Physical Sciences and Mathematics Commons^™

Montan Wax From California Lignites, Robert John Kvick

University of the Pacific Theses and Dissertations

Montan wax has been extracted from the lignite deposits of Germany since the early part of the twentieth century, The wax was named by von Boyen (1901), The word Montan is derived from the Latin term montanus meaning "of a mountain," The wax has found extensive uses in polishes, insulating materials, candles, explosives, and special applications in the rubber industry, The increased demand for waxes for industrial uses and the limited supply of domestic origin has made the study of the sources and characteristics of domestic waxes desirable, California lignite has been shown to be a valuable source of Montan …

4-Benzoyl-4-Methyl-1, 2-Epoxypentane, An Attempted Synthesis, Robert L. Snell

Masters Theses

"The object of this research was to prepare first the simplest homologue of the epoxy-ketone considered by Russell to have been his product. If this homologue, 4-benzoyl-4-methyl-1,2-epoxypentane, could be prepared and caused to form a cyclic derivative of the type given by 1,4-diketones with 2,4-dinitrophenylhydrazone, the organic chemist would be given a new approach to substituted 1,2-diazines as well as a previously unreported reaction of the epoxide grouping. If this reaction could be made to occur, other epoxides of this series would be prepared and treated in the same manner.

It was decided that the shortest route to 4-benzoyl-4-methyl-1,2-epoxypentane would …

The Determination Of Moisture In Active Dry Yeast, Richard F. Fenske

Bachelors’ Theses

The writer, having been employed for the past three years, in the control laboratory of one of this country's largest yeast concerns, is very much interested in the determination of moisture in active dry yeast and has there­ tore made the investigation presented in this paper.

The moisture content is, of critical importance in the production of active dry yeast. A yeast whose moisture content is too low will have poor baking characteristics while a yeast whose moisture content is too high will have poor keeping quality. Inconsistent results have been obtained by using various methods to determine the moisture …

The Fluorescence Of Uranium In Solid Solution, Robert Emmett Kelly

Masters Theses

"The fluorescence of uranium finds its greatest application in the so-called "bead test" which is a method of qualitative analysis. In the form of a bead, the uranium is in solid solution, and if the proper chemical solvent is used, the bead will fluoresce under ultraviolet radiation.

In the systematic separation of the metallic elements, uranium is associated with the aluminum group in that it is not precipitated by hydrogen sulfide in 0.3 N H ion but is precipitated by ammonium hydroxide and ammonium sulfide. In the analytical scheme, uranium acts like beryllium. This process of detection is sometimes tedious …

Halogenated Epoxide-Phenol Reactions A Mechanism Study, Richard L. Rowton

Masters Theses

"The object of this investigation was to study the reactions of two other halogenated epoxides--namely, 3-bromo-1,2-epoxybutane and l-bromo-2,3-epoxybutane--with the phenolate ion, with the hope that the results obtained would shed additional light upon the mechanisms of such reactions. At the present time, no direct practical applications of the results can be forseen. However, the information gained will be a worthwhile addition to the vast existing store of knowledge already at our disposal, and might be of some help to future investigators"--Introduction, page 2.

The Partition Function Of Silver, Ralph H. Lilienkamp

Masters Theses

"The study of the thermodynamic properties of solids at low temperatures has shown that most theories either break down or become too cumbersome.

A theory based upon a crystal lattice of atoms gives the best physical picture of a solid. Fisher has developed partition functions from this theory for the simple cubic, body-centered cubic, and the face-centered cubic lattices. In his paper Fisher gave three partition functions of increasing complexity and accuracy for each of the three lattices. In this paper the three partition functions for a face-centered cubic lattice shall be applied to silver and compared.

