Physical Sciences and Mathematics Commons^™

Study Of Electrochemistry Of Aloe-Emodin And Determination Of It With 1.5th Order Derivative Anodic Stripping Voltammetry, Xin Hua Lin, Li Ying Huang, Wei Chen, Hong-Bin Luo, Bin Qiu, Chun-Yan Li

Journal of Electrochemistry

In 0.1 mol/L HAc solution(pH=2.89),the voltammetric behaviours of aloe emodin at a glassy carbon electode has been studied. One pair of current peak of the voltammogram may be attributed to a quasireversible two electron transfer of aloe emodin molecules at the glassy carbon electrode. A new method, the derivative anodic stripping voltammetry, for aloe emodin determination is described. The adsorptive potential of aloe emodin is -0.80V(vs. SCE),while its stripping potential is -0.38V(vs.SCE). The peak current is propotional to the concentration of aloe emodin over the range of 2.0×10 -7 ～8.0×10 -6 mol/L. The method is simple, rapid and reliable for …

Analyses On Spm Images And Theoretical Investigations On Oxygen Vacancy Concentration Of Light-Induced Nanostructured Titania Super Hydrophilic Films, Ren-Jie Zeng, Zhong-Hua Lin, Zhi-Min Fang

Journal of Electrochemistry

A typical nanostructured titania super hydrophilic film was chosen for general characterization employing a Scanning Probe Microscope(SPM)and an electrochemical measurement system.Following from the principles of the solid state chemistry and nanomechanics,intensive theoretical. analyses on the SPM images,the oxygen vacancy concentrations and the mechanism of the super hydrophilicity were made;further illuminations on a reaction equation of titania defect formation,a tentative universal surface physical mode for the wet ability,a concept,amphiphobicity,and surface design were carried out after the author's previous introduction and proposal in the end of 1999.

The Investigation Of Prepare Condition For Micropores Membranes From Poly(Vinylidene Fluoride), Xu-Mei Ren, Feng Wu, Ying Bai, Hang-Jun Li, Xue Jie Huang

Journal of Electrochemistry

The micropores membranes from Poly (vinylidene fluoride) were prepared by the phase inversion process. The effects of the casting solution composition, exposure time prior to coagulation and temperature of the coagulation bath on properties of prepared membranes were investigated. For all prepared membranes an asymmetric structure, sometimes without a dense skin layer, was observed.

Studies On The Properties Of The Anodic Films Formed On Lead- Lanthanum And Lead-Samarium Alloys In Sulfuric Acid Solution, Hou Tian Liu, Chun Xuao Yang, Hai Heng Liang, Jiong Yang, Wei-Fang Zhou

Journal of Electrochemistry

AC voltammetry,linear sweep voltammetry,and cyclic voltammetry were applied to study the anodic corrosion of Pb,Pb 1.0at%La and Pb 1.0at%Sm electrodes in 4.5 mol·dm -3 H 2SO 4 solution (25 ℃).The experiment results show that samarium can inhibit the anodic corrosion of lead and decrease the impedance of anodic Pb(Ⅱ) film. Lanthanum can also decrease the impedance of the anodic Pb(Ⅱ)film, but the effect is smaller.

Adsorption And Oxidation Of Methanol On Pt And Sb, S Modified Pt Electrodes Using Cyclic Voltammetry And Eqcm, Guo-Liang Chen, Sheng-Pei Chen, Heng Lin, Xing-Hong Zheng, Shi-Gang Sun

Journal of Electrochemistry

The processes of adsorption and oxidation of methanol on Pt, Pt/Sb ad and Pt/S ad electrodes were studied by using cyclic voltammetry and electrochemical quartz crystal microba_lance (EQCM). The results demonstrated that the oxidation of methanol depends strongly on oxidation states of electrode surface. Sb adatoms on Pt surface can adsorb oxygen at relatively low potentials, and exhibit catalytic effects for methanol oxidation. In contrast to Pt electrodes, the oxidation peak potential of methanol in this case negatively shifted to about 130 mV. In a contrary, the oxidation of S adatoms consumes oxygen species of Pt electrode surface. As a …

Corrosion Of Steel In Sea-Bottom Mud Of Nothern China Sea Area, Gong-Yu Guo, Jing-Lei Zhang, Bao-Rong Hou, Fang-Ying Yang

