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2007

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Articles 31 - 60 of 6758

Full-Text Articles in Physical Sciences and Mathematics

Science Plan For Potential 2008 Experimental High Flow At Glen Canyon Dam, Grand Canyon Monitoring And Research Center Dec 2007

Science Plan For Potential 2008 Experimental High Flow At Glen Canyon Dam, Grand Canyon Monitoring And Research Center

All U.S. Government Documents (Utah Regional Depository)

No abstract provided.


Model-Robust Bayesian Regression And The Sandwich Estimator, Adam A. Szpiro, Kenneth M. Rice, Thomas Lumley Dec 2007

Model-Robust Bayesian Regression And The Sandwich Estimator, Adam A. Szpiro, Kenneth M. Rice, Thomas Lumley

UW Biostatistics Working Paper Series

PLEASE NOTE THAT AN UPDATED VERSION OF THIS RESEARCH IS AVAILABLE AS WORKING PAPER 338 IN THE UNIVERSITY OF WASHINGTON BIOSTATISTICS WORKING PAPER SERIES (http://www.bepress.com/uwbiostat/paper338).

In applied regression problems there is often sufficient data for accurate estimation, but standard parametric models do not accurately describe the source of the data, so associated uncertainty estimates are not reliable. We describe a simple Bayesian approach to inference in linear regression that recovers least-squares point estimates while providing correct uncertainty bounds by explicitly recognizing that standard modeling assumptions need not be valid. Our model-robust development parallels frequentist estimating equations and leads to intervals …


Imaging Thermal Stratigraphy In Freshwater Lakes Using Georadar, John H. Bradford, Cody R. Johnson, Troy Brosten, James P. Mcnamara, Michael N. Gooseff Dec 2007

Imaging Thermal Stratigraphy In Freshwater Lakes Using Georadar, John H. Bradford, Cody R. Johnson, Troy Brosten, James P. Mcnamara, Michael N. Gooseff

CGISS Publications and Presentations

Thermal stratification exerts significant control over biogeochemical processing in freshwater lakes. Thus, the temporal and spatial distribution of the thermal structure is an important component in understanding lake ecosystems. We present the first reported observations of lake thermal stratification from surface based georadar measurements acquired over two small freshwater lakes. This method is very useful because it can provide rapid acquisition of 2D or 3D lotic stratification.


Toward A New Generation Of Ice Sheet Models, Christopher M. Little, Michael Oppenheimer, Richard B. Alley, Venkatramani Balaji, Garry K. C. Clarke, Thomas L. Delworth, Robert Hallberg, David Holland, Christina L. Hulbe, Stan Jacobs, Jesse V. Johnson, Hiram Levy, William Lipscomb, Shawn J. Marshall, Byron R. Parizek, Antony J. Payne, Gavin A. Schmidt, Ronald J. Stouffer, David G. Vaughan, Michael Winton Dec 2007

Toward A New Generation Of Ice Sheet Models, Christopher M. Little, Michael Oppenheimer, Richard B. Alley, Venkatramani Balaji, Garry K. C. Clarke, Thomas L. Delworth, Robert Hallberg, David Holland, Christina L. Hulbe, Stan Jacobs, Jesse V. Johnson, Hiram Levy, William Lipscomb, Shawn J. Marshall, Byron R. Parizek, Antony J. Payne, Gavin A. Schmidt, Ronald J. Stouffer, David G. Vaughan, Michael Winton

Computer Science Faculty Publications

This report summarizes the conclusions and recommendations of a 1-day workshop on ice sheet modeling held at the NOAA Geophysical Fluid Dynamics Laboratory on 8 January 2007, sponsored by NOAA and by the Program in Science, Technology, and Environmental Policy of the Woodrow Wilson School of Public and International Affairs at Princeton University, N. J.


Tidal Asymmetry And Residual Circulation Over Linear Sandbanks And Their Implication On Sediment Transport: A Process-Oriented Numerical Study, Rosario Sanay, George Voulgaris, John C. Warner Dec 2007

Tidal Asymmetry And Residual Circulation Over Linear Sandbanks And Their Implication On Sediment Transport: A Process-Oriented Numerical Study, Rosario Sanay, George Voulgaris, John C. Warner

Faculty Publications

A series of process-oriented numerical simulations is carried out in order to evaluate the relative role of locally generated residual flow and overtides on net sediment transport over linear sandbanks. The idealized bathymetry and forcing are similar to those present in the Norfolk Sandbanks, North Sea. The importance of bottom drag parameterization and bank orientation with respect to the ambient flow is examined in terms of residual flow and overtide generation, and subsequent sediment transport implications are discussed. The results show that although the magnitudes of residual flow and overtides are sensitive to bottom roughness parameterization and bank orientation, the …


