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2009

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Articles 5611 - 5640 of 7615

Full-Text Articles in Physical Sciences and Mathematics

Toward Social Search: From Explicit To Implicit Collaboration To Predict Users' Interests, Luca Longo, Stephen Barrett Jan 2009

Toward Social Search: From Explicit To Implicit Collaboration To Predict Users' Interests, Luca Longo, Stephen Barrett

Conference papers

Inspection methods and cheap self-reporting procedures have been significantly employed in the field of Human- Computer Interaction for assessing the usability of interfaces, systems and technologies. However, there is a tendency to overlook aspects related to the context and features of the users during the usability assessment process. This research introduces the concept of mental workload as an aid to enhance usability measurement. A user-study has been designed and executed in the context of human-web interaction. The aim was to investigate the relationship between the perception of usability of three popular web-sites, and the mental workload imposed by a set …


The Potential Contribution Of Organic Salts To New Particle Growth, Kelley Barsanti, Peter H. Mcmurry, J. N. Smith Jan 2009

The Potential Contribution Of Organic Salts To New Particle Growth, Kelley Barsanti, Peter H. Mcmurry, J. N. Smith

Civil and Environmental Engineering Faculty Publications and Presentations

Field and lab measurements suggest that low-molecular weight (MW) organic acids and bases exist in accumulation and nucleation mode particles, despite their relatively high pure-liquid vapor pressures. The mechanism(s) by which such compounds contribute to the mass growth of existing aerosol particles and newly formed particles has not been thoroughly explored. One mechanism by which low- MW compounds may contribute to new particle growth is through the formation of organic salts. In this paper we use thermodynamic modeling to explore the potential for organic salt formation by atmospherically relevant organic acids and bases for two system types: one in which …


An Improved Upfc Control For Oscillation Damping, Jagannathan Sarangapani, Mariesa Crow, Jianjun Guo Jan 2009

An Improved Upfc Control For Oscillation Damping, Jagannathan Sarangapani, Mariesa Crow, Jianjun Guo

Electrical and Computer Engineering Faculty Research & Creative Works

This paper proposes a new control approach for a unified power flow controller (UPFC) for power system oscillation damping. This control is simple to implement, yet is valid over a wide range of operating conditions. It is also effective in the presence of multiple modes of oscillation. The proposed control is implemented in several test systems and is compared against a traditional PI control.


Analysis Of Privacy And Security Policies, Elisa Bertino, Carolyn Brodie, Seraphin Calo, Lorrie Faith Cranor, Clare Marie Karat, John Karat, Ninghui Li, Dan Lin, Jorge Lobo, Qun Ni, Prathima Rao, Xiping Wang Jan 2009

Analysis Of Privacy And Security Policies, Elisa Bertino, Carolyn Brodie, Seraphin Calo, Lorrie Faith Cranor, Clare Marie Karat, John Karat, Ninghui Li, Dan Lin, Jorge Lobo, Qun Ni, Prathima Rao, Xiping Wang

Computer Science Faculty Research & Creative Works

The distributed nature of the environment in which privacy and security policies operate requires tools that help enforce consistency of policy rules across different domains. Furthermore, because changes to policy rules are required as policies evolve over time, such tools can be used by policy administrators to ensure the consistency of policy changes. in this paper, we describe a number of different policy analysis tools and techniques that we have developed over the years and present them in a unified framework in which both privacy and security policies are discussed. We cover dominance analyses of general policies, conflicts among authorizations …


Modeling Gag Grouper (Mycteroperca Microlepis) In The Gulf Of Mexico: Exploring The Impact Of Marine Reserves On The Population Dynamics Of A Protogynous Grouper, Robert D. Ellis Jan 2009

Modeling Gag Grouper (Mycteroperca Microlepis) In The Gulf Of Mexico: Exploring The Impact Of Marine Reserves On The Population Dynamics Of A Protogynous Grouper, Robert D. Ellis

