Physical Sciences and Mathematics Commons^™

Cross-Linking Of Polystyrene By Friedel–Crafts Chemistry To Improve Thermal Stability, Zhitao Wang, David D. Jiang, Michael A. Mckinney, Charles Wilkie

Chemistry Faculty Research and Publications

Copolymers which contain either alcohol or chloride functionalized polystyrene units have been prepared and they participate in Friedel–Crafts chemistry to give cross-linked polymers by the evolution of either hydrogen chloride or water. Proof of cross-linking comes from the identification of the evolved gas, the insolubility of the product, and the thermal resistance of the newly formed polymer. The onset temperature for the degradation is raised by about 100°C relative to that of polystyrene and the fraction which is not volatile at 800°C ranges from 10% for the alcohol copolymers to 20% for the chloride copolymers.

Detection Of Gradual Transitions Through Temporal Slice Analysis, Chong-Wah Ngo, T. C. Pong, R. T. Chin

Research Collection School Of Computing and Information Systems

In this paper, we present approaches for detecting camera cuts, wipes and dissolves based on the analysis of spatio-temporal slices obtained from videos. These slices are composed of spatial ly and temporal ly coherent regions which can be perceived as shots. In the proposed methods, camera breaks are located by performing color-texture segmentation and statistical analysis on these video slices. In addition to detecting camera breaks, our methods can classify the detected breaks as camera cuts, wipes and dissolves in an efficient manner

Evolving Compact Decision Rule Sets, Robert E. Marmelstein

Theses and Dissertations

While data mining technology holds the promise of automatically extracting useful patterns (such as decision rules) from data, this potential has yet to be realized. One of the major technical impediments is that the current generation of data mining tools produce decision rule sets that are very accurate, but extremely complex and difficult to interpret. As a result, there is a clear need for methods that yield decision rule sets that are both accurate and compact. The development of the Genetic Rule and Classifier Construction Environment (GRaCCE) is proposed as an alternative to existing decision rule induction (DRI) algorithms. GRaCCE …

Multiobjective Evolutionary Algorithms: Classifications, Analyses, And New Innovations, David A. Van Veldhuizen

Theses and Dissertations

This research organizes, presents, and analyzes contemporary Multiobjective Evolutionary Algorithm (MOEA) research and associated Multiobjective Optimization Problems (MOPs). Using a consistent MOEA terminology and notation, each cited MOEAs' key factors are presented in tabular form for ease of MOEA identification and selection. A detailed quantitative and qualitative MOEA analysis is presented, providing a basis for conclusions about various MOEA-related issues. The traditional notion of building blocks is extended to the MOP domain in an effort to develop more effective and efficient MOEAs. Additionally, the MOEA community's limited test suites contain various functions whose origins and rationale for use are often …

Cobol Reengineering Using The Parameter Based Object Identification (Pboi) Methodology, Sonia De Jesus Rodrigues

Theses and Dissertations

This research focuses on how to reengineer Cobol legacy systems into object oriented systems using Sward's Parameter Based Object Identification (PBOI) methodology. The method is based on relating categories of imperative subprograms to classes written in object oriented language based on how parameters are handled and shared among them. The input language of PBOI is a canonical form called the generic imperative model (GIM), which is an abstract syntax tree (AST) representation of a simple imperative programming language. The output is another AST, the generic object model (GOM), a generic object oriented language. Conventional languages must be translated into the …

Model Predictive Satisficing Fuzzy Logic Control, Richard L. Frost, Michael A. Goodrich, Wynn C. Stirling

Faculty Publications

Model-predictive control, which is an alternative to conventional optimal control, provides controller solutions to many constrained and nonlinear control problems. However, even when a good model is available, it may be necessary for an expert to specify the relationship between local model predictions and global system performance. We present a satisficing fuzzy logic controller that is based on a receding control horizon, but which employs a fuzzy description of system consequences via model predictions. This controller considers the gains and losses associated with each control action, is compatible with robust design objectives, and permits flexible defuzzifier design. We demonstrate the …

Implementation Of A Two-Dimensional Hydrodynamic Shock Code Based Upon The Weighted Average Flux Method, Mark P. Wittig

Theses and Dissertations

Numerical modeling of shock propagation and reflection is of interest to the Department of Defense (DoD). Propriety state-of-the-art codes based upon E. F. Toro's weighted average flux (WAF) method are being used to investigate complex shock reflection phenomena. Here we develop, test, and validate a one-dimensional hydrodynamic shock code. We apply WAF to Gudonov's first-order upwind method to achieve second-order accuracy. Oscillations, typical of second-order methods, are then removed using adaptive weight limiter functions based upon total variation diminishing (TVD) flux limiters. An adaptive Riemann solver routine is also implemented to improve computational efficiency. This one-dimensional code is then extended …

