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2001

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Articles 2731 - 2760 of 3030

Full-Text Articles in Physical Sciences and Mathematics

Identities For The Multiple Polylogarithm Using The Shuffle Operation, Ji Hoon Ryoo Jan 2001

Identities For The Multiple Polylogarithm Using The Shuffle Operation, Ji Hoon Ryoo

Electronic Theses and Dissertations

At the beginning of my research, I understood the shuffle operation and iterated integrals to make a new proof-method (called a combinatorial method). As a first work, I proved an combinatorial identity 2 using a combinatorial method. While proving it, I got four identities and showed that one of them is equal to an analytic identity 1 which is found at the paper [2] written by David M. Bradley and Doug Bowman. Furthermore, I derived an formula involving nested harmonic sums. Using Maple (a mathematical software), I found a new combinatorial identity 3 and derived two formulas: One is related …


An Analysis Of A Radio Frequency Sensor As A Means To Remotely Sense Selected Surface Topographies In An Agriculture Environment, Barry Michael Alexia Jan 2001

An Analysis Of A Radio Frequency Sensor As A Means To Remotely Sense Selected Surface Topographies In An Agriculture Environment, Barry Michael Alexia

Dissertations and Theses @ UNI

Remote sensing is the science and art of obtaining information about an object, area or phenomenon through the analysis of data acquired by a device that is not in contact with the object, area, or phenomenon under investigation. The remotely sensed data can be of many forms, including variations in force distribution, acoustic wave distribution, or electromagnetic energy distribution.Information thus acquired can be used for observing,monitoring, and studying planetary surfaces and environments.

Because there are many ways to acquire data about targets of interest, there are many types of remote sensors that can be used, including visible, infrared, and active …


Field And Polarization Effects Arising In Neutrino-Lepton Processes In A Magnetic Field, V. A. Gusseinov Jan 2001

Field And Polarization Effects Arising In Neutrino-Lepton Processes In A Magnetic Field, V. A. Gusseinov

Turkish Journal of Physics

We discuss the effects arising in the neutrino-lepton processes (\nu_{\mu}+e^{-} \rightarrow \nu_{e}+\mu^{-} and \overline{\nu}_{e}+e^{-}\rightarrow\overline{\nu}_{\mu}+\mu^{-}) in a constant uniform magnetic field in the framework of the Weinberg-Salam-Glashow model. It is shown that in the case of a superstrong magnetic field and for the muon producing on the ground Landau level the leading term of the cross section asymptotics of the \nu_{\mu}-process does not depend on the field intensity and it effectively describes the one-dimensional free process. In the \nu_{\mu}-process the muons with the spins oriented opposite to the direction of the field are mostly produced. The electrons with the spins oriented …


The Resonance Bremsstrahlung Of A Fast Charged Particle In A Medium, Khamidbi M. Beshtoev Jan 2001

The Resonance Bremsstrahlung Of A Fast Charged Particle In A Medium, Khamidbi M. Beshtoev

Turkish Journal of Physics

The bremsstrahlung of a fast charged particle in the medium with dielectric permittivity \epsilon at velocities v \ge \frac{c}{n} (\mbox{Re}\epsilon = n^2) was considered. Bremsstrahlung radiation has singularity at \beta = \frac{1}{n \cos\theta} (\beta = \frac{v}{c}, \theta is an angle of the bremsstrahlung.) and is interpreted as resonance bremsstrahlung with the width characterized by Im\epsilon = \epsilon_2; and smaller \epsilon_2 is, the higher the peak of the resonance. The angle distribution of the bremsstrahlung is determined by \cos \theta = \frac{1}{n\beta} and \theta coincides with the angle of Cherenkov radiation. At \beta = \frac{1}{n} the resonance bremsstrahlung goes in the …


Properties Of Mos Capacitors Produced On Sige Formed By Ge-Implanted Si, M. Şahi̇n, Serhat Özder, Raşi̇t Turan Jan 2001

Properties Of Mos Capacitors Produced On Sige Formed By Ge-Implanted Si, M. Şahi̇n, Serhat Özder, Raşi̇t Turan

