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2010

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Articles 7681 - 7710 of 8621

Full-Text Articles in Physical Sciences and Mathematics

Effluent Organic Nitrogen (Eon): Bioavailability And Photochemical And Salinity-Mediated Release, Deborah A. Bronk, Quinn N. Roberts, Marta P. Sanderson, Elizabeth A. Canuel, Patrick G. Hatcher, Rajaa Mesfioui, Katherine C. Filippino, Margaret R. Mulholland, Nancy G. Love Jan 2010

Effluent Organic Nitrogen (Eon): Bioavailability And Photochemical And Salinity-Mediated Release, Deborah A. Bronk, Quinn N. Roberts, Marta P. Sanderson, Elizabeth A. Canuel, Patrick G. Hatcher, Rajaa Mesfioui, Katherine C. Filippino, Margaret R. Mulholland, Nancy G. Love

Chemistry & Biochemistry Faculty Publications

The goal of this study was to investigate three potential ways that the soluble organic nitrogen (N) fraction of wastewater treatment plant (WWTP) effluents, termed effluent organic N (EON), could contribute to coastal eutrophication - direct biological removal, photochemical release of labile compounds, and salinity-mediated release of ammonium (NH4+). Effluents from two WWTPs were used in the experiments. For the bioassays, EON was added to water from four salinities (∼0 to 30) collected from the James River (VA) in August 2008, and then concentrations of N and phosphorus compounds were measured periodically over 48 h. Bioassay results, based …

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An Examination Of The Association Of Selected Toxic Metals With Total And Central Obesity Indices: Nhanes 99-02, Miguel A. Padilla, Mai Elobeid, Douglas M. Ruden, David B. Allison Jan 2010

An Examination Of The Association Of Selected Toxic Metals With Total And Central Obesity Indices: Nhanes 99-02, Miguel A. Padilla, Mai Elobeid, Douglas M. Ruden, David B. Allison

Psychology Faculty Publications

It is conceivable that toxic metals contribute to obesity by influencing various aspects of metabolism, such as by substituting for essential micronutrients and vital metals, or by inducing oxidative stress. Deficiency of the essential metal zinc decreases adiposity in humans and rodent models, whereas deficiencies of chromium, copper, iron, and magnesium increases adiposity. This study utilized the NHANES 99-02 data to explore the association between waist circumference and body mass index with the body burdens of selected toxic metals (barium, cadmium, cobalt, cesium, molybdenum, lead, antimony, thallium, and tungsten). Some of the associations were significant direct relationships (barium and thallium), …

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Synthesis And Uranyl Ion Adsorption Study Of Cross-Linked Allyl Propionate-Maleic Anhydride-Styrene Terpolymer, Elchin Akperov, Abel Maharramov, Oktay Akperov Jan 2010

Synthesis And Uranyl Ion Adsorption Study Of Cross-Linked Allyl Propionate-Maleic Anhydride-Styrene Terpolymer, Elchin Akperov, Abel Maharramov, Oktay Akperov

Turkish Journal of Chemistry

Allyl propionate-maleic anhydride-styren terpolymer has been modified with glycerin in order to prepare a new cross-linked functional polymer sorbent. The synthesized cross-linked polymer sorbent has a network structure and contains carboxylic acid, carbonyl, hydroxy, and ester groups, all of which are capable ofinteracting with metal ions. The sorption behavior of UO_2^{2+} ions under optimum sorption conditions was determined. The sorption properties of the sorbent were determined under different conditions by varying of the pH of medium, the sorbent weight, and the initial concentration of uranyl ions. The maximum experimental sorption capacity of the sorbent for uranyl ions was measured as …

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Some Bioactive Organotin(Iv) Derivatives With 3,4-Dichlorophenylacetic Acid: Synthesis, Spectroscopic Properties, And X-Ray Structure Of [Sn_4(C_4h_9)_8(Oocch_2c_6h_3cl_2)_4o_2], Muhammad Adeel Saeed, Muhammad Khawar Rauf, . Imtiaz-Ud-Din, Amin Badshah, Muhammad Zaeem Akhtar, Bushra Mirza Jan 2010

