Physical Sciences and Mathematics Commons^™

Fourier Transform Infrared Analysis Of Hydroxyl Content Of Hydrothermally Processed Heteroepitaxial Barium Titanate Films, Sandeep K. Patil, Nipun Shah, Frank D. Blum, M. N. Rahaman

Chemistry Faculty Research & Creative Works

The concentration of hydroxyl (-OH) groups in epitaxial barium titanate (BaTiO3) films (thickness ≈ 200 nm), deposited on single-crystal strontium titanate (SrTiO3) at 150 °C by a hydrothermal technique, was investigated using x-ray photoelectron spectroscopy and Fourier transform infrared (FTIR) spectroscopy. After hydrothermal treatment, a broad FTIR resonance for the hydroxyl groups indicated a significant concentration of surface -OH groups in the films. The as-deposited films were subsequently treated hydrothermally with D2O, and the kinetics of the exchange reaction between -OH incorporated into the film and -OD from the D2O were studied using FTIR. For reactions carried out intermittently, the …

Deuterium Nmr Studies Of Segmental Dynamics Of Anopore-Adsorbed Poly(Methyl Acrylate), Macduff O. Okuom, Frank D. Blum

Chemistry Faculty Research & Creative Works

Studies of segmental dynamics of polymers at interfaces provide a basis for understanding the properties of composite materials. Interfacial phenomena in multi-phase systems need to be understood as devices made from multi-phase polymeric systems become smaller. Various techniques have been used to investigate interfacial polymers at the air-polymer-solid interface; for example, ellipsometry,1 X-ray,2 and neutron reflectometry.3 These techniques typically characterize the structure (often the thickness) of the polymer layer and are normally used to determine the glass-transition temperature (Tg) through a break in the thicknesstemperature curve. There have been a few reports where the dynamics of polymers at the surface-air …

Magnetic Properties Of (Γ-Fe₂O₃)₈₀Ag₂₀ Nanocomposites Prepared In Reverse Micelles, Joan A. Wiemann, Jianbiao Dai, Jinke Tang, Gary J. Long, Leonard Spinu

Chemistry Faculty Research & Creative Works

The magnetic properties of nanoparticles of gamma-Fe2O3 prepared by reverse micelles have been studied by dc magnetization, transverse ac susceptibility, and Mössbauer spectroscopy. The nanoparticles of gamma-Fe2O3 in the nanocomposite (gamma-Fe2O3)80Ag20 exhibit superparamagnetic behavior. The blocking temperatures determined by the three methods indicate the superparamagnetic nature of (gamma-Fe2O3)80Ag20 above 70-80 K and show correlation with measuring time. The average particle diameter obtained by transmission electron microscopy of the gamma-Fe2O3 particles is ~10 nm and that of the Ag particles is ~20 nm. The average particle size determined from the magnetic analyses for the gamma-Fe2O3 particles is ~12 nm. Mössbauer spectra …

Anodic Stripping Voltammetric Behavior Of Mercury In Chloride Medium And Its Determination At A Gold Film Electrode, Füsun Okçu, F. Ni̇l Ertaş, H. İsmet Gökçel, Hüseyi̇n Tural

Turkish Journal of Chemistry

The electrochemical behavior of aqueous Hg(II) ions at a gold film electrode is described. The effects of supporting electrolyte and halide ions on the anodic stripping voltammetric behavior of Hg(II) ions was illustrated to prepare a basis for the analysis in real samples with high saline content. The concentration ratio of metallic mercury to halide ions at the electrode surface determines the resulting peak characteristics. The peak potentials in particular shift in a more negative direction as the halide concentration increases. A comparative study with Cu(II) ions revealed that a different mechanism is involved in their reoxidation steps. Mercuric ions …

The Determination Of Environmentally Important Metals In Marine Sediments, Linda Tyrrell