Turkish Journal of Physics

Metal-oxide-semiconductor (MOS) capacitors fabricated on Ge-implanted Si have been investigated by using C-V and G-V measurements. The control sample on pure Si substrate yielded normal C-V and G-V characteristics. The Ge-implanted MOS samples exhibited anomalous C-V and G-V behavior. The C-V curves of the samples were strongly frequency dependent both in the accumulation and inversion regions. They shift almost in parallel to higher values with decreasing frequency, reaching the oxide capacitance value in the quasi-static (QS) measurement. A band structure and equivalent circuit model were introduced to explain this and other features of the experimental observations. It is shown that …


Zeros Of Scattering Amplitude For A Spin-Dependent Gaussian Potential, Nilufar Farhat Hossain, Hasna Banu, A. K. Halder Jan 2001

Zeros Of Scattering Amplitude For A Spin-Dependent Gaussian Potential, Nilufar Farhat Hossain, Hasna Banu, A. K. Halder

Turkish Journal of Physics

In the proposed model, polarization in the scattering amplitude for a Gaussian potential including spin is considered. The problem of scattering amplitude is formulated in two different ways: the first and second Born approximations along with their high energy limits and the eikonal approximation including Wallace corrections. A comparison of the numerical zeros of the scattering amplitude computed in the above two approximations is studied in the complex momentum transfer plane. An analysis of the zero trajectories shows that the contribution of the spin part in the potential is quite significant at high energies whereas at low energies the spin-part …


Features Of The Compound Multiplicity Of The Interactions Of ^{24}Mg And ^{28}Si Ions With Emulsion Nuclei At 4.5a Gev/C, N. N. Abd-Allah, M. Mohery Jan 2001

Features Of The Compound Multiplicity Of The Interactions Of ^{24}Mg And ^{28}Si Ions With Emulsion Nuclei At 4.5a Gev/C, N. N. Abd-Allah, M. Mohery

Turkish Journal of Physics

The present paper deals with the interactions of ^{24}Mg and ^{28}Si nuclei at 4.5A GeV/c with emulsion. Some characteristics of the compound multiplicity given by the numerical sum of grey and shower particles have been investigated. The obtained results indicate that the compound multiplicity distribution is consistent with KNO-Scaling and its width increases with the size of the projectile nucleus.The dependence of the average compound multiplicity on the numbers of black and the grey particles and the sum of them is obvious and the values of the slope has been found to be independent of the projectile nucleus.


Effect Of Carrier Concentration Dependant Mobility On The Performance Of High Electron Mobility Transistors, Mustafa Erol Jan 2001

Effect Of Carrier Concentration Dependant Mobility On The Performance Of High Electron Mobility Transistors, Mustafa Erol

Turkish Journal of Physics

The influence of the sheet carrier concentration dependence on mobility on the performance of High Electron Mobility Transistor (HEMT) structures is theoretically modeled. The model basically takes into account both the drift and diffusion part of the overall drain current. The normalised drain current and normalised transconductance are found to be greatly affected by the carrier concentration dependant mobility.


Effect Of Flux Re-Distribution On Resistivity In Granular Ybco, Muhammad Muneeb Asim, Syed Khurshid Hasanain Jan 2001

Effect Of Flux Re-Distribution On Resistivity In Granular Ybco, Muhammad Muneeb Asim, Syed Khurshid Hasanain

Turkish Journal of Physics

Dc resistivity of a zero-field cooled YBCO was previously studied as a function of angle between applied field and transport current. The resistivity followed a sin^{2}\theta variation that was understood as a consequence of Lorentz force like effect. The resistivity deviated from the harmonic curve giving a minimum at low angles before following the true sin^{2}\theta behavior. The angle corresponding to minimum voltage \theta_{min} has been thoroughly studied in this paper as a function of applied field, transport current and temperature. sin^{2}\theta behavior of resistivity is not affected by the fields below Hc1 at their respective temperatures. The angle \theta_{min} …


Viscous Dissipation Of Magnetosonic Waves In Solar Corona, Belinda Kalomeni, D. Özlem Hürkal, E. Rennan Pekünlü, Kadri̇ Yakut Jan 2001