LSU Master's Theses

The gag grouper (Mycteroperca microlepis) population in the Gulf of Mexico supports both a commercial and recreational fishery but has experienced a decrease in the male to female sex ratio over the past thirty years. Protogynous fish populations naturally have a smaller male to female ratio than gonochoristic fish populations; however the decline in the gag population is such that sperm limitation may be occurring. In an effort to correct the decline in sex ratio, fishery managers have recently implemented two marine reserves designed specifically to protect gag spawning aggregations. Results from two population models (an age-structured model and an …


Provenance Studies Of Volcanic Clasts From The Santa Fe Group, San Luis Basin, Colorado: A Guide To Tectonic Evolution, Corine Kay Armstrong Jan 2009

Provenance Studies Of Volcanic Clasts From The Santa Fe Group, San Luis Basin, Colorado: A Guide To Tectonic Evolution, Corine Kay Armstrong

LSU Master's Theses

Volcanic clasts at the base of the Tertiary Santa Fe Group of the San Luis Basin (SLB), a major extensional feature of the northern Rio Grande Rift, provide evidence for the direction of sediment transport and timing of regional tectonic events. A combination of clast whole rock geochemistry (major and trace element), mineral chemistry (amphibole, biotite, pyroxene and feldspar) and geochronology (40Ar/39Ar of amphibole and biotite and U-Pb of zircons) is used to constrain the possible source scenarios. Several potential sources with requisite geochemical and geochronological information exist for the Santa Fe Group volcanic clasts including rocks from Spanish Peaks …


Fine- To Basin-Scale Distributions Of Calanus Finmarchicus And Its Predators In Three Deep Basins Of The Gulf Of Maine During December 1998 And 1999 From Video Plankton Recorder (Vpr) Data, Christian Briseño-Avena Jan 2009

Fine- To Basin-Scale Distributions Of Calanus Finmarchicus And Its Predators In Three Deep Basins Of The Gulf Of Maine During December 1998 And 1999 From Video Plankton Recorder (Vpr) Data, Christian Briseño-Avena

LSU Master's Theses

The calanoid copepod Calanus finmarchicus is broadly distributed in the North Atlantic, where it dominates the spring zooplankton biomass of shelf ecosystems. Calanus finmarchicus diapauses in the deep basins of the Gulf of Maine (GOM) during late-summer through early-winter. During diapause, predators that co-occur in regions of high copepod abundance may reduce survivorship through predation. Consequently it is important to measure the distribution patterns of C. finmarchicus and its predators. Two cruises were carried out during December of 1998 and 1999 in the GOM. Video Plankton Recorder (VPR) data collected in Wilkinson, Jordan and Georges Basins were used to describe …


A Multi-Proxy Approach To Investigating The Latest Holocene (~4,500 Yrs. Bp) Vegetational History Of Catahoula Lake, Louisiana, Rebecca Ann Tedford Jan 2009

A Multi-Proxy Approach To Investigating The Latest Holocene (~4,500 Yrs. Bp) Vegetational History Of Catahoula Lake, Louisiana, Rebecca Ann Tedford

LSU Doctoral Dissertations

A multi-proxy investigation of sediments examined from Catahoula Lake, Louisiana has provided a record of late-Holocene vegetational changes, related to both hydrology and climate. This study integrates data from phytoliths, pollen, stable isotopes, magnetic susceptibility, and core sediment analysis. A modern phytolith analog assessed the phytoliths production in local plants and their modern soil sample distribution within the established lake vegetation zones. Fifty of the 76 species produced both distinctive and redundant phytoliths. The modern soil sample database indicates that phytoliths produced from both monocotyledon and dicotlyledon plant groups prove useful in distinguishing between forest and grassland communities and identifying …


Hydrodynamic Response To Cold Fronts Along The Louisiana Coast, Zhixuan Feng Jan 2009