Journal of Electrochemistry

Corrosion experiments of A 3, 16Mn, 20 # as well as ZCE36_225 steel were carried out in southern Bohai sea and Qingdao sea areas. The sea_bottom mud in southern Bohai sea area is the sandy mud and that in Qingdao sea area is pure beach sand. In this experiment, the compareing test of two modes with electric connected and non_electric connected modes was carried out. The experiment results showed that: 1) the corrosion rate of steel in sea_bottom mud has a strong relation with mud types. The corrosion rates of steels in pure beach sand are much higher than those …

The Research Of Organic Electrolyte Solutions For Li-Ion Batteries, Quang Chao Zhuang, Shan Wu, Wen Yuan Liu, Zhao-Da Lu

Journal of Electrochemistry

The characteristics of organic electrolyte solutions and its influences on the ion conductivity are summarized. The chemistry and electrochemistry of organic electrolyte solutions and characteristics of ordinary organic solvents are introduced. Progresses in studies of organic electrolyte solutions such as electrolyte salts, organic solvents, additives in recent years are reviewed, current situation of the studies of organic electrolyte solutions were also discussed.

New Progress Of Intrinsic Conducting Polymers' Application, Wan Chen, Cheng-Hao Liang, Yang Xie

Journal of Electrochemistry

As a kind of functional polymer, the intrinsic conducting polymer has the special chemical, electrochemical and optical properties. So it has wide application such as batteries, electromagnetic wave shielding, electroluminescent etc. Recent development and the problems of the intrinsic conducting polymers' application were briefly reviewed in this paper.

Research Progress On Proton Exchange Membranes Of Fuel Cells, Jing-Rong Yu, Dan-Min Xing, Fu-Qiang Liu, Jian-Guo Liu, Bao-Lian Yi

Journal of Electrochemistry

The proton exchange membrane fuel cells(PEMFC) use proton exchange membranes(PEM) as their electrolytes. The performance of the PEMFC is strongly dependent on the characteristics of the PEM. In this paper, the requirements of the PEM utilized in the PEMFC were analyzed. The per_fluorinated, partially fluorinated and non_fluorinated PEM were introduced respectively. The structures, preparation, properties of the various types of PEM and their applications in the PEMFC were also discussed in detail.

Electrosynthesis Of A New Electroactive Poly(2,2'-Diaminophenyloxydisulfide), Yu Zhi Su, Yan Wen Rao, Ye Yang, Mei-Bing Chen, Yin Ling Qiu, Yong-Hua Zhang, Ke Cheng Gong

Journal of Electrochemistry

A new electroactive poly(2,2' diaminophenyloxydisulfide) (PDAPD) was successfully synthesized from acetonitrile(AN)/tetrahydrofuran(THF)solutions containing the supporting electrolyte(LiClO 4)and the various kinds of acids(HCl,CF 3COOH,CCl 3COOH) on Pt electrode by consecutive cyclic voltammiry. The effects of the concentrations of supporting electrolyte(LiClO 4) and acid(HCl,CF 3COOH,CCl 3COOH) on electrodepositon of PDAPD film were investigated. The best experimental conditions for electrosynthesis of a highly electroactive conducting polymer film are that the concentrations are 0.1 mol/L and between 0.05 mol/L～0.5 mol/L,respectively for LiClO 4 and HCl.

On Some Optimal Tests In Finite Mixtures: Constructions And Applications., Chandranath Pal Dr.

Doctoral Theses

Mixtures of distributions are now-a-days playing very important roles in both theoretical and applied statistics. There is an abundance of real-life situations where mixture distributions are being extensively used for modelling data and drawing inference. Several books and monographs on mixtures have so far been published, e.g., Everitt and Hand (1981), Titterington et al. (1985), McLachlan and Basford (1988), McLachlan (1997) etc., which cover a wide area on different aspects of mixture distributions and their applications. The book by Titterington et al. (1985, pp. 16-21), in particular, contains a comprehensive list of references on direct applications of finite mixtures in …

Regional Variations Of Kachina Iconography In Eastern Pueblo Rock Art, Dara Leigh Saville

Geography ETDs

This research addresses the problem of identifying patterns of regional variation in the kachina iconography of the Eastern Pueblo Province. Data produced in this study is also used to reevaluate the Rio Grande Hypothesis, which proposes a Jornada Mogollon origin for Pueblo kachinas. The author examines a sample of kachina images that are present in the rock art of the Rio Grande Valley and Eastern Mountain region of central New Mexico. The sample includes kachinas from the Lyden site on Black Mesa, Frijoles Canyon of Bandelier National Monument, Piedras Marcadas Canyon of Petroglyph National Monument, Cerro Indio at San Acacia, …

