Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

2005

Discipline
Institution
Keyword
Publication
Publication Type
File Type

Articles 5101 - 5130 of 5573

Full-Text Articles in Physical Sciences and Mathematics

Water-Level Changes In Shallow Wells Before And After The 1999 İzmit And Düzce Earthquakes And Comparison With Long-Term Water-Level Observations (1999–2004), Nw Turkey, Cenk Yaltirak, Tolga Yalçin, Erkan Bozkurtoğlu, Gali̇p Yüce Jan 2005

Water-Level Changes In Shallow Wells Before And After The 1999 İzmit And Düzce Earthquakes And Comparison With Long-Term Water-Level Observations (1999–2004), Nw Turkey, Cenk Yaltirak, Tolga Yalçin, Erkan Bozkurtoğlu, Gali̇p Yüce

Turkish Journal of Earth Sciences

It is well known that earthquakes cause hydrological changes, such as drying or flooding of water wells, fluctuations in ground-water levels in wells, changes in water quality, and formation of new springs. Significant drops in ground-water levels in wells were recorded during recent earthquakes in NW Turkey on August 17, 1999 in İzmit and on November 12, 1999 in Düzce. The İzmit earthquake (Ms 7.4) caused pre-seismic water-level changes in wells at Eskişehir, located 118-216 km away from the epicentre. Well-level changes in the Eskişehir, Sakarya, Bursa, Yalova, Yenişehir and İnegöl basins were recorded prior to and after the Düzce …


Integration Of Vmc++ Into A Commercial Treatment Planning System, Joseph Kingsley Gardner Jan 2005

Integration Of Vmc++ Into A Commercial Treatment Planning System, Joseph Kingsley Gardner

Theses and Dissertations

Recently, there has been interest to integrate VMC++ into the commercial treatment planning system at VCU as another Monte Carlo code option, since it has been shown to increase efficiency dramatically without introducing a significant amount of systematic error. Also, independent validation of VMC++ for photon beams is of interest since this has not been performed previously in literature. This study included several tests required to integrate VMC++. Output factor normalization was performed and found to agree with experiment to within 1% for all field sizes except 1x1 cm2. Geometric validation was successful. Dosimetric validation was performed with respect to …


On An Extension Of Abel-Gontscharoff's Expansion Formula, Tian-Xiao He, Leetsch Hsu, Peter Shiue Jan 2005

On An Extension Of Abel-Gontscharoff's Expansion Formula, Tian-Xiao He, Leetsch Hsu, Peter Shiue

Scholarship

We present a constructive generalization of Abel-Gontscharoff’s series expansion to higher dimensions. A constructive application to a problem of multivariate interpolation is also investigated. In addition, two algorithms for the constructing the basis functions of the interpolants are given.


Environment Friendly Organic Synthesis Using Bismuth Compounds. An Efficient Method For Carbonyl-Ene Reactions Catalyzed By Bismuth Triflate, Ram Mohan, Erin Anderson, Justin Ernat, Mai Nguyen, Ann Palma Jan 2005

Environment Friendly Organic Synthesis Using Bismuth Compounds. An Efficient Method For Carbonyl-Ene Reactions Catalyzed By Bismuth Triflate, Ram Mohan, Erin Anderson, Justin Ernat, Mai Nguyen, Ann Palma

Scholarship

Bismuth triflate (0.1 mol %) is a highly efficient catalyst for the cyclization of citronellal 1, a reaction that yields a ratio of 80:20 of isopulegol 2 and neoisopulegol 3. This methodology has also been extended to the synthesis of substituted piperidines. The bismuth triflate catalyzed ene reaction of aldehyde 4 gives a 70:30 mixture of piperidines 5 and 6. The advantages of these methods include the use of a highly efficient catalyst that is relatively nontoxic, cheap and easy to handle.


A Study Of Epoxyolefin Cyclizations Catalyzed By Bismuth Trifluoromethanesulfonate And Other Metal Triflates, Ram Mohan, Joshua Lacey, Peter Anzalone, Christopher Duncan, Matthew Hackert Jan 2005

A Study Of Epoxyolefin Cyclizations Catalyzed By Bismuth Trifluoromethanesulfonate And Other Metal Triflates, Ram Mohan, Joshua Lacey, Peter Anzalone, Christopher Duncan, Matthew Hackert

Scholarship

Epoxyolefin cyclizations have attracted considerable interest due to their importance in biosynthetic pathways. Bismuth trifluoromethanesulfonate as well as several other metal triflates are shown to be highly effective (0.1 mol %) catalysts for the cyclization of geraniolene oxide. The product composition is found to be more dependent on solvent and substrate concentration than on the nature of the metal triflate. Cyclization products are favored in CH2Cl2 and under high dilution conditions. Ether solvents favored acyclic products.


