Physical Sciences and Mathematics Commons^™

Capillary Electrophoresis Based Microbial Detection And Separation, Ryan Nelson, Andrew Lantz

Student Summer Scholars Manuscripts

Capillary Electrophoresis (CE) represents a significant tool for the separation of microorganisms as well as the detection and isolation of Candida albicans (CA) fungus in human blood. There currently exists few rapid means by which biological pathogens can be tested, at low concentration, in blood, and other organic matrices. Other common chromatographic techniques, such as GC, HPLC, IR and MS do not have the capability of analyzing living microorganisms, nor the ability to separate them with any precision. CE offers the rare opportunity to separate individual cells by the charge to size ratio as well as their isoelectric focusing point …

Conversion Of Cellulose To Value Added-Chemicals, Shane Mcgrath, Dalila Kovacs, Jim Krikke

Student Summer Scholars Manuscripts

Biomass-derived feedstock is of growing importance in the development of new synthetic pathways for commodity and specialty chemicals. Utilizing basic catalytic concepts such as hydrolysis, dehydration, isomerisation, and other common transformations of sugar in biomass conversion has already produced significant advances in the fundamental understanding of biomass conversion.

Despite the progress that has already been made, very few studies are dedicated to understanding the fundamentals of cellulose conversion under heterogeneous catalytic conditions. This is due to the complexity of both the catalytic steps at the metal/support interface and the structure of cellulose itself, being a highly functionalized homopolymer, characterized by …

Cns Connections, Winter 2009-10, University Of Northern Iowa. College Of Natural Sciences.

CNS Connections

Inside this issue:

-- Message from the Dean
-- CNS explores alternative energy possibilities
-- CNS News in Short
-- Green promises kept at CEEE
-- Applause
-- Transitions
-- Summer camps help middle school students to experience science firsthand
-- CNS students in the news
-- IMSEP awards grants
-- Citizen Science aims to make science accessible
-- CNS team participates in project to explore Earth's interior
-- Faculty research
-- Imagine the impact
-- South campus trail provides portal to nature
-- Internationally distinguished UNI grad establishes teaching and learning award
-- Alumni News
-- CNS advisory board

Fundamentals For Using Geographic Information Science To Measure The Effectiveness Of Land Conservation Projects, Robert G. Pontius Jr., Shaily Menon, Joseph Duncan, Shalini Gupta

Other Scholarly Publications

Some humans spend a tremendous amount of effort to change landscapes from a “natural” state to a “developed” state for a variety of desirable economic uses, such as urban, agriculture, transportation, and mining. Others spend a tremendous amount of effort to prevent such development in order to conserve the landscapes for a variety of important environmental uses, such as biodiversity maintenance, carbon storage, water filtration, and landslide prevention. It would be efficient in theory if a society were to focus its development efforts at locations that give the largest economic utility per area developed, and to focus its conservation efforts …

Fixing Numbers Of Graphs And Groups, Courtney Gibbons, Joshua D. Laison

Articles

The fixing number of a graph G is the smallest cardinality of a set of vertices S such that only the trivial automorphism of G fixes every vertex in S. The fixing set of a group Γ is the set of all fixing numbers of finite graphs with automorphism group Γ. Several authors have studied the distinguishing number of a graph, the smallest number of labels needed to label G so that the automorphism group of the labeled graph is trivial. The fixing number can be thought of as a variation of the distinguishing number in which every label …

Rook Polynomials In Higher Dimensions, Nicholas Krzywonos, Feryal Alayont

Student Summer Scholars Manuscripts

A rook polynomial counts the number of placements of non-attacking rooks on a board. In this paper we describe generalizations of the definition and properties of rook polynomials to "boards" in three and higher dimensions. We also defefine generalizations of special two dimensional boards to three dimensions, including the triangle board and the board representing the probleme des rencontres. The number of rook placements on these three dimensional families of rook boards are shown to be related to famous number sequences, such as central factorial numbers, the number of Latin rectangles and the Genocchi numbers.