High-Precision Dating Of Volcanic Events (A.D. 1301–1995) Using Ice Cores From Law Dome, Antarctica, Anne S. Palmer, Tas D. Van Ommen, Mark A. J. Curran, Vin Morgan, Joe M. Souney, Paul Andrew Mayewski

Earth Science Faculty Scholarship

A record of volcanic activity over the period A.D. 1301–1995 has been extracted from three Law Dome ice cores (East Antarctica). The record dating is unambiguous at the annual level from A.D. 1807 to 1995 and has an uncertainty of ±1 year at A.D. 1301. Signals from 20 eruptions are preserved in the record, including those of two unknown eruptions with acid deposition beginning in A.D. 1810.8 and A.D. 1685.8. The beginning of the ice core signal from the A.D. 1815 Tambora eruption is observed in the austral summer of A.D. 1816/1817. The mean observed stratospheric transport and deposition time …

Precision Measurement Of The Spin-Dependent Asymmetry In The Threshold Region Of 3He (E,E'), F. Xiong, D. Dutta, W. Xu, B. Anderson, L. Auberbach, T. Averett, W. Bertozzi, T. Black, J. Calarco, L. Cardman, G. D. Cates, Z. W. Chai, J. P. Chen, S. Choi, E. Chudakov, S. Churchwell, G. S. Corrado, C. Crawford, D. Dale, A. Deur, P. Djawotho, B. W. Filippone, J. M. Finn, H. Gao, R. Gilman, A. V. Glamazdin, C. Glashausser, W. Glockle, J. Golak, J. Gomez, V. G. Gorbenko, J. O. Hansen, F. W. Hersman, D. W. Higinbotham, R. Holmes, C. R. Howell, E. Hughes, B. Humensky, S. Incerti, C. W. De Jager, J. S. Jensen, X. Jiang, C. E. Jones, M. Jones, R. Kahl, H. Kamada, A. Kievsky, I. Kominis, W. Korsch, K. Kramer, G. Kumbartzki, M. Kuss, Enkeleida K. Lakuriqi, M. Liang, N. Liyanage, J. Lerose, S. Malov, D. J. Margaziotis, J. W. Martin, K. Mccormick, R. D. Mckeown, K. Mcilhany, Z. E. Meziani, R. Michaels, G. W. Miller, E. Pace, T. Pavlin, G. G. Petratos, R. I. Pomatsalyuk, D. Pripstein, D. Prout, R. D. Ransome, Y. Roblin, M. Rvachev, A. Saha, G. Salme, M. Schnee, T. Shin, K. Slifer, P. A. Souder, S. Strauch, R. Suleiman, M. Sutter, B. Tipton, L. Todor, M. Viviani, B. Vlahovic, J. Watson, C. F. Williamson, H. Witala, B. Wojtsekhowski, J. Yeh, P. Zolnierczuk

Enkeleida K. Lakuriqi

We present the first precision measurement of the spin-dependent asymmetry in the threshold region of 3He (e,e') at Q2 values of 0.1 and 0.2(GeV/c)2. The agreement between the data and nonrelativistic Faddeev calculations which include both final-state interactions and meson-exchange current effects is very good at Q2=0.1(GeV/c)2, while a small discrepancy at Q2=0.2(GeV/c)2 is observed.

Tachyonic Instability And Dynamics Of Spontaneous Symmetry Breaking, Gary Felder, Lev Kofman, Andrei Linde

Physics: Faculty Publications

Spontaneous symmetry breaking usually occurs due to the tachyonic (spinodal) instability of a scalar field near the top of its effective potential at φ=0. Naively, one might expect the field φ to fall from the top of the effective potential and then experience a long stage of oscillations with amplitude O(v) near the minimum of the effective potential at φ=v until it gives its energy to particles produced during these oscillations. However, it was recently found that the tachyonic instability rapidly converts most of the potential energy V(0) into the energy of colliding classical waves of the scalar field. This …

Reflection Of A Long-Period Gravity Wave Observed In The Nightglow Over Arecibo On May 8–9, 1989?, Michael P. Hickey Ph.D.

