Physical Sciences and Mathematics Commons^™

Springtime Photochemistry At Northern Mid And High Latitudes, Yuhang Wang, Brian Ridley, A Fried, C A. Cantrell, D D. Davis, Gao Chen, J Snow, B J. Heikes, R. Talbot, Jack E. Dibb, F Flocke, Andrew Weinheimer, N J. Blake, D R. Blake, R E. Shetter, Barry Lefer, Elliot Atlas, Michael T. Coffey, J Walega, B Wert

Earth Sciences

Physical and chemical properties of the atmosphere at 0–8 km were measured during the Tropospheric Ozone Production about the Spring Equinox (TOPSE) experiments from February to May 2000 at mid (40°–60°N) and high latitudes (60°–80°N). The observations were analyzed using a diel steady state box model to examine HO_x and O₃ photochemistry during the spring transition period. The radical chemistry is driven primarily by photolysis of O₃ and the subsequent reaction of O(¹D) and H₂O, the rate of which increases rapidly during spring. Unlike in other tropospheric experiments, observed H₂O_{2 …}

Effect Of Sulfate Aerosol On Tropospheric Nox And Ozone Budgets: Model Simulations And Topse Evidence, Xuexi Tie, L K. Emmons, Larry Horowitz, Guy Brasseur, Brian Ridley, Elliot Atlas, Craig Stround, Peter Hess, Andrzej Klonecki, Sasha Madronich, R. Talbot, Jack E. Dibb

Earth Sciences

The distributions of NO_x and O₃ are analyzed during TOPSE (Tropospheric Ozone Production about the Spring Equinox). In this study these data are compared with the calculations of a global chemical/transport model (Model for OZone And Related chemical Tracers (MOZART)). Specifically, the effect that hydrolysis of N₂O₅ on sulfate aerosols has on tropospheric NO_x and O₃ budgets is studied. The results show that without this heterogeneous reaction, the model significantly overestimates NO_x concentrations at high latitudes of the Northern Hemisphere (NH) in winter and spring in comparison to the observations during TOPSE; …

Tunable Diode Laser Measurements Of Formaldehyde During The Topse 2000 Study: Distributions, Trends, And Model Comparisons, A Fried, Yuhang Wang, C A. Cantrell, B Wert, J Walega, Brian Ridley, Elliot Atlas, R E. Shetter, Barry Lefer, Michael T. Coffey, James W. Hannigan, D R. Blake, N J. Blake, Simone Meinardi, R. Talbot, Jack E. Dibb, Eric Scheuer, Oliver Wingenter, J Snow, B J. Heikes, Dieter Ehhalt

Earth Sciences

Airborne measurements of formaldehyde (CH₂O) were acquired employing tunable diode laser absorption spectroscopy (TDLAS) during the 2000 Tropospheric Ozone Production About the Spring Equinox (TOPSE) study. This study consisted of seven deployments spanning the time period from 4 February to 23 May 2000 and covered a wide latitudinal band from 40°N to 85°N. The median measured CH₂O concentrations, with a few exceptions, did not show any clear temporal trends from February to May in each of five altitude and three latitude bins examined. Detailed measurement–model comparisons were carried out using a variety of approaches employing two …

Order Parameter Measurements Of Dichroic Dyes Dissolved In Smectic Liquid Crystals That Tilt Without Layer Contraction, Peter J. Collings, B. R. Ratna, R. Shashidhar

Physics & Astronomy Faculty Works

Measurements of the orientational order parameter of dissolved dichroic dyes are reported for two smectic-A liquid crystals that tilt in the presence of an in-plane electric field without any decrease in the layer spacing. The dye order parameter is determined by measuring the anisotropic absorption of linearly polarized light. Different dyes are used and measurements are also performed on a smectic liquid crystal that tilts with the expected layer contraction to check how closely the measurements reflect the order parameter of the liquid crystal. The variation of the dye order parameter with electric field is in accordance with the recently …