Steel Hull Corrosion Of Uss Arizona With Applications To Submerged Resources, D. L. Johnson, D. J. Medlin, M. A. Russell, D. L. Conlin, L. E. Murphy, J. D. Carr

Chemistry Department: Faculty Publications

The USS Arizona Preservation project is a multi-year, interdisciplinary and cumulative effort with each discipline contributing to basic research required to make informed management decisions for long-term preservation. Three significant issues include: (1) USS Arizona is a grave site for 900 or more Navy and Marine personal lost with the USS Arizona when Japanese forces attacked Pearl Harbor on Dec 7, 1941. (2) Minimizing environmental hazard from a potential fuel oil release of an estimated 500,000 gallons remaining in fuel bunkers or compartment overheads. A cross section view of the ship and bunkers before and after the attack is shown …

The Dape-Encoded N-Succinyl-L,L-Diaminopimelic Acid Desuccinylase From Haemophilus Influenzae Contains Two Active-Site Histidine Residues, Danuta Gillner, David L. Bienvenue, Boguslaw P. Nocek, Andzrej Joachimiak, Vincentos Zachary, Brian Bennett, Richard C. Holz

Physics Faculty Research and Publications

The catalytic and structural properties of the H67A and H349A dapE-encoded N-succinyl-l,l-diaminopimelic acid desuccinylase (DapE) from Haemophilus influenzae were investigated. On the basis of sequence alignment with the carboxypeptidase from Pseudomonas sp. strain RS-16, both H67 and H349 were predicted to be Zn(II) ligands. The H67A DapE enzyme exhibited a decreased catalytic efficiency (180-fold) compared with wild-type (WT) DapE towards N-succinyldiaminopimelic acid. No catalytic activity was observed for H349A under the experimental conditions used. The electronic paramagnetic resonance (EPR) and electronic absorption data indicate that the Co(II) ion bound to H349A-DapE is analogous to that of WT …

Field Induced Domain Wall Collisions In Thin Magnetic Nanowires, Andrew Kunz

Physics Faculty Research and Publications

In a two-dimensional magnetic nanowire, it is possible to engineer collisions between two domain walls put into motion by an externally applied field. We show that the topological defects that define the domain wall can be controlled to allow for both domain wall annihilation and preservation during the collisions as long as the wire remains thin. The preservation process can be used to release pinned domain walls from notches with small applied fields.

Measurement Of Beauty Photoproduction Using Decays Into Muons In Dijet Events At Hera, S. Chekanov, M. Derrick, S. Magill, B. Musgrave, D. Nicholass, J. Repond, R. Yoshida, Margarita C. K. Mattingly, P. Antonioli, G. Bari, L. Bellagamba, D. Boscherini, A. Bruni, G. Bruni, F. Cindolo, M. Corradi, G. Iacobucci, A. Margotti, R. Nania, A. Polini, S. Antonelli, M. Basile, M. Bindi, L. Cifarelli, A. Contin, S. De Pasquale, G. Sartorelli, A. Zichichi, D. Bartsch, I. Brock, H. Hartmann

Faculty Publications

Beauty photoproduction in dijet events has been measured at HERA with the ZEUS detector using an integrated luminosity of 126 pb-1. Beauty was identified in events with a muon in the final state by using the transverse momentum of the muon relative to the closest jet. Lifetime information from the silicon vertex detector was also used; the impact parameter of the muon with respect to the primary vertex was exploited to discriminate between signal and background. Cross sections for beauty production as a function of the muon and the jet variables as well as dijet correlations are compared to QCD …

Emission Of Low-Energy Photons By Electrons At Electron-Positron And Electron-Ion Colliders With Dense Bunches, Ulrich D. Jentschura, G. L. Kotkin, V. G. Serbo

Physics Faculty Research & Creative Works

Usually, the emission of low-energy photons in electron-positron (or electron-ion) bunch collisions is calculated with the same approach as for synchrotron radiation (beamstrahlung). However, for soft photons (Eγ

Coulomb-Field-Induced Conversion Of A High-Energy Photon Into A Pair Assisted By A Counterpropagating Laser Beam, Erik Lotstedt, Ulrich D. Jentschura, Christoph H. Keitel

Physics Faculty Research & Creative Works

The laser-induced modification of a fundamental process of quantum electrodynamics, the conversion of a high-energy gamma photon in the Coulomb field of a nucleus into an electron-positron pair, is studied theoretically. Although the employed formalism allows for the general case where the gamma photon and laser photons cross at an arbitrary angle, we here focus on a theoretically interesting and numerically challenging setup, where the laser beam and gamma photon counterpropagate and impinge on a nucleus at rest. For a peak laser field smaller than the critical Schwinger field and gamma photon energy larger than the field-free threshold, the total …

