Physical Sciences and Mathematics Commons^™

Prerapation And Supercapacitor Property Of Mesoporous Carbon Nanofibers, Yong-Wen Wang, Ming-Bo Zheng, Jian Cao, Jie-Ming Cao, Guang-Bin Ji, Jie Tao

Journal of Electrochemistry

Two different mesoporous carbon nanofibers with large mesopore or core-shell structure were prepared by using the resol/F127 mixture to fill the AAO template. The morphology and structural parameters of the samples were characterized by SEM,TEM,and N2 adsorption-desorption analysis. The supercapacitive behaviors of the electrodes were tested by cyclic voltammetry and galvanostatic charge-discharge. The results show that the specific capacitances of mesoporous carbon nanofibers increased obviously and the fine supercapacitive performances were achieved at high scan rate or large current density.

Synthesis And Electrochemical Properties Of Li_3v_2(Po_4)_3/C Cathode Materials For Lithium Ion Battery, Li-Ying Liu, Hai-Yan Zhang, Lian Chen, Yu-Chun Zhai

Journal of Electrochemistry

Cathode material Li3V2( PO4) 3 /C for Lithium-ion battery was synthesized by combination of ball milling and baking. Physical and electrochemical performances of as-prepared materials were characterized through XRD,EIS and galvanostatic cell cycling. The results show that the products were monoclinic Li3 V2 ( PO4) 3 with well-developed crystal structure. At 0. 1C,0. 25C and 0. 5C,the initial discharge capacities were 150. 6,134. 1 and 107. 1 mAh·g-1 ,respectively. Capacity retention rates were 87. 3% after 130 cycles at 0. 25C and 87. 2% after 105 cycles at 0. 5C. Charge-discharge efficiencies were all above 80% and the average discharge …

Nano-Sized Au On Nickel Foam As Cathode Of Alkaline Al-H_2o_2 Semi Fuel Cell, Shu-Li Chen, Bang-An Lu, Yao Liu, Gui-Ling Wang, Dian-Xue Cao

Journal of Electrochemistry

Nano-sized Au particles were deposited on a nickel foam substrate by a fast spontaneous deposition method using AuCl3 as the source of Au. The effects of AuCl3 concentration and deposition time on the size and distribution of Au particles,and the performance of the obtained Au/Ni electrode as the cathode of Al-H2O2 semi fuel cell were investigated. It was found that after the nickel foam was immersed in a 2 mmol·L-1 AuCl3 solution for 60 s,Au particles with diameters smaller than 100 nm were deposited on its surfaces and cover the surface completely. The Al-H2O2 semi fuel cell with Au/Ni cathode …

Optimization Of Membrane Electrode Assembly In Air-Breathing Direct Methanol Fuel Cell, Liang Ma, Wei-Wei Cai, Jing Zhang, Liang Liang, Jian-Hui Liao, Chang-Peng Liu, Wei Xing

Journal of Electrochemistry

The structure and performance of MEA were optimized by tailoring the catalyst layer,cathodic microporous layer ( MPL) ,anodic MPL and membrane,with the considerations of unique characteristics of airbreathing direct methanol fuel cell ( DMFC) such as methanol crossover and cathode flooding. It was found that high catalyst loading could suppress the methanol crossover effectively,but too high catalyst loading can lead to high mass transport resistance. Hydrophobic anodic MPL with 30% ( by mass) PTFE could facilitate the CO2 bubble detachment,which decreased the methanol concentration gradient and suppressed the methanol crossover accordingly. When Nafion 115 was used as membrane,methanol crossover was …

High-Rate Cyclic Properties Of Hollow Carbon Hemisphere As Anode Materials For Lithium Ion Batteries, Guang-Hui Zhang, Zao-Xue Yan, Hong-Li Zou, Pei-Kang Shen

Journal of Electrochemistry

High surface area hollow carbon hemispheres ( HCHs) covered with hard carbon layers have been synthesized by using polystyrene spheres ( PSs) as templates under hydrothermal method combined with the intermittent microwave heating ( IMH) method. The morphologies of the materials are characterized by SEM and TEM. The electrochemical properties of the HCHs are tested. Comparing with graphite and mesocarbon microbeads ( MCMB) ,the HCHs show higher capacity and excellent cyclic life performance.