The Helmholtz free …

A Study Of The Effect Of Jointing On The Blasting Of Granite, Graniteville, Missouri, Avery Ala Drake

Masters Theses

"Purpose of investigation: The purpose of this investigation is to attempt to determine the influence that joints exert upon the blasting of granite and if joints are induced by blasting. The problem grew out of an explosive evaluation project that was conducted by the Mining Department, Missouri School of Mines. In late May 1950, the project was moved into the granite area near Graniteville, Missouri. It became apparent upon study of this area that the jointing would have certain effects upon the results obtained. Dr. J. D. Forrester, Chairman, Department of Mining Engineering, Missouri School of Mines, Rolla, Missouri, suggested …

A New Basic Copper Phosphate Mineral From Santa Rita, New Mexico, David B. Givens

Earth and Planetary Sciences ETDs

Supergene minerals are not common, nor are they rare at Santa Rita, New Mexico. Kerr (1950,307) reports the presence of cuprite, melaconite, native copper, chrysocolla, machite and azurite. There is also smithsonite present.

The physical appearance of the mineral, coupled with preliminary determinations of the indices of refraction, gave a rough correspondence with dihydrite (Larson and Berman, 1934, 135). However, enough discrepancy existed to warrant taking powder and Weissenberg X-Ray pictures. From these it was evident immediately that the specimen was a new mineral species.

The Synthesis And Pharmacologic Activity Of Some Bis-(2-Aminoethyl)-Benzenes, Ching Chen Tung

Doctoral Dissertations

Introduction: The isolation of epinephrine from the medulla of the suprarenal gland and the discovery of its amazing therapeutic effects have stimulated intensive research on the synthesis of compounds possessing the basic skeleton of 2-aminoethyl-benzene. The investigation in the past forty years have culminated in the preparation of a large number of this type of amine which are pharmacologically classified as "sympatho-mimetic" or "pressor" agents because they generally act on the sympathetic nervous system and cause in increase of blood pressure. However, the 2-aminoethylbenzene derivatives most thoroughly studied have been those whose molecules possessed only one aminoethyl side chain per …

Enrichment Of Tin Activity Through The Szilard-Chalmers Separation, Herta W. Spano

Chemistry and Chemical Biology ETDs

It was the purpose of this investigation to utilize the Szilard-Chalmers reaction in order to prepare tin solutions of high specific activity.

Tetraphenyl tin was chosen for the target compound. It is a white, crystalline solid of excellent thermal stability. No data have been reported in the literature on the rate of exchange between inorganic forms of tin and tetraphenyl tin but it seemed highly probable that this exchange would be very slow. Tetraphenyl tin is soluble in various organic solvents but insoluble in water, and this suggested solvent extraction as a possible means of separation of the activated tin …

A Sensitive Electronic Photometer Employing Negative Feedback, John Lee Pack

Physics & Astronomy ETDs

Purpose of the Instrument

The instrument to be described in these pages was tentatively intended to be used for the purpose of scanning the night sky automatically for investigations of the zodiacal light. It was to detect light below the noise level of a photomultiplier tube, to have linearity up to signals 100 times greater than the noise level, and to have a response time of about 10-4 seconds.

An Experimental Investigation Of The Dead Time Of Geiger-Mueller Counters, Peter H. Jessner

Physics & Astronomy ETDs

As ever more sensitive and precise experiments are being performed with Geiger Counters, especially in cosmic ray research, the resolving power of these instruments assumes an ever increasing importance. With the present perfection of electronic circuitry, this resolving time has become largely a function of the dead time of the Geiger counter tube itself. It was therefore proposed to investigate methods of reducing this dead time. Only self-quenching counter tubes had to be considered in this connection since the dead time of all other types of Geiger counters is inherently longer.