Low Mitochondrial Dna Variation In Double-Crested Cormorants In Eastern North America, Juliann L. Waits, Michael L. Avery, Mark E. Tobin, Paul L. Leberg

United States Department of Agriculture Wildlife Services: Staff Publications

Double-crested Cormorant (Phalacrocorax auritus) numbers are increasing throughout eastern North America. We compared variation for five portions of mtDNA to determine if genetic differences existed among portions of the breeding range that would need to be considered when formulating management programs. Sequences for four mtDNA regions were identical across sample locations; frequencies of two haplotypes of the mitochondrial Control Region were similar across sampling locations. There is no evidence of restricted gene flow among breeding areas, or between subspecies with different migratory patterns.

Neutral-Plasma Oscillations At Zero Temperature, Scott D. Bergeson, Ross L. Spencer

Faculty Publications

Cold plasma theory is used to calculate the response of an ultracold neutral plasma to an applied rf field. The free oscillation of the system has a continuous spectrum and an associated damped quasimode. This quasimode dominates the driven response and is resonant in the tail of the density distribution. Recent experiments used the plasma response to an applied rf field to determine the plasma density in an expanding ultracold plasma. The comparison between experiment and theory indicates that this method accurately determines the expansion velocity and underestimates the initial plasma density by a factor of 3 in weakly collisional …

Hyperspectral Remote Sensing Protocol Development For Submerged Aquatic Vegetation In Shallow Waters, Charles R. Bostater Jr., T. Ghir, L. Bassetti, Carlton Hall, E. Reyier, R. Lowers, K. Holloway-Adkins, Robert Virnstein

Ocean Engineering and Marine Sciences Faculty Publications

Submerged aquatic vegetation (SAV) is an important indicator of freshwater and marine water quality in almost all shallow water aquatic environments. Throughout the world the diversity of submerged aquatic vegetation appears to be in decline, although sufficient historical data, of sufficient quantitative quality is lacking. Hyperspectral remote sensing technology, available from low altitude aircraft sensors, may provide a basis to improve upon existing photographic regional assessments and monitoring concerned with the aerial extent and coverage of SAV. In addition, modern low altitude remote sensing may also help in the development of environmental satellite requirements for future satellite payloads. This paper …

Complex C: A Low-Metallicity High-Velocity Cloud Plunging Into The Milky Way, Todd M. Tripp, Bart P. Wakker, Edward B. Jenkins, C. W. Bowers, A. C. Danks, R. F. Green, S. R. Heap, C. L. Joseph, M. E. Kaiser, J. L. Linsky, B. E. Woodgate

Todd M. Tripp

We present evidence that high-velocity cloud (HVC) complex C is a low-metallicity gas cloud that is plunging toward the disk and beginning to interact with the ambient gas that surrounds the Milky Way. This evidence begins with a new high-resolution (7 km s-1 FWHM) echelle spectrum of 3C 351 obtained with the Space Telescope Imaging Spectrograph (STIS). 3C 351 lies behind the low-latitude edge of complex C, and the new spectrum provides accurate measurements of O I, Si II, Al II, Fe II, and Si III absorption lines at the velocity of complex C; N I, S II, Si IV, …

Measurement Of The Anti-Cancer Agent Gemcitabine In Human Plasma By High-Performance Liquid Chromatography, Bruce Keith, Yan Xu, Jean L. Grem

Chemistry Faculty Publications

A reversed-phase HPLC assay has been developed to determine the concentration of the anti-metabolite 2′,2′-difluorodeoxycytidine (gemcitabine, dFdC) in human plasma over the concentration range of 0.5–150 μM (0.13–39.44 μg/ml), and 2′,2′-difluorodeoxyuridine (dFdU), the deaminated, inactive metabolite, over the range of 1.0–227 μM (0.26–60 μg/ml). After the addition of 20 nmol 2′-fluorodeoxycytidine (FdC) as an internal standard, 0.5-ml samples of plasma were subjected to acetonitrile precipitation, followed by analysis using a gradient reversed-phase HPLC assay with UV detection. A Phenomenex Columbus™ C18 column, 5 μm, 150×4.6 mm, and a Waters C18, 4 μm, Nova-Pak Sentry guard column were used to achieve …