Electrochemical Behaviors Of Hydrazine In Bmimpf_6 Solution At Ag Electrode, Jie Sun, Yan Li, Yi-Ling Feng, Rong Wang, Xia-Qin Wu

Journal of Electrochemistry

In this work,the electrochemical behaviors of hydrazine at Ag electrode in the room temperature ionic liquid,BmimPF6,were studied by cyclic voltammetry. Results suggested that Ag electrode showed a good catalytic activity towards hydrazine oxidation. The catalytic peak current showed a good linear relationship with the hydrazine concentration in the range of 0 ～ 3. 4 mmol/L. The rate-determining step of the electrocatalytic reaction involved one electron transfer form hydrazine molecule to Ag + ion.

Study On Electrocatalytic Properties For Oxygen Evolution Of Ti/Iro_2-Ta_2o_5 Anodes With Different Ir Contents, Yong-Lei Xin, Li-Kun Xu, Jun-Tao Wang

Journal of Electrochemistry

The anodes of Ti/IrO2-Ta2O5 were prepared by Pechini method. The effects of coating loading on the surface morphology and electrochemical properties of the anodes were characterized by scanning electron microscope ( SEM) ,energy dispersive X-ray detector ( EDX) ,potentiodynamic polarization,cyclic voltammetry and accelerated life test. The results indicate that with the increase of the coating loading,the oxide anode presents evident IrO2 crystallite segregation,and cracks become narrow and shallow. Moreover,it has larger electrochemically active surface area,better electrocatalytic activity for oxygen evolution and higher stability. It was observed that for an iridium content of 1. 98 ～ 9. 08 g/m2 the service …

Blocking Method In Enzyme-Amplified Amperometric Dna Biosensor, Miao He, Wei Chen, Xiong-Wei Xu, Ai-Lin Liu, Xin-Hua Lin

Journal of Electrochemistry

Non-specific absorption of enzyme and nucleotide is a main source leading to the background staining in enzyme-amplified amperometric detection of DNA. To eliminate the background staining in this system, the blocking procedure by mercapto-hexanol ( MCH) and bovine serum albumin ( BSA) was studied systematically. The results show that the anti-fouling effect of BSA is better than that of MCH. A simple and efficient blocking strategy employing BSA as the sole blocking reagent was established and applied in the detection of PMLRARα fusion gene in acute promyelocytic leukemia. It can effectively eliminate the background staining,shorten the pre-processing time,and achieve strong …

Electrochemical Behavior Of Kaempferide Interaction With Protein, Li-Qing Lin, Xin-Hua Lin, Jing-Hua Chen, Li-Ying Huang, Yin-Huan Liu, Guang-Wen Li

Journal of Electrochemistry

The electrochemical behavior of kaempferide at activated GCE and the interaction of kaempferide with human serum albumin( HSA) were investigated by cyclic voltammetry. A differential pulse voltammetric method has been proposed for the determination of the HSA with kaempferide. In pH 4. 5 phosphate buffer solutions ( PBS) kaempferide can react with HSA to form an electrochemically non-active supermolecular complex at activated GCE,resulting in the decrease of oxidation peak ( at 0. 468 V) without the change of peak potential. The decrease of the peak current is proportional to HSA concentration in the range of 0. 05 ～ 0. 25 …

Iris : Digital Scholarship, Publishing, And Preservation At Northeastern University, Hillary Corbett

Hillary Corbett

No abstract provided.

Collisional Transfer Of Population And Orientation In Nak, Seth T. Ashman, C. M. Wolfe, J. Huennekens, B. Beser, J. Bai, A. M. Lyyra

Engineering & Physics Faculty Publications

We report current work to study transfer of population and orientation in collisions of NaK molecules with argon and potassium atoms using polarization labeling (PL) and laser- induced fluorescence (LIF) spectroscopy. In the PL experiment, a circularly polarized pump laser excites a specific NaK A1Σ +(v 0=16, J 0 ) ← X1Σ +(v 00=0, J 0 ± 1) transition, creating an orientation (non-uniform MJ0 level distribution) in both levels. The linearly polarized probe laser is scanned over various 31Π(v, J 0±1) ← A1Σ +(v 0=16, J 0 ) transitions. The probe laser passes through a crossed linear polarizer before detection, …

Collaborative Proposal: 2000+ Year Detailed, Calibrated Climate Reconstruction From A South Pole Ice Core Set In An Antarctic - Global Scale Context, Paul Andrew Mayewski Dr., Karl J. Kreutz, Andrei V. Kurbatov