Publications

During the Arecibo Initiative for Dynamics of the Atmosphere (AIDA) campaign in 1989 a characteristic of gravity wave perturbations observed in mesopause region airglow emissions was that airglow brightness fluctuations and airglow-derived temperature fluctuations often occurred either in phase or in antiphase. This stimulated the development of a theory suggesting that such in-phase fluctuations were most probably the result of strong reflections occurring in the mesosphere and lower thermosphere region. Recent examination of a particular wave event and application of simple WKB-type theory has appeared to support this hypothesis. Here we use a full-wave model and a WKB-type model, each …

Land Use Of Riparian Zones In Two Communities In The Palcazu Basin, Central Andean Amazon, Peru, Rosa E. Cossio-Solano

FIU Electronic Theses and Dissertations

The purpose of this study was to compare outcomes in forms of riparian zone land use between a native and a colonist community of the Palcazu basin in Peru. Data were gathered through a survey of 79 settler households and an ethnographic study. The results showed that riparian zones are highly valued for the conservation of fertile lowland soils by both communities. Statistical tests showed that riparian land use practices (including non-riparian land use) in both communities are similar; only significant differences were found in the percentage of protection fringe forested, in the area of riparian zone under use and …

Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials: Aaa Task-4 Quarterly (September 1 – November 30, 2001) Report, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The primary objective of this task is to evaluate the effect of hydrogen on environment-assisted cracking of candidate materials for applications in spallation-neutron-target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). The materials selected for evaluation and characterization are martensitic stainless steels including HT- 9, EP 823 and 422. The susceptibility to stress corrosion cracking (SCC) and hydrogen embrittlement (HE) of these alloys will be evaluated in environments of interest using tensile specimens under constant load and slow-strain-rate (SSR) conditions. The extent and morphology of cracking of these alloys will further be evaluated …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823: Task 10, First Quarter Report, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The objective of this task is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. The test material will be thermally treated prior to evaluation of its tensile properties at temperatures relevant to the transmutation applications. The deformation characteristics of tensile specimens, upon completion of testing, will be evaluated by surface analytical techniques including scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The overall results are expected to provide a mechanistic understanding of high-temperature deformation behavior of Alloy EP-823 as a function of heat treatment.

Highlights of Accomplishment

• …

Fine-Tuning Solution For Hybrid Inflation In Dissipative Chaotic Dynamics, Rudnei O. Ramos

Dartmouth Scholarship

We study the presence of chaotic behavior in phase space in the preinflationary stage of hybrid inflation models. This is closely related to the problem of initial conditions associated with these inflationary types of model. We then show how an expected dissipative dynamics of fields just before the onset of inflation can solve or ease considerably the problem of initial conditions, driving the system naturally toward inflation. The chaotic behavior of the corresponding dynamical system is studied by computation of the fractal dimension of the boundary in phase space separating inflationary from noninflationary trajectories. The fractal dimension for this boundary …

Terahertz Gain In A Sige/Si Quantum Staircase Utilizing The Heavy-Hole Inverted Effective Mass, Richard A. Soref, Greg Sun

Physics Faculty Publications

Modeling and design studies show that a strain-balanced Si_1−xGe_x/Si superlattice onSi_1−yGe_y-buffered Si can be engineered to give an inverted effective mass HH2 subband adjacent to HH1, thereby enabling a 77 K edge-emitting electrically pumped p–i–pquantum staircase laser for THz emission at energies below the 37 meV Ge–Ge optical phonon energy. Analysis of hole-phonon scattering, lifetimes, matrix elements, and hole populations indicates that a gain of 450 cm⁻¹ will be feasible at f = 7.3 THz during 1.7 kA/cm² current injection.

An Optimal Importance Sampling Method For A Transient Markov System, H. Qi, Y. C. Wei, L. Wei

Faculty of Informatics - Papers (Archive)

In this paper an optimal importance sampling (IS) method is derived for a transient markov system. Several propositions are presented. It is showned that the optimal IS method is unique, and it must converge to the standard Monte Carlo (MC) simulation method when the sample path length approaches infinity. Therefore, it is not the size of the state space of the Markov system, but the sample path length, that limits the efficiency of the IS method. Numerical results are presented to support the argument.

Ecotones: The Heartbeat Of Huxley, 2001, Fall, Issue 09, Kate Koch, Huxley College Of The Environment, Western Washington University

Historical Collection of Huxley Newsletters

No abstract provided.

Interactions Of Ultrashort, Ultrahigh Intensity Laser Pulses With Underdense Plasmas, Xiaofang Wang, Wei Yu, Sterling Backus, Margaret Murnane, Henry Kapteyn, Donald P. Umstadter

Donald Umstadter Publications

The interactions of ultraintense laser pulses with underdense plasmas are studied in a new regime in which the longitudinal spatial extent of the pulse duration is close to both the laser focal spot size and the plasma wavelength.

