Physical Sciences and Mathematics Commons^™

Growth And Nutrition Of Plants As Affected By Different Osmotic Concentrations Of Calcium Chloride And Sodium Chloride In The Substrate, Mumtaz Ali Khan

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Considerable experimental evidence supports the concept that the growth of plants generally decreases progressively as the salt concentration of the substrate increases, but certain relationships between plant and substrate are still not fully understood. The chemistry of salt toxicity to plants involves many interactions both as to the quantity and kind of ions presented to the roots and those accumulated in the plants. Many plant species have shown sensitivity to excess accumulation of specific salts frequently encountered in saline soils. Thus Eaton (1942), Wadleigh, Hayward, and Ayers (1951) have shown most of the fruit trees to be susceptible to injury …

The Thermodynamics And Some Practical Aspects Of Zinc Adsorption On Calcite, Dolomite, And Calcian-Magnesite Minerals, Jerome J. Jurinak

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Zinc is one of the essential elements required for the normal growth of plants. The total amount of zinc commonly occurring in soils is usually many times greater than that necessary to supply the needs of actively growing plants. The ability of the soil to "fix" zinc in form unavailable for plant use, however, has made the zinc deficiency disease an important plant nutrition problem in the major fruit and nut growing regions of the West. Fixation mechanisms which have been postulated as contributing to zinc deficiency include organic complexes, precipitation of insoluble inorganic salts, and strong zinc-clay intersections. It …

Coprecipitation Of The Transuranium Elements With The Rare Earths Coprecipitation Of Americium With Lanthanum Oxalate, John A. Hermann

Chemistry and Chemical Biology ETDs

Coprecipitation is a process whereby a substance soluble by itself is "carried" with an insoluble crystalline precipitate. As used here, coprecipitation applies to the "carrying" of a tracer by a precipitate formed in the presence of the tracer. The phenomenon is important in analytical chemistry¹, in the problem of impurities in precipitates; in radiochemistry^2,3, in the separation of radioactive tracers originally present in very low concentrations; and in general, whenever a solid is separated from its mother liquid by precipitation.

Chelation Of The Transition Metal Ions With A Series Of Polyhodrozyamine Compounds, William Percy Moore

Master's Theses

Chelation was reviewed with emphasis on the work done by contemporary workers.

The following polyhydroxyamine compounds were synthesized, purified and· analyzed:

1,2-bis[tris(hydroxymethyl)methylamino]ethane dihydrochloride

1,3-b1s[tris(hydroxymethyl)methylamino]propane dihydrochloride

1,3-b1s[tris(hydroxymethyl)methylamino]-2-propanone dihydrochloride

1,2,3-tris[tris(hydroxymethyl)methylamino)propane tri­ hydrochloride

The latter two compounds have not been reported in the literature.

Chelates were prepared by reacting the above compounds, and 1-3bis[tris(hydroxymethyl)methylamino]-2-propanol dihydrochloride ("disec") and the "disec" free base, with the ions of the first transition metals. Stability cons­tants were obtained where appreciable coordination occurred before precipitation of the metallic ion took place . A list of the metal ions studied with one or more chelating agents follows: Cu⁺², …

Geology Of The Northwest Quarter Of The Washington Quadrangle, Missouri, James Anthony Martin

Masters Theses

"This report presents the results of detailed mapping of the geology of the northwest quarter of the Washington Quadrangle, Missouri. Extensive mapping and stratigraphic work have been done in St. Louis and St. Charles Counties to the east and in Callaway and Boone Counties to the west. These two well studied areas are separated by approximately 45 miles. This study adds geologic information to the area immediately between the above locations. In this area a gentle regional dip to the north permits a study of sediments ranging in age from lower Ordovician in the south to late Paleozoic and Pleistocene …

New Methods For The Study Of Fast Electrode Reactions., Talivaldis Berzins

LSU Historical Dissertations and Theses

No abstract provided.

The Late Tertiary History Of The Upper Little Missouri River, North Dakota, Charles K. Petter Jr.

Theses and Dissertations

No abstract provided.

Tannin Content Of English Walnuts : Thesis ..., Joseph G. Natoli

University of the Pacific Theses and Dissertations

Present methods for the production of leather from animal hides still depend from the most part on the use of natural tannin extracts. During the year, 1952, the amount of natural tannin extracts used by the leather industry was 560,452,119 pounds as compared to 35,793,000 pounds of synthetic tanning materials. It is not as yet possible to produce synthetic materials as economically as the natural extracts; the result being that there is still a very great demand for natural tannin extracts. The need for finding new domestic sources of tannins is apparent when the amounts of domestic and imported extracts …

The Effects Of Structural Changes On The Formation Of Urea Adducts Of Esters, Gerard Vinton Smith

University of the Pacific Theses and Dissertations

An unexpected discovery in 1940 revealed that urea has the peculiar property to form crystalline adducts with many straight chain organic compounds. Since the discovery, considerable time and money have been spent on the elucidation of this phenomenon, and the field of urea adducts has now advanced to the stage at which many empirical rules have been observed but, unfortunately, no sound theory has been formulated.