Hydrodynamic Response To Cold Fronts Along The Louisiana Coast, Zhixuan Feng

LSU Master's Theses

Cold fronts play important roles in flushing water out of the Louisiana estuaries. This study is aimed at examining the impact of cold front passages on the hydrodynamics in autumn-winter-spring of 2006-2007, and tries to determine the geographic difference, correlation and relative importance of winds, tides, and river discharge on water level variability and flow field. The amplitude spectra of water level reveal that diurnal tides dominate most stations. Areas west of 91°W have relatively high semidiurnal tides. The subtidal fluctuations are mainly wind-driven. Only the station in the Atchafalaya River shows obvious response to the spring flood of the …


Microscopic Dynamics Of The Orientation Of A Hydrated Nanoparticle In An Electric Field, C. D. Daub, D. Bratko, A. Towshif, A. Luzar Jan 2009

Microscopic Dynamics Of The Orientation Of A Hydrated Nanoparticle In An Electric Field, C. D. Daub, D. Bratko, A. Towshif, A. Luzar

Chemistry Publications

We use atomistic simulations to study the orientational dynamics of a nonpolar nanoparticle suspended in water and subject to an electric field. Due to molecular-level effects we describe, the torque exerted on the nanoparticle exceeds continuum-electrostatics based estimates by about a factor of two. The reorientation time of a 16.2×16.2×3.35 ̊A3 nanoparticle in a field E > 0.015V/ ̊A is an order of magnitude less than the field-free orientational time (∼ 1 ns). Surprisingly, the alignment speed is nearly independent of the nanoparticle size in this regime. These findings are relevant for design of novel nanostructures and sensors and development of …


Helping Kindergarteners Make Sense Of Numbers To 100, L. B. Jaslow, V. R. Jacobs Jan 2009

Helping Kindergarteners Make Sense Of Numbers To 100, L. B. Jaslow, V. R. Jacobs

Journal of Mathematics and Science: Collaborative Explorations

The authors share what was learned about kindergarteners' abilities to make sense of numbers to 100 when one of the authors, Linda Jaslow, took over a kindergarten class from February through the end of the school year. Through examples of how she engaged her students in nine weeks of problem solving and discussions focused on making sense of the number system, we provide evidence that the children grew substantially in their ability to count and show understanding when counting by 10's and using 10's during problem solving. Suggestions for tasks to promote continued growth are also provided. Throughout this teaching …


Citizen Sensing, Social Signals, And Enriching Human Experience, Amit P. Sheth Jan 2009

Citizen Sensing, Social Signals, And Enriching Human Experience, Amit P. Sheth

Kno.e.sis Publications

In this article, I introduce the exciting paradigm of citizen sensing enabled by mobile sensors and human computing - that is, humans as citizens on the ubiquitous Web, acting as sensors and sharing their observations and views using mobile devices and Web 2.0 services.


Magnetism In Assembled And Supported Silicon Endohedral Cages: First-Principles Electronic Structure Calculations, R. Robles, Shiv N. Khanna Jan 2009

Magnetism In Assembled And Supported Silicon Endohedral Cages: First-Principles Electronic Structure Calculations, R. Robles, Shiv N. Khanna

Physics Publications

First principles electronic structure calculations on a free CrSi12cluster, a (CrSi12)2 dimer, and CrSi12 clusters supported on Si(111) surfaces have been carried out within a gradient corrected density functional formalism using a supercell approach. The ground state of CrSi12 is a Cr centered hexagonal biprism of Si atoms in which the Cr spin moment is completely quenched. As two CrSi12 motifs are brought together, they form different composite units depending on initial direction of approach and, in most cases, the composite cluster is found to have a net spin moment. Cluster assemblies obtained by depositing CrSi12 motifs on a Si(111) …


Manipulation Tools For Laser-Cooled Rubidium Atoms : Ultrathin Optical Fibres And Magnetic Diffraction Gratings / Michael J. Morrissey., Michael J. Morrissey Jan 2009

