Physical Sciences and Mathematics Commons^™

Chemical Modification Of Cvd Diamond Electrodes, Robert Matthew Johnson

Chemistry & Biochemistry Theses & Dissertations

The micro-array behavior of boron doped CVD diamond thin film electrodes has been studied in acetonitrile containing two redox couples. The analytical technique employed in these studies was cyclic voltammetry. One system is 0.4 mM ferrocene containing 0.1 M tetrabutylammonium hexafluorophosphate (TBAH). This reversible redox system is not only well-known, but also involves only one electron transfer with no breakage/formation of chemical bonds, thus making it a simple system for analysis. The second test is 0.8 mM cobaltocenium hexafluorophosphate, with 0.4 mM ferrocene as an internal standard. Unlike ferrocene, which is neutral initially, cobaltocenium is positively charged, and is reduced …

Lead Shot Concentration In Soil At The Overton Wildlife Management Area, Nevada, George R. Bertoty

UNLV Theses, Dissertations, Professional Papers, and Capstones

During the spring of 1998, soil samples were collected from two areas at the Overton Wildlife Management Area (OWMA), located in the Moapa Valley of Clark County, Nevada. Lead shot has been banned for the hunting of waterfowl since 1986 but is still legal for upland game hunting. Both types of hunting occur at OWMA. One area sampled is a cultivated field and serves primarily as a dove hunting area. The other area is primarily a waterfowl hunting area and is flooded during the waterfowl-hunting season. Lead shot was recovered from 83% of the samples from the dove hunting area, …

Hubble Space Telescope Images And Spectra Of The Remnant Of Sn 1885 In M31, Robert A. Fesen, Christopher L. Gerardy, Kevin M. Mclin, Andrew J. S. Hamilton

Dartmouth Scholarship

Near-UV Hubble Space Telescope images of the remnant of SN 1885 (S And) in M31 show a 070±005 diameter absorption disk silhouetted against M31's central bulge, at SN 1885's historically reported position. The disk's size corresponds to a linear diameter of 2.5±0.4 pc at a distance of 725±70 kpc, implying an average expansion velocity of 11,000±2000 km s-1 over 110 yr. Low-dispersion Faint Object Spectrograph spectra over 3200-4800 Å reveal that the absorption arises principally from Ca II H and K (equivalent width 215 Å), with weaker absorption features of Ca I 4227 Å and Fe I 3720 Å. The …

Variability Analysis Of Discrete Cosine Transform Coefficient (Dctc) Features For Speech Processing, Bingjun Dai

Electrical & Computer Engineering Theses & Dissertations

In this research, the variability of Discrete Cosine Transform Coefficient (DCTC) features was investigated. Additionally, a new pitch-synchronous processing method was explored to increase the stability of features and to reduce window effects when compared to the regular method. The noise sources that lead to feature variability were analyzed, and different smoothing methods were tested. It was found that longer frames, frequency warping, time smoothing of the log spectrum, and DCS level time smoothing, all help reduce DCTC variability and increase classification performance. The pitch­ synchronous method was implemented with Matlab. Important processing methods, including pitch period estimation, time­ domain …

Computer Simulations Of Electromigration Based On A Molecular Dynamics Approach, John Stephen Peake

Electrical & Computer Engineering Theses & Dissertations

Most research on electromigration has centered around macroscopic simulations of electromigration where a value for the diffusion coefficient was assumed to be spatially uniform throughout the material. The research in this thesis goes a step further and, through microscopic molecular dynamics computer simulations, calculates and updates the atomic drift velocity and atomic position as a function of time to analyze how various defects within the conductor affect these quantities. The simulations are carried out with defects in the form of dislocation half-planes placed in different locations within the simulation space. The atomic drift velocity and position changes derived from these …

Morphogenesis Of Douglas Fir Buds Is Altered At Elevated Temperature But Not At Elevated Co2, Martha E. Apple, Melissa S. Lucash, David M. Olszyk, David T. Tingey