On The Geometries Of Conic Section Representation Of Noisy Object Boundaries, Qiuming Zhu

Computer Science Faculty Publications

This paper studies some geometrical properties of conic sections and the utilization of these properties for the generation of conic section representations of object boundaries in digital images. Several geometrical features of the conic sections, such as the chord, the characteristic point, the guiding triangles, and their appearances under the tessellation and noise corruption of the digital images are discussed. The study leads to a noniterative algorithm that takes advantage of these features in the process of formulating the conic section parameters and generating the approximations of object boundaries from the given sequences of edge pixels in the images. The …

Photochemistry And Pinhole Photography: An Interdisciplinary Experiment, Angeliki A. Rigos, Kevin Salemme

Visual & Performing Arts Faculty Publications

This interdisciplinary activity combines chemistry and art through the construction and use of a pinhole camera. We focused on the chemistry of the black and white photographic process as the science component of this activity. The reactions involved are good examples of photochemistry and multiphase chemical reactions, since the light sensitive materials (silver halides) are in the form of a gelatin emulsion of microscopic crystals.

Spectroscopic And Kinetic Investigation Of Carbocation Reactivity In Supercritical Carbon Dioxide, Hongshu Jin

Masters Theses

Recent interest in the use of supercritical CO₂ as an environmentally benign reaction medium has included the development of solvent systems that may support polar and ionic chemistry. Carbocations are key intermediate in a variety of synthetically important reactions and characterization of their reactivity is the focus of this work. UV-visible absorption, and steady-state and time-resolved fluorescence spectroscopy has been used to identify and monitor the reaction kinetics of 9- phenylxanthenium carbocation. The arylcarbocation is conveniently generated from 9- phenylxanthen-9-ol in supercritical CO₂ under mildly acidic conditions. Under these conditions 9-phenylxanthenium ion is extremely stable and persists for …

Multiple Isotopic Studies Of Calcium Carbonate Growths In Concrete Structures, Danielle M. Schmitt

Masters Theses

Secondary minerals, predominantly carbonates, forming under concrete structures have received attention in terms of their possible role in the degradation of their hosts. δ¹³C and δ¹⁸O analyses of several calcium carbonate growths collected from bridges in Michigan and New York were performed. The δ¹³C and δ¹⁸O values clustered around -24.7 ± 1(PDB) and 13.7 ± 1(SMOW) ‰, respectively. A positive δ¹⁸O- δ¹³C correlation suggests kinetically driven precipitation involving atmospheric CO2• ¹⁴C activities determined for select samples support the theory that atmospheric CO₂ is involved …

The Weierstrass–Enneper System For Constant Mean Curvature Surfaces And The Completely Integrable Sigma Model, Paul Bracken, A. M. Grundland, L. Martina

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

The integrability of a system which describes constant mean curvature surfaces by means of the adapted Weierstrass–Enneper inducing formula is studied. This is carried out by using a specific transformation which reduces the initial system to the completely integrable two-dimensional Euclidean nonlinear sigma model. Through the use of the apparatus of differential forms and Cartan theory of systems in involution, it is demonstrated that the general analytic solutions of both systems possess the same degree of freedom. Furthermore, a new linear spectral problem equivalent to the initial Weierstrass–Enneper system is derived via the method of differential constraints. A new procedure …

Camera Break Detection By Partitioning Of 2d Spatio-Temporal Images In Mpeg Domain, Chong-Wah Ngo

Research Collection School Of Computing and Information Systems

In this paper, we propose a new approach to detect camera cuts and wipes. The approach projects a video into two images representing the spatio-temporal continuity of a video life. Visually, these images are composed by regions of different patterns, each region represents the temporal location of a shot. The shape of a region boundary inherently classifies cut and wipe, and most importantly, marks the start and end of a wipe sequence. We hence formulate algorithms to locate the color and texture discontinuities occurring at the boundaries of image regions.

An Environment For The Facilitation Of Robotic Programming, Artem Lifschitz

Computer Science Technical Reports

I have developed, tested, and evaluated a robot programming environment organized as a library of flexible data structures to facilitate the creation of robotics programs. Abstractions are the basis of all of the achievements of Computer Science, and if it were possible to create a truly flexible, generic abstraction for the programming of robots -- the science of robotics could advance at a faster pace. For this reason, I have attempted to implement the abstraction of low-level commands, and the assembling of them into hierarchies of higher-level actions. My libraries provide mechanisms for the manipulation and queuing of actions, as …

Reference Materials For Calorimetry And Differential Thermal Analysis, R. Sabbah, An Xu-Wu, J.S. Chickos, M.L.Planas Leitão, M.V. Roux, L.A. Torres

James Chickos

No abstract provided.