Manipulation Tools For Laser-Cooled Rubidium Atoms : Ultrathin Optical Fibres And Magnetic Diffraction Gratings / Michael J. Morrissey., Michael J. Morrissey

Theses

This thesis describes the construction and characterisation of a standard six-beam configuration magneto-optical trap (MOT) used to cool and trap neutral 85Rb atoms. This system is capable of producing a cloud of ~108 atoms whose average temperature is in the sub-Doppler range. The fabrication process for the production of subwavelength tapered optical nanofibres (TONFs) is also described, as well as their guiding properties. These have many proposed applications in the field of cold atoms. However, significant technical progress must be made before many of these applications can be realised. The objective of the research work was to combine …


Information Brokerage - A New Approach Using Knowledge Management, Robert Loew Jan 2009

Information Brokerage - A New Approach Using Knowledge Management, Robert Loew

Theses

Traditional knowledge management attempts to store the total enterprise knowledge into IT related structures, but knowledge management strategies should focus also on people and organisations and not just on technology.

This can be addressed in part by communicating knowledge between people, in and across organisations. Such communication focuses on the development and exchange of people’s experience.

This thesis introduces a hybrid knowledge management solution consisting of an automated system that includes people: employees, experts and Knowledge Brokers (KB). The hybrid concept supports the identification of suitable people for certain topics of discussion. Further, it supports the knowledge communication process by …


Characterisation Of Immunosensor Surfaces Using Scanning Force Microscopy, Eva Maria Gil Romero Jan 2009

Characterisation Of Immunosensor Surfaces Using Scanning Force Microscopy, Eva Maria Gil Romero

Theses

The overall aim of this thesis was twofold. Firstly, to evaluate how scanning force microscopy (SFM) could be used to characterise the surfaces of immunosensors. Four aspects of immunosensor characteristics where SFM has particular application potential have been identified: (a) immobilisation chemistry and (b) the surface density, (c) orientation and (d) specificity of the immobilised antibodies. Secondly, to examine experimentally how the Explorer SFM instrument could be used for such characterisation.

The Explorer SFM instrument is of an open-loop actuator design that is exposed to the intrinsic inadequacies of piezoelectric actuators. In this regard, careful calibration has shown that achieving …


Analysis And Treatment Of Emerging Polar Contaminants, Daniel E. Connors Jan 2009

Analysis And Treatment Of Emerging Polar Contaminants, Daniel E. Connors

Electronic Theses and Dissertations

Two major classes of polar compounds have recently become a major focus as sources of contamination of water systems. Pharmaceuticals and personal care products (PPCPs) enter water through wastewater streams, and many of these compounds survive current wastewater treatment processes. High production volume chemicals (HPVCs), defined as chemicals produced in excess of one million pounds per year have numerous entries into surface and drinking waters due to their ubiquity. The commonality between many of these compounds is their polarity, which makes them water-soluble.

While both PPCPs and HPVCs have been entering into the environment for decades, advances in analyte detection …


Application Of Multiple Mass Spectrometric Techniques In The Isolation, Determination And Characterisation Of The Marine Toxins; Azaspiracid, Keith O'Callaghan Jan 2009

Application Of Multiple Mass Spectrometric Techniques In The Isolation, Determination And Characterisation Of The Marine Toxins; Azaspiracid, Keith O'Callaghan

Theses

The Azaspiracids are a class of polyether marine biotoxins that present a significant health risk to consumers of shellfish. Since their discovery in the late 1990s several human intoxications have been reported, and traced to Irish shellfish farms resulting in closures or harvest rejections. As such incidents involving azaspiracid shellfish poisoning have a major socio-economic impact on communities that rely on shellfish farming revenues.