Environmental Science and Management Faculty Publications and Presentations

Global climatic change as expressed by increased CO₂ and temperature has the potential for dramatic effects on trees. To determine what its effects may be on Pacific Northwest forests, Douglas-fir (Pseudotsuga menziesii ) seedlings were grown in sun-lit controlled environment chambers at ambient or elevated (+4°C above ambient) temperature, and at ambient or elevated (+200 ppm above ambient) CO₂. In 1995–1996 and 1996–1997, elevated CO₂ had no effect on vegetative bud morphology, while the following unusual morphological characteristics were found with greater frequency at elevated temperature than at ambient: rosetted buds with reflexed and loosened outer …

Experimental Studies Of Fe-Mg Carbonates And Their Role In Petrogenesis

Andrea M. Koziol

Spectral Features Of The Stimulated Raman Backscattering Of Modulated Laser Pulses In A Plasma, Nikolai E. Andreev, Serguei Y. Kalmykov

Serge Youri Kalmykov

The characteristic features of the stimulated Raman backscattering of short modulated (multi-frequency) laser pulses in an underdense plasma are investigated. A laser pulse consisting of a given pair of spectral components with the frequency difference close to the double plasma frequency is studied in the weak mode coupling approximation. The scattering of the component with the higher frequency is shown to be a five-wave resonant process, and the conditions under which this process is totally suppressed are found. The scattering of the component with the lower frequency is an ordinary three-wave decay process without any suppression. When the difference between …

"Wcfields": A Magnetic Rotating Stellar Wind Model From Wind Compression Theory., R. Ignace, J. P. Cassinelli, J. E. Bjorkman

Richard Ignace

A stellar wind model for a magnetic rotating star is presented. We use the semianalytic wind compression model that predicts the two-dimensional geometry of outflows from rotating stars and consider the addition of a magnetic field. In the limit of weak magnetic fields, in such a way that the fields are unimportant in accelerating the flow, the wind compression model can be used to predict the magnetic field distribution throughout the wind, which is shown to follow the mass flux distribution. A compression of field lines near the equator results as the flow of material from higher latitudes brings magnetic …

A Heavy Top Quark From Flavor-Universal Colorons, Marko Popovic, Elizabeth Simmons

Marko B. Popovic

Ordinary technicolor and extended technicolor cannot produce the heavy top quark unaided. We demonstrate that a flavor-universal extension of the color interactions combined with an extended hypercharge sector that singles out the third generation can provide the necessary assistance. We discuss current experimental constraints and suggest how collider experiments can search for the predicted new heavy gauge bosons.

Weyl-Type Fields With Geodesic Lines Of Force, Brendan Guilfoyle

Publications

The static electrogravitational equations are studied and it is shown that an aligned type D metric which has a Weyl-type relationship between the gravitational and electric potential has shearfree geodesic lines of force. All such fields are then found and turn out to be the fields of a charged sphere, charged infinite rod and charged infinite plate. A further solution is also found with shearing geodesic lines of force. This new solution can have m > |e| or m < |e|, but cannot be in the Majumdar-Papapetrou class (in which m = |e|). It is algebraically general and has flat equipotential surfaces.

Improved Treatment Of Loop Diagrams In Su(3) Baryon Chiral Perturbation Theory, Jf Donoghue, Br Holstein

Barry R Holstein

Baryon chiral perturbation theory as conventionally applied has a well-known problem with the SU(3) chiral expansion in that loop diagrams generate very large SU(3) breaking corrections and greatly upset the subsequent phenomenology. We argue that the problem comes from the portions of loop integrals corresponding to propagation at such short distances that the effective theory is not valid. One can reformulate the theory equally rigorously by regulating the loop integrals using a momentum-space cutoff which removes the spurious short-distance physics. We show that this reformulation improves the phenomenology for reasonable values of the cutoff.