Tomography Of The Darcy Velocity From Self-Potential Measurements, A. Jardani, A. Revil, A. Bolève, A. Crespy, J.-P. Dupont, W. Barrash, Bwalya Malama Dec 2007

Tomography Of The Darcy Velocity From Self-Potential Measurements, A. Jardani, A. Revil, A. Bolève, A. Crespy, J.-P. Dupont, W. Barrash, Bwalya Malama

Natural Resources Management and Environmental Sciences

An algorithm is developed to interpret self-potential (SP) data in terms of distribution of Darcy velocity of the ground water. The model is based on the proportionality existing between the streaming current density and the Darcy velocity. Because the inverse problem of current density determination from SP data is underdetermined, we use Tikhonov regularization with a smoothness constraint based on the differential Laplacian operator and a prior model. The regularization parameter is determined by the L-shape method. The distribution of the Darcy velocity depends on the localization and number of non-polarizing electrodes and information relative to the distribution of the …


Measurement Of The Pp̅Wz + X Cross Section At √S =1.96 Tev And Limits On Wwz Trilinear Gauge Couplings, V. M. Abazov, Kenneth A. Bloom, Gregory R. Snow, D0 Collaboration Dec 2007

Measurement Of The Pp̅ → Wz + X Cross Section At √S =1.96 Tev And Limits On Wwz Trilinear Gauge Couplings, V. M. Abazov, Kenneth A. Bloom, Gregory R. Snow, D0 Collaboration

Kenneth Bloom Publications

We present measurements of the process pp̅WZ + X → ℓ′νℓℓ&#; at √s = 1.96 TeV, where ℓ and ℓ′ are electrons or muons. Using 1 fb-1 of data from the D0 experiment, we observe 13 candidates with an expected background of 4.5 ± 0.6 events and measure a cross section σ(WZ) = 2.7-1.3+1.7 pb. From the number of observed events and the Z boson transverse momentum distribution, we limit the trilinear WWZ gauge couplings to -0.17 ≤ λZ ≤ 0.21(ΔκZ= 0) at the 95% C.L. for a form …


Observation Of P-Wave Threshold Behavior In Electron Attachment To F2 Molecules, M. Braun, M.-W. Ruf, Ilya I. Fabrikant, H. Hotop Dec 2007

Observation Of P-Wave Threshold Behavior In Electron Attachment To F2 Molecules, M. Braun, M.-W. Ruf, Ilya I. Fabrikant, H. Hotop

Ilya Fabrikant Publications

Using the high resolution laser photoelectron attachment method, we demonstrate that the cross section for F- formation due to electron capture by F2 (X1Σg+) molecules at very low energies exhibits p-wave threshold behavior. This finding confirms the theoretical expectation that low-energy attachment to F2 proceeds through the F2-(2 Σu+) p-wave shape resonance in contrast with previous experimental claims for s-wave threshold behavior.


Tomography Of The Darcy Velocity From Self-Potential Measurements, A. Jardani, A. Revil, A. Bolève, A. Crespy, J.-P. Dupont, Warren Barrash, Bwalya Malama Dec 2007

Tomography Of The Darcy Velocity From Self-Potential Measurements, A. Jardani, A. Revil, A. Bolève, A. Crespy, J.-P. Dupont, Warren Barrash, Bwalya Malama

CGISS Publications and Presentations

An algorithm is developed to interpret self-potential (SP) data in terms of distribution of Darcy velocity of the ground water. The model is based on the proportionality existing between the streaming current density and the Darcy velocity. Because the inverse problem of current density determination from SP data is underdetermined, we use Tikhonov regularization with a smoothness constraint based on the differential Laplacian operator and a prior model. The regularization parameter is determined by the L-shape method. The distribution of the Darcy velocity depends on the localization and number of non-polarizing electrodes and information relative to the distribution of the …


Biogeochemical Evolution Of Cryoconite Holes On Canada Glacier, Taylor Valley, Antarctica, Elizabeth A. Bagshaw, Martyn Tranter, Andrew G. Fountain, Kathleen A. Welch, Hassan J. Basagic, W. Berry Lyons Dec 2007

Biogeochemical Evolution Of Cryoconite Holes On Canada Glacier, Taylor Valley, Antarctica, Elizabeth A. Bagshaw, Martyn Tranter, Andrew G. Fountain, Kathleen A. Welch, Hassan J. Basagic, W. Berry Lyons