Scavenging By Vertebrates: Behavioral, Ecological, And Evolutionary Perspectives On An Important Energy Transfer Pathway In Terrestrial Ecosystems, Travis L. Devault, Olin E. Rhodes Jr., John A. Shivik

United States Department of Agriculture Wildlife Services: Staff Publications

Carrion use by terrestrial vertebrates is much more prevalent than conventional theory implies, and, rather than a curiosity of animal behavior, is a key ecological process that must be accounted for. Human aversion to rotted substances and difficulties associated with identifying scavenged material in studies of food habits have contributed to the relative lack of information concerning scavenging behavior in vertebrates. Several lines of evidence, however, suggest that carrion resources are more extensively used by vertebrates than has been widely assumed: 1) a substantial number of animals die from causes other than predation and become available to scavengers, 2) a …

Experimental Investigation Of Steel Corrosion In Lead Bismuth Eutectic (Lbe): Characterization, Species Identification, And Chemical Reactions, John Farley, Dale L. Perry, Allen L. Johnson

Transmutation Sciences Materials (TRP)

The goal of the present research is to achieve a basic understanding of corrosion of steels by Lead Bismuth Eutectic (LBE). Liquid LBE is under consideration in the transmuter as both a spallation target and as a blanket coolant. There have been previous studies of LBE, especially by the Russians, who have over 80 reactor-years experience with LBE coolant in their Alpha-class submarine reactors. The Russians found that the presence of small amounts (ppm) of oxygen in the LBE significantly reduced corrosion. However, a fundamental understanding and verification of its role in the corrosion of steels is still very incomplete. …

Monitoring Relative Abundance Of Young Of Year American Eel, Anguilla Rostrata, In The Virginia Tributaries Of Chesapeake Bay, Marcel M. Montane, M. Todd Mathes, Hank Brooks

Reports

The Atlantic States Marine Fisheries Commission (ASMFC) adopted the Interstate Fishery Management Plan (hereafter referred to as FMP) for the American Eel in November 1999. The FMP focuses on increasing the states’ efforts to collect data on the resource and the fishery it supports through both fishery dependent and independent studies. To this end, member jurisdictions (including Virginia) agreed to implement an annual abundance survey for young of year (YOY) American eels. The survey is intended to “…characterize trends in annual recruitment of the young of year eels over time [to produce a] qualitative appraisal of the annual recruitment of …

Hydrogenic Spin Quantum Computing In Silicon: A Digital Approach, A. J. Skinner, M. E. Davenport, B. E. Kane

Dartmouth Scholarship

We suggest an architecture for quantum computing with spin-pair encoded qubits in silicon. Electron-nuclear spin-pairs are controlled by a dc magnetic field and electrode-switched on and off hyperfine interaction. This digital processing is insensitive to tuning errors and easy to model. Electron shuttling between donors enables multiqubit logic. These hydrogenic spin qubits are transferable to nuclear spin-pairs, which have long coherence times, and electron spin-pairs, which are ideally suited for measurement and initialization. The architecture is scalable to a highly parallel operation.