Some Bioactive Organotin(Iv) Derivatives With 3,4-Dichlorophenylacetic Acid: Synthesis, Spectroscopic Properties, And X-Ray Structure Of [Sn_4(C_4h_9)_8(Oocch_2c_6h_3cl_2)_4o_2], Muhammad Adeel Saeed, Muhammad Khawar Rauf, . Imtiaz-Ud-Din, Amin Badshah, Muhammad Zaeem Akhtar, Bushra Mirza

Turkish Journal of Chemistry

Some bioactive organotin(IV) derivatives of 3,4-dichlorophenylacetic acid (HL) were synthesized by reacting the ligand acid with various di- or tri-organotin compounds (in suitable mole ratios) in the presence of triethylamine. The structural investigation was carried out via multinuclear (^1H, ^{13}C, and ^{119}Sn) NMR, IR spectroscopy, and X-ray crystallography. The crystal structure of 4 comprises a central Sn_2O_2 core with O atoms bonded to 2 dibutylbis(3,4-dichlorophenylacetato)tin(IV) units. All the Sn atoms of 4 are essentially 5-coordinated in distorted trigonal-bipyramidal geometry. Some of the compounds exhibited significant antibacterial and antifungal activity.

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Density Functional Theory Investigation Of Electrophilic Addition Reaction Of Chlorine To Tricyclo[4.2.2.2^{2,5}]Dodeca-1,5-Diene, Rza Abbasoğlu, Ahmet Yaşar Jan 2010

Density Functional Theory Investigation Of Electrophilic Addition Reaction Of Chlorine To Tricyclo[4.2.2.2^{2,5}]Dodeca-1,5-Diene, Rza Abbasoğlu, Ahmet Yaşar

Turkish Journal of Chemistry

Potential energy surface (PES) of the tricyclo[4.2.2.2^{2,5}]dodeca- 1,5-diene (TCDD)-Cl_2 system was studied by B3LYP/6-311+G(d,p) method and the configurations [reactants, molecular charge-transfer (CT) complex, transition states (TS1 and TS2), intermediate (INT), and product (P)] corresponding to the stationary points (minima or saddle points) were determined. Initially, a molecular CT-complex forms between Cl_2 and TCDD. With a barrier of 22.362 kcal mol^{-1} the CT-complex can be activated to an intermediate (INT) with energy 14.682 kcal mol^{-1} higher than that of the CT-complex. The intermediate (INT) then transforms easily (barrier 5.102 kcal mol^{-1}) into the final, N-type product. Accompanying the breaking of the …

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Interference Elimination Studies During The Determination Of Trace Elements In Cow Liver Using Differential Pulse Polarography, Ümmi̇han T. Yilmaz, Güler Somer Jan 2010

Interference Elimination Studies During The Determination Of Trace Elements In Cow Liver Using Differential Pulse Polarography, Ümmi̇han T. Yilmaz, Güler Somer

Turkish Journal of Chemistry

The liver is known to accumulate many trace elements; thus it is very important to determine their level in a sensitive way. The objective of this study was to develop a simple method for the simultaneous determination of trace elements in cow liver in which the elimination of interference can be accomplished. It was observed that Cd, Pb, Zn, and Cu ions could not be determined correctly in the presence of Se(IV), because of interference of Se. It was shown that this interference could be eliminated by using pH 8.5 NaAc electrolyte. In this medium first Cd and Zn were …

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Template Synthesis And Characterization Of 16-Membered Octaazamacrocyclic Complexes: A Photoelectron Spectroscopic Study, Abul Kalam, Vishnu Tripathi, Shekhar Srivastava, Yogesh Pandey, Anil Kumar, Alok Gupta, Sharat Srivastava, Ankoor Purohit Jan 2010

Template Synthesis And Characterization Of 16-Membered Octaazamacrocyclic Complexes: A Photoelectron Spectroscopic Study, Abul Kalam, Vishnu Tripathi, Shekhar Srivastava, Yogesh Pandey, Anil Kumar, Alok Gupta, Sharat Srivastava, Ankoor Purohit

Turkish Journal of Chemistry

A novel series of complexes of the type [MLX_2] where M= Mn(II), Co(II), Ni(II), Cu(II) and Zn(II); X= C^- or NO_3^- were synthesized by template condensation of hydrazine hydrate, acetaldehyde, 2,4-pentanedione, and thiocarbohydrazide in the presence of divalent metal salt in methanolic solution. The complexes were characterized with the help of elemental analysis, conductance measurements, magnetic measurements, electronic, NMR, XPS, and infrared and far infrared spectral studies. Electronic spectra along with magnetic moments suggest 6-coordinated octahedral geometry for these complexes. The low value of molar conductance indicates them to be non-electrolytes.