Masters

Surface sediment samples were collected at sites within the Rockall Through at water depth ranges from 700 – 2774 metres. The study area was predefined by the availability of samples. Samples were collected by the British Geological Survey during their gravity core survey undertaken in 1998. Methods were optimised and validated for lead, cadmium, chromium, copper, nickel, zinc, lithium and aluminium using atomic absorption spectroscopy following total digestion, and for mercury, using cold vapour atomic fluorescence spectroscopy following partial digestion. The measured metal concentration were normalised to Li to compensate for the influence of natural variability in the concentration of …

Ramanujan's Formula For The Riemann Zeta Function Extended To L-Functions, Katherine J. Merrill

Electronic Theses and Dissertations

Ramanujan's formula for the Riemann-zeta function is one of his most celebrated. Beginning with M. Lerch in 1900, there have been many mathematicians who have worked with this formula. Many proofs of this formula have been given over the last 100 years utilizing many techniques and extending the formula. This thesis provides a proof of this formula by the Mittag-Leffler partial fraction expansion technique. In comparison to the most recent proof by utilizing contour integration, the proof in this thesis is based on a more natural growth hypothesis. In addition to a less artificial approach, the partial fraction expansion technique …

Variations In Mineralogy, Temperature, And Oxygen Fugacity In A Suite Of Strongly Peralkaline Lavas And Tuffs, Pantelleria, Italy., John C. White, Minghua Ren, Don Parker

EKU Faculty and Staff Scholarship

Eight samples of pantelleritic lava and tuff and a lithic inclusion of trachyte from Pantelleria, Italy, have been thoroughly analyzed with an electron microprobe. These samples reveal five different mineral assemblages if classified by the presence of fayalite, aenigmatite, ilmenite, and magnetite: (1) augite + fayalite + ilmenite + magnetite, (2) augite + fayalite + ilmenite, (3) hedenbergite or sodian hedenbergite + fayalite + ilmenite + aenigmatite + quartz, (4) sodian hedenbergite or aegirine-augite + ilmenite + aenigmatite + quartz ± ferrorichterite, and (5) aegirine-augite + aenigmatite + quartz. Alkali feldspar (Or35–37) is present as the dominant phyric phase in …

Groundwater Irrigation In The Development Of The Grand Prairie Rice Industry, 1896-1950, John B. Gates

Department of Earth and Atmospheric Sciences: Faculty Publications

Elucidates some of the ways in which groundwater and groundwater irrigation have affected the Grand Prairie's rice industry over time and conversely how the development of the industry has altered the region's groundwater conditions. Concentrates on aspects of the industry's history that have often been overlooked in favor of rice cultivation's social dimensions and consider hydrological systems not just as resources awaiting exploitation or as simple constraints on production but as variables whose roles and effects can change over time.

New Stratigraphic Subdivision, Depositional Environment, And Age Estimate For The Upper Cretaceous Djadokhta Formation, Southern Ulan Nur Basin, Mongolia, Demberelyin Dashzeveg, Lowell Dingus, David B. Loope, Carl C. Swisher Iii, Togtokh Dulam, Mark R. Sweeney

Department of Earth and Atmospheric Sciences: Faculty Publications

Studies of key and newly discovered sections of the Upper Cretaceous Djadokhta Formation along the southern margin of the Ulan Nur Basin allow a new subdivision based on lithology. The formation and its members were mapped at both Bayn Dzak, an area that includes the Flaming Cliffs, and Tugrugyin Shireh, an area about 50 km to the northwest of Bayn Dzak. Stratigraphic sections at both localities were remeasured. The considerably enlarged formation comprises a lower Bayn Dzak Member, dominated by moderate reddish orange sands with subordinate mudstone units, and an upper Tugrugyin Member, composed of pale orange to light gray …

Calcareous Nannoplankton Response To Late Albian Oceanic Anoxic Event 1d In The Western North Atlantic, David K. Watkins, Matthew J. Cooper, Paul A. Wilson