Surface Relief Profile Of Photopolymerisable Systems In A Single Illuminated Spot, Tsvetanka Babeva, Dana Mackey, Izabela Naydenova, Suzanne Martin, Vincent Toal

Conference Papers

The formation of surface relief profile in photopolymerisable systems when illuminated with a focused beam of light is simulated numerically using a two-way diffusion model that accounts both for monomer and short polymer chains diffusion. The concentration and spatial distribution dynamics of monomer, short and long polymer chains are calculated. It is assumed that the surface profile is a linear combination of monomer and polymer concentration with appropriate coefficients accounting for polymer shrinkage. A good agreement between the calculated and the experimentally measured profiles is observed thus demonstrating the successful application of the two way diffusion in modeling this system.

A Single Beam Data Writing Process For Holographic Data Storage, Suzanne Martin, Denis Bade, Izabela Naydenova, Vincent Toal

Conference Papers

A concept is described that could allow Holographic Data Storage with angular multiplexing using, uniquely, only one data writing beam; pre-recorded ‘seed’ gratings are illuminated with one writing beam in order to produce a data grating.

Out-Of-Plane Vibration Analysis With A Transmission Holographic Optical Element Based Electronic Speckle Pattern Interferometer, Viswanath Bavigadda, Vincent Toal, Raghavendra Jallapuram, Emilia Mihaylova

Conference Papers

A simple electronic speckle pattern interferometer (ESPI) using a transmission holographic optical element (THOE) is presented. The THOE is designed to create a speckled reference beam in the interferometer. It is a transmission hologram of a diffusely transmitting glass plate A specific requirement for the fabrication of the THOEs is for them to be recorded at one wavelength at which the recording material is photosensitive and reconstructed using a near infrared laser diode which can be current modulated for phase shifting purposes. A partially reflective glass plate provides illumination of the object along the normal to its surface, ensuring that …

Ocular Microtremor Laser Speckle Metrology, Mohammed Al-Kalbani, Emilia Mihaylova, Niamh Collins, David Coakley, Gerard Boyle, Vincent Toal

Conference Papers

Ocular Microtremor (OMT) is a continual, high frequency physiological tremor of the eye present in all subjects even when the eye is apparently at rest. OMT causes a peak to peak displacement of around 150nm-2500nm with a broadband frequency spectrum between 30Hz to 120Hz; with a peak at about 83Hz. OMT carries useful clinical information on depth of consciousness and on some neurological disorders. Nearly all quantitative clinical investigations have been based on OMT measurements using an eye contacting piezoelectric probe which has low clinical acceptability. Laser speckle metrology is a candidate for a high resolution, non-contacting, compact, portable OMT …

Research In Bioenergy And Other Renewable Energy Sources In Bulgaria, Emilia Mihaylova, Anna Garo Aladjadjian

Conference Papers

The interest in Renewable Energy Sources (RES) in Bulgaria reflects the changes in the field of energy policy worldwide and in Europe. The key to successful development of renewable energies in Bulgaria requires a combination of political commitment and decision making as well as support mechanisms including well-defined government targets, technological advances and public acceptance. The renewable energy sources (RES) theoretical potential in Bulgaria is considerable. It is evaluated to 14387 J/year for geothermal energy; 77156,7 J/year for solid agricultural waste; 478,4 J/year – biomass from paper waste; 9605,2 J/year –biomass from wood for heating; 79,8 J/year –biomass from natural …

Influence Of Magnesium Nitrate On The Corrosion Performance Of Sol-Gel Coated Aa2024-T3 Aluminium Alloy, Rajath Varma, Brendan Duffy, John Cassidy

Articles

Traditional anti-corrosion technology has relied heavily on using reducible metal species, predominantly hexavalent chromium (Cr(VI)), for protecting reactive metal alloys such as aluminium which is extensively used in the aerospace sector. However, the impending changes in the use of Cr(VI) in Europe and the United States have forced aerospace manufacturers to examine alternative materials for protecting aluminium. One of the most promising alternatives being investigated are organosilane based sol-gels containing anticorrosion additives. In this work the anti-corrosion properties of magnesium (II) nitrate (Mg(NO3)2) as a inhibitor was investigated at different concentrations (0.1% - 1.0 wt %) in a methyltriethoxysilane (MTEOS) …

Silver Doped Perfluoropolyether-Urethane Coatings: Antibacterial Activity And Surface Analysis, Niall Stobie, Brendan Duffy, Steven Hinder, Patrick Mchale, Declan Mccormack