Geography Faculty Publications and Presentations

The cryoconite holes of the McMurdo Dry Valleys are simple, closed biogeochemical systems involving water, ice, mineral and organic debris, which serve as ecosystems for consortia of microorganisms. This study is the first to document the seasonal and annual chemical evolution of solutes in cryoconite holes. Samples of glacier ice, frozen cryoconite holes and those containing water were collected during the austral summer of 2005–2006. The isolation age was calculated from the excess Cl‾ in the holes, and varied from 0 to 5 years (a), consistent with the last hot summer when the cryoconite holes were open to the atmosphere. …


Controlling The Inhibition Of The Sarcoplasmic Ca2+-Atpase By Tuning Phospholamban Structural Dynamics, Kim Ha, Nathaniel J. Traaseth, Raffaello Verardi, Jamillah Zamoon, Alessandro Cembran, Christine B. Karim, Gianluigi Veglia Dec 2007

Controlling The Inhibition Of The Sarcoplasmic Ca2+-Atpase By Tuning Phospholamban Structural Dynamics, Kim Ha, Nathaniel J. Traaseth, Raffaello Verardi, Jamillah Zamoon, Alessandro Cembran, Christine B. Karim, Gianluigi Veglia

Kim N. Ha, Ph.D.

No abstract provided.


Review Of The Triumph Of Numbers By I. B. Cohen, H L. Vacher Dec 2007

Review Of The Triumph Of Numbers By I. B. Cohen, H L. Vacher

Numeracy

I. Bernard Cohen, The Triumph of Numbers: How Counting Shaped Modern Life. (New York: W.W. Norton & Company, 2005). 209 pp. $24.95 (USA). ISBN 0-393-05769-0.

The premier historian of science ends his career telling how the world has become awash in numbers—“how numbers entered the conduct of life and of government, the understanding of nature, and the analysis of societies.” The stories begin with Kepler and end with Florence Nightingale. In between, major players include Galileo, Harvey, Leeuwenhoek, and Halley; Graunt and Petty; Jefferson and Franklin; Lavoisier, Sinclair, Pinel and Louis; Guerry and Quetelet. The book tells of the spread …


Birds–Dead And Deadly: Why Numeracy Needs To Address Social Construction, Joel Best Dec 2007

Birds–Dead And Deadly: Why Numeracy Needs To Address Social Construction, Joel Best

Numeracy

Sociologists use the term social construction to refer to the processes by which people assign meaning to their world. This paper argues that numeracy education needs to address social construction. In particular, thinking critically about the statistics the news media report regarding social issues requires understanding the competitive nature of the social problems marketplace, and the social forces that allow questionable numbers to receive widespread public attention. Such critiques must incorporate more than assessing how the numbers were calculated; they must consider the social construction of particular statistics. Two recent examples—claims about the number of birds killed flying into windows, …


Development Of Case Stories By Interviewing Students About Their Critical Moments In Science, Math, And Engineering Classes, Vicki V. May, Thomas H. Luxon, Kathy Weaver, Rachel Esselstein, Cynthia Char Dec 2007

Development Of Case Stories By Interviewing Students About Their Critical Moments In Science, Math, And Engineering Classes, Vicki V. May, Thomas H. Luxon, Kathy Weaver, Rachel Esselstein, Cynthia Char

Numeracy

Dartmouth’s Critical Moments project is designed to promote discussions among faculty and graduate students about the retention of students, particularly women and minorities, in science, math, and engineering (SME) disciplines. The first phase of the ongoing project has been the development of four case stories, which are fictionalized composites drawn from surveys and interviews of real Dartmouth students. The surveyed population was 125 students in general chemistry. Of the 77 who agreed to be interviewed, 61 reported having experienced a critical moment – i.e., a positive or negative event or time that had a significant impact on the student’s academic …


Teachers Talk: Pressure Points In The K-8 Mathematics Curriculum, Kim Rheinlander, Dorothy Wallace, Wells Morrison, Daniel Ansari, Donna Coch, B. Venus Williams Dec 2007

Teachers Talk: Pressure Points In The K-8 Mathematics Curriculum, Kim Rheinlander, Dorothy Wallace, Wells Morrison, Daniel Ansari, Donna Coch, B. Venus Williams