The purpose of this research was to determine the effect, if any, of changes in structure upon the amount of urea required to adduct with esters. The change in structure consisted of changing the …

The Geology Of The Grassy Butte Area, Mckenzie County, North Dakota, Elmer G. Meldahl

Theses and Dissertations

The Grassy Butte area lies in southern McKenzie County, just southwest of the deepest part of the Williston Basin, and is bordered on the north by the North Unit of the Theodore Roosevelt National Memorial Park.

the purpose of this investigation was: (1) to prepare a geological map of the area; (2) to map the geologic structure of the area; (3) to measure and describe detailed stratigraphic sections which would aid in correlating rock units in this area with previously described rock units in adjacent areas; (4) to indicate lignite beds of possible economic value.

The western three-fifths of the …

An Introduction To The Derivative Of A Polynomial, Floyd A. Miller

Masters Theses

No abstract provided.

A Procedure For The Estimation Of Total Radioactivity In Water, Kenneth Vergil Marsh

University of the Pacific Theses and Dissertations

One of the essential duties of the State of California Department of Civil Defense in times of nuclear weapon attack will be radiological monitoring. The workers in this field will operate from a mobile laboratory truck, equipped with radiation counters and meters, but containing only the simplest of chemical equipment. One of their main problems will be the determination of the total amount of radioactive material, especially fallout of fission products, in a water sample. As yet no method of analysis both simple and rapid enough for application to mobile operation has been developed.

It was the purpose of this …

Waxes From Peat Soils Of San Joaquin Delta, Masao Ueda

University of the Pacific Theses and Dissertations

Wax has been extracted from pest formations in Europe and especially in Britain. However, little or no work have been done in the United States.

The increased demand for waxes and the limited supply of domestic origin has made the study of the sources and characteristics of domestic waxes desirable. Extensive work have been done with montan wax, which is similar to peat wax, in the United States.

The object of this research is to establish a suitable process for extraction of wax from pest material, and to determine the chemical and physical nature of the wax. The process may …

The Effect Of Ph On Phase Reversals Of Protein-Stabilized Emulsions, Samuel Arthur Bradford

Masters Theses

"The phase reversal of an emulsion from a system in which oil droplets are dispersed in a water medium to a system in which water droplets are dispersed in oil is dependent upon the interfacial characteristics of the liquids and the emulsifying agent being used, as well as the volume ratio of the two liquid phases. A preliminary investigation at this institution has indicated a possible relationship between phase reversal and the isoelectric point of gelatin used as the emulsifying agent. Since the properties of proteins vary so greatly with the hydrogen ion concentration, particularly near their isoelectric points, research …

The Effect Of Metallic Naphthenates On The Oxidation Of Linoleic Acid, David Elliott Troutner

Masters Theses

"It has been known for many years that certain metallic soaps catalyse the drying of oils. A great deal of information is available concerning the use of these soaps, but there is little knowledge of the actual manner in which the soaps catalyse drying. As the drying is known to be an autoxidation reaction, it is generally believed that the soaps must affect the oxidation of the oil in some way. The work described in this thesis was undertaken to gain some knowledge of the mechanism of the catalysis, and to correlate the effect of the soaps on the drying …

Thermal Conductivity Of Sodium Chloride Within The Temperature Range 375°K To 637°K, Paul E. Ohlsen

Masters Theses

"The transport of heat in dielectric solids is attributed entirely to lattice waves whereas in metals there is in addition a transfer by the flow of valence electrons. The thermal conductivity of a non-electrical-conductor is limited by a number of scattering processes giving rise to thermal resistances. Scattering results from impurity atoms and from vacancies and dislocations within the crystal structure and from the interaction of the lattice vibrations amongst themselves. Scattering also occurs at the boundaries of the crystal. The thermal resistance of an ideal crystal at low temperatures is due almost entirely to boundary scattering and at high …

The Thermal Conductivity Of Potassium Chloride At Elevated Temperatures, Wendell D. Miller

Masters Theses

"The transport of heat in solids is attributed to the combined effect of the quantized vibrations of lattice points, or phonons, and the flow of valence electrons. In dielectric solids, the thermal conductivity is due almost entirely to phonons, while in metals the latter method preponderates. Scattering processes in dielectric solids, giving rise to thermal resistance, also serve to limit the thermal conductivity. Scattering results from vacancies, dislocations, interstitial atoms and phonon interaction. Crystal boundaries also function as scattering points and in crystals of small dimensions, this process is the most pronounced conductivity-limiting factor. At low temperatures the thermal resistance …

Direct Correlation Functions For Liquid Argon, Arthur Reetz Jr.

