Physical Sciences and Mathematics Commons^™

Solution And Solid State Interactions Between Ionic Π-Systems, Jing Chen

University of Kentucky Doctoral Dissertations

Although attractive interactions between π systems (π-π interaction) have been known for many years, understanding of its origin is still incomplete. Quantitative measuring of π-stacking is challenging due to the weak nature of the π-π interaction. This dissertation aims at elucidating a quantitative conformational analysis by NMR ring current anisotropy of an organic compound capable of intramolecular π-stacking in solution and studying charge effects on the stacking of π-systems. This dissertation offers four contributions to the area. (1) A general approach to four-state, conformational analysis based on the magnetic anisotropy of molecules undergoing fast dynamic exchange is described. (2) Study …

Potential Of Vibrational Spectroscopy In The Diagnosis Of Human Tumours., Eoghan O'Faolain

Doctoral

Just fewer than 20,000 people are annually diagnosed with some form of cancer in Ireland and one in three people are likely to contract some form of cancer by age 74. With the number of cases increasing at an annual rate of 2%, the early detection and treatment of cancer is becoming increasingly important. Both IR and Raman spectroscopy offer the potential for real time, quantitative detection of cancer and even precancer. This study investigates the potential of Raman and Fourier transform infrared, both benchtop and synchrotron spectroscopies for the detection of cervical cancer. The tissue was classified and its …

Fast Bounds On The Distribution Of Smooth Numbers, Scott T. Parsell, Jonathan P. Sorenson

Scholarship and Professional Work - LAS

In this paper we present improvements to Bernstein’s algorithm, which finds rigorous upper and lower bounds for (x, y).

Loop Current Warming By Hurricane Wilma, Lie-Yauw Oey, Tal Ezer, Dong-Ping Wang, S. J. Fan, Xun-Qiang Yin

CCPO Publications

Hurricanes mix and cool the upper ocean, as shown here in observations and modeling of the Caribbean Sea and the Gulf of Mexico during the passage of hurricane Wilma. Curiously, the upper ocean around the Loop Current warmed prior to Wilma's entrance into the Gulf. The major cause was increased volume and heat transports through the Yucatan Channel produced by storm-induced convergences in the northwestern Caribbean Sea. Such oceanic variability may have important impacts on hurricane predictions.

Topographic Influence On Overflow Dynamics: Idealized Numerical Simulations And The Faroe Bank Channel Overflow, Tal Ezer

CCPO Publications

Properties of the North Atlantic Deep Water (NADW) depend on mixing that occurs in the Denmark Strait (DS) and the Faroe Bank Channel (FBC) overflow regions. How the sill's topography in those regions may affect mixing processes and downstream variability is thus investigated using a high-resolution terrain-following ocean model. Model results agree with observations that show enhanced mixing and entrainment downstream from the sill; however, mixing seems to occur over a longer distance downstream from the FBC sill and more abruptly downstream from the DS sill. Sensitivity experiments with various FBC sill widths demonstrate that the narrow sill is responsible …

Projects That Assist With Content In A Traditional Organic Chemistry Course, John J. Esteb, John R. Magers, Luanne Mcnulty, Anne M. Wilson

Scholarship and Professional Work - LAS

Projects that engage undergraduate students in content-based courses, such as organic chemistry, must relate to the material and provide useful tools for the divergent needs of the students. There are few examples of these types of projects in the literature. Herein, we describe two projects, the reaction notebook and the end-of-semester synthesis activity. Each project is designed to stimulate student ownership of the material and leads to engagement with the content of the course.

Circulation, Vol. 13, No. 1, Center For Coastal Physical Oceanography, Old Dominion University, John M. Klinck

CCPO Circulation

Winter 2006 issue of CCPO Circulation featuring article "Biological Processes in Bivalves as Revealed by Numerical Models" by Dr. John Klinck

Floss As Democratic Principle, Mark Perry, Brian Fitzgerald

Law Publications

No abstract provided.