Numeracy

Forty K-8 teachers participated in small, in-depth, facilitated discussions about "pressure points" in the curriculum. We define a pressure point as a topic, skill, or concept that is crucial to future mathematics learning but which many or most students do not master to the extent expected at a given grade level. They are issues that persist from one grade level to the next; eventually they impair the ability of students to succeed in technical disciplines. The teachers identified a number of pressure points; we focus on an understanding of place value and "reasonableness" of answer as two examples that were …


Scientifically Based Research In Quantitative Literacy: Guidelines For Building A Knowledge Base, Richard L. Scheaffer Dec 2007

Scientifically Based Research In Quantitative Literacy: Guidelines For Building A Knowledge Base, Richard L. Scheaffer

Numeracy

Research in quantitative literacy (QL) is in its infancy, so now is the time to begin a regimen for healthy growth into adulthood. As a new discipline still defining itself, QL has the opportunity to build a sound infrastructure for accumulating a solid body of interconnected research that will serve the discipline well in years to come. To that end, much can be learned from recent studies of the weaknesses of mathematics education research and recommendations on how to overcome them. Mathematics education lacks a strong research foundation, one that is scientific, cumulative, interconnected, and intertwined with teaching practice. These …


Evolution Of Numeracy And The National Numeracy Network, Bernard L. Madison, Lynn Arthur Steen Dec 2007

Evolution Of Numeracy And The National Numeracy Network, Bernard L. Madison, Lynn Arthur Steen

Numeracy

The National Numeracy Network grew from heightened awareness of the complex and sophisticated nature of quantitative literacy and the resulting need for interdisciplinary attention to education for quantitative literacy in schools and colleges. This complexity and sophistication applies especially to the US where it is fueled by an agile economy and the needs of a democratic society. This paper describes the environment surrounding the National Numeracy Network’s establishment, some of its activities, and some complementary and synergistic actions by other professional societies. The paper concludes with a sample of quantitative literacy programs in colleges and universities


The Scope Of Numeracy, H L. Vacher, Dorothy Wallace Dec 2007

The Scope Of Numeracy, H L. Vacher, Dorothy Wallace

Numeracy

No abstract provided.


A Harmadik Világháború. Minden Héten Háromszor., Pal R. Molnar Dec 2007

A Harmadik Világháború. Minden Héten Háromszor., Pal R. Molnar

Pal R. Molnar

Pesszimista jóslatok szerint közeledik a harmadik világháború, a világégés. Ezt a háborút valószínűleg atomfegyverekkel vívják, ami évezredekre megmérgezi a földet és elhozza az emberiség végét.


The World War Iii. Three Times In Every Week, Pal R. Molnar Dec 2007

The World War Iii. Three Times In Every Week, Pal R. Molnar

Pal R. Molnar

The pessimistic prophecies say the third world war, the ‘world burning’ is approaching. This war probably will fight by nuclear weapons, it will poison the Earth for thousands of years, and it will bring the end of mankind.


An Ab Initio Study Of The Structures, Vibrational Spectra, And Energetics Of Alshx (X = –1, 0, +1), Sujata Guha, Joseph S. Francisco Dec 2007

An Ab Initio Study Of The Structures, Vibrational Spectra, And Energetics Of Alshx (X = –1, 0, +1), Sujata Guha, Joseph S. Francisco

Chemistry Faculty Research

The ground state of aluminum hydrosulfide, AlSHX (where X = − 1,0, + 1), has been examined using high-level ab initio electronic structure calculations at the CCSD(T) level with an augmented correlation-consistent basis set. The geometries have been optimized up through the aug-cc-pV5Z level and vibrational frequencies calculated using the aug-cc-pV5Z basis set. The energetic properties of AlSH are also examined. The adiabatic ionization potential and electron affinity of AlSH are calculated to be 198.5 and 7.7 kcal mol−1, respectively. Dissociation of AlSH into AlS + H will require 78.2 kcal mol−1 of energy, and the Al-S bond energy is …


Merged Ionization/Dissociation Fronts In Planetary Nebulae, William J. Henney, R. J. R. Williams, Gary J. Ferland, Gargi Shaw, C. R. O'Dell Dec 2007

Merged Ionization/Dissociation Fronts In Planetary Nebulae, William J. Henney, R. J. R. Williams, Gary J. Ferland, Gargi Shaw, C. R. O'Dell

Physics and Astronomy Faculty Publications

The hydrogen ionization and dissociation front around an ultraviolet radiation source should merge when the ratio of ionizing photon flux to gas density is sufficiently low and the spectrum is sufficiently hard. This regime is particularly relevant to the molecular knots that are commonly found in evolved planetary nebulae, such as the Helix Nebula, where traditional models of photodissociation regions have proved unable to explain the high observed luminosity in H2 lines. In this paper we present results for the structure and steady state dynamics of such advection-dominated merged fronts, calculated using the Cloudy plasma/molecular physics code. We find …