Future Reasoning Machines: Mind And Body, Brian Duffy, Gregory O'Hare, John Bradley, Bianca Schoen-Phelan Jan 2005

Future Reasoning Machines: Mind And Body, Brian Duffy, Gregory O'Hare, John Bradley, Bianca Schoen-Phelan

Articles

In investing energy in developing reasoning machines of the future, one must abstract away from the specific solutions to specific problems and ask what are the fundamental research questions that should be addressed. This paper aims to revisit some fundamental perspectives and promote new approaches to reasoning machines and their associated form and function. Core aspects are discussed, namely the one-mind-many-bodies metaphor as introduced in the Agent Chameleon work. Within this metaphor the agent’s embodiment form may take many guises with the artificial mind or agent potentially exhibiting a nomadic existence opportunistically migrating between a myriad of instantiated embodiments. We …


Isram: Information Security Risk Analysis Method, Bilge Karabacak, Ibrahim Sogukpinar Jan 2005

Isram: Information Security Risk Analysis Method, Bilge Karabacak, Ibrahim Sogukpinar

All Faculty and Staff Scholarship

Continuously changing nature of technological environment has been enforcing to revise the process of information security risk analysis accordingly. A number of quantitative and qualitative risk analysis methods have been proposed by researchers and vendors. The purpose of these methods is to analyze today's information security risks properly. Some of these methods are supported by a software package. In this study, a survey based quantitative approach is proposed to analyze security risks of information technologies by taking current necessities into consideration. The new method is named as Information Security Risk Analysis Method (ISRAM). Case study has shown that ISRAM yields …


A Brief History Of Bioperl, Colin Crossman, Arti K. Rai Jan 2005

A Brief History Of Bioperl, Colin Crossman, Arti K. Rai

Faculty Scholarship

Large-scale open-source projects face a litany of pitfalls and difficulties. Problems of contribution quality, credit for contributions, project coordination, funding, and mission-creep are ever-present. Of these, long-term funding and project coordination can interact to form a particularly difficult problem for open-source projects in an academic environment.

BioPerl was chosen as an example of a successful academic open-source project. Several of the roadblocks and hurdles encountered and overcome in the development of BioPerl are examined through the telling of the history of the project. Along the way, key points of open-source law are explained, such as license choice and copyright.

The …


Structural Property Relationships In Conjugated Polymers, Patrick Lynch, Luke O'Neill, J. Whelan, Mary Mcnamara, Hugh Byrne Jan 2005

Structural Property Relationships In Conjugated Polymers, Patrick Lynch, Luke O'Neill, J. Whelan, Mary Mcnamara, Hugh Byrne

Articles

The synthesis of a series of PPV derivative polymers by the Wittig-Horner reaction is described. The structure of each polymer is varied and the effects of these variations on the optical properties is explored. The effects of alkyloxy side chains is observed between the PPV derivatives Poly(-p-phenylvinylene-co-2,5-bis-octyloxy phenylvinylene.) PPV-OPV and Poly (para-2,5-bis-(n-octyloxy)-phenylvinylene) POPV. The phenyl units of the soluble PPV derivative POPV are replaced by alternate naphthyl units in the polymer Poly(2,5-bis(n-octyloxy)-1,4-phenylene vinylene-1,5-bis(n-octyloxy)-2,6-naphthylene vinylene) POPN-ONV and then fully by naphthyl units in Poly(2,6-bis-(n-octyloxy)-1,5-NaphthyleneVinylene) PONV. The addition of alkyloxy sidechains served to red shift the fluorescence emission as expected. The systematic …


Beam-Helicity Asymmetries In Double-Charged-Pion Photoproduction On The Proton, H. Bagdasaryan, M. Bektasoglu, S. Bültmann, Gail Dodge, N. Guler, C. E. Hyde-Wright, H. G. Juengst, A. Klein, S. E. Kuhn, L. M. Qin, W. Roberts, F. Sabatié, S. Tkachenko, L. B. Weinstein, J. Yun, J. Zhang, Et Al., Clas Collaboration Jan 2005