Evaluating The Deep-Sea Coral Acanella From Hawaii As A Paleoceanographic Archive, Geraldine Hourigan Lantier

Geology Theses and Dissertations

Deep-sea corals have emerged as potential proxies of changing paleoceanographic properties. The utility of deep-sea corals for the purpose of interpreting paleoclimatic reconstructions is still in the discovery phase. However, long life spans, a relatively stable habitat, and unique growth geometry provide support to the growing body of research that has identified deep-sea corals as indicators of past climate and ocean properties. Two colonies of Acanella were collected from the permanent thermocline at depths between 414 and 437 m in the Makapuu Coral Bed, Oahu, HI in 1997 by submersible. Here I present results from a pilot study of the …

Thermochronological Evidence For Neogene Incision Of The Rio Pativilca Canyon, Northern Peru, Matthew James Montario

Geology Theses and Dissertations

The Peruvian Andes have attained modern elevations of ~4000 m. Many peaks along the drainage divide are in excess of 5500 m with ~2-3 km of vertical relief, and canyons cut into the western edge have up to 3.5 km relief. The Rio Pativilica Canyon is cut into a folded Mesozoic marine sequence intruded by granitic rocks of the Coastal Batholith, which are overlain by Tertiary volcanics: this canyon has relief in excess of ~3 km. Based on geomorphological evidence, two episodes of valley incision cut the Puna erosional surface: 1) The Vallé stage, which is characterized by broad valleys …

The Effects Of Land Use Changes On Soil Carbon In The Russian Steppe, Andrew M. Ratigliano

Geology Theses and Dissertations

Increasing atmospheric CO2 levels within the past few centuries have led to many studies about the global carbon cycle. An important aspect in balancing the modern global carbon budget revolves around a missing sink of carbon. It is thought that the carbon accumulation in soil may be a significant component in this loss. As changes in land use under natural conditions have increased over the years, it is not well understood how these changes may affect the soil carbon. A useful technique in determining these changes are with the use of archived samples. Within a Russian steppe preserve that has …

Thermochronology And Provenance Of The Yakutat Terrane, Southern Alaska Based On Fission-Track And U/Pb Analysis Of Detrital Zircon, Stephanie Ellen Perry

Geology Theses and Dissertations

Northward transport of the Yakutat terrane along the Transition and Queen Charlotte-Fairweather transform faults led to Neogene collision of the Yakutat terrane with the southern continental Alaska margin. Northward translation resulted in a stratigraphy that records the erosion of thermotectonic terranes along its path. The strata of the Yakutat terrane includes the Lower Oligocene to Lower Eocene Kulthieth Formation, the Upper Eocene to Lower Miocene Poul Creek Formation and the Miocene-Pleistocene Yakataga Formation. Detrital zircon fission-track (DZFT) ages from stratigraphically coordinated samples collected in the Northern Robinson Mountains yield provenance information of the units that can shed light on their …

Assessing The Paleoceanographic Potential Of The Coral Montipora Venosa At Fanning Atoll, Central Equatorial Pacific, Alexa Stolorow

Geology Theses and Dissertations

As interest in global climate change increases, so does the need for better and more extensive climate proxies. The central equatorial Pacific has been established as the region with the largest ENSO-related sea surface temperature (SST) and precipitation (PPT) anomalies, which are known to impact global interannual climate variability. To date, the coral genus Porites has been most commonly utilized for coral-based paleo-reconstructions of ENSO and lower frequency phenomena. However, due to questions of biological artifacts in coral, to more fully understand coral-based reconstruction, different coral genera need to be analyzed.
In this study, oxygen (δ18O) and carbon (δ13C) isotopic …

Mapping Of A Detachment Fault In Kythera Island And Study Of The Related Structural Shear Sense Indicators, Antonios Marsellos

Geology Theses and Dissertations

Kythera Island is located on the prominent submarine horst between Crete and the Peloponnese in the southwestern part of the Aegean. The structure of Kythera is characterized by a pile of tectonic slices derived from different paleogeographic zones. The upper unmetamorphosed units comprise pelagic limestones and cherts of Pindos zone emplaced by thrusting in the Eocene on top of Tripolis zone neritic limestones. These units are separated from the lower metamorphosed unit of Phyllite-Quartzite (PQU) exposed in the northern part of Kythera by an extensional detachment fault of Late Miocene age. The lower tectonic unit of PQU was affected by …

Optimization Of Long Range Electron Transfer For Solar Energy, Randall H. Goldsmith