University of Maine Office of Research Administration: Grant Reports

This award supports a project to examine an existing ice core of opportunity from South Pole (SPRESO core) to develop a 2000+ year long climate record. SPRESO ice core will be an annually dated, sub-annually-resolved reconstruction of past climate (atmospheric circulation, temperature, precipitation rate, and atmospheric chemistry) utilizing continuous, co-registered measurements (n=45) of: major ions, trace elements, and stable isotope series, plus selected sections for microparticle size and composition. The intellectual merit of this project relates to the fact that few 2000+ year records of this quality exist in Antarctica despite increasing scientific interest in this critical time period as …

Convective Distribution Of Tropospheric Ozone And Tracers In The Central American Itcz Region: Evidence From Observations During Tc4, M A. Avery, Cynthia Twohy, David Mccabe, J Joiner, Kurt Severance, E L. Atlas, D R. Blake, T P. Bui, John D. Crounse, Jack E. Dibb, Glenn Diskin, Paul Lawson, Matthew Mcgill, David Rogers, G W. Sachse, Eric Scheuer, A M. Thompson, Charles Trepte, Paul Wennberg, Jerald Ziemke

Earth Sciences

During the Tropical Composition, Clouds and Climate Coupling (TC4) experiment that occurred in July and August of 2007, extensive sampling of active convection in the ITCZ region near Central America was performed from multiple aircraft and satellite sensors. As part of a sampling strategy designed to study cloud processes, the NASA ER‐2, WB‐57 and DC‐8 flew in stacked “racetrack patterns” in convective cells. On July 24, 2007, the ER‐2 and DC‐8 probed an actively developing storm and the DC‐8 was hit by lightning. Case studies of this flight, and of convective outflow on August 5, 2007 reveal a significant anti‐correlation …

Evidence Of Nitric Acid Uptake In Warm Cirrus Anvil Clouds During The Nasa Tc4 Campaign, Eric Scheuer, Jack E. Dibb, Cynthia Twohy, David Rogers, Andrew J. Heymsfield, Aaron Bansemer

Earth Sciences

Uptake of HNO3 onto cirrus ice may play an important role in tropospheric NOx cycling. Discrepancies between modeled and in situ measurements of gas-phase HNO3 in the troposphere suggest that redistribution and removal mechanisms by cirrus ice have been poorly constrained. Limited in situ measurements have provided somewhat differing results and are not fully compatible with theory developed from laboratory studies. We present new airborne measurements of HNO3 in cirrus clouds from anvil outflow made during the Tropical Composition, Cloud, and Climate Coupling Experiment (TC4). Upper tropospheric (>9 km) measurements made during three flights while repeatedly traversing the same …

Dissecting Galaxy Formation. Ii. Comparing Substructure In Pure Dark Matter And Baryonic Models, Emilio Romano-Diaz, Isaac Shlosman, Clayton Heller, Yehuda Hoffman

Department of Physics and Astronomy Faculty Publications

We compare the substructure evolution in pure dark matter (DM) halos with those in the presence of baryons, hereafter PDM and BDM models, respectively. The prime halos have been analyzed in the previous work. Models have been evolved from identical initial conditions which have been constructed by means of the constrained realization method. The BDM model includes star formation and feedback from stellar evolution onto the gas. A comprehensive catalog of subhalo populations has been compiled and individual and statistical properties of subhalos analyzed, including their orbital differences. We find that subhalo population mass functions in PDM and BDM are …

Exotic Smoothness In Four Dimensions And Euclidean Quantum Gravity, Christopher L. Duston

Physics Faculty Publications

In this paper we calculate the effect of the inclusion of exotic smooth structures on typical observables in Euclidean quantum gravity. We do this in the semiclassical regime for several gravitational free-field actions and find that the results are similar, independent of the particular action that is chosen. These are the first results of their kind in dimension four, which we extend to include one-loop contributions as well. We find these topological features can have physically significant results without the need for additional exotic physics.