Viscous Dissipation Of Magnetosonic Waves In Solar Corona, Belinda Kalomeni, D. Özlem Hürkal, E. Rennan Pekünlü, Kadri̇ Yakut

Turkish Journal of Physics

Wave propagation and dissipation of magnetosonic waves are considered in an inhomogenous viscous coronal plasma permeated by a spatially varying magnetic field. In the linear magnetohydrodynamic approximation the dispersion relation yields two wave modes, fast and slow respectively. Depending on the physical parameters of the medium the damping length scales of the modes show varying behaviours. Damping length scales of the modes show sudden decrease at relevant heights. These drops may be due to phase mixing and resonance absorption. Wave flux density of the magnetosonic waves turns out to be of the order of 10^6 erg cm^{-2} s^{-1}. This is …


The Temperature Dependence Of Dark Conductivity In Hydrogenated Amorphous Sin_X Films, Hüseyi̇n Tolunay, İlker Ay Jan 2001

The Temperature Dependence Of Dark Conductivity In Hydrogenated Amorphous Sin_X Films, Hüseyi̇n Tolunay, İlker Ay

Turkish Journal of Physics

Thin film samples of hydrogenated amorphous silicon nitride with varying nitrogen content were prepared by conventional plasma deposition from a mixture of SiH_4 and NH_3 . The dark conductivity (\sigma_d) of the films have been measured in the temperature range 420 K - 100 K. The conductivity is thermally activated with a single activation energy down to 250 K and conduction is dominated by electrons in extended states. A strong decrease is observed sigma _d when the nitrogen content is increased.


Exciton Investigations And The Urbach Tails Of Gd Doped And Undoped Gase, Beki̇r Gürbulak Jan 2001

Exciton Investigations And The Urbach Tails Of Gd Doped And Undoped Gase, Beki̇r Gürbulak

Turkish Journal of Physics

Absorption measurements were carried out in GaSe and GaSe:Gd samples in temperature range 10-320 K in steps 10 K. The first and the second (n=1 and n=2) excitonic levels were marked. The first exciton energies for n=1 were calculated as 2.118, 2.008 eV in GaSe, and 2.125, 2.006 eV in GaSe:Gd at 10, 320 K and respectively. The second exciton energies for n=2 were calculated as 2.140, 2.125 eV in GaSe at 10, 80 K and 2.141, 2.120 eV in GaSe:Gd at 10, 120 K and respectively. Binding energies of GaSe and GaSe:Gd were calculated as (29.46\pm 1 and 21.33\pm …


On The Statistical Properties Of A Q-Oscillator, Abdullah Algin Jan 2001

On The Statistical Properties Of A Q-Oscillator, Abdullah Algin

Turkish Journal of Physics

Several statistical properties of the Coon-Baker-Yu (CBY) q-oscillator algebra are discussed. Particular emphasis is given to a careful derivation of second quantized particle statistics obtained via the CBY q-oscillator. It is outlined that, beside other limiting cases, the limit q = 0 of the CBY q-oscillator gives the Cuntz oscillator and the Fock space properties of both of these oscillators lead to various interesting results.


A Theoretical Analysis Of Transverse Mode Control In Waveguide Gas Lasers, Erol Taşal, M. Selami̇ Kiliçkaya Jan 2001

A Theoretical Analysis Of Transverse Mode Control In Waveguide Gas Lasers, Erol Taşal, M. Selami̇ Kiliçkaya

Turkish Journal of Physics

Theoretical of multiple transverse mode laser oscillation involving spatially varying gain and loss are investigated. The effect of gain and loss distribution on mode competition is analyzed. A theoretical analysis of laser transverse mode competition is investigated from the perspective of the spetial overlap of modes with a transverse gain-loss distribution. The dominant mode of laser oscillation is the mode that is stable under small perturbations.