Beam-Helicity Asymmetries In Double-Charged-Pion Photoproduction On The Proton, H. Bagdasaryan, M. Bektasoglu, S. Bültmann, Gail Dodge, N. Guler, C. E. Hyde-Wright, H. G. Juengst, A. Klein, S. E. Kuhn, L. M. Qin, W. Roberts, F. Sabatié, S. Tkachenko, L. B. Weinstein, J. Yun, J. Zhang, Et Al., Clas Collaboration

Physics Faculty Publications

Beam-helicity asymmetries for the two-pion-photoproduction reaction 𝛾⃗p → p π+π- have been studied for the first time in the resonance region for center-of-mass energies between 1.35 and 2.30 GeV. The experiment was performed at Jefferson Lab with the CEBAF Large Acceptance Spectrometer using circularly polarized tagged photons incident on an unpolarized hydrogen target. Beam-helicity-dependent angular distributions of the final-state particles were measured. The large cross-section asymmetries exhibit strong sensitivity to the kinematics and dynamics of the reaction. The data are compared with the results of various phenomenological model calculations, and show that these models currently do not …


The Effects Of Satellite-Derived Vegetation Cover Variability On Simulated Land–Atmosphere Interactions In The Nams, Toshi Matsui, Venkataraman Lakshmi, Eric Small Jan 2005

The Effects Of Satellite-Derived Vegetation Cover Variability On Simulated Land–Atmosphere Interactions In The Nams, Toshi Matsui, Venkataraman Lakshmi, Eric Small

Faculty Publications

Substantial evolution of Normalized Difference Vegetation Index (NVDI)-derived vegetation cover (Fg)exists in the southwestern United States and Mexico. The intraseasonal and wet-/dry-year fluctuations of Fgare linked to observed precipitation in the North American monsoon system (NAMS). The manner in whichthe spatial and temporal variability of Fg influences the land–atmosphere energy and moisture fluxes, andassociated likelihood of moist convection in the NAMS regions, is examined. For this, the regional climatemodel (RCM) is employed, with three different Fg boundary conditions to examine the influence ofintraseasonal and wet-/dry-year vegetation variability. Results show that a strong link exists between evaporativefraction (EF), surface temperature, and …


Predicted Properties Of Microhollow Cathode Discharges In Xenon, J. P. Boeuf, L. C. Pitchford, K. H. Schoenbach Jan 2005

Predicted Properties Of Microhollow Cathode Discharges In Xenon, J. P. Boeuf, L. C. Pitchford, K. H. Schoenbach

Bioelectrics Publications

A fluid model has been developed and used to help clarify the physical mechanisms occurring in microhollow cathode discharges (MHCD). Calculated current-voltage (I-V) characteristics and gas temperatures in xenon at 100 Torr are presented. Consistent with previous experimental results in similar conditions, we find a voltage maximum in the I-V characteristic. We show that this structure reflects a transition between a low-current, abnormal discharge localized inside the cylindrical hollow cathode to a higher-current, normal glow discharge sustained by electron emission from the outer surface of the cathode. This transition, due to the geometry of …


Simulations Of Nanopore Formation And Phosphatidylserine Externalization In Lipid Membranes Subjected To A High-Intensity, Ultrashort Electric Pulse, Q. Hu, R. P. Joshi, K. H. Schoenbach Jan 2005

Simulations Of Nanopore Formation And Phosphatidylserine Externalization In Lipid Membranes Subjected To A High-Intensity, Ultrashort Electric Pulse, Q. Hu, R. P. Joshi, K. H. Schoenbach

Bioelectrics Publications

A combined MD simulator and time dependent Laplace solver are used to analyze the electrically driven phosphatidylserine externalization process in cells. Time dependent details of nanopore formation at cell membranes in response to a high-intensity (100kV∕cm), ultrashort (10ns) electric pulse are also probed. Our results show that nanosized pores could typically be formed within about 5ns. These predictions are in very good agreement with recent experimental data. It is also demonstrated that defect formation and PS externalization in membranes should begin on the anode side. Finally, the simulations confirm that PS externalization is a nanopore facilitated event, rather than the …


Levitation Using Microwave-Induced Plasmas, R. J. Exton, S. Popovic, G. C. Herring, M. Cooper Jan 2005

Levitation Using Microwave-Induced Plasmas, R. J. Exton, S. Popovic, G. C. Herring, M. Cooper

Physics Faculty Publications

The levitation of objects above a microwave horn is demonstrated. High-power microwave pulses generate a low-temperature, diffuse plasma on the surface of the horn window. The thermal effect of the surface plasma brings about a localized increase in the pressure and results in a vertical flow of air, thus levitating the object.