Mississippi Canyon 252 Incident Nrda Tier 1 For Deepwater Communities, Gregory Boland, Gary Brewer, Erik Cordes, Amanda Demopoulos, Chuek Fisher, Chris German, Ken Sulak

United States Geological Survey: Staff Publications

The northern Gulf of Mexico (GOM) is geologically diverse basin, described as the most complex continental slope region in the world. Regional topography of the slope consists of basins, knolls, ridges, and mounds derived from the dynamic adjustments of salt and the introduction of large volumes of sediment over long time scales. More than 99% of the sea floor in the GOM consists of soft sediment made up of various mixtures of primarily silt and clay. These wide-spread soft bottom communities are described in reports from major MMS studies by Gallaway et al. (1998) and Rowe and Kennicutt (2009). Relative …

An Empirical Approach To Evaluating Sufficient Similarity: Utilization Of Euclidean Distance As A Similarity Measure, Scott Marshall

Theses and Dissertations

Individuals are exposed to chemical mixtures while carrying out everyday tasks, with unknown risk associated with exposure. Given the number of resulting mixtures it is not economically feasible to identify or characterize all possible mixtures. When complete dose-response data are not available on a (candidate) mixture of concern, EPA guidelines define a similar mixture based on chemical composition, component proportions and expert biological judgment (EPA, 1986, 2000). Current work in this literature is by Feder et al. (2009), evaluating sufficient similarity in exposure to disinfection by-products of water purification using multivariate statistical techniques and traditional hypothesis testing. The work of …

Density Functional Studies Of The Stability Of Clusters, Penee Clayborne

Theses and Dissertations

Theoretical studies using the Kohn-Sham density functional formalism have been carried out to identify and investigate the stability of a variety of atomic clusters for their use in cluster assembled materials. The stable behavior found in a cluster system provides a way to classify inorganic clusters. The clusters in this study can be categorized in one of the following, jellium, all-metal aromatic, Zintl analogue or as a covalent metal-carbide. By understanding the electronic structure and ultimately the stable nature of a cluster first, it is proposed one can construct assemblies based on the stable cluster. The methodology presented is a …

Estuarine Blue Infrastructure: Priority Conservation Areas For The Seaside Of Virginia’S Eastern Shore, Center For Coastal Resources Management, Virginia Institute Of Marine Science

Reports

This project is an extension of earlier efforts within the coastal zone of Virginia to build a platform for enhanced Blue and Green Infrastructure planning. This project is motivated by an interest in extending statewide conservation efforts into estuarine systems and recognition that land use decisions on the upland effect water quality and habitat health in the receiving waters. The project in its entirety has been accomplished in distinct parts. Part one develops a Cumulative Resource Assessment to evaluate the distribution of aquatic natural resources within waters of Virginia’s Chesapeake Bay waters, Back Bay of Virginia Beach, Virginia, and the …

Experimental Studies Of The Nacs 53Π0 And 1(A)3Σ+ States, Seth T. Ashman, Brett Mcgeehan, Christopher Wolfe, Carl Faust, John Huennekens

Engineering & Physics Faculty Publications

We present experimental studies of the NaCs molecule that are currently underway in our laboratory. The opticaloptical double resonance method is used to obtain Doppler-free excitation spectra for several excited states. Selected data from the 53Π0 electronic state are used to obtain Rydberg-Klein-Rees (RKR) and Inverse Perturbation Approach (IPA) potential curves. We are also mapping the repulsive wall of the 1(a) 3Σ +potential using many resolved bound-free fluorescence spectra from individual ro-vibrational levels of the 53Π0 electronic state to the 1(a) 3Σ + state. Using the determined 53Π0 state potential we fit the repulsive wall of the 1(a) 3Σ + …

New Bedford/Fairhaven Municipal Harbor Plan, Fort Point Associates, Inc., Apex Companies, Llc, Urban Harbors Institute, University Of Massachusetts Boston, Fxm Associates

Urban Harbors Institute Publications

The historic harbor lying between the City of New Bedford and Town of Fairhaven has shaped the identities and economies of these two municipalities for centuries. Today, the Harbor is one of nation’s preeminent fishing ports, ranked #1 nationally in 2007 in dollar value ($268 million) of fish landings with an estimated total economic regional impact of nearly $1 billion. The New Bedford’s seafood processing industry has grown in size and sophistication in recent years and is an internationally established center for this industry. Marine service and vessel repair industries, centered in Fairhaven, have an excellent reputation with commercial fleets …

Functionalization Of Fibers Using Azlactone-Containing Polymers: Layer-By-Layer Fabrication Of Reactive Thin Films On The Surfaces Of Hair And Cellulose-Based Materials, Maren E. Buck, David M. Lynn