The Elastic Scattering Of Deuterons By Deuterons, Richard John Runge

Physics & Astronomy ETDs

The concern of this work is the calculation of elastic scattering of deuterons by deuterons. The solution of the problem will be given in the usual center of mass system of coordinates, the conversion of results from this to the laboratory system being standard. Since the deuteron itself consists of a neutron and a proton, the problem is thus one of four bodies. The nuclear three body problem of the scattering of a neutron by a deuteron has been treated by previous authors and we will have occasion to employ methods used by these authors extending them to the four …

Investigation Of Penetrating Cosmic-Ray Showers In Water, George William Rollosson

Physics & Astronomy ETDs

In this investigation, some of the properties of the radiation which produces penetrating showers in its passage through matter are studied. Geiger techniques are used to measure the average distance over which the neutral radiation produces one penetrating shower. This distance, called collision length, is measured in water...

The collision length, on the other hand, is measured by placing the material near the apparatus and measuring the mean distance in which one shower is produced and eliminating from the observation any penetrating showers which may be produced subsequently either (a) by the original particle or (b) by the secondaries from …

The Peroxide Numbers Of Vegetable Oils, Robert J. Bruce

Bachelors’ Theses

A survey of the literature will indicate that the peroxide numbers of fats and oils are of importance in ii many industries. The dairy, fish oil, vegetable oil, and meat processing industries all have use for peroxide number determinations. as a measure of the degree of rancidity of their products. The paint industry has used it in the study of protective coatings, and the textile industry has used it in the study of the lubrication of fibers. All of these uses were applied to the study of partial oxidation of the samples under consideration.

Since the various methods in use …

Solubility Product Constants Of The Metallic Sulfides, Marvin Bernard Gordon

Theses and Dissertations

A survey of the chemical literature revealed a lack of agreement in the values reported by various investigators for the solubility product constants of the metallic sulfides. The object of this thesis was to obtain a reliable set of solubility product constant values for the metallic sulfides by means of thermodynamic calculations. Of considerable importance in calculating the values of the solubility product constants of the metallic sulfides is the value of the standard free energy of formation of the sulfide ion. A critical review of the values that have been reported by various investigators for this constant , including …

2-Pyrrolidinoethyl Esters Of Para Alkoxybenzoic And Para Alkox Alkoxycinnamic Acids, Michael James Fletcher

Master's Theses

One of the most important groups of local anesthetics is the class of alkyl and dialkylaminoalkyl esters of aromatic acids. Of these compounds, the diethylaminoethyl esters are particularly valuable.

It is obvious that pyrrolidine is merely a modified form of diethylamine. The purpose of this work is to learn the effect of substituting the N-pyrrolidyl nucleus for the diethyl amino nucleus in various esters of the local anesthetic type.

Derivatives Of M-Xylene, Henry J. Muller

Chemistry and Chemical Biology ETDs

Since m-xylene of 95-98% purity has recently become available from petroleum, this is an appropriate time to prepare an examine its derivatives. Isophtalic and m-toluic acids can be prepared from the hydrocarbon. The purpose of this work was to prepare imidazolines from these acids

Geology Of The Pre-Cambrian Rocks Of The Northern End Of The Sandia Mountains, Bernalillo And Sandoval Counties, New Mexico, Philip T. Hayes

Earth and Planetary Sciences ETDs

Most of the pre-Cambrian metamorphic rocks of the northern end of the Sandia Mountains crop out on and adjacent to a prominent spur, called the Rincon, which lies to the west of the main mountain mass. These metamorphic rocks which consist of quartzite, schist, and greenstone are considered to be the result of moderate regional metamorphism of clastic sedimentary rocks and possibly some basic flows and stills. These rocks are here tentatively named the Juan Tabo sequence and are Archeozoic or early Proterozoic age. The Sandia granite, which lies to the east and south of the Juan Tabo sequence, was …

Phase Behavior Of Sodium Stearate In Anhydrous Cyclohexane, Walter Edward Reid Jr.

Master's Theses

Soap solutions, aqueous and non-aqueous, are characteristic in that they firm colloidal systems at certain concentrations, the properties of which are influenced by temperature and pressure. Application of the Gibbs phase rule to such systems makes possible the location of the various phases of a particular system and hence enables phase diagrams to be constructed. For systems of soap-hydrocarbons such as are found in fuels, beauty preparations, greases, medical preparations, etc., a phase diagram would show very readily the most satisfactory composition for the conditions desired.