Articles

The colonisation of clinical and industrial surfaces with pathogenic microorganisms has prompted increased research into the development of effective antibacterial and antifouling coatings. There is evidence that implanted biomedical surfaces coated with metallic silver can be inactivated by hysiological fluids, thus reducing the bioactivity of the coating. In this work, we report the biofilm inhibition of Staphylococcus epidermidis using a roomtemperatureprocessedsilver dopedperfluoropolyether-urethane coating. The release of silver ions from these fluoropolymers over a six-day period inhibited bacterial encrustation – as observed by scanning electron microscopy (SEM). X-ray photoelectron spectroscopy (XPS) analysis indicated differences in carbon, fluorine and sodium surface composition …

Tyflos: A Wearable Navigation Prototype For Blind & Visually Impaired; Design, Modelling And Experimental Results, Dimitrios Dakopoulos

Browse all Theses and Dissertations

The need for assistive devices has, had and will have a large merit in many engineering research arenas. This dissertation deals with the design, modeling, implementation and experimentation of the navigation component of a wearable assistive system for blind and visually impaired people, called TYFLOS (ΤΥΦΛΟΣ) which is the Greek word for "Blind".

The current prototype consists of two mini cameras attached to a pair of conventional eye-glasses, a 2D tactile display vibration array) which consists of 16 vibrating elements arranged in a 4x4 manner, attached to an elastic vest worn on the user's abdomen, a portable computer, an ear-speaker …

Comparison Of The Electrochemical Properties Of Ethanol In Perchloric Acid And Ionic Liquids, Sandra Felix-Balderrama

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1-Ethyl-3-Methylimidazolium Tetrafluroborate (EMImBF₄) and 1-Ethyl-3-Methylimidazlium Bis(trifluoromethanesulfonyl)imide (EMImTFSI) ionic liquids were synthesized and characterized in order to study the electrochemical oxidation of ethanol in these ionic liquids on a platinum surface electrode.

It was found that pure EMImBF₄ exhibits an electrochemical window of 4.4 V,while EMImTFSI exhibits an electrochemical window of 5.0 V.

Electrochemical study of ethanol in perchloric acid showed that the oxidation of ethanol strongly depends on the concentration of ethanol and on the temperature of the solution. The poisoning of the platinum electrode only depends on the concentration of ethanol. At a low concentration of …

Cationic Exchange Reactions Involving Dilithium Phthalocyanine, Morgan M. Hart

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Dilithium phthalocyanine (Li₂Pc) consists of an aromatic macrocycle possessing a doubly negative charge and two Li⁺ counterions. One Li⁺ ion is easily displaceable while the other remains coordinated to the phthalocyanine ring. The displaceable Li⁺ cation can be exchanged with other cations, such as a singly charged tetra-alkyl ammonium cation, by using several variations of a general procedure. It has been demonstrated that tetraalkylammonium lithium phthalocyanines (TAA-LiPcs) can be successfully and reproducibly synthesized with yields ranging from 54.5% up to 64.3%. All TAA-LiPcs demonstrated poor solubilities from approximately <0.2 mg/mL to 5 mg/ml in the solvents tested (with the exception of tetrapropylammonium lithium phthalocyanine and tetrahexylammonium lithium phthalocyanine). All of the TAA-LiPcs synthesized were dark-purple in color, with the exception of tetraheptylammonium lithium phthalocyanine and tetraoctylammonium lithium phthalocyanine. These two compounds were dark - blue in color. Melting points varied greatly from >370.4°C to 157.9°C and depended greatly upon …

"One-Pot" Oligomeric A2 + B3 Approach To Branched Poly(Arylene Ether Sulfone)S: Reactivity Ratio Controlled Polycondensation, Andrea M. Elsen

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The synthesis of fully soluble branched poly(arylene ether)s via an oligomeric A2 + B3 system, in which the A2 oligomers are generated in situ, is presented. This approach takes advantage of the significantly higher reactivity toward nucleophilic aromatic substitution reactions, NAS, of B2, 4-Fluorophenyl sulfone, relative to B3, tris(4-Fluorophenyl) phosphine oxide. The A2 oligomers were synthesized by reaction of Bisphenol-A and B2, in the presence of the B3 unit, at temperatures between 100 and 160 °C, followed by an increase in the reaction temperature to 180 °C at which point the branching unit was incorporated. The presence of branching was …