The Design And Construction Of A Rainfall Simulator, Jacqueline Blanquies, Misty Scharff, Brent Hallock

Earth and Soil Sciences

A reliable, accurate and portable rainfall simulator was needed for vegetative and erosion control research at California Polytechnic State University, San Luis Obispo (Cal Poly) for California Department of Transportation (Caltrans) and California State University Sacramento. This simulator was designed to be easily set up and maintained as well as able to create a variety of rainfall regimes. The nozzle performance tests and lateral spacing tests were performed at Cal Poly’s Erosion Research Facility. This simulator was designed and constructed based upon the principles of the Norton Ladder Type Rainfall Simulator. This simulator is the standard for research involving simulated …

Vegetation Establishment For Erosion Control Under Simulated Rainfall, Brent G. Hallock, Misty Scharff, Steve Rein, Kaila Dettman

Earth and Soil Sciences

The California Department of Transportation (Caltrans) manages rights of ways that transect 41 m H (101m ac) and span over 3000 m (9000 ft) in elevation from seashore to sup alpine. There are approximately 4,900 native and 1,000 naturalized alien plant species in California. Only a few hundred are reliably useful in erosion and sediment control. Specifying native and naturalized vegetation mixes for use in hydroseeding or plug planting in conjunction with mechanical erosion control methods can have varying result for minimizing accelerated soil erosion. To investigate these factors, Cal Poly, San Luis Obispo, in conjunction with Caltrans and CSU, …

Structures And Stabilities Of Small Silicon Clusters: Ab Initio Molecular-Orbital Calculations Of Si7–Si11, Xiaolei Zhu, Xiao Cheng Zeng

Xiao Cheng Zeng Publications

Ab initio all-electron molecular-orbital calculations have been carried out to study the structure and relative stability of small silicon clusters (Si_n , n=7 – 11). A number of low-energy geometric isomers are optimized at the second-order Møller–Plesset (MP2) MP2/6-31G(d) level. Harmonic vibrational analysis has been performed to assure that the optimized geometries are stable. The total energies of stable isomers are computed at the coupled-cluster single and double substitutions (including triple excitations) [CCSD(T)] CCSD(T)/6-31G(d) level. The calculated binding energies per atom at both the MP2/6-31G(d) and CCSD(T)/6-31G(d) levels agree with …

Spectral Triples And Metric Aspects Of Geometry On Some Noncommutative Spaces., Partha Sarathi Chakraborty Dr.

Doctoral Theses

Quantization of mathematical theories is now more than half a century old idea in mathe- matics. It goes back to Gelfand-Naimarks seminal paper [37] in 1943. As the name suggests noncommutative geometry is the quantization" of differential geometry. It is the study of noncommutative algebras as if they were algebras of functions on spaces like the commuta- tive algebras associated to affine algebraic varieties, smooth manifolds, topological spaces. One can trace its roots in the Gelfand-Naimark theorems (1943, 37]). In modern terminol- ogy their theorem says there is an antiequivalence between the category of (locally) compact Hausdorff spaces and (proper, …

Cooperative Effects In One-Dimensional Chains Of Three-Center Hydrogen Bonding Interactions, Ruben D. Parra, Satya S. Bulusu, Xiao Cheng Zeng

Xiao Cheng Zeng Publications

Cooperative effects in a one-dimensional network of intermolecular bifurcated hydrogen bonding interactions are investigated by means of ab initio calculations. The trans–trans conformation of the diformamide molecule is used as a basic motif to model a chain of bifurcated H bonds. In this model system, the two proton–acceptor atoms belong to the same molecule. The one-dimensional network is modeled then by periodically stacking up to 12 molecules of the unit motif. Different indicators of H-bond strength such as energetic, structural, dielectric, vibrational frequencies, and isotropic chemicals shifts consistently show significant cooperative effects in the chains. The dissociation energy in the …

Pathoecology Of Chiribaya Parasitism, Elizabeth Martinson, Karl J. Reinhard, Jane E. Buikstra, Katharina Dittmar De La Cruz

School of Natural Resources: Faculty Publications

The excavations of Chiribaya culture sites in the Osmore drainage of southern Peru focused on the recovery of information about prehistoric disease, including parasitism. The archaeologists excavated human, dog, guinea pig, and llama mummies. These mummies were analyzed for internal and external parasites. The results of the analysis and reconstruction of prehistoric life from the excavations allows us to interpret the pathoecology of the Chiribaya culture.