Impurity Conductivity In Semiconductors Resulting From Radiant Excitation, Vakhab T. Toulanov, Aziza Sh. Davletova, Lesbek T. Tashimov, Kamila A. Ortaeva Jan 2001

Impurity Conductivity In Semiconductors Resulting From Radiant Excitation, Vakhab T. Toulanov, Aziza Sh. Davletova, Lesbek T. Tashimov, Kamila A. Ortaeva

Turkish Journal of Physics

This paper deals with the derivation of common formulae for induced impurity photosensibility with an arbitrary set of energy levels in the semiconductor gap. We give the expression for the real recombinational situation with two types of impurity levels as well. The basic properties and certain common peculiarities concerning induced photoconductivity in semiconductors are under consideration.


Electron Impact Double Ionization Of Helium From [E, (3-1)E] Experiments}, Mevlut Dogan Jan 2001

Electron Impact Double Ionization Of Helium From [E, (3-1)E] Experiments}, Mevlut Dogan

Turkish Journal of Physics

Electron impact double ionization of helium has been observed in an [e,(3-1)e] experiment at an incident electron energy of 200 eV. 110 eV scattered and 10 eV ejected electrons are observed in coincidence without detection of the second ejected electron (1 eV). Present and previous observations are discussed.


Optical Absorption And Photoluminescence Measurements In Inp And Inp:Fe Bulk Crystals And Inspection Of The Relations Between These Measurements, Seydi̇ Doğan, Sebahatti̇n Tüzemen, Beki̇r Gürbulak, Aytunç Ateş, Muhammet Yildirim Jan 2001

Optical Absorption And Photoluminescence Measurements In Inp And Inp:Fe Bulk Crystals And Inspection Of The Relations Between These Measurements, Seydi̇ Doğan, Sebahatti̇n Tüzemen, Beki̇r Gürbulak, Aytunç Ateş, Muhammet Yildirim

Turkish Journal of Physics

Optical absorption and photoluminescence (PL) measurements were carried out in both undoped and Fe-doped samples and the effect of Fe doping on absorption and PL spectra were studied. The results show that Fe or Fe-related defects behave as non-radiative recombination centers in InP. This is very important from the point of view that the control of minority carrier lifetime is possible. On the other hand, comparative analysis of the PL results with the optical absorption data show that quantitative assessment of relative PL intensities is possible with respect to Fe concentrations.


Directional Solidification Of Pure Succinonitrile And Succinonitrile- Salol Alloys, İbrahi̇m Karaca, Emi̇n Çadirli, Hasan Kaya, Necmetti̇n Maraşli Jan 2001

Directional Solidification Of Pure Succinonitrile And Succinonitrile- Salol Alloys, İbrahi̇m Karaca, Emi̇n Çadirli, Hasan Kaya, Necmetti̇n Maraşli

Turkish Journal of Physics

Pure succinonitrile (SCN) and succinonitrile-salol alloys with four different concentrations of salol were unidirectionally solidified at five different growth rates in a temperature gradient. The microstructure parameters, viz., the primary dendrite arm spacing \lambda _{1}, dendrite tip radius R and mushy zone depth d, were measured. The dependence of the microstructure parameters on the solidification parameters for pure SCN and SCN-Salol alloys were determined via linear regression analysis. The results are compared with published data.


On The Semi-Markovian Random Walk Process With Reflecting And Delaying Barrriers, Selahatti̇n Maden Jan 2001

On The Semi-Markovian Random Walk Process With Reflecting And Delaying Barrriers, Selahatti̇n Maden

Turkish Journal of Mathematics

In this paper, a semi-Markovian random walk process X(t) with reflecting barrier on the zero-level and delaying barrier on the \beta(\beta>0 )-level and the first falling moment of the process into the delaying barrier, (\gamma), are considered. Some probability characteristics of \gamma , such as its distribution function, moment generating function and expected value are calculated.