Masters Theses

"The purpose of this research is to obtain the direct interaction functions from the liquid argon x-ray scattering structure factors of Eisenstein at various temperatures and over a wide range of interatomic separations"--Introduction, page 1.

Geothermometry At The Balmat No. 2 Mine, New York By The Fes-Zns System, Bruce R. Doe

Masters Theses

"Definition Of The Study. The study consists of an investigation of the variation in the temperature of formation of sphalerite on the 500 and 1500 ft levels of the Balmat zinc deposit at Balmat, New York. A subsidiary investigation was performed on the use of x-ray fluorescence as a means of chemical quantitative analysis. Twelve samples of sphalerite from the 500 ft level and 13 samples from the 1500 ft level were analyzed for atomic percent iron content by measuring Zn/Fe x-ray fluorescent ratios. The x-ray fluorescent ratios were standardized by ''wet" quantitative analysis. The results of the analyses are …

An Investigation Of The Internal Friction Of Manganese-Copper Alloys, Ed. (Edward) Sickafus

Masters Theses

"Internal friction is defined as the ability of a vibrating solid to convert its mechanical energy of vibration into heat, even when completely isolated from its surroundings. (1) The most familiar manifestation of internal friction is the damping of a freely vibrating body, such as a torsional pendulum. Another example would be the increased width of the resonance peak observed when a nonelastic body is forced to vibrate over a spectrum of frequencies.(2) Internal friction manifests itself in numerous ways, and we will here be concerned with the first example cited and the potency of data gained in studying the …

Pre-Cambrian Geology Of Washington County Area, Missouri, Gordon Blair French

Masters Theses

"The Problem.

Washington County, Missouri contains a limited number of outcrops of pre-Cambrian igneous rocks, the majority of which are in the extreme southern part of the county. The known association of lead ore with buried or partially buried pre-Cambrian igneous knobs and ridges in this part of Missouri has led the St. Joseph Lead Company to prospect in areas known to contain these features. In its exploration program, the St. Joseph Lead Company has drilled a number of prospect holes which have encountered other occurrences of pre-Cambrian igneous rocks within the limits of Washington County. This drilling, correlated with …

Geology Of The White Pine District, Fred L. Humphrey

UNLV Theses, Dissertations, Professional Papers, and Capstones

The White Pine district of Nevada is about 30 miles east of Eureka, midway between eureka and Ely, and includes approximately 270 square miles. the area comprises essentially the southeast quarter of the Seligman No. 1 quadrangle, the southwest quarter of the Illipah No. 2 quadrangle, the northwest quarter of the Treasure Hill quadrangle, and the northeast quarter of the Mount Hamilton quadrangle in T. 15, 16, 17, N., and R. 57, 58 E., M.D.B. and M.

The original purpose of the geological work, done under the direction of the Nevada Bureau of Mines, was to prepare a map of …

Stapes Ankylosis And Its Mobilization, Emery I. Pick

Loma Linda University Electronic Theses, Dissertations & Projects

[Abstract Not Included - Preface Included Here]

Otosclerosis is a frequent affliction resulting in progressive hearing loss. With the advance of ear surgery during the past 25 years various procedures have been proposed for the correction of this condition. Among their number surgical mobilization of the stapes has assumed considerable importance. In this paper, which is presented as a thesis to fulfill the requirements for the degree of Master of Science, the operation will be discussed on the basis of the literature and the author's own experiences with the procedure.

The Synthesis Of 1-Methyl-3,4-Benzpyrene, 8-Methyl-3,4-Benzpyrene And 1,8-Dimethyl-3,4-Benzpyrene, William Carter Doyle

Chemistry and Chemical Biology ETDs

The search for the carcinogenic factor present in crude oil tar fractions was begun around 1915. With the observation that the high-boiling, most carcinogenic fractions exhibited fluorescence spectra similar to those of many polycyclic aromatic hydrocarbons, several synthetic hydrocarbons were tested (1) on mice by skin painting techniques. Tumors were produced by 1,2,5,6-dibenzanthracene (I), 3'-methyl-1,2,5,6-dibenzanthracene (II) and 6-isopropyl-1,2-benzanthracene (III). One of the most widely used synthetic hydrocarbon carcinogens at the present is 1,2,5,6-dibenzanthracene.