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Food Phone Application, Shengyu Li Jan 2010

Food Phone Application, Shengyu Li

Master's Projects

This project is about implementing a food menu application for users to search and upload food information by using a mobile phone. People sometimes may just know what food they wish to eat instead of the restaurants' name. Without knowing any restaurants' names, our food application's search only requires the name of the dish (e.g., hamburger, spaghetti, etc) in order to get the list of restaurants that serve these items and their corresponding information (e.g., location, hours, phone number, item's price, etc.). An advantage of using my food application is the system not only includes Google Map, but any information …

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Enhancing Open-Source Localization, Farzana Forhad Jan 2010

Enhancing Open-Source Localization, Farzana Forhad

Master's Projects

Pootle is a web portal which is designed to be a web translation tool. We can run Pootle like an internet server and run a local copy on an intranet. Pootle has a user friendly interface which ensures better quality and easier translation of projects. Users can log into the Pootle and create their own projects under any language, and they can also add or retrieve any language from any project or any project from any language. Although Pootle has many advantages, it also has its drawbacks, and one of the biggest drawbacks of Pootle is that whatever translation is …

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Exhaustive Statistical Analysis For Detection Of Metamorphic Malware, Aditya Govindaraju Jan 2010

Exhaustive Statistical Analysis For Detection Of Metamorphic Malware, Aditya Govindaraju

Master's Projects

Malware is a serious threat to the security of the system. With the widespread use of the World Wide Web, there has been a tremendous increase in virus attacks, making computer security an essential for every personal computer. The rat-race between virus writers and detectors has led to improved viruses and detection techniques. In recent years, metamorphic malwares have posed serious challenge to anti-virus writers. Current signature based detection techniques, heuristic based techniques are not comprehensive solutions. A formidable solution to detection of metamorphic malware is void. This paper investigates the problem of malware detection, specifically metamorphic malwares. The paper …

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How Smart Is Your Android Smartphone?, Deepika Mulani Jan 2010

How Smart Is Your Android Smartphone?, Deepika Mulani

Master's Projects

Smart phones are ubiquitous today. These phones generally have access to sensitive personal information and, consequently, they are a prime target for attackers. A virus or worm that spreads over the network to cell phone users could be particularly damaging. Due to a rising demand for secure mobile phones, manufacturers have increased their emphasis on mobile security. In this project, we address some security issues relevant to the current Android smartphone framework. Specifically, we demonstrate an exploit that targets the Android telephony service. In addition, as a defense against the loss of personal information, we provide a means to encrypt …

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A Study Of Satisfaction Level Of Hong Kong Tourists With Hot Springs Hotels And Resorts In Guangdong, China, Rob Law, Ruby Yip Jan 2010

A Study Of Satisfaction Level Of Hong Kong Tourists With Hot Springs Hotels And Resorts In Guangdong, China, Rob Law, Ruby Yip

Hospitality Review

The research reported here aimed at examining Hong Kong tourists’ level of satisfaction with hot springs hotels and resorts in Guangdong, China. Primary data were collected and service quality and tourist satisfaction levels were measured using the SERVQUAL model. The empirical findings indicate that most tourists are satisfied with the service quality of these hotels and resorts. Among the different dimensions of service quality, empathy receives the highest score. Overall satisfaction receives a score only slightly better than average. The results also reveal significant relationships among customer satisfaction level, loyalty, and recommendation.

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Pathogenic And Opportunistic Microorganisms In Caves, Valme Jurado, Leonila Laiz, Veronica Rodriguez-Nava, Patrick Boiron, Bernardo Hermosin, Sergio Sanchez-Moral, Cesareo Saiz-Jimenez Jan 2010

Pathogenic And Opportunistic Microorganisms In Caves, Valme Jurado, Leonila Laiz, Veronica Rodriguez-Nava, Patrick Boiron, Bernardo Hermosin, Sergio Sanchez-Moral, Cesareo Saiz-Jimenez

International Journal of Speleology

With today’s leisure tourism, the frequency of visits to many caves makes it necessary to know about possible potentially pathogenic microorganisms in caves, determine their reservoirs, and inform the public about the consequences of such visits. Our data reveal that caves could be a potential danger to visitors because of the presence of opportunistic microorganisms, whose existence and possible development in humans is currently unknown.