Automated Refinement And Augmentation Of Web Service Description Files, Marc Fisher Ii, Sebastian Elbaum, Gregg Rothermel Dec 2007

Automated Refinement And Augmentation Of Web Service Description Files, Marc Fisher Ii, Sebastian Elbaum, Gregg Rothermel

CSE Technical Reports

Web Service Description Language (WSDL) is being increasingly used to specify web service interfaces. Specifications of this type, however, are often incomplete or imprecise. For example, cursory examination of the WSDL file for Amazon’s E-Commerce Web Service reveals that it often uses a less specific type where a more specific type is applicable, or declares that elements could be missing where other documentation indicates that they are required. Further, specifications reflecting the temporal relationships between operations are completely missing, which is not surprising since they are not supported by the current WSDL standard. These problems in WSDL specifications can cause …


Ultrashort Intense-Field Optical Vortices Produced With Laser-Etched Mirrors, James Strohaber, Timothy D. Scarborough, Cornelis J. Uiterwaal Dec 2007

Ultrashort Intense-Field Optical Vortices Produced With Laser-Etched Mirrors, James Strohaber, Timothy D. Scarborough, Cornelis J. Uiterwaal

C.J.G.J. Uiterwaal Publications

We introduce a simple and practical method to create ultrashort intense optical vortices for applications involving high-intensity lasers. Our method utilizes femtosecond laser pulses to laser etch grating lines into laser-quality gold mirrors. These grating lines holographically encode an optical vortex. We derive mathematical equations for each individual grating line to be etched, for any desired (integer) topological charge. We investigate the smoothness of the etched grooves. We show that they are smooth enough to produce optical vortices with an intensity that is only a few percent lower than in the ideal case. We demonstrate that the etched gratings can …


Evidence For A Population Of High-Redshift Submillimeter Galaxies From Interferometric Imaging, Joshua D. Younger, Giovanni G. Fazio, Jia Sheng Huang, Min S. Yun, Grant W. Wilson, Matthew L.N. Ashby, Mark A. Gurwell, Kamson Lai, Alison B. Peck, Glen R. Petitpas, David J. Wilner, Daisuke Iono, Kotaro Kohno, Ryohei Kawabe, David H. Hughes, Itziar Aretxaga, Tracy Webb, Alejo Martínez-Sansigre, Sungeun Kim, Kimberly S. Scott, Jason Austermann, Thushara Perera, James Lowenthal, Eva Schinnerer, Vernesa Smolčić Dec 2007

Evidence For A Population Of High-Redshift Submillimeter Galaxies From Interferometric Imaging, Joshua D. Younger, Giovanni G. Fazio, Jia Sheng Huang, Min S. Yun, Grant W. Wilson, Matthew L.N. Ashby, Mark A. Gurwell, Kamson Lai, Alison B. Peck, Glen R. Petitpas, David J. Wilner, Daisuke Iono, Kotaro Kohno, Ryohei Kawabe, David H. Hughes, Itziar Aretxaga, Tracy Webb, Alejo Martínez-Sansigre, Sungeun Kim, Kimberly S. Scott, Jason Austermann, Thushara Perera, James Lowenthal, Eva Schinnerer, Vernesa Smolčić

Astronomy: Faculty Publications

We have used the Submillimeter Array to image a flux-limited sample of seven submillimeter galaxies, selected by the AzTEC camera on the JCMT at 1.1 mm, in the COSMOS field at 890 μm with ∼2″ resolution. All of the sources - two radio-bright and five radio-dim - are detected as single point sources at high significance (>6 σ), with positions accurate to ∼0.2″ that enable counterpart identification at other wavelengths observed with similarly high angular resolution. All seven have IRAC counterparts, but only two have secure counterparts in deep HST ACS imaging. As compared to the two radio-bright sources …


Preparation Of Divalent And Trivalent Antigens For Immunogical Studies On Degranulation Of Mast Cells And Preparation Of Ceragenins For Antiviral Studies Against Vaccinia Virus., Dianliang Geng Dec 2007

Preparation Of Divalent And Trivalent Antigens For Immunogical Studies On Degranulation Of Mast Cells And Preparation Of Ceragenins For Antiviral Studies Against Vaccinia Virus., Dianliang Geng