Link Foundation Energy Fellowship Reports

Organic photovoltaics have the potential to become an accessible form of alternative energy production because of their ease of manufacture via traditional printing techniques and consequent low cost.1 However, the simplicity of device manufacture belies the complex cascade of processes that allow light to be efficiently converted into electrical power.2 Electron transfer (ET) events constitute the most critical steps. ET is known to be governed by a complex function of many system-specific variables including distance, orientation, and energetics of the donor and acceptor species.3

Securing Networks Of Information Age, Bilge Karabacak, Mert Uneri

All Faculty and Staff Scholarship

Internet and IT devices are being used for business and entertainment more frequently. Internet has been becoming a vital part of social fabric. Threats to Internet and other complex commercial networks are solid and growing. Globalization and the need for interoperability complicates security of IT Networks and Internet. Cyber threats have an important potential damage capacity. Proactive security methodologies are needed to protect valuable information. According to the situation described above, the purpose of this paper is to examine the current trends in network security, and to propose a roadmap for protecting information from cyber threats.

Paleontology Of The Coastal Plain Province., David R. Schwimmer

Faculty Bibliography

No abstract provided.

Simultaneous Transitional And Multiplicative Tiling And Wavelet Sets In R2, Eugen J. Ionascu

Faculty Bibliography

Simultaneous tiling for several different translational sets has been studied rather extensively, particularly in connection with the Steinhaus problem. The study of orthonormal wavelets in recent years, particularly for arbitrary dilation matrices, has led to the study of multiplicative tilings by the powers of a matrix. In this paper we consider the following simultaneous tiling problem: Given a lattice in Z ∈ Rd and a matrix A ∈ GL (d, R), does there exist a measurable set T such that both {T + α : α ∈ L} and {AnT : n ∈ Z} are tilings of Rd? This problem …

The Communicator, Volume [2], Issue [1], May 2006

The Communicator: News from the Nebraska Cooperative Fish and Wildlife Research Unit

New Faces

News to Celebrate!

Current Research

Monitoring, Mapping and Risk Assessment for

Non-Indigenous Invasive Species in Nebraska

Landowner Incentives Program (LIP)

Impact of White Perch on Walleye

Amphibians in the Rainwater Basin

Spatial Risk Assessment of Invasive Species

Impacts on Native Species in Nebraska

Resilience in Ecosystems

Cross-Scale Structure in Ecosystems

Diversity and Ecological Functions

Boat Safety Certification

Graduate Students (Elizabeth (Beth) Forbus; Nathan (Nate) Gosch; Aaron Lotz; Donald (Don) Wardwell; Thaddeus (Thad) Miller)

WE’RE MOVING!

Teaching

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The Equation, Winter 2006, College Of Science And Mathematics, Wright State University

College of Science and Mathematics Newsletters

This 6 page newsletter discusses various happenings within the College of Science and Mathematics. It begins with a letter from the dean, and continues on with news, events, alumni news, and other community news.

Fm-Test: A Fuzzy-Set-Theory-Based Approach To Differential Gene Expression Data Analysis, Lily R. Liang, Shiyong Lu, Xuena Wang, Yi Lu, Vinay Mandal, Dorrelyn Patacsil, Deepak Kumar

Wayne State University Associated BioMed Central Scholarship

Abstract

Background

Microarray techniques have revolutionized genomic research by making it possible to monitor the expression of thousands of genes in parallel. As the amount of microarray data being produced is increasing at an exponential rate, there is a great demand for efficient and effective expression data analysis tools. Comparison of gene expression profiles of patients against those of normal counterpart people will enhance our understanding of a disease and identify leads for therapeutic intervention.

Results

In this paper, we propose an innovative approach, fuzzy membership test (FM-test), based on fuzzy set theory to identify disease associated genes from microarray …

Limited Proteolysis Of Human Histone Deacetylase 1, Nayana Kamath, Paulina Karwowska-Desaulniers, Mary Kay H. Pflum

Wayne State University Associated BioMed Central Scholarship

Abstract

Background

Histone deacetylase (HDAC) proteins are associated with cell proliferation, differentiation, apoptosis, and cancer. Specifically, HDAC1 is linked with cell growth, a hallmark of cancer formation. HDAC1 is a phosphoprotein and phosphorylation at S421 and S423 promotes HDAC1 enzymatic activity and protein association. While single and double point mutants of HDAC1 at S421 and S423 appear functionally similar, the evidence suggests that HDAC1 is phosphorylated simultaneously at both S421 and S423 in vivo. Additional experiments are necessary to probe the role of double phosphorylation of HDAC1 at S421 and S423.