The Occurrences Of Non-Metallic Minerals In Montana, Samuel T. Mitchell

Bachelors Theses and Reports, 1928 - 1970

This thesis is essentially an abstract of the literature concerning occurrences in Montana of minerals with a non-metallic luster. The dis­cussions give a general description of the occurrences of minerals as reported by the various references, but is not complete as less than 40 percent of the non-metallic minerals known to exist in Montana are discussed.

Studies On Some Reactions Of Portland Cement, Edward Shannon Clark

Honors Theses

Studies are made on 1. The mechanism of cement setting, 2. Cement – sawdust mixtures, 3. The effect of soluble compounds on cement, 4. Cement – latex mixtures and 5. Cement – plastic compositions.

Inhibition Of The Thermal Polymerization Of Styrene, Herman Ernst Opitz

Honors Theses

It is the purpose of this thesis to further study the inhibition of the thermal polymerization of styrene along the same lines as Cohen, and wherever necessary to improve and correct his work.

The Effect Of Electrolytes On The Viscosity Of Protein Solutions, Thomas Anthony White

Honors Theses

This project was undertaken to study the Hofmeister series and Loeb's contention that it is incorrect. The protein chosen for study was gelatin. The three salts used were: sodium chloride, sodium acetate and sodium nitrate.

The Reliquefaction Of Zirconia Gels, Hubert Joseph Keily

Honors Theses

The initial reliquefaction of zirconia gels at room temperatures seems to be unique. The following study was made to provide a further description of this phenomenon and to attempt to suggest the nature of it.

A Study Of The Mechanism Of The Reaction Between Styrene And Tung Oil, Rowan Joseph Coyle

Honors Theses

It is the purpose of this thesis to study the possible mechanisms by which styrene may react with tung oil. To this end, styrene is reacted with tung oil, using a peroxide catalyst, the reaction product is separated into its components, and a preliminary analysis of these components is made, in an attempt to determine whether the reaction occurs through a Diels-Alder or a co-polymerization type mechanism.

Electrodeposition Apparatus Employing A Controlled Cathode Potential, Carl Arthur Hirt

Honors Theses

The present work was undertaken with the idea of building a simple electrodeposition apparatus employing a controlled cathode potential so that quantitative separations and determinations of various cations could be made. When finished the apparatus was to be employed in the investigation of electrochemical problems. However, so many difficulties arose in the construction of the apparatus that there was not time available for this latter work.

Catalytic Vapor Phase Ethylation Of Phenol, George Wendell Putman

Honors Theses

The object of this research was to study the reaction between ethyl alcohol and phenol and to try to identify some of the products. Further study of the effect of catalyst on the reaction was also undertaken.

The Ultraviolet Absorption Of Some Nitrogen Heterocycles, Benzotriazole, Benzimidazole, Indazole, Indole, John Edward Fagel Jr.

Honors Theses

The ultraviolet absorption spectra of benzotriazole, 5, (6)-chloro-benzotriazole, benzimidazole, indazole, and indole have been determined in aqueous solutions of varying acidity in the region 210-300 mmu. An attempt has been made to correlate the absorption spectra of these compounds with their molecular structure. The acidic dissociation constants of several of the compounds have been determined graphically from the absorption data.

Microfauna Of The Colorado Shale In The Sunburst Dome Area, Montana, Merle W. Emmert

Bachelors Theses and Reports, 1928 - 1970

It has been hoped that a micropaleontological study of the shales of the Upper Cretaceous Colorado Group in northern Montana would reveal certain faunal zones which would serve as markers in an otherwise drab, undifferentiated, 1800 feet of grey, fissile shale. This paper presents the results of a study of the microfauna in certain samples from this shale in the Sunburst Dome area north of Shelby, Montana.