Preparation Of Several Lactams And Correlation Of Their Structure With Their Infrared Spectra, Kenneth Curtiss Heckeler

Honors Theses

Simple amides are neutral compounds with infrared absorptions characterized by a strong carbonyl absorption. N-H absorptions, and other less significant and unassigned absorptions. Lack of basic nature of amides has been attributed to strong resonance of the unshared pair of electrons on nitrogen with the C=O double bond. This stabilized the molecule to an extent not possible when the electron pair on nitrogen is protonated, since resonance stabilization of such an ammonium structure is no longer possible.

Acidic Properties Of Clay Minerals And Alumina, Kenneth H. Anderson

Theses and Dissertations

Acidic properties of dialyzed alumina and representative clay minerals were studied by performing titrations with various bases. For the first group of experiments the titrations were made in a water system using KOH and NaOH. For this study in a water system the experimental data includes individual cationic activities as well as pH values. Adsorption of the cations was adequately described over a pH range of 5-11 by the equation 1-θ/θ ⋅ aNa+ ⋅ aOH- = 1/K'3 [aOH- + KW/K'2 + 1/K'1], in which θ represents the fraction of the total sites that have reacted. Thermodynamic constants K'3 and K0= …

Some Aspects Of The Chemistry Of The Hydroquinoxalines Unsubstituted On The Nitrogen Atoms, Evan L. Allred

Theses and Dissertations

A search of the literature revealed that almost nothing is known concerning the class of compounds known as decahydroquinoxalines. Since this posed a problem involving a search for a systematic synthetic method of general application as well as a method for establishing the characteristic class and individual properties, a research project under the guidance of Dr. H. Smith Broadbent was initiated. Of particular interest aside from matters of purely chemical interest was the recognition that the hydroquinoxalines possess obvious structural similarities with atropine and other well-known drugs which have valuable application as hypotensive agents, analgesics, spasmolytic agents, parasympathetic depressants, antihistaminics, …

The Effect Of Ferrous And Ferric Ions On The Conversion Of Malate To Pyruvate By A Cell Free Extract Of Pigeon Liver, Keith Erwin Richardson

Theses and Dissertations

Recent investigations on the crude pigeon liver extracts have shown the presence of an enzyme which catalyzes the oxidative decarboxylation of malate to pyruvate and carbon dioxide. The name malic enzyme has been given to this enzyme to distinguish it from malic dehydrogenase. Under aerobic conditions the addition of ferrous sulfate resulted in inhibition of the action of malic enzyme. Subsequent investigation showed that the inhibition obaerved was not due to ferrous ions, but due to ferric ions which were contaminating the ferrous sulfate. It was also shown that under aerobic conditions ferrous ions were rapidly oxidized to ferric ions. …

A Study Of The Chelation Of 1,3-Bis-(Tris-(Hydroxymethyl)-Methylamino)-2-Propanol Dihydrochloride With Copper (Ii), Nickel (Ii), Cobalt (Ii), Velta Erdmanis

Master's Theses

In this study 1,3-bis-(tris-(hydroxymethyl)-methyl­ amino)-2-prapanol dihydrochloride chelates with calcium, manganous, cobaltous, nickelous, cupric and zinc ions were investigated.

Potentiometric titrations were performed to obtain information about the stability of the chelates formed. Calcium and manganous ions showed little chelating ability. Cobaltous, nickelous, cupric and zinc ions formed stable chelates when the ratio of the chelating agent Concentration to the metal ion concentration was 1:1 or larger.

Job 's method of continuous variations was used for determining the composition of the cupric, nickelous and cobaltous chelates and it was found that these metal ions form a 1:1 chelate with l,3-bis-(tris-(hydroxymethyl)­ methyl …

A Study Of The Chelation Of 1,3-Bis (Tris (Hydroxymethyl) Methylamino) 2-Propanol With Iron (Iii), Jane Bell Grinnan Gladding

Master's Theses

The element Iron is so important that a major era of history bore its name. Its magnetic and metallic properties have long been studied and used. It is also well known that iron. is the cental element in the oxygen-carrying compound hemo­ globin and therefore essential to life. Its biological importance is also evidenced by its presence in the cytochrome oxidases . These important biochemical compounds are iron chelates

Fundamental research with iron chelates may therefore shed light on the operations of certain enzyme systems, drugs and poisons. Analytical chemistry and the dye industry have used chelate compounds for many …