A Messy, But Instructive, Case Study In Design Of Experiments, Leroy A. Franklin, Belva J. Cooley, Gary Elrod

Mathematical Sciences Technical Reports (MSTR)

A company manufacturing fans wished to conduct an experimental design to determine the best combination of three factors affecting the breaking torque of the fans. Analysis of the data ceased to be straightforward when the authors found that the data failed the test for homogeneity of variances. After unsuccessfully attempting to transform the data and thereby meet the assumptions necessary to carry on the analysis, the authors relied upon a graphical analysis and a careful study of the means for each design point. This paper describes a statistically sound but novel strategy used to complete the analysis.

A Zero Point And Accidental Errors For Published Values Of [Fe/H] For Cool Giants, B. J. Taylor

Faculty Publications

This paper is one of a series based on published values of [Fe/H] for late-type evolved stars. Only values of [Fe/H] from high-dispersion spectroscopy or related techniques are used. The narrative in this paper begins at a point where mean values of [Fe/H] have been derived for xiVir, alphaBoo, betaGem, and the Hyades giants. By using these stars as standard stars when necessary, a zero-point data base is assembled. This data base is then expanded into its final version by correcting and adding additional data in a step-by-step process. As that process proceeds, data comparisons are used to establish rms …

Construction Of Some Combinatorial Designs Arising Out Of Statistical Experiments., Tridib Kumar Dutta Dr.

Doctoral Theses

Chis dissertation considers construction of two kinds of combi natorial sesigns as used by statisticians: repeated measurements designs (RMDS) and symmetric balanced squares (SBSS). 1.1. REPEATED MEASUREMENTS DESIGNS The researchers need to perform experiments where each experimental unit receives some or all of the treatments in an appropriate sequence over a number of successive periods. These designs are known by several names in the statistical 1iterature: repeated measurements designs, crossover or changeover designs, (multiple) time series designs, and before-after designs. If there are n experimental units 1,2, ... n, t treatments and p periods 0,1, .. .p-1, applied, then an …

Certalert: Grasses Attractive To Hazardous Wildlife

Other Bird Strike and Aviation Materials

Recently, several reports have been received of airport owners or airport contractors planting disturbed areas (construction sites, re-grading projects, etc) with seed mixtures containing brown-top millet. All millets are a major attractant to doves and other seed eating birds.

An Analysis Of Temperature Dependent Photoluminescence Line Shapes In Ingan, John S. Colton, K. L. Teo, P. Y. Yu, E. R. Weber, M. F. Li, W. Lui, K. Uchida, H. Tokunaga, N. Akutsu, K. Matsumoto

Faculty Publications

Photoluminescence (PL) line shapes in InGaN multiple quantum well structures have been studied experimentally and theoretically between 10 and 300 K. The higher temperature PL spectra can be fitted qualitatively with a thermalized carrier distribution and a broadened joint-density-of-states. The low temperature PL line shapes suggest that carriers are not thermalized, as a result of localization by band-gap fluctuations. We deduce a localization energy of ~7 meV as compared with an activation energy of ~63 meV from thermal quenching of the PL intensity. We thus conclude that this activation energy and the band-gap fluctuation most likely have different origins.

Near-Infrared Galaxy Counts To J And K ∼ 24 As A Function Of Image Size, Matthew A. Bershady, James D. Lowenthal, David C. Koo

Astronomy: Faculty Publications

We have used the Keck 10 m telescope to count objects as a function of image size in two high Galactic latitude Ðelds covering 1.5 arcmin2 and reaching 50% completeness depths of K \ 24 and J \ 24.5 for stellar sources. Our counts extend D1 mag deeper in K than those of surveys with other telescopes; complement other Keck surveys in the K-band that provide counts at comparable or shallower depths but that have not utilized image structure; and extend by several magnitudes the J-band counts from brighter surveys using smaller telescopes that cover larger areas. We Ðnd the …