Investigation Of Safe And Sustainable Yields For The Sandy Complex Aquifer System In The Ergene River Basin, Thrace Region, Turkey, Şebnem Ökten, Hasan Yazicigi̇l Jan 2005

Investigation Of Safe And Sustainable Yields For The Sandy Complex Aquifer System In The Ergene River Basin, Thrace Region, Turkey, Şebnem Ökten, Hasan Yazicigi̇l

Turkish Journal of Earth Sciences

This study aims to determine the safe and sustainable yields for the Sandy Complex aquifer system in Ergene River basin in northwestern Turkey. A numerical ground-water flow model was developed for the Sandy Complex aquifer, which is the most productive and the most widespread aquifer in the basin. The finite difference ground-water model was used to simulate steady and unsteady flow in the aquifer. The model was calibrated in two steps: a steady-state calibration, by using the observed ground-water levels of January 1970; then a transient calibration, by using the observed ground-water levels for the period of January 1970 and …


Modernization Of The Hilger And Watts Guage-Block Interferometer, Michael O'Hora, Brian Bowe, Vincent Toal, Sean Peyton Jan 2005

Modernization Of The Hilger And Watts Guage-Block Interferometer, Michael O'Hora, Brian Bowe, Vincent Toal, Sean Peyton

Articles

The Hilger & Watts gauge-block interferometer was designed and manufactured commercially in the 1950s. The instrument uses isotope lamps as wavelength standards to perform absolute length calibration of gauge blocks (slip gauges) up to 100 mm in length, to an accuracy of approximately 1 ppm. It is entirely manually operated. In order to make the instrument more suitable for the modern laboratory, new hardware has been added, and a customized software package developed to automate the measurement process. This paper shows how interferograms may be imaged successfully at each of the eight available wavelengths, and the critical fringe fraction measurement …


Identification Of 'Structural Alerts' And Associated Mechanisms Of Action Of Mammary Gland Carcinogens In Female Rodents, Shanna Tommika Moss Jan 2005

Identification Of 'Structural Alerts' And Associated Mechanisms Of Action Of Mammary Gland Carcinogens In Female Rodents, Shanna Tommika Moss

LSU Master's Theses

A new structure-activity relationship (SAR) approach to modeling was utilized to study mammary gland carcinogens. A set of chemicals tested for mammary tumorigenesis that have been analyzed in the Carcinogenic Potency Database (CPDB) were subjected to several computational analyses in an attempt to predict each chemical’s carcinogenic potential. A total of six learning sets (rat and mouse mammary gland carcinogen, CPDB rat and mouse, and female-specific rodent models) were developed and validated using a SAR modeling algorithm called categorical-SAR (cat-SAR). The predictive cat-SAR program evaluates active and inactive compounds of known biological activity and predicts their biological activity from this …


Study Of The Electronic Structure Of Cafeo₃, Jinbo Yang, M. S. Kim, Qingsheng Cai, X.-D. Zhou, Harlan U. Anderson, William Joseph James, William B. Yelon Jan 2005

Study Of The Electronic Structure Of Cafeo₃, Jinbo Yang, M. S. Kim, Qingsheng Cai, X.-D. Zhou, Harlan U. Anderson, William Joseph James, William B. Yelon

Materials Science and Engineering Faculty Research & Creative Works

We have studied the charge disproportionation phenomenon in CaFeO3 using the local-spin density approximation with the on-site Coulomb interaction parameter U and exchange parameter J. The calculation reveals that the total number of the 3d electrons is about 5.1 for both Fe(1)(Fe5+) and Fe(2)(Fe3+) atoms, and that there are about 0.25 electron holes in the O-2p band. Therefore, the charge disproportionation can be more accurately described as 2d5L(Fe4+)=d5L2(Fe5+)+d5(Fe3+), where L denotes a hole in the oxygen 2p band, instead of 2d4(Fe4+)=d3(Fe5+)+d5(Fe3+). The hybridization between the Fe-3d and O-2p orbitals is stronger for Fe(1) than for Fe(2) due to the shorter …


Evaluation Of A Wind Power Parameterization Using Tower Observations, Steven M. Lazarus, Jennifer Bewley Jan 2005

Evaluation Of A Wind Power Parameterization Using Tower Observations, Steven M. Lazarus, Jennifer Bewley