Department of Earth and Atmospheric Sciences: Faculty Publications

Well-preserved nannofossil and stable isotope records from the mid-Cretaceous of Ocean Drilling Project Leg 171B (western North Atlantic) indicate cyclical, productivity-based variations in surface water characteristics, suggesting orbitally paced changes in upwelling intensity and the strength of deep mixing associated with oceanic anoxic event (OAE)1d. Paleontologic and isotopic evidence suggest that collapse of upper water column stratification associated with OAE1d was preceded by approximately 1 m.y. of progressively decreasing water column stability and increasing surface water fertility. Thirteen species went extinct during a short (ca. 200 k.y.) interval associated with OAE1d. Nine of these have morphological characters suggesting adaptation to …

Do Meteorologists Suppress Thunderstorms? Radar-Derived Statics And The Behavior Of Moist Convection, Matthew D. Parker, Jason C. Knievel

Department of Earth and Atmospheric Sciences: Faculty Publications

Most meteorologists are acquainted with the no- tion of a weather hole—that is, a place that receives less exciting weather than does its surroundings. Exciting weather takes many forms, but when people use the term weather hole, they tend to mean a place that thunderstorms often barely miss, or near which approaching storms often dissipate. For this paper, that is the meaning we adopt.

In our experience, many meteorologists and lay weather enthusiasts genuinely believe that they live in weather holes, and this belief, almost without fail, seems to stem from countless hours spent gazing at displays of radar reflectivity. …

Performance Of Quality Assurance Procedures For An Applied Climate Information System, K. G. Hubbard, S. Goddard, Bill Sorensen, N. Wells, Thomas Osugi

Department of Earth and Atmospheric Sciences: Faculty Publications

Valid data are required to make climate assessments and to make climate-related decisions. The objective of this paper is threefold: to introduce an explicit treatment of Type I and Type II errors in evaluating the performance of quality assurance procedures, to illustrate a quality control approach that allows tailoring to regions and subregions, and to introduce a new spatial regression test. Threshold testing, step change, persistence, and spatial regression were included in a test of three decades of temperature and precipitation data at six weather stations representing different climate regimes. The magnitude of thresholds was addressed in terms of the …

Registros De Sedimentos Lacustres De La Vegetación Del Holoceno Y Historia Del Fuego En El Páramo De Costa Rica. (Lake-Sediment Records Of Holocene Vegetation And Fire History In The Costa Rican Páramos), Sally P Horn, Brandon L. League

Geography Publications and Other Works

We examined pollen, pteridophyte (ferns and fern-allies) spores, and charcoal in a 5.6 m long sediment core from Lago de las Morrenas 1, and charcoal in a 1.1 m long sediment core from Lago Chirripó, to reconstruct postglacial vegetation and fire history in the Chirripó páramo. Lago de las Morrenas 1, the largest lake in the Valle de las Morrenas of Chirripó National Park, is presently surrounded by treeless páramo vegetation and has apparently been so since deglaciation approximately 10,000 radiocarbon years ago. Pollen spectra suggest no pronounced changes in vegetation since ice retreat. Pollen percentages for Gramineae and other …

The Discovery-Oriented Approach To Organic Chemistry. 6. Selective Reduction In Organic Chemistry: Reduction Of Aldehydes In The Presence Of Esters Using Sodium Borohydride, Ram Mohan, Ashvin Baru

Scholarship

Chemoselective reductions are valuable in organic synthesis and are routinely discussed in a sophomore organic chemistry course. Yet, there are few examples of laboratory experiments that illustrate such chemoselectivity. A reaction that is routinely discussed in sophomore organic chemistry is the selective reduction of aldehydes and ketones using sodium borohydride. Esters are typically not affected by NaBH4. However, none of the lab experiments reported to date illustrate this chemoselectivity (1). We have developed a discovery-oriented lab experiment that illustrates the chemoselective nature of reductions using sodium borohydride. The experiments involve the reduction of vanillin acetate (Scheme I) and methyl 4-formylbenzoate …