Results

To characterize HDAC1 phosphorylation at S421 and S423, …

A Database And Tool, Im Browser, For Exploring And Integrating Emerging Gene And Protein Interaction Data For Drosophila, Svetlana Pacifico, Guozhen Liu, Stephen Guest, Jodi R. Parrish, Farshad Fotouhi, Russell L. Finley Jr

Wayne State University Associated BioMed Central Scholarship

Abstract

Background

Biological processes are mediated by networks of interacting genes and proteins. Efforts to map and understand these networks are resulting in the proliferation of interaction data derived from both experimental and computational techniques for a number of organisms. The volume of this data combined with the variety of specific forms it can take has created a need for comprehensive databases that include all of the available data sets, and for exploration tools to facilitate data integration and analysis. One powerful paradigm for the navigation and analysis of interaction data is an interaction graph or map that represents proteins …

The Environmental Effects Of War, Philip Swintek

Student Theses 2001-2013

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Vector Theory Of Spontaneous Lorentz Violation, Shu Hong Fung

Undergraduate Research Symposium (UGRS)

Classical electromagnetism predicts two massless propagating modes, which are known as the two polarizations of the photon. On the other hand, if the Lorentz symmetry of classical electromagnetism is spontaneously broken, the new theory will still have two massless Nambu-Goldstone modes resembling the photon. If the Lorentz symmetry is broken by a bumblebee potential that allows for excitations out of the minimum, then massive modes arise. Furthermore, in curved spacetime, such massive modes will be created through a process other than the usual Higgs mechanism because of the dependence of the bumblebee potential on both the vector field and the …

Recommended Management Arrangements For The West Coast Commercial 'Wetline' Fishery. A Report To The Minister For Fisheries., West Coast And Gascoyne Management Planning Panel.

Fisheries management papers

No abstract provided.

Recommended Access And Allocation Criteria For The West Coast And Gascoyne Commercial 'Wetline' Fisheries. A Report To The Ministry Of Fisheries., The Commercial Access Panel.

Fisheries management papers

The CAP’s primary responsibility was to develop criteria for access and allocation within the context of the management framework developed by the MPP. It is therefore important that this management paper is read in conjunction with the papers prepared by the MPP that outline the recommended management arrangements for the Gascoyne (Fisheries Management Paper No. 205) and the West Coast (Fisheries Management Paper No. 206) regions.

Assessment Of Western Rock Lobster Strategic Management Options. How Do Quota Management Systems Work In Rock Lobster Fisheries? Vol. 4, Tim Bray, Steven Gill, Ron Edwards

Fisheries management papers

Quota management systems are now in place for the New Zealand, Tasmanian and South Australian rock lobster fisheries. New Zealand was the first to move to QMS (1989), followed by the Southern Zone of South Australia (1993), Tasmania (1998) and Northern Zone South Australia (2001). As part of a review of the system of management used for the West Coast Rock Lobster Fishery, a West Australian delegation visited New Zealand, Tasmania and South Australia in 2004 to learn more about the management systems in place for their respective rock lobster fisheries.

Assessment Of Western Rock Lobster Strategic Management Options. An Overview Of Bio-Economic, Sociological And Comparative Analysis. Vol. 1., Department Of Fisheries.

Fisheries management papers

The purpose of this review paper is to present the options for managing the fishery and to compare the current fishing effort control system to a more flexible one and to two types of individually transferable quota (ITQ) management systems, one with the current effort controls and the other without or with reduced1 effort controls.

Assessment Of Western Rock Lobster Strategic Management Options. A Bio-Economic Evaluation Of Management Options For The West Coast Rock Lobster Fishery. Vol. 2, Economic Research Associates Pty Ltd

Fisheries management papers

Economic Research Associates (ERA) was commissioned to evaluate the relative ‘socio-economic’ benefits of alternative management Scenarios for the Western Rock Lobster Managed Fishery. This study is intended as input into industry’s consideration of the future management policy direction for the fishery.