Recent evidence suggests that azaspiracid poisoning events may become more commonplace. With this increased risk the understanding of azaspiracids mode of action and biological targets becomes crucial. To support these endeavours effective analytical methods need to …


The Influence Of Affect, Attitude And Usefulness In The Acceptance Of Telemedicine Systems, Soussan Djamasbi,, Ann L. Fruhling, Eleanor T. Loiacono Jan 2009

The Influence Of Affect, Attitude And Usefulness In The Acceptance Of Telemedicine Systems, Soussan Djamasbi,, Ann L. Fruhling, Eleanor T. Loiacono

Information Systems and Quantitative Analysis Faculty Publications

Grounded in current theories of affect this study examines the role positive and negative moods play on the acceptance of a specialized telemedicine system for microbiology consultation and diagnostics, referred to as telepathology. From a laboratory experiment using microbiology laboratory assistants, the notion that healthcare users’ attitude is an important factor in the acceptance behavior of a healthcare information system is supported. A regression analysis of the data revealed the need to tailor the IS Technology Acceptance Model for the healthcare field. Specifically, our results show that ease of use which is thought to be a main antecedent of end-user …


Gold Nanoparticles: Synthesis, Property Study And Applcications For Biomolecular Detection And Photothermal Therapy, Xiong Liu Jan 2009

Gold Nanoparticles: Synthesis, Property Study And Applcications For Biomolecular Detection And Photothermal Therapy, Xiong Liu

Electronic Theses and Dissertations

This dissertation presents a systematic study on gold nanoparticles: from their chemical synthesis, modification of surface functionalities, optical properties studies with emphasis on the absorption and scattering properties, to applications of gold nanoparticles in biomolecular detection, imaging and photothermal therapy. In chapter 2, we studied the kinetics of gold nanoparticle growth under Brust-Shiffrin reaction conditions. In chapter 3, we further examined the reaction mechanism and growth kinetics of gold nanoparticles using oleylamine as both a reducing reagent and particle growth passivation ligand. From these two projects, important understanding was revealed on gold nanoparticle formation and growth mechanism. Chapter 4 describes …


Standing Waves Of Spatially Discrete Fitzhugh-Nagumo Equations, Joseph Segal Jan 2009

Standing Waves Of Spatially Discrete Fitzhugh-Nagumo Equations, Joseph Segal

Electronic Theses and Dissertations

We study a system of spatially discrete FitzHugh-Nagumo equations, which are nonlinear differential-difference equations on an infinite one-dimensional lattice. These equations are used as a model of impulse propagation in nerve cells. We employ McKean's caricature of the cubic as our nonlinearity, which allows us to reduce the nonlinear problem into a linear inhomogeneous problem. We find exact solutions for standing waves, which are steady states of the system. We derive formulas for all 1-pulse solutions. We determine the range of parameter values that allow for the existence of standing waves. We use numerical methods to demonstrate the stability of …


Tunable Terahertz Detectors Based On Plasmon Exciation In Two Dimensional Electron Gasses In Ingaas/Inp And Algan/Gan Hemt, Himanshu Saxena Jan 2009

Tunable Terahertz Detectors Based On Plasmon Exciation In Two Dimensional Electron Gasses In Ingaas/Inp And Algan/Gan Hemt, Himanshu Saxena

Electronic Theses and Dissertations

The observation of voltage-tunable plasmon resonances in the terahertz range in two dimensional electron gas (2-deg) of a high electron mobility transistor (HEMT) fabricated from the InGaAs/InP and AlGaN/GaN materials systems is reported. The devices were fabricated from a commercial HEMT wafer by depositing source and drain contacts using standard photolithography process and a semi-transparent gate contact that consisted of a 0.5 [micro]m period transmission grating formed by electron-beam lithography. Narrow-band resonant absorption of THz radiation was observed in transmission in the frequency range 10-100 cm-1. The resonance frequency depends on the gate voltage-tuned sheet-charge density of the 2deg. The …