2005- 2008 Unlv Mcnair Journal, Valerie Avery, Shana Bachus, Karmen K. Boehlke, Andrea Flores, Alden Kelly, Erick Lopez, Carol Preussler, Heather Shay, Ava Bookatz, Shaun Elsasser, Veronica Hicks, Shaida A. Jetha, Anthony Quinn, Thurithabhani Seneviratne, Teddy Boado Sim Jr., Liza Ward, Amris Henry-Rodgers, Jacquelynn Kaaa-Logan, Jason Orozco, Juan C. Plata, Bonnie Bartlett, Kathleen Bell, Vacheral M. Carter, Nydia Diaz, Kimberly Hackstock, Julio A. Luna, Charles Mao, Sandra Ramos, Precious Rideout, Benjamin Lee Watrous, Chet R. Whitley

McNair Journal

Journal articles based on research conducted by undergraduate students in the McNair Scholars Program

Table of Contents

Biography of Dr. Ronald E. McNair

Statements:

Dr. Neal J. Smatresk, UNLV President

Dr. Juanita P. Fain, Vice President of Student Affairs

Dr. William W. Sullivan, Associate Vice President for Retention and Outreach

Mr. Keith Rogers, Deputy Executive Director of the Center for Academic Enrichment and Outreach

McNair Scholars Institute Staff

Southern Nevada Interagency Volunteer Program, Public Lands Institute

Get Outdoors Nevada

To encourage, support, and build volunteerism to conserve, protect, enhance, and foster an appreciation of the diverse natural, cultural, and recreational areas in Southern Nevada.

Campus Community And Their Responsibility To Our Public Lands, Mark Valentin

Presentations (PLI)

• To heighten awareness of UNLV’s community on the laws governing the uses of public lands and the personal liabilities associated with such use.
• To provide the campus community with the most efficient permitting service possible.
• To provide accurate, concise permit information to the appropriate agency.

Regional Open Space & Trails Workgroup Presentation, Public Lands Institute

Presentations (PLI)

The Public Lands Institute is dedicated to strengthening the national fabric that is essential for the protection, conservation, and management of public lands.

Inventing The Future 2005 Planning Retreat, Public Lands Institute

Presentations (PLI)

• Foster an integrated, holistic approach to managing and stewarding public lands.
• Focus initially on externally funded cooperative conservation projects, research initiatives, and capital improvement projects.
• Attract projects that are local, regional, and national in scope.

Oliver Ranch Science School Complex & Wild Horse And Burro Facility: Quarterly Progress Report, Period Ending March 31, 2005, Margaret N. Rees

Oliver Ranch Project

Assist in project coordination between numerous stakeholders such as the Clark County School System, Desert Research Institute, Community College of Southern Nevada, UNR Cooperative Extension, Nevada State College, local museums, state parks, non-profit organizations, federal agencies, and the public to ensure appropriate educational curricular activities and venues are provided for in the conceptual design of the School and the Wild Horse and Burro facility where appropriate as well as assist in the NEPA process as needed. The activities will be conducted at least in part by university faculty, staff and students as part of the university’s research, teaching, and service …

Oliver Ranch Science School Complex & Wild Horse And Burro Facility: Quarterly Progress Report, Period Ending September 30, 2005, Margaret N. Rees

Oliver Ranch Project

Executive Summary

Activity highlights during the first quarter of Year Two include the following actions toward task agreement deliverables:

• Agenda and minutes prepared and distributed for three core group meetings
• Wild horse and burro curriculum completed and vetted through local, regional, and national levels
• Historical curriculum completed and ready for review by core group
• Two RRDLC PowerPoint presentations coordinated, written, and illustrated by Public Lands Institute staff for BLM presentations to the Clark County School District Executive Cabinet and the Board of Trustees.
• RRDLC informational handouts provided to community members, teachers, and students at Joshua Jubilee community event and Clark …

Oliver Ranch Science School Complex & Wild Horse And Burro Facility: Quarterly Progress Report, Period Ending December 31, 2005, Margaret N. Rees

Oliver Ranch Project

Executive Summary

Activity highlights during the first quarter of Year Two include the following actions toward task agreement deliverables:

• Agenda and minutes prepared and distributed for two core group meetings
• Historical curriculum 100% completed
• Cultural curriculum 100% completed
• Night sky curriculum 50% completed
• Green Building curriculum 25% completed
• Communications/Outreach Plan revised and prioritized
• RRDLC newsletter under final review by BLM state office