A Case Of Megacolon In Rio Grande Valley As A Possible Case Of Chagas Disease, Karl J. Reinhard, Thomas M. Fink, Jack Skiles

School of Natural Resources: Faculty Publications

We have been searching for evidence of Chagas disease in mummified human remains. Specifically, we have looked for evidence of alteration of intestinal or fecal morphology consistent with megacolon, a condition associated with Chagas disease. One prehistoric individual recovered from the Chihuahuan Desert near the Rio Grande exhibits such pathology. We present documentation of this case. We are certain that this individual presents a profoundly altered large intestinal tract and we suggest that further research should focus on confirmation of a diagnosis of Chagas disease. We propose that the prehistoric activity and dietary patterns in Chihuahua Desert hunter/gatherers promoted the …

Louse Infestation Of The Chiribaya Culture, Southern Peru: Variation In Prevalence By Age And Sex, Karl J. Reinhard, Jane E. Buikstra

School of Natural Resources: Faculty Publications

In order to improve the interpretive potential of archaeoparasitology, it is important to demonstrate that the epidemiology of ancient parasites is comparable to that of modern parasites. Once this is demonstrated, then we can be secure that the evidence of ancient parasitism truly reflects the pathoecology of parasitic disease. Presented here is an analysis of the paleoepidemiology of Pediculus humanus infestation from 146 mummies from the Chiribaya culture 1000-1250 AD of Southern Peru. The study demonstrates the modern parasitological axiom that 10% of the population harbors 70% of the parasites holds true for ancient louse infestation. This is the first …

Inca Expansion And Parasitism In The Lluta Valley: Preliminary Data, Santoro Calagero, Karl J. Reinhard, Sheila D. Vinton

School of Natural Resources: Faculty Publications

Assessing the impact of cultural change on parasitism has been a central goal in archaeoparasitology. The influence of civilization and the development of empires on parasitism has not been evaluated. Presented here is a preliminary analysis of the change in human parasitism associated with the Inca conquest of the Lluta Valley in Northern Chile. Changes in parasite prevalence are described. It can be seen that the change in life imposed on the inhabitants of the Lluta Valley by the Incas caused an increase in parasitism.

Paleopharmacology And Pollen: Theory, Method, And Application, Sérgio A.M. Chaves, Karl J. Reinhard

School of Natural Resources: Faculty Publications

Parasitism was a universal human condition. Because of this, people developed herbal medicines to treat parasites as part of their pharmacopoeias. We propose that it is possible to recover evidence of medicinal plants from archaeological sites and link their use to specific health conditions. This is a multidisciplinary approach that must involve at least paleoethnobotanists, archaeoparasitologists, paleopathologists, and pharmacologists.

Parasite Remains In Archaeological Sites, Françoise Bouchet, Niéde Guidon, Katharina Dittmar, Stephanie Harter, Luiz F. Ferreira, Sérgio A.M. Chaves, Karl J. Reinhard, Adauto Araújo

School of Natural Resources: Faculty Publications

Organic remains can be found in many different environments. They are the most significant source for paleoparasitological studies as well as for other paleoecological reconstruction. Preserved paleoparasitological remains are found from the driest to the moistest conditions. They help us to understand past and present diseases and therefore contribute to understanding the evolution of present human sociality, biology, and behavior. In this paper, the scope of the surviving evidence will be briefly surveyed, and the great variety of ways it has been preserved in different environments will be discussed. This is done to develop to the most appropriated techniques to …

Diagnosing Ancient Diphyllobothriasis From Chinchorro Mummies, Karl J. Reinhard, Otto Urban