Wavelength-Division-Multiplexed Transmission Using Semiconductor Optical Amplifiers And Electronic Impairment Compensation, Xiaoxu Li Jan 2009

Wavelength-Division-Multiplexed Transmission Using Semiconductor Optical Amplifiers And Electronic Impairment Compensation, Xiaoxu Li

Electronic Theses and Dissertations

Over the last decade, rapid growth of broadband services necessitated research aimed at increasing transmission capacity in fiber-optic communication systems. Wavelength division multiplexing (WDM) technology has been widely used in fiber-optic systems to fully utilize fiber transmission bandwidth. Among optical amplifiers for WDM transmission, semiconductor optical amplifier (SOA) is a promising candidate, thanks to its broad bandwidth, compact size, and low cost. In transmission systems using SOAs, due to their large noise figures, high signal launching powers are required to ensure reasonable optical signal-to-noise ratio of the received signals. Hence the SOAs are operated in the saturation region and the …


Nonlinear Femtosecond Near Infrared Laser Structuring In Oxide Glasses, Arnaud Royon Jan 2009

Nonlinear Femtosecond Near Infrared Laser Structuring In Oxide Glasses, Arnaud Royon

Electronic Theses and Dissertations

Three-dimensional femtosecond laser structuring has a growing interest because of its ease of implementation and the numerous possible applications in the domain of photonic components. Structures such as waveguides, diffraction gratings, optical memories or photonic crystals can be fabricated thanks to this technique. Its use with oxide glasses is promising because of several advantages; they are resistant to flux and ageing, their chemical composition can easily be changed to fit the well-defined requirements of an application. They can already be found in Raman amplifiers, optical fibers, fiber lasers, and other devices. This thesis is based on two axes. The first …


Realnav: Exploring Natural User Interfaces For Locomotion In Video Games, Brian Williamson Jan 2009

Realnav: Exploring Natural User Interfaces For Locomotion In Video Games, Brian Williamson

Electronic Theses and Dissertations

We present an exploration into realistic locomotion interfaces in video games using spatially convenient input hardware. In particular, we use Nintendo Wii Remotes to create natural mappings between user actions and their representation in a video game. Targeting American Football video games, we used the role of the quarterback as an exemplar since the game player needs to maneuver effectively in a small area, run down the field, and perform evasive gestures such as spinning, jumping, or the "juke". In our study, we developed three locomotion techniques. The first technique used a single Wii Remote, placed anywhere on the user's …


Gathering Leadership Momentum Across Great Distances: Creating An Online Community Of Practice, Erin Dini-Davis, Danielle Theiss-White Jan 2009

Gathering Leadership Momentum Across Great Distances: Creating An Online Community Of Practice, Erin Dini-Davis, Danielle Theiss-White

Library Faculty & Staff Publications

At the 2007 Mountain Plains Library Association Leadership (MPLA) Institute, held in New Mexico, USA, eight academic librarians formed an online multi-state, multigenerational community of practice. MPLA is a twelve-state library association within the United States. Using Google Groups™, the members formed an online environment called the MPLA Community of Practice for continuing development of the leadership skills presented at the Institute. These early-career librarians represent diverse educational backgrounds and work in libraries serving varied populations with differing disciplinary emphases. The group meets monthly with each member preparing and facilitating online discussions, complete with personal assessments, topical readings, and questions. …


Synergistic Effects Of Iron And Temperature On Antarctic Phytoplankton And Microzooplankton Assemblages, J. M. Rose, Y. Feng, Et Al, Walker O. Smith Jr., B. Sigist, S. Tozzi, Et Al Jan 2009

Synergistic Effects Of Iron And Temperature On Antarctic Phytoplankton And Microzooplankton Assemblages, J. M. Rose, Y. Feng, Et Al, Walker O. Smith Jr., B. Sigist, S. Tozzi, Et Al