Chemistry: Faculty Publications

We report an approach to the functionalization of fibers and fiber-based materials that is based on the deposition of reactive azlactone-functionalized polymers and the "reactive" layer-by-layer assembly of azlactone-containing thin films. We demonstrate (i) that the azlactone-functionalized polymer poly(2-vinyl-4,4-dimethylazlactone) (PVDMA) can be used to modify the surfaces of a model protein-based fiber (horsehair) and cellulose-based materials (e.g., cotton and paper), and (ii) that fibers functionalized in this manner can be used to support the fabrication of covalently cross-linked and reactive polymer multilayers assembled using PVDMA and poly(ethyleneimine) (PEI). The growth, chemical reactivity, and uniformity of films deposited on these substrates …

Inquiry In Support Of The Knowledge Sharing Life Cycle Within A Higher Education Database Practicum: A Case Study At Regis University, Martha Jorgensen

Regis University Student Publications (comprehensive collection)

The Regis University database practicum provides an opportunity for students to get hands-on experience with Database Administrator (DBA) tasks as they support the virtual lab environment used by students enrolled in database courses at the university. The student DBA team is new each semester and has a short time to become familiar with the environment they are supporting and the tools they will be using. Inefficient communication and organization delay the resolution of production issues. This study analyzed the current knowledge sharing culture, technologies, and processes of the database practicum. The goal of the study was to determine accessibility of …

Control System Performance And Efficiency For A Mid-Depth Lagrangian Profiling Float, B. Mcgilvray, C. Roman

Christopher N. Roman

This paper presents the development of a new mid-depth Lagrangian profiling float with a primary emphasis on the control system performance and efficiency. While deep water floats have demonstrated much success in open ocean environments, many are not suited for the additional challenges associated with coastal regions. To study these regions, which are often subject to varying bathymetry within the operating range and higher variations in water density, a more advanced system is required. This new design utilizes pressure and altitude feedback to drive a high volume auto-ballasting system (ABS). The main operating modes of this float include step inputs …

Robin Lite 3d Fmcw Bird Radar: Revolutionizing Airport Birdstrike Prevention, Addy Borst

Bird Strike Committee-USA/Canada Joint Annual Meeting: 11th (2009)

Table of Contents:
The avian radar arena
A new kid in town: ROBIN Lite 3D FMCW avian radar
Our roots in radar technology
Our roots in avian radars
From raw radar data to realtime info bird movements
ROBIN Lite 3D FMCW: System design requirements driven by users
Main avian radar system requirements
System design conclusions ROBIN Lite 3D FMCW
ROBIN Lite 3D FMCW implementation
ROBIN Lite 3D FMCW: Horizontal radar
ROBIN Lite 3D FMCW: Vertical radar
ROBIN Lite 3D FMCW: Data acquisition electronics
ROBIN Lite 3D FMCW Signal/image processing
ROBIN Lite 3D FMCW ground clutter filter
ROBIN Lite 3D FMCW …

Raptors On Three Rnlaf Airbases, Numbers, Strikes, Trapping And Relocation.

Bird Strike Committee-USA/Canada Joint Annual Meeting: 11th (2009)

Since gulls, pigeons, starlings, waders and corvids are the dominant bird species on NW European airfields it is not surprising that habitat management systems are aimed at reducing the numbers of these species from the runway environment. In the RNLAF this is realized by a “poor grass” regime. This is based on the idea that by bottoming out the soil the available biomass will decrease and hence the number of birds foraging on this biomass. In practice this means that the grass is mown and the clippings are removed without applying any fertilization. Neither length nor species composition of the …

Light Scalar Puzzle In Qcd, Joseph Schechter, Amir H. Fariborz, Renata Jora

Physics - All Scholarship

An approach to understanding the light scalar meson phenomenology is briefly reviewed.

Interview With Steve Jones, Us Forest Service, 2010 (Audio), Steve Jones

All Sustainability History Project Oral Histories

Interview of Steve Jones by Scott Swenson at Hood River, Oregon on May 25th, 2010.

The interview index is available for download.

Study Of Nano Structure Mn/Alumina Catalyst Deactivation Through Catalytic Oxidation Of O-Vocs, Hosein Afshary

Hosein Afshary

the deactivation and selectivity behavior of nanostructure Mn/γ-Al2O3 catalyst in catalytic oxidation of an O-VOC (isopropanol) was studied. The polluted air was simulated and the catalyst was tested in the course of 50-h time-on-stream. Characterization of fresh and used catalysts was done using FT-IR, XRD, SEM and EDS methods. Comparing the testing results of this catalyst and that of the industrial Pt/Al2O3 catalyst showed that prepared catalyst can be suitable for substitution with the expensive pt/Al2O3 catalyst in environmental applications.