Comparison Between Dc-8 And Er-2 Species Measurements In The Tropical Middle Troposphere: No, NoY, O3, Co2, Ch4, And N2O, A. J. Weinheimer, D. D. Montzka, T. L. Campos, J. G. Walega, B. A. Ridley, Stephen G. Donnelly Ph.D., E. R. Keim, L. A. Del Negro, M. H. Proffitt, J. J. Margitan, K. A. Boering, A. E. Andrews, B. C. Daube, S. C. Wofsy, B. E. Anderson, J. E. Collins, G. W. Sachse, S. A. Vay, J. W. Elkins, P. R. Wamsley, E. L. Atlas, F. Flocke, S. Schauffler, C. R. Webster, R. D. May, M. Loewenstein, J. R. Podolske, T. P. Bui, K. R. Chan, S. W. Bowen, M. R. Schoeberl, L. R. Lait

Chemistry Faculty Publications

We compare measurements of six species taken aboard NASA DC-8 and ER-2 aircraft during two flight legs in the tropical middle troposphere near Hawaii. NO, NOy, O3, CH4, and N2O measurements agree to within the limits set by the known systematic errors. For CO2, which can be measured with better relative precision than the other five species, differences in measured values from the two platforms are slightly larger than expected if the air masses sampled by the two aircraft were indeed similar in CO2 composition to better than 0.08%. Copyright 1998 by the American Geophysical Union.

Monte Carlo Renormalization Of 2d Simplicial Quantum Gravity Coupled To Gaussian Matter, Simon Catterall, Eric B. Gregory, G. Thorleifsson

Physics - All Scholarship

We extend a recently proposed real-space renormalization group scheme for dynamical triangulations to situations where the lattice is coupled to continuous scalar fields. Using Monte Carlo simulations in combination with a linear, stochastic blocking scheme for the scalar fields we are able to determine the leading eigenvalues of the stability matrix with good accuracy both for c = 1 and c = 10 theories.

Ua12/2/1 College Heights Herald, Vol. 74, No. 7, Wku Student Affairs

WKU Archives Records

WKU campus newspaper reporting campus, athletic and Bowling Green, Kentucky news. This issue contains articles:

• Harper, Molly. General Education Requirements May Toughen
• Lanter, Charlie. Staff Left in Dark by Staff Advisory Council Committee
• Goddard, Holly. Reclaiming the Night – Sexual Assault
• Goetz, Kristina. Dropping Masks, Women Reveal Pain, Strength – Sexual Assault
• Karen, Mattias. Intramural Field Opens After 5-Year Delay
• Standing Up Takes Courage – Diddle Arena
• Tabor, Chris. Editorial Cartoon: Big Red Pointing Way to Alumni Seating
• Durbin, Derek. U.S. Policy Invites Terrorism
• Ward, Teresa. Column on Grammar Mistakes Had Some Errors
• Chooljian, Cheryl. Hunting: Alternative to TV?
• Whitt, …

New Analytical Results On Anisotropic Membranes, Mark Bowick, Alex Travesset

Physics - All Scholarship

We report on recent progress in understanding the tubular phase of self-avoiding anisotropic membranes. After an introduction to the problem, we sketch the renormalization group arguments and symmetry considerations that lead us to the most plausible fixed point structure of the model. We then employ an epsilon-expansion about the upper critical dimension to extrapolate to the physical interesting 3-dimensional case. The results are $\nu=0.62$ for the Flory exponent and $\zeta=0.80$ for the roughness exponent. Finally we comment on the importance that numerical tests may have to test these predictions.

Dynamics Of The Conformal Mode And Simplicial Gravity, Simon Catterall, Emil Mottola, T. Bhattacharya

Physics - All Scholarship

We review the derivation of the Liouville action in 2DQG via the trace anomaly and emphasize how a similar approach can be used to derive an effective action describing the long wavelength dynamics of the conformal factor in 4D. In 2D we describe how to make an explicit connection between dynamical triangulations and this continuum theory, and present results which confirm the equivalance of the two approaches. By reconstructing a lattice conformal mode from DT simulations it should be possible to test this equivalence in 4D also.