Electrorheological Properties Of Suspensions Prepared From Polystyrene- Block- Polyisoprene Copolymer, Hali̇l İbrahi̇m Ünal, Yilmaz Yildirir, Mustafa Yavuz Jan 2001

Electrorheological Properties Of Suspensions Prepared From Polystyrene- Block- Polyisoprene Copolymer, Hali̇l İbrahi̇m Ünal, Yilmaz Yildirir, Mustafa Yavuz

Turkish Journal of Chemistry

Considerable scientific and industrial interest is currently being focused on a class of materials known as electrorheological (ER) fluids, which display remarkable rheological behaviour, being able to convert rapidly and repeatedly from a liquid to solid when an electric field (E) is applied or removed. In this article, the synthesis, characterization, partial hydrolysis and ER properties of polystyrene- block}-polyisoprene copolymer (COP) were investigated. The block copolymer was characterized by GPC, viscosity measurements, ^1 H-NMR and FTIR spectroscopies, particle size measurements, and elemental analysis. The polystyrene block of the copolymer was partially hydrolyzed by a series of chemical reactions and then …


Determination Of Hydrochlorothiazide And Enalapril Maleate In Tablet Formulations By Reversed-Phase Hplc, Idrees F. Al-Momani̇ Jan 2001

Determination Of Hydrochlorothiazide And Enalapril Maleate In Tablet Formulations By Reversed-Phase Hplc, Idrees F. Al-Momani̇

Turkish Journal of Chemistry

A high-performance liquid chromatographic procedure is presented for the determination of hydrochlorothiazide (HCT) and enalapril maleate (EM) in pharmaceutical tablets. An aliquot of the sample is dissolved in 15% acetonitrile (ACN) containing thiophylline as an internal standard and chromatographed on a Supelcosil LC-8 (5 \mu m), (150 mm x 4.6 mm i.d.) column. The mobile phase was 3.0 mM tetrabutylammoniumhydrogen sulfate (TBAHS) in ACN/water/triethylamine (TEA), (14, 85.6, 6.4 V/V) adjusted to pH 4.1 by glacial acetic acid. The detection was at 220 nm. The method was tested for linearity, accuracy, recovery, and specificity.


Studies On The Thermal Decomposition Of Copper (Ii) Flouride Complexes With Various Amino Acids In Nitrogen Atmosphere, Muhammad Arif, Saeed-Ur Rehman, Muhammad Arshad, Khalid Masud, Nasima Arshad Jan 2001

Studies On The Thermal Decomposition Of Copper (Ii) Flouride Complexes With Various Amino Acids In Nitrogen Atmosphere, Muhammad Arif, Saeed-Ur Rehman, Muhammad Arshad, Khalid Masud, Nasima Arshad

Turkish Journal of Chemistry

Thermal decomposition reactions of various copper (II) fluoride complexes of the general type Cu (L) F.xH_2O (L= asparagine(asp), arginine (arg), methionine (meth) and proline (pro), x = 3 to 4) have been studied in nitrogen atmosphere using TG and DTA techniques. A possible mechanism of decomposition is suggested on the basis of the reactions of their pyrolysis. The residues obtained at the end of various decomposition processes were identified through IR spectrometry. The kinetic parameters such as energy of activation (E^o ) and order of reaction (n) were also determined.


Fluorimetric Detection Of Insulin In The Presence Of Eu(Iii) - {Pyridine - 2,6 - Dicarboxylate} Tris Complex, Elmas Gök, Serdar Ateş Jan 2001

Fluorimetric Detection Of Insulin In The Presence Of Eu(Iii) - {Pyridine - 2,6 - Dicarboxylate} Tris Complex, Elmas Gök, Serdar Ateş

