquifer System. As the population has grown, a cone of depression has formed extending from Savannah, GA to St. Catherines Island, GA, a barrier island 50 km southeast of Savannah. On St. Catherines Island, the cone of depression has reversed the lateral and horizontal groundwater flow gradients causing saltwater intrusion into the Upper Floridan Aquifer from the Lower Floridan Aquifer through joints, faults, or solution collapse features. Previous studies from the southern and central areas of the island have found evidence …

Herbicide Management Alters Fungal Biomass And Community Composition In Great Lakes Coastal Wetlands, Erica Danae Lathers

Master's Theses and Doctoral Dissertations

Wetlands provide many ecosystem services, and invasive species and their management can alter these services. Plant responses to wetland management actions are typically monitored, but less is known about how soils respond. Phragmites australis, an invasive wetland plant, can alter soil conditions, potentially impacting soil microbial structure and function. We sampled soil communities in Great Lakes coastal wetlands in southeastern Michigan dominated by Phragmites and sites that had been previously invaded by Phragmites then treated with herbicide from 2011-2017, to understand how herbicide management alters soil fungal communities. We assessed microbial and fungal biomass, fungal community composition, greenhouse gas emissions, …

Effect Of Silicon Nano Particles Added To The Polymeric Coatings, Ramesh Chandra Tripathi

Master's Theses and Doctoral Dissertations

The purpose of this research was to compare mechanical and tribological properties of a coatingto the same coating with added nano silica. The sample coating for this project was bis-ureasil which was synthesized using 1:1 equivalent ratio of bis (3-trimethoxysilyl-propyl) amine (BTMSPA) (318.0g) and IPDI (52.0g) in 400g of anhydrous THF. The other coating was prepared by adding 10% nano silica particles. A scanning probe microscope was used to study the surface morphology of the coating samples, a Raman microscope was used to study the silicon concentration on and underneath the surface of the coating, and nano-indentation was used to …

Formation Rates Of Silver Metal Danoprisms As A Function Of Halide Concentration, Steven Akins

Master's Theses and Doctoral Dissertations

anosystem morphology control is proving to be vital for developing nano technologies. This control allows for the optimization of a nanoparticle’s optical and electrical properties. One form of control is the addition of defects during nanocrystal formation. Nanoprisms are highly responsive to this form of control through halide concentration. However, the rate at which this control occurs has remained relatively unexplored. The formation kinetics of silver nanoprisms were monitored before, during, and after crystal formation as a function of halide concentration. The standard deviations between multiple replicates were found to be too large for this method to reach conclusions about …

Using Virus Like Particle Conjugates Of Synthetic Targeting Compounds To Deliver Chemotherapeutic Drugs To Cancer Stem Cells, Austen W. Kerzee

Chemistry Theses

Cancer stem cells are a type of cell that have the properties of both cancer cells and stem cells. They can differentiate into other types of cancer cells, are resistant to conventional chemotherapeutics, and seem to contribute greatly to the metastasis and recurrence of cancer. Due to these properties, eliminating cancer stem cells would be greatly beneficial in the treatment of cancer. While there have been approved therapeutic methods for the removal of a few of the cancer stem cells types, treatment for most types of cancer stem cells are still in the experimental phase and have yet to be …