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Mineral And Whole-Rock Geochemistry Of The Kestanbol Granitoid (Ezine-Çanakkale) And Its Mafic Microgranular Enclaves In Northwestern Anatolia: Evidence Of Felsic And Mafic Magma Interaction, Sabah Yilmaz Şahi̇n, Yüksel Örgün, Yildirim Güngör, A. Feti̇ Göker, A. Haydar Gülteki̇n, Zeki̇ye Karacik Jan 2010

Mineral And Whole-Rock Geochemistry Of The Kestanbol Granitoid (Ezine-Çanakkale) And Its Mafic Microgranular Enclaves In Northwestern Anatolia: Evidence Of Felsic And Mafic Magma Interaction, Sabah Yilmaz Şahi̇n, Yüksel Örgün, Yildirim Güngör, A. Feti̇ Göker, A. Haydar Gülteki̇n, Zeki̇ye Karacik

Turkish Journal of Earth Sciences

The Miocene Kestanbol granitoid, in Ezine-Çanakkale, Turkey, is one of post-collision granitoids of western Anatolia, which have been related to the the late Cretaceous collision between the Anatolide-Tauride platform and the Pontides. Magmatism began during the early Miocene, with coeval alkaline to calc-alkaline plutonism and volcanism, controlled by the regional tectonic evolution. The Kestanbol pluton intruded regionally metamorphosed basement rocks. Volcanic and volcano-clastic sedimentary rocks overlie the pluton, which is bounded in the west and east by major faults. The pluton is frequently cut by felsic and mafic dykes and includes mafic microgranular enclaves (MMEs) that are mixing products of …

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Petrography And Geochemistry Of The Jajarm Bauxite Ore Deposit, Northeast Iran: Implications For Source Rock Material And Ore Genesis, Dariush Esmaeily, Hosein Rahimpour-Bonab, Amir Esna-Ashari, Ali Kananian Jan 2010

Petrography And Geochemistry Of The Jajarm Bauxite Ore Deposit, Northeast Iran: Implications For Source Rock Material And Ore Genesis, Dariush Esmaeily, Hosein Rahimpour-Bonab, Amir Esna-Ashari, Ali Kananian

Turkish Journal of Earth Sciences

The Jajarm bauxite deposit, northeast Iran, is the largest such deposit in Iran. The deposit is sandwiched between the Triassic Elika formation and the Jurassic Shemshak formation, housed within karstic features developed within the former unit. The deposit generally shows an internal layering defined by the following four distinct horizons (from bottom to top): (a) a lower argillaceous horizon, approximately 50-80 cm thick, is mainly composed of clay minerals that directly overlies the carbonate footwall (Elika formation); (b) a bauxitic clay layer approximately 2-3 m thick that consists mainly of hematite, kaolinite, anatase, and diaspore; (c) a red bauxite layer …

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Dictyoptychus Douvillé: Taxonomic Revision, Phylogeny And Biogeography, Saci̇t Özer Jan 2010

Dictyoptychus Douvillé: Taxonomic Revision, Phylogeny And Biogeography, Saci̇t Özer

Turkish Journal of Earth Sciences

The late Campanian-Maastrichtian transgressive sequences of the southeastern Anatolia (northernmost part of the Arabian platform) and only one Maastrichtian limestone block within the ophiolitic association of the easternmost part of the Taurus Orogenic Belt contain very well-preserved specimens of Dictyoptychus Douvillé 1905. Study of Turkish specimens and also of those described in the literature reveals considerable ontogenic variability, hence need for revision of the species of the genus erected hitherto. Dictyoptychus leesi (Kühn 1929), Dictyoptychus paronai (Kühn 1929), Dictyoptychus persicus (Cox 1934), Dictyoptychus euphratica Karacabey-Öztemür 1979 and Dictyoptychus orontica Karacabey-Öztemür 1979 are accordingly re-interpreted to represent a single species synonymous …

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Structure And Optical Properties Of Cuals_2 Thin Films Prepared Via Chemical Bath Deposition, Tariq Alwan, Mushtak Jabbar Jan 2010

Structure And Optical Properties Of Cuals_2 Thin Films Prepared Via Chemical Bath Deposition, Tariq Alwan, Mushtak Jabbar

Turkish