Ocean Engineering and Marine Sciences Faculty Publications

The spatial and temporal components of a published wind power parameterization method are evaluated using observed winds (9 m to 90 m) from 7 years of data collected at four towers in the Kennedy Space Center/Cape Canaveral Air Force Station network. The temporal component is governed by two parameterization inputs which represent the amplitude and mean of an assumed sinusoidal diurnal variation of the ratio of the 80 m to 10 m winds, respectively. Comparison with tower observations shows that the estimates of the mean ratio are robust but biased high, indicating that the temporal variation of the observations can …


Mapping Properties Of Co-Existentially Closed Continua, Paul Bankston Jan 2005

Mapping Properties Of Co-Existentially Closed Continua, Paul Bankston

Mathematics, Statistics and Computer Science Faculty Research and Publications

A continuous surjection between compacta is called co-existential if it is the second of two maps whose composition is a standard ultracopower projection. A continuum is called co-existentially closed if it is only a co-existential image of other continua. This notion is not only an exact dual of Abraham Robinson's existentially closed structures in model theory, it also parallels the definition of other classes of continua defined by what kinds of continuous images they can be. In this paper we continue our study of co-existentially closed continua, especially how they (and related continua) behave in certain mapping situations.


2005 Undergraduate Mathematics Day Poster, University Of Dayton. Department Of Mathematics Jan 2005

2005 Undergraduate Mathematics Day Poster, University Of Dayton. Department Of Mathematics

Undergraduate Mathematics Day: Programs, Lectures, Promotional Materials

No abstract provided.


A Parallel Computing-Visualization Framework For Polycrystalline Minerals, Venkatasrirama Pavankumar Yerraguntla Jan 2005

A Parallel Computing-Visualization Framework For Polycrystalline Minerals, Venkatasrirama Pavankumar Yerraguntla

LSU Master's Theses

In this report, we have reported some preliminary results in the development of a parallel computing-visualization framework for large-scale molecular dynamics simulations of polycrystals of minerals, which are geophysically relevant for Earth’s mantle. First, we have generated the input configurations of atoms belonging to various grains distributed in the space in a way, which resembles the polycrystalline structure of the minerals. The Input configuration is developed using Voronoi geometry. Thus generated polycrystalline system is simulated using the PolyCrystal Molecular Dynamics algorithm. Performance tests conducted using up to 256 processors and a couple of millions of atoms have shown that the …


Coupled Electrical And Magnetic Properties In (La,Sr)Feo3-Δ, X.-D. Zhou, Qingsheng Cai, Jinbo Yang, M. S. Kim, William B. Yelon, William Joseph James, Y.-W. Shin, B. J. Scarfino, Harlan U. Anderson Jan 2005

Coupled Electrical And Magnetic Properties In (La,Sr)Feo3-Δ, X.-D. Zhou, Qingsheng Cai, Jinbo Yang, M. S. Kim, William B. Yelon, William Joseph James, Y.-W. Shin, B. J. Scarfino, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

This article is aimed at studying the temperature dependence oxygen nonstoichiometry, magnetic moments, Fe3+ fraction, Néel temperature and conductivity of (La,Sr)FeO3-δ. It is found that the magnetic properties in La0.60 Sr0.40 Fe3-δ is determined by Fe3+ and its concentration, and the conductance is resulted from Fe4+ ions, which act as electron holes. Both of magnetic and electrical properties were directly governed by oxygen nonstoichiometry (δ). when δ=0.2, the compound has maximum Fe3+, the saturation magnetic moments and Néel temperature are 3.8 µB and 410 °C, both at the highest level, …


2005 Program And Abstracts, University Of Dayton. Department Of Mathematics Jan 2005

2005 Program And Abstracts, University Of Dayton. Department Of Mathematics

Undergraduate Mathematics Day: Programs, Lectures, Promotional Materials

No abstract provided.


Zeros Of The Jost Function For A Class Of Exponentially Decaying Potentials, Daphne Gilbert, Alain Kerouanton Jan 2005

Zeros Of The Jost Function For A Class Of Exponentially Decaying Potentials, Daphne Gilbert, Alain Kerouanton

Articles

We investigate the properties of a series representing the Jost solution for the differential equation $-y''+q(x)y=lambda y$, $x geq 0$, $q in mathrm{L}({mathbb{R}}^{+})$. Sufficient conditions are determined on the real or complex-valued potential $q$ for the series to converge and bounds are obtained for the sets of eigenvalues, resonances and spectral singularities associated with a corresponding class of Sturm-Liouville operators. In this paper, we restrict our investigations to the class of potentials $q$ satisfying $|q(x)| leq ce^{-ax}$, $x geq 0$, for some $a>0$ and $c$ greator than 0.