Laser Acceleration Of Protons From Thin Film Targets, K. Flippo, Sudeep Banerjee, V. Yu. Bychenkov, S. Gu, Anatoly Maksimchuk, G. Mourou, K. Nemoto, Donald P. Umstadter

Donald Umstadter Publications

A collimated beam of fast protons, with energies as high as 10 MeV and total number of 10⁹, confined in a cone angle of 40°±10° has been observed when a 10 TW laser with frequencies either ω₀ (corresponding to 1 μm) or 2ω₀ was focused to an intensity of a few times 10¹⁸ W/cm² on the surface of a thin film target. The protons, which originate from impurities on the front side of the target, are accelerated over a region extending into the target and exit out the backside in a direction normal to …

Status Of The Lilac Experiment, N. Saleh, P. Han, C. Keppel, P. Gueye, V Yanovsky, Donald P. Umstadter

Donald Umstadter Publications

We present the status of the LILAC experiment [1], including results on the propagation of 30-fs duration laser pulses in plasmas of the requisite density, and measurements of the dark current [2]. We also discuss the status of a laser upgrade, an electron beam line and plans for the future.

Magnetite Morphology And Life On Mars, Peter R. Buseck, Rafal E. Dunin-Borkowski, Bertrand Devouard, Richard B. Frankel, Martha R. Mccartney, Paul A. Midgley, Mihály Pósfai, Mathew Weyland

Physics

Nanocrystals of magnetite (Fe₃O₄) in a meteorite from Mars provide the strongest, albeit controversial, evidence for the former presence of extraterrestrial life. The morphological and size resemblance of the crystals from meteorite ALH84001 to crystals formed by certain terrestrial bacteria has been used in support of the biological origin of the extraterrestrial minerals. By using tomographic and holographic methods in a transmission electron microscope, we show that the three-dimensional shapes of such nanocrystals can be defined, that the detailed morphologies of individual crystals from three bacterial strains differ, and that none uniquely match those reported from …

Titanium Dioxide Photocatalytic Degradation Of Aliphatic Ethers And Their Primary Oxidation Products, Vivian Cruz

FIU Electronic Theses and Dissertations

Two studies were performed to obtain fundamental mechanistic information on the TiO₂ catalyzed degradation of organic substrates irradiated at 350 nm in dilute aqueous solutions under oxygenated conditions: (a) The photodecomposition of methyl tert-butyl ether (MTBE) and its intermediate products from β - oxidation, 2-methoxy-2-methylpropanol and 2-methoxy-2-methylpropanal. (b) The photodecomposition of two haloethers, bis-(2-chloroethyl) ether, and bis-(2-chloroisopropyl) ether. Controls were carried out throughout the two studies in the absence of light, and without the semiconductor in order to evaluate the role of photolysis.

The syntheses of proposed intermediate products, 2-methoxy-2-methylpropanol, 2-methoxy-2-methylpropanal, 2-methoxy-2-methylpropanoic acid, 2-chloroethyl formate, and 1-chloro-2-propyl acetate, …

Three-Dimensional Spectral Classification Of Low-Metallicity Stars Using Artificial Neural Networks, Shawn Snider, Ted Von Hippel, Et Al.

Publications

We explore the application of artificial neural networks (ANNs) for the estimation of atmospheric parameters (T_eff, log g, and [Fe/H]) for Galactic F- and G-type stars. The ANNs are fed with medium-resolution (Δλ ~ 1-2 Å) non-flux-calibrated spectroscopic observations. From a sample of 279 stars with previous high-resolution determinations of metallicity and a set of (external) estimates of temperature and surface gravity, our ANNs are able to predict T_eff with an accuracy of σ(T_eff) = 135-150 K over the range 4250 ≤ T_eff ≤ 6500 K, log g with an accuracy …

Charged-Particle Multiplicity Pp̅ Collisions At √S = 1.8 Tev, T. Affolder, Kenneth A. Bloom, Collider Detector At Fermilab Collaboration

Kenneth Bloom Publications

We report on a measurement of the mean charged-particle multiplicity of jets in dijet events with dijet masses in the range 80-630 GeV/c², produced at the Tevatron in pp̅ collisions with √s= 1.8 TeV and recorded by the Collider Detector at Fermilab. The data are fit to perturbative-QCD calculations carried out in the framework of the modified leading log approximation and the hypothesis of local parton-hadron duality. The fit yields values for two parameters in that framework: the ratio of parton multiplicities in gluon and quark jets, r=N^g-jet _partons/N^q-jet _partons =1.7 ± …