Turkish Journal of Chemistry

Bovine insulin solutions (pH=9.3) have maximum absorption at 278 \pm 2 nm and an intrinsic emission at 305 nm when excited at 282 nm. The relative fluorescence intensities show linear dependence on its concentration: 10 \mug/mL< [Ins] < 200 \mug/mL. When Eu(PDA)_{3}^{3-} tris complex is added to these solutions, it has a hyperchromic effect at 278 nm absorption band of insulin, sensitizing the emission intensities of central Eu^{3+} metal ion of the complex at 590 and 615 nm, and simultaneously quenching the emission intensity of hormone at 305 nm. Stern-Volmer plots show that a mechanism of bimolecular quenching at 305 nm and sensitization at 615 nm are valid up to a mole ratio, R = [Eu(PDA)_{3}^{3-}]/[Ins] < 2.0. An intramolecular rather than an intermolecular energy transfer is proposed. An apparent binding constant, log K_{app}=4.70 \pm 0.13, is calculated for Ins-[Eu(PDA)_{3}^{3-}]_{2} type product, the presence of which may offer a new luminescence technique as a diagnostic tool and an alternative to radio-iodinated (^{131}I -) insulin. A simple, rapid and accurate quantitation of insulin is proposed by using a fixed concentration of Eu(PDA)_{3}^{3-}, and measuring its initial F_{0} at \lambda_{exc}/ \lambda_{em}=282/615 nm and the difference, \DeltaF after sensitization when \sim 100 microliters of insulin sample is added. The coefficient of variation (CV), the relative error and minimum detectable amount of bovine insulin hormone are found to be 3.0%, 1.2% and 7.3 \pm 0.2 \mug /mL respectively.


Analysis Of Polychlorinated Dibenzofurans (Pcdfs) Isomers In Soil Samples, Mustafa Pehli̇van, Erol Pehli̇van Jan 2001

Analysis Of Polychlorinated Dibenzofurans (Pcdfs) Isomers In Soil Samples, Mustafa Pehli̇van, Erol Pehli̇van

Turkish Journal of Chemistry

This study presents an analytical method for the separation of a series of polychlorinated dibenzofurans (PCDFs) emitted to the soil. PCDF contaminants were concentrated from soil samples and isolated from other materials by chromatographic methods and their quantitative determinations were performed by GC/MS (gas chromatography/mass spectroscopy).


Accumulation Of Heavy Metals In Freshwater Organisms: Assessment Of Toxic Interactions, Neylan Di̇ri̇lgen Jan 2001

Accumulation Of Heavy Metals In Freshwater Organisms: Assessment Of Toxic Interactions, Neylan Di̇ri̇lgen

Turkish Journal of Chemistry

Heavy metals are continuously released into the terrestrial environment by natural sources and human activities. The uptake and accumulation of heavy metals by plants promotes a mechanistic understanding of the biological significance of particular metal concentrations and distributions in biota. The toxicity of chromium, zinc, copper and cobalt ions and their binary mixtures are studied at varying test levels using duckweed as the test organism. The accumulation of metal ions are determined by atomic absorption spectroscopy. The type of toxic interactions in binary mixtures is assessed as `synergistic', `antagonistic' and `additive' by a statistical approach.


The Composition Of Essential Oils From Two Varieties Of Sideritis Erythrantha Var. Erythrantha And Var. Cedretorum, Nurhayat Tabanca, Neş'E Kirimer, K. Hüsnü Can Başer Jan 2001

The Composition Of Essential Oils From Two Varieties Of Sideritis Erythrantha Var. Erythrantha And Var. Cedretorum, Nurhayat Tabanca, Neş'E Kirimer, K. Hüsnü Can Başer

Turkish Journal of Chemistry

Water distilled essential oils from two varieties of Sideritis erythrantha: var. erythrantha} and var. cedretorum, both endemic in Turkey, were analysed by GC/MS. The main components were characterized as \alpha -pinene (16.3-19.5%) and sabinene (6.1- 10.4%) for var. erythrantha; myrcene (21.9-24.3%) and \alpha -pinene (11.4- 12.4%) for var. cedretorum.


Structural Studies Of Water-Soluble \Beta-Brominated Manganese Porphyrins: Stabilities Of Mntdcsppbr _{8} And Mntsppbr _{8} As Homogeneous And Supported Reagents Toward Hydrogen Peroxide And Sodium Hypochlorite, Hayretti̇n Türk, Hüseyi̇n Berber Jan 2001

Structural Studies Of Water-Soluble \Beta-Brominated Manganese Porphyrins: Stabilities Of Mntdcsppbr _{8} And Mntsppbr _{8} As Homogeneous And Supported Reagents Toward Hydrogen Peroxide And Sodium Hypochlorite, Hayretti̇n Türk, Hüseyi̇n Berber