Oliver Ranch Science School Complex & Wild Horse And Burro Facility: Annual Progress Report, Year Ending June 30, 2005, Margaret N. Rees

Oliver Ranch Project

Assist in project coordination between numerous stakeholders such as the Clark County School System, Desert Research Institute, Community College of Southern Nevada, UNR Cooperative Extension, Nevada State College, local museums, state parks, non-profit organizations, federal agencies, and the public to ensure appropriate educational curricular activities and venues are provided for in the conceptual design of the School and the Wild Horse and Burro facility where appropriate as well as assist in the NEPA process as needed. The activities will be conducted at least in part by university faculty, staff and students as part of the university’s research, teaching, and service …

Forever Earth Program: An Overview, Public Lands Institute

Presentations (DM)

• Education
• Scientific studies and research
• Water quality monitoring
• Command post activities

Discover Mojave Outdoor World: Open House, Public Lands Institute

Presentations (DM)

Increase the connection of urban youth to the natural world and our public lands through discovery, recreation, and education.

Assessing “Discover Mojave” Instrument Development And Analysis, Lori Olafson, Gregory Schraw, Jeanne A. Klockow

Reports (DM)

We developed a comprehensive assessment plan and tested the curriculum to determine whether hands-on outdoor recreation events promote knowledge, attitudes, and performance among at-risk urban children. Knowledge, attitude, and performance assessments were developed, refined and conducted through various stages based on cultural and language barriers as well a variety of age groups participating within the events. Findings revealed that knowledge, attitudes, and performance increased substantially as a result of participating in the outdoor recreation events. We conclude that the implementation and assessment of the program is strong. We also make several recommendations for future programs.

Science In The Community: A Look At Informal Science Organizations In Clark County, Public Lands Institute

Presentations (PLI Education)

UNLV’s Public Lands Institute is partnering with area-wide Informal Science Organizations to provide experiences that can have significant and lasting impacts on student learning.

Radiation Transport Modeling Using Parallel Computational Techniques, William Culbreth, Denis Beller

Reactor Campaign (TRP)

One of the most significant tools available for the design and analysis of accelerator-driven systems, such as the systems proposed for transmutation, is the high-energy particle transport code MCNPX. The MCNPX code suite, developed by the national laboratories, allows researchers and engineers to model the complex interactions of high-energy particles with the target and related systems, including the spallation reaction and subsequent neutron multiplication expected in the accelerator targets.

The next stage in the development of the MCNPX code suite is to validate the code by comparing the theoretical predictions from the models with experimental observations. Additionally, the nuclear database, …

University Of Nevada, Las Vegas Transmutation Research Program: Annual Report Academic Year 2004-2005, Anthony Hechanova, Kathy Lauckner

Transmutation Research Program Reports (TRP)

It is my pleasure to present the UNLV Transmutation Research Program’s fourth annual report that highlights the academic year 2004 – 2005. Supporting this document are the many technical reports and scientific papers that have been generated over the past three years.

In the fourth year of our program, we added 11 new research tasks and saw the conclusion of 8 of the initial 16 independent student research tasks started in 2001 and 2002. In all, the program has sponsored to their conclusion 28 M.S. and 2 Ph.D. degrees. The program supported 58 graduate students and 13 undergraduates in 6 …

Corrosion Of Steel By Lead Bismuth Eutectic, John Farley, Allen L. Johnson, Dale L. Perry

Transmutation Sciences Materials (TRP)

There is an active international interest in lead-bismuth eutectic and similar liquid lead systems because of the relevance to the transmutation of nuclear waste, fast reactors, and spallation neutron sources.

Materials in these systems must be able to tolerate high neutron fluxes, high temperatures, and chemical corrosion. For lead bismuth eutectic (LBE) systems, there is an additional challenge because the corrosive behaviors of materials in LBE are not well understood. Most of the available information on LBE systems has come from the Russians, who have over 80 reactor-years experience with LBE coolant in their Alpha-class submarine reactors. The Russians found …