VIMS Articles

Iron availability and temperature are important limiting factors for the biota in many areas of the world ocean, and both have been predicted to change in future climate scenarios. However, the impacts of combined changes in these two key factors on microbial trophic dynamics and nutrient cycling are unknown. We examined the relative effects of iron addition (+1 nM) and increased temperature (+4 degrees C) on plankton assemblages of the Ross Sea, Antarctica, a region characterized by annual algal blooms and an active microbial community. Increased iron and temperature individually had consistently significant but relatively minor positive effects on total …


Ultrashort Pulse Electron Gun With A Mhz Repetition Rate, D. Wytrykus, Martin Centurion, P. Reckenthaeler, F. Krausz, A. Apolonski, E. Fill Jan 2009

Ultrashort Pulse Electron Gun With A Mhz Repetition Rate, D. Wytrykus, Martin Centurion, P. Reckenthaeler, F. Krausz, A. Apolonski, E. Fill

Martin Centurion Publications

We report the construction of an electron gun emitting ultrashort pulses with a repetition rate of 2.7 MHz. The gun works at an acceleration voltage of 20 kV and is operated with a laser oscillator having an ultralong cavity. A low number of electrons per pulse eliminates space charge broadening. Electron yield and beam profiles are measured for operation with laser wavelengths of 800, 400, and 266 nm. The initial energy spread of the electrons is determined for these three wavelengths, and pulse durations of 600, 390, and 270 fs are inferred from the data.


Complex Magnetic Phase In Submonolayer Fe Stripes On Pt(997), Jan Honolka, T. Y. Lee, K. Kuhnke, D. Repetto, V. Sessi, Peter Wahl, A. Buchsbaum, P. Varga, S. Gardonio, C. Carbone, S. R. Krishnakumar, P. Gambardella, M. Komelj, R. Singer, M. Fähnle, K. Fauth, G. Schütz, Axel Enders, K. Kern Jan 2009

Complex Magnetic Phase In Submonolayer Fe Stripes On Pt(997), Jan Honolka, T. Y. Lee, K. Kuhnke, D. Repetto, V. Sessi, Peter Wahl, A. Buchsbaum, P. Varga, S. Gardonio, C. Carbone, S. R. Krishnakumar, P. Gambardella, M. Komelj, R. Singer, M. Fähnle, K. Fauth, G. Schütz, Axel Enders, K. Kern

Axel Enders Publications

Correlations between magnetism and morphology of iron nanostructures of monatomic height on Pt(997) substrates are studied using x-ray magnetic circular dichroism as well as scanning tunneling microscopy and helium scattering. A drastic collapse of the average magnetization by more than a factor of 4 is observed when increasing the iron coverage from 0.1 to 0.2 ML. This effect goes along with a softening of the magnetic anisotropy energy and a gradual reorientation of the magnetic easy axis from in plane to out of plane. The experimental findings together with electronic density-functional calculations suggest the formation of a complex magnetic phase …


Electron Attachment To Cl2 From 300 To 1100 K: Experiment And Theory, Jeffrey Friedman, Thomas Miller, Linda Schaffer, A. A. Viggiano, Ilya I. Fabrikant Jan 2009

Electron Attachment To Cl2 From 300 To 1100 K: Experiment And Theory, Jeffrey Friedman, Thomas Miller, Linda Schaffer, A. A. Viggiano, Ilya I. Fabrikant

Ilya Fabrikant Publications

Rate constants for dissociative electron attachment to Cl2 have been measured from 300 to 1100 K in a high-temperature flowing-afterglow Langmuir-probe apparatus. R-matrix calculations have been carried out which compare well with the present measurements with possible deviation at the highest temperatures. The attachment rate constants do not show Arrhenius behavior. The temperature dependence of the calculated rate constants for successive vibrational levels provides insight as to this behavior. While the lowest vibrational level of Cl2 dominates attachment at low temperatures, the rate constant is not flat with temperature because of the p-wave character of the …