Turkish Journal of Chemistry

This article describes the structural stabilities of [2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(2,6-dichloro-3-sulfonatophenyl)porphinato]manganese(III) X (where X = H_{2}O and/or OH^{-} , depending on pH) (MnTDCSPPBr_{8} ) and [2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetra(4-sulfonatophenyl)porphinato] manganese(III) X (where X = H_{2}O and/or OH^{-} , depending on pH) (MnTSPPBr_{8} ) toward H_{2}O_{2} and NaOCl at various pH's, I = 0.2 M and 30^oC. In addition, the structural stabilities of these manganese porphyrins were investigated when they were bound to quaternary ammonium containing supports, namely, hexadecyltrimethylammonium bromide (CTAB), 2,6-ionene, 2,10-ionene and a poly[(vinylbenzyl)trimethylammonium chloride] latex. In alkaline media, both manganese porphyrins degraded and precipitated even in the absence of both of the oxidants. In …


Incorporation Of Edta For The Elimination Of Metal Inhibitory Effects In An Amperometric Biosensor Based On Mushroom Tissue Polyphenol Oxidase, Arzum Erdem, Di̇lşat Özkan, Burcu Meri̇ç, Kağan Kerman, Mehmet Özsöz Jan 2001

Incorporation Of Edta For The Elimination Of Metal Inhibitory Effects In An Amperometric Biosensor Based On Mushroom Tissue Polyphenol Oxidase, Arzum Erdem, Di̇lşat Özkan, Burcu Meri̇ç, Kağan Kerman, Mehmet Özsöz

Turkish Journal of Chemistry

Enzyme based biosensors are highly selective devices which rely on the specific binding of the target analyte (the substrate) to the active-site regions of the enzyme. The enzymatic reaction between mushroom tissue polyphenol oxidase and its substrate phenol is coupled with the use of potassium ferrocyanide (K_{4}Fe(CN)_{6}) as the mediator in ammonia buffer solution (pH 8.80). The response of devices is often affected by the presence of inhibitors, which combine with the free enzyme in a manner that prevents substrate binding. The objective of this study is to describe an efficient and yet simple strategy to eliminate the interference of …


Evaluation Of Sample Pre-Treatment Procedures For The Determination Of Cr, Ni And V In Biological Matrices By Etaas, Jan Medved, Jana Kubova, Eva Chmielewska, Vladimir Stresko Jan 2001

Evaluation Of Sample Pre-Treatment Procedures For The Determination Of Cr, Ni And V In Biological Matrices By Etaas, Jan Medved, Jana Kubova, Eva Chmielewska, Vladimir Stresko

Turkish Journal of Chemistry

Electrothermal atomic absorption spectrometry (ETAAS) was applied for the determination of chromium, nickel and vanadium in biological materials (earthworms, feather, lucerne). Three different decomposition procedures of biological matrices are presented. The utilization of NH_4H_2PO_4, Mg(NO_3)_2 and Pd(NO_3)_2+ Mg(NO_3)_2 as chemical modifiers are investigated and compared. Optimal temperature conditions for the electrothermal determination of Cr, Ni and V are selected. Precision of the determination expressed as relative standard deviations for Cr, Ni and V varied from 6 to 22% . The detection limits are for Cr 8 \\mu g kg^{ - 1}, Ni 12 \\mu g kg^{ - 1}, and V …


Silver Recovery From Waste Photographic Films By Using Enzymatic Method, Nuri̇ Naki̇boğlu, Duygu Toscali, İhsan Yaşa Jan 2001

Silver Recovery From Waste Photographic Films By Using Enzymatic Method, Nuri̇ Naki̇boğlu, Duygu Toscali, İhsan Yaşa

Turkish Journal of Chemistry

A different enzymatic method was developed for stripping the silver from waste X-ray photographic films. The silver having purity of > 99% was recovered by smelting the obtained slurry in the presence of borax. Enzyme extract, obtained from Bacillus subtilis ATCC 6633 by modifying Horikoshi medium, was used for stripping the silver layer. The metal impurities (Al, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb and Sn) in the recovered silver were determined using the ICP-MS method. The results were compared those in with literature for high purity silver using the same method.