Theses and Dissertations

CHAPTER 1

Aggregation of receptors for IgE (Fc RI) causes mast cells and basophils to release preformed contents of granules, including histamine and a variety of enzymes. This process, called degranulation plays a central role in allergic reactions. Methods to study this process are to create multivalent ligands which can interact with the receptors and, in turn, lead to aggregation of the receptors. We prepared a series of fluorophore-labeled divalent and trivalent antigens to study the degranulation of mast cells. Trivalent antigens proved to be much better stimulators for degranulation of mast cells than divalent antigens. These results indicate that …


Spatio-Temporal Associations Between Goes Aerosol Optical Depth Retrievals And Ground-Level Pm2.5, Christopher J. Paciorek, Yang Liu, Hortensia Moreno-Macias, Shobha Kondragunta Dec 2007

Spatio-Temporal Associations Between Goes Aerosol Optical Depth Retrievals And Ground-Level Pm2.5, Christopher J. Paciorek, Yang Liu, Hortensia Moreno-Macias, Shobha Kondragunta

Harvard University Biostatistics Working Paper Series

We assess the strength of association between aerosol optical depth (AOD) retrievals from the GOES Aerosol/Smoke Product (GASP) and ground-level fine particulate matter (PM2.5) to assess AOD as a proxy for PM2.5 in the United States. GASP AOD is retrieved from a geostationary platform and therefore provides dense temporal coverage with half-hourly observations every day, in contrast to once per day snapshots from polar-orbiting satellites. However, GASP AOD is based on a less-sophisticated instrument and retrieval algorithm. We find that correlations between GASP AOD and PM2.5 over time at fixed locations are reasonably high, except in the winter and in …


Pyridinium Bisretinoids: Synthesis And Photoactivated Cytotoxicity, Junping Gao Dec 2007

Pyridinium Bisretinoids: Synthesis And Photoactivated Cytotoxicity, Junping Gao

Theses and Dissertations

This thesis discusses pyridinium bisretinoid compounds (PBRs), which were prepared for two purposes: 1) to use them as standards for detection of novel fluorophores in human RPE cells, which may be involved in age-related macular degeneration (AMD), and 2) to use them in the development of a targeted and triggered drug delivery system for cancer therapy. We prepared a selection of PBRs using a one-pot biomimetic method; synthesis, mechanisms for formation, and characterization of these compounds is described. We also explored the photoreactivity of three novel PBR compounds and found that these PBRs form oxidation products under blue-light irradiation. The …


Total Synthesis Of (+/-)-Goniomitine Via A Formal Nitrile/Donor-Acceptor Cyclopropane [3 + 2] Cyclization., Christian L Morales, Brian L Pagenkopf Dec 2007

Total Synthesis Of (+/-)-Goniomitine Via A Formal Nitrile/Donor-Acceptor Cyclopropane [3 + 2] Cyclization., Christian L Morales, Brian L Pagenkopf

Chemistry Publications

The total synthesis of (+/-)-goniomitine has been accomplished in 17 linear steps with 5.2% overall yield starting from commercially available delta-valerolactam. A synthetic highlight includes the first application of a formal [3 + 2] cycloaddition between a highly functionalized nitrile and a donor-acceptor cyclopropane to prepare an indole nucleus. The use of a microwave reactor is shown to greatly improve the reaction times for two steps.


Interfacial Coherency And Ferroelectricity Of Batio3/Srtio3 Superlattice Films, Y. L. Li, S. Y. Hu, Dmitri Tenne, A. Soukiassian, D. G. Schlom, X. X. Xi, K. J. Choi Dec 2007

Interfacial Coherency And Ferroelectricity Of Batio3/Srtio3 Superlattice Films, Y. L. Li, S. Y. Hu, Dmitri Tenne, A. Soukiassian, D. G. Schlom, X. X. Xi, K. J. Choi

Physics Faculty Publications and Presentations

We studied the phase transitions, domain morphologies, and polarizations in BaTiO3/SrTiO3 superlattices grown on SrTiO3 substrates. Using the phase field approach, we discovered the remarkable influence of film/substrate interfacial coherency on the ferroelectricity of the SrTiO3 layers within a superlattice: it is an orthorhombic ferroelectric for an incoherent interface while it exhibits only induced polarization by the adjacent BaTiO3 layers for a coherent interface. We presented the domain morphologies within individual BaTiO3 and SrTiO3 layers which have different ferroelectric symmetries. The results are compared to ultraviolet Raman spectroscopy and variable temperature x-ray …