Anisotropic Membranes, Simon Catterall, Mark Bowick, Simeon Warner, Gudmar Thorleifsson, Marco Falcioni

Physics - All Scholarship

We describe the statistical behavior of anisotropic crystalline membranes. In particular we give the phase diagram and critical exponents for phantom membranes and discuss the generalization to self-avoiding membranes.

Electron Transfer Catalysis Of The Hydrogenolysis Of Acyl Dicarbonyl Cyclopentadienyliron Complexes By Tributyltin Hydride, Christian Amatore, Mekki Bayachou, Olivier Buriez, Jean Noel Verpeaux

Chemistry Faculty Publications

The conversion of acyl dicarbonyl cyclopentadienyliron compounds Cp(CO)2Fe(COR) into aldehydes is not straightforward. It is shown here, mainly from electrochemical results, that the hydrogenolysis of the metal acyl bond can be efficiently achieved by trialkytin hydrides under very mild conditions, according to a chain reaction process initiated by an electron transfer to the acyl complex. The expected aldehyde is formed together with the heterobinuclear iron-tin complex.

Chemical Signals From Submarine Fluid Advection Onto The Continental Shelf, W. S. Moore, Timothy J. Shaw

Faculty Publications

No abstract provided.

Wave-Vector-Dependent Exchange Splitting In A Local Moment System, C. Waldfried, T. Mcavoy, D. Welipitiya, Takashi Komesu, Peter A. Dowben, Elio Vescovo

Peter Dowben Publications

Wave-vector-dependent exchange splitting in a local moment system The electronic structure of strained thin films of Gd has been studied with spin- and angle-resolved photoemission and spin-polarized inverse photoemission. The spin-dependent electronic structure is dominated by a very distinct k dependence of the exchange splitting. The surface magnetic structure is observed to be different from that of the bulk, as indicated by the different electronic structure and a much higher surface Curie temperature. The 4% strain within the Gd films results in an enhanced Curie temperature.

Simultaneous Formation Of Functional Leading And Lagging Strand Holoenzyme Complexes On A Small, Defined Dna Substrate, Anthony J. Berdis, Stephen J. Benkovic

Chemistry Faculty Publications

The biochemical characterization of leading and lagging strand DNA synthesis by bacteriophage T4 replication proteins has been addressed utilizing a small, defined primer/template. The ATP hydrolysis activity of 44/62, the clamp loading complex responsible for holoenzyme assembly, was monitored during assembly of both the leading and lagging strand holoenzyme complex. The ATPase activity of 44/62 diminishes once a functional holoenzyme is assembled on both the leading and lagging strand. The assembly of the lagging strand holoenzyme is facilitated by several factors including biotinylated streptavidin blocks at the end of the fork strands, preassembly of the leading strand holoenzyme, and by …

Catalogs Of Temperatures And [Fe/H] Averages For Evolved G And K Stars, B. J. Taylor

Faculty Publications

A catalog of mean values of [Fe/H] for evolved G and K stars is described. The zero point for the catalog entries has been established by using differential analyses. Literature sources for those entries are included in the catalog. The mean values are given with rms errors and numbers of degrees of freedom, and a simple example of the use of these statistical data is given. For a number of the stars with entries in the catalog, temperatures have been determined. A separate catalog containing those data is briefly described.

Comment On A Critique Of The Instantaneous Normal Mode (Inm) Approach To Diffusion, T. Keyes, Wu Xiong Li, Ulrich Zurcher

Physics Faculty Publications

A critique of the instantaneous normal mode (INM) theory of diffusion by Gezelter, Rabani, and Berne (GRB) [J. Chem. Phys. 107, 4618 (1997)] is analyzed. GRB assert that imaginary-frequency INM are corrupted with modes unrelated to barrier crossing, that proposals for removing such nondiffusive (ND) modes are inadequate, and thus that INM cannot be used to predict the self-diffusion constant, D. In rebuttal it is argued that Lennard-Jones, the system studied by GRB, is anamolously rich in ND modes. INM in molecular liquids are shown to behave as excellent indicators of barrier crossing. Even in LJ ND-INM, while plentiful, do …