Cadmium, Chromium And Lead In Environmental Samples : Speciation And Determination, Hsing-Hui Yu

Dissertations

Heavy metals are important contaminants in many environmental media. This work focuses on the improvement of current methods for water and sediment analysis for three metals, cadmium, chromium and lead. Batch ion exchange was used for water speciation and a microwave assisted sequential extraction scheme was developed for sediment characterization. The developed methods were applied to a group of environmental samples.

The exchangeable species of these metals in water were preconcentrated on ion exchange resins. These include the bioavailable free ions and weakly complexed ions. Metals sorbed on particles and strongly complexed ions, less bioavailable, were eliminated. The method was …

Applications Of A Microtrap For On-Line Monitoring Of Volatile Organics, Chaohua Feng

Dissertations

Microtrap is made by packing a narrow metal tubing with adsorbents. The advantage of a microtrap is that it can be heated and cooled in the order of seconds. It has been used previously as a concentration cum injection device for on-line gas chromatography and also monitoring non-methane organic carbon in air emissions. In this research breakthrough and desorption characteristics of the microtrap were studied. A two-stage microtrap system was developed to reduce breakthrough while making sharp injection for GC separation. Microtrap was also used as a concentrator cum injector in on-line mass spectrometry. Finally, a microtrap based, continuous non-methane …

Development Of Membrane Extraction Systems For Measuring Trace Level Organic Compounds In Water, Xuemei Guo

Dissertations

The presence of volatile organic compounds (VOCs) in ground and surface water resources poses a threat to public health. The measurement of these trace level contaminants in water is of significant importance. Conventional methods for analysis of trace volatile organic compounds in water include purge and trap, head space analysis, and solid phase microextraction (SPME). While these are excellent laboratory techniques, none of them can be used for continuous, on-line monitoring of water streams. Membrane separation of organic compounds from water provides an exciting possibility for on-line extraction and analysis. In previous investigations, water continuously flowed on the feed side …

Developing Techniques For Enhancing Comprehensibility Of Controlled Medical Terminologies, Huanying Gu

Dissertations

A controlled medical terminology (CMT) is a collection of concepts (or terms) that are used in the medical domain. Typically, a CMT also contains attributes of those concepts and/or relationships between those concepts. Electronic CMTs are extremely useful and important for communication between and integration of independent information systems in healthcare, because data in this area is highly fragmented. A single query in this area might involve several databases, e.g., a clinical database, a pharmacy database, a radiology database, and a lab test database.

Unfortunately, the extensive sizes of CMTs, often containing tens of thousands of concepts and hundreds of …

Porting The Sisal Functional Language To Distributed-Memory Multiprocessors, Jui-Yuan Ku

Dissertations

Parallel computing is becoming increasingly ubiquitous in recent years. The sizes of application problems continuously increase for solving real-world problems. Distributed-memory multiprocessors have been regarded as a viable architecture of scalable and economical design for building large scale parallel machines. While these parallel machines can provide computational capabilities, programming such large-scale machines is often very difficult due to many practical issues including parallelization, data distribution, workload distribution, and remote memory latency.

This thesis proposes to solve the programmability and performance issues of distributed-memory machines using the Sisal functional language. The programs written in Sisal will be automatically parallelized, scheduled and …

Flame Dynamics In Steady Strained Flows, Zili Huang

Dissertations

In this dissertation, the response of a premixed flame to time-dependent strained flow fields is investigated. Because of the potential application to turbulent combustion modeling, the main focus is on the particular case of a flame in stagnation point flow with an imposed oscillatory strain rate. The flame is modeled as a hydrodynamic discontinuity separating burned from unburned gasses. To complete the formulation of the problem, conditions relating the fluid variables across the flame front are needed, as is a flame speed equation that determines the evolution of the discontinuity. These conditions are derived through asymptotic analysis of the flame …

Dynamical Systems Associated With Particle Flow Models : Theory And Numerical Methods, Roman V. Samulyak

Dissertations

A new class of integro - partial differential equation models is derived for the prediction of granular flow dynamics. These models are obtained using a novel limiting averaging method (inspired by techniques employed in the derivation of infinite-dimensional dynamical systems models) on the Newtonian equations of motion of a many-particle system incorporating widely used inelastic particle-particle force formulas. By using Taylor series expansions, these models can be approximated by a system of partial differential equations of the Navier-Stokes type. Solutions of the new models for granular flows down inclined planes and in vibrating beds are compared with known experimental and …