On-Road Remote Sensing Of Automobile Emissions In The Omaha Area: Year 2, September 2004, Gary A. Bishop, Daniel A. Burgard, Donald H. Stedman Jan 2005

On-Road Remote Sensing Of Automobile Emissions In The Omaha Area: Year 2, September 2004, Gary A. Bishop, Daniel A. Burgard, Donald H. Stedman

Fuel Efficiency Automobile Test Publications

No abstract provided.


Flaws In Orr’S Laws (And The Paradigm That Produced Them): An Abbreviated Response, Nicole Haynes Mccoy, Sheldon Atwood Jan 2005

Flaws In Orr’S Laws (And The Paradigm That Produced Them): An Abbreviated Response, Nicole Haynes Mccoy, Sheldon Atwood

Behavioral Education for Human, Animal, Vegetation, and Ecosystem Management (BEHAVE)

Conservation of biological diversity is often hampered by ignorance and short-sightedness. Yet knowledge is not enough; biology illuminates ecological relationships, but it alone cannot conserve ecosystems. Therefore, we agree that there is no higher priority for conservation biologists than to improve their understanding of economics (Orr 2004, Law 1). Unfortunately, from many of his comments and the tenor of subsequent responses (Hayes 2004; Vitek 2004; Lovejoy 2004), it is evident that economics and, more important, parallels between ecology and economics are misunderstood, implying the two disciplines are more different than they are and that knowledge of economics is primarily needed …


Particle Size, Caco3, Chemical, Magnetic, And Age Data From Surficial Deposits In And Around Canyonlands National Park, Utah, Harland Goldstein, Richard Reynolds, Marith Reheis, James Yount, Paul Lamothe, Helen Roberts, John Mcgeehin Jan 2005

Particle Size, Caco3, Chemical, Magnetic, And Age Data From Surficial Deposits In And Around Canyonlands National Park, Utah, Harland Goldstein, Richard Reynolds, Marith Reheis, James Yount, Paul Lamothe, Helen Roberts, John Mcgeehin

Canyonlands Research Bibliography

No abstract provided.


How Generic Scale Invariance Influences Quantum And Classical Phase Transitions, D. Belitz, T. Kirkpatrick, Thomas Vojta Jan 2005

How Generic Scale Invariance Influences Quantum And Classical Phase Transitions, D. Belitz, T. Kirkpatrick, Thomas Vojta

Physics Faculty Research & Creative Works

This review discusses a paradigm that has become of increasing importance in the theory of quantum phase transitions, namely, the coupling of the order-parameter fluctuations to other soft modes and the resulting impossibility of constructing a simple Landau-Ginzburg-Wilson theory in terms of the order parameter only. The soft modes in question are manifestations of generic scale invariance, i.e., the appearance of long-range order in whole regions in the phase diagram. The concept of generic scale invariance and its influence on critical behavior is explained using various examples, both classical and quantum mechanical. The peculiarities of quantum phase transitions are discussed, …


Tunable Conductivity And Conduction Mechanism In An Ultraviolet Light Activated Electronic Conductor, Mariana I. Bertoni, Thomas O. Mason, Julia E. Medvedeva, Arthur J. Freeman, Kenneth R. Poeppelmeier, B. Delley Jan 2005

Tunable Conductivity And Conduction Mechanism In An Ultraviolet Light Activated Electronic Conductor, Mariana I. Bertoni, Thomas O. Mason, Julia E. Medvedeva, Arthur J. Freeman, Kenneth R. Poeppelmeier, B. Delley

Physics Faculty Research & Creative Works

A tunable conductivity has been achieved by controllable substitution of an ultraviolet light activated electronic conductor. The transparent conducting oxide system H-doped Ca12-xMgxAl14O33 (x=0,0.1,0.3,0.5,0.8,1.0) presents a conductivity that is strongly dependent on the substitution level and temperature. Four-point dc-conductivity decreases with x from 0.26 S/cm (x=0) to 0.106 S/cm (x=1) at room temperature. At each composition the conductivity increases (reversibly with temperature) until a decomposition temperature is reached; above this value, the conductivity drops dramatically due to hydrogen recombination and loss. The observed conductivity behavior is consistent with the predictions of our first principles density functional calculations for the Mg-substituted …