Semantics Enriched Service Environments, Karthik Rajagopal Gomadam

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During the past seven years services centric computing has emerged as the preferred approach to architect complex software. Software is increasingly developed by integrating remotely existing components, popularly called services. This architectural paradigm, also called Service Oriented Architecture (SOA), brings with it the benefits of interoperability, agility and flexibility to software design and development. One can easily add or change new features to existing systems, either by the addition of new services or by replacing existing ones. Two popular approaches have emerged for realizing SOA. The first approach is based on the SOAP protocol for communication and the Web Service …

Burst Scheduling, Grooming And Qos Provisioning In Optical Burst-Switched Networks, Yuqi Fan

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The demand of network capacity has been increasing steadily with more users than ever connected to the Internet through broadband access and the popularity of video based applications, such as YouTube. Optical wavelength division multiplexing (WDM) networks are expected to form the next-generation backbone network and to fulfill the insatiable appetite for bandwidth.

Wavelength routed WDM optical networks offer the granularity of switching at a fiber, waveband, or a wavelength level. The finest granularity offered is at a wavelength level by provisioning lightpaths for different clients/services. All-optical packet switching is still deemed technically infeasible and its competitiveness as a backbone …

Lithiation Reactions Of 3-(4-Chlorophenyl)Sydnone And 3-(4-Methylphenyl)Sydnone, Nigel Ngonidzashe Chitiyo

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Ortho-iodophenyl sydnones are key intermediates in Sonogashira coupling reactions and the resulting ortho alkynyl sydnones are useful precursors to functionalized sydnonquinolines. In this work, three synthetic routes leading to the synthesis of these versatile intermediates were explored.

Lithiation reactions of 3-(4-chlorophenyl) sydnone and 3-(4-methylphenyl) sydnone followed by trapping with iodine electrophiles yielded the expected disubstituted species 3-(4-chloro-2-iodophenyl)-4-iodosydnone and 3-(4-methyl-2-iodophenyl)-4-iodosydnone in yields ranging from 14% to 75%. Subsequent reduction with sodium sulfite removed the iodine at the C-4 position in both species yielding the ortho iodophenyl sydnones in 80% and 85% yield, respectively.

A surprising result was the discovery that careful …

A Cryptanalysis Methodology For The Reverse Engineering Of Encrypted Information In Images, Allan Anthony Rwabutaza

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Security is an important issue related to the storage and communication of data and information. In data and information security, cryptography and steganography are two of the most common security techniques. On one hand, there is cryptography, which is the secret communication between two parties by message scrambling on the sender's side and message unscrambling on the receiver's side so that only the intended receiver gets the secret message. On the other hand, there is steganography, which is the hiding of information in a medium in such a way that no one other than the sender or the intended receiver …

Transportation Of Machinery Through A Confined Space, Diana Atwood

Undergraduate Journal of Mathematical Modeling: One + Two

Our goal in this paper is to determine whether a packaging machine of negligible width will fit through a hallway and into a certain room (see page 4 for comments about negligible width). Given the width of the hallway and the room, we apply calculus to find the minimum length available between the two. We determine that the machine will successfully fit into the room.

One More Decidable Class Of Finitely Ground Programs, Yuliya Lierler, Vladimir Lifschitz

Computer Science Faculty Proceedings & Presentations

When a logic program is processed by an answer set solver, the first task is to generate its instantiation. In a recent paper, Calimeri et el. made the idea of efficient instantiation precise for the case of disjunctive programs with function symbols, and introduced the class of “finitely ground” programs that can be efficiently instantiated. Since that class is undecidable, it is important to find its large decidable subsets. In this paper, we introduce such a subset—the class of argumentrestricted programs. It includes, in particular, all finite domain programs, ω-restricted programs, and λ-restricted programs.

Automated Offspring Sizing In Evolutionary Algorithms, André Chidi Nwamba

Masters Theses

"Evolutionary Algorithms (EAs) are a class of algorithms inspired by biological evolution. EAs are applicable to a wide range of problems; however, there are a number of parameters to set in order to use an EA. The performance of an EA is extremely sensitive to these parameter values; setting these parameters often requires expert knowledge of EAs. This prevents EAs from being more widely adopted by nonexperts. Parameter control, the automation of dynamic parameter value selection, has the potential to not only alleviate the burden of parameter tuning, but also to improve performance of EAs on a variety of problem …