School of Natural Resources: Faculty Publications

Diphyllobothrium pacificum has been reported as a human parasite from coprolites and skeletons in Peru and Chile. Our analysis of Chinchorro mummies from Chile provides the oldest evidence of D. pacificum directly associated with human mummies. These mummies date between 4,000 and 5,000 years ago. The basis for our diagnosis is presented. We find that the size of the eggs in the mummies is smaller than other discoveries of D. pacificum. We suggest that this is due to the peculiar circumstances of preservation of parasite eggs within mummies and the release of immature eggs into the intestinal tract as the …

Predicted Hcp Ag-Al Metastable Phase Diagram, Equilibrium Ground States, And Precipitate Structure, Nikolai A. Zarkevich, Duane D. Johnson

Nikolai A. Zarkevich

Formation energies of a number of hcp-based Ag-Al structures are obtained from ab initio electronic-structure calculations and used within a cluster expansion approach to construct an effective alloy Hamiltonian. Formation energies are found to be inherently asymmetric versus composition, providing an incipient tendency for precipitation in Al-rich alloy. Both ground-state search and Monte Carlo simulations based on the cluster expansion are used to determine the metastable hcp Ag-Al phase diagram. A new equilibrium hcp AgAl ground state is predicted and zero-energy domain boundary defects are found. From thermodynamic results, we discuss the precipitate structure and composition in Al-rich Al-Ag alloys …

Control Of Denitrification In A Permanently Ice Covered Antarctic Lake: Potential For Regulation By Bioactive Metals, Mark Wells

University of Maine Office of Research Administration: Grant Reports

Lake Bonney is a permanently ice-covered lake in the Dry ValleyÆs region of Antarctica separated into two deep lobes by a shallow (12 m) sill. Denitrification occurs in the sub-oxic, saline waters of the west lobe but not in that of the east lobe for reasons unknown. Previous work has established this disparity cannot be attributed to temperature or salinity limitations, nor by the comparative availability of organic carbon substrates. Our research objective is to determine if trace metal limitation or toxicity may be responsible for this unusual feature. The broader objective is to assess the likelihood that denitrification in …

Flexible And Scalable Public Key Security For Ssh, Yasir Ali

Dartmouth College Master’s Theses

A standard tool for secure remote access, the SSH protocol uses public-key cryptography to establish an encrypted and integrity-protected channel with a remote server. However, widely-deployed implementations of the protocol are vulnerable to man-in-the-middle attacks, where an adversary substitutes her public key for the server's. This danger particularly threatens a traveling user Bob borrowing a client machine.

Imposing a traditional X.509 PKI on all SSH servers and clients is neither flexible nor scalable nor (in the foreseeable future) practical. Requiring extensive work or an SSL server at Bob's site is also not practical for many users.

This paper presents our …

Characteristics Of Current And Historical Kit Fox (Vulpes Macrotis) Dens In The Great Basin Desert, Wendy M. Arjo, Tim J. Bennett, Adam J. Kozlowski

United States Department of Agriculture Wildlife Services: Staff Publications

We examined the ecological and physical characteristics of den sites for 13 adult kit fox (Vulpes macmtis) in western Utah from December 1998 to February 2001. We also compared current and historical den distribution among habitat types. The number of den sites used was not influenced by home-range size (P = 0.11) or season (P = 0.40), but was influenced by geographical area. Home-range size was smallest (P = 0.007) and the number of dens used was greatest (P = 0.009) in mountainous areas. Ecological and physical characteristics of single-use dens (n = …

Protoplanetary Disk Mass Distribution In Young Binaries, Eric L.N. Jensen, R. L. Akeson

Physics & Astronomy Faculty Works

We present millimeter-wave continuum images of four wide (separations 210-800 AU), young stellar binary systems in the Taurus-Auriga star-forming region. For all four sources, the resolution of our observations is sufficient to determine the millimeter emission from each of the components. In all four systems, the primary star's disk has stronger millimeter emission than the secondary's, and in three of the four the secondary is undetected; this is consistent with predictions of recent models of binary formation by fragmentation. The primaries circumstellar disk masses inferred from these observations are comparable to those found for young single stars, confirming that the …