Automatic Document Classification And Extraction System (Adoces), Xuhong Li

Dissertations

Document processing is a critical element of office automation. Document image processing begins from the Optical Character Recognition (OCR) phase with complex processing for document classification and extraction. Document classification is a process that classifies an incoming document into a particular predefined document type. Document extraction is a process that extracts information pertinent to the users from the content of a document and assigns the information as the values of the “logical structure” of the document type. Therefore, after document classification and extraction, a paper document will be represented in its digital form instead of its original image file format, …

Knowledge Management For Texpros, Jianshun Hu

Dissertations

Most of the document processing systems today have applied Al technologies to support their system intelligent behaviors. For the application of Al technologies in such systems, the core problem is how to represent and manage different kinds of knowledge to support their inference engine components' functionalities. In other words, knowledge management has become a critical issue in the document processing systems. In this dissertation, within the scope of the TEXt PROcessing System (TEXPROS), we identify knowledge of various kinds that are applicable in the system. We investigate several problems of managing this knowledge and then develop a knowledge base for …

Pattern Discovery In Trees : Algorithms And Applications To Document And Scientific Data Management, Chia-Yo Chang

Dissertations

Ordered, labeled trees are trees in which each node has a label and the left-to-right order of its children (if it has any) is fixed. Such trees have many applications in vision, pattern recognition, molecular biology and natural language processing.

In this dissertation we present algorithms for finding patterns in the ordered labeled trees. Specifically we study the largest approximately common substructure (LACS) problem for such trees. We consider a substructure of a tree T to be a connected subgraph of T. Given two trees T₁, T₂ and an integer d, the LACS problem is to find …

A New-Generation Class Of Parallel Architectures And Their Performance Evaluation, Qian Wang

Dissertations

The development of computers with hundreds or thousands of processors and capability for very high performance is absolutely essential for many computation problems, such as weather modeling, fluid dynamics, and aerodynamics. Several interconnection networks have been proposed for parallel computers. Nevertheless, the majority of them are plagued by rather poor topological properties that result in large memory latencies for DSM (Distributed Shared-Memory) computers. On the other hand, scalable networks with very good topological properties are often impossible to build because of their prohibitively high VLSI (e.g., wiring) complexity. Such a network is the generalized hypercube (GH). The GH supports full-connectivity …

Modeling Controlled Vocabularies Using Oodbs And Multilevel Area Diagrams, Li-Min Liu

Dissertations

A Controlled Vocabulary (CV) is a software system of domain knowledge that consolidates and unifies the terminology of a large application domain. With a common, centralized CV, costly and time-consuming translations can be eliminated between pairs of organizations and pairs of software systems. Unfortunately, the more knowledge we put into a CV, the harder it is to understand and maintain it. In this dissertation, a comprehensive theoretical methodology for modeling CVs using Object-Oriented Database (OODB) technology is presented. We present two methods for representing a semantic network CV as an equivalent OODB, which we call an Object-Oriented Vocabulary Repository (OOVR). …

Recasting Cohn's Many Sorted Logic Into A Constrained Logic, Christopher Brendan Koelbl

Theses

The use of a many sorted logic for theorem proving carries many advantages over a traditional unsorted logic. By placing restrictions on the search space, a many sorted logic can significantly reduce the amount steps in the resolution process. However, as a logic becomes more efficient, it increases in complexity.

One of these efficient log ics is Cohn's Many Sorted Logic, LLAMA. It uses complex data structures such as the sort lattice and sort arrays to maintain information about the sorts. Recasting LLAMA into Bürckert's constrained logic will keep the functionality of LLAMA while using a format that reduces the …

Catalyctic Reduction Of Nitric Oxide By Copper Catalyzed Granular Activated Carbon In The Presence Of Oxygen, Shan Xiao

Theses

The catalytic reduction of nitric oxides by solid carbonaceous material consisting primarily of granular activated carbon or (GAC) was studied in a fix bed catalytic reactor in order to develop the technology for removing NO and soot simultaneously from diesel engine exhaust. The catalytic activity and conversion of NO as a function of reaction temperature was evaluated as a function of space velocity. The results show that at lean condition and high gaseous hourly space velocity, vis., 50,000 ~ 80,000, Cu-ZSM-5 does not perform as well with CO and GAC as it does with gaseous hydrocarbons(HC). Plain GAC has low …

Decision Support System For Forecasting Product And Waste Disposal Over Time, Amit P. Amte

Theses

A current barrier to the end-of-life product strategies is a lack of knowledge of the quantity and timing of product returns or waste generation. Consequently, a Decision Support System (DSS), to predict the timing and quantity of waste generation is needed. Therefore a web-based system that predicts the rate of product entering the waste-stream has been developed. The system accepts information relating to sales, reliability, storage and disposal behavior. This data is used to simulate the return waste flow. The DSS can be used to simulate the effect of different policies and to provide data for end-of-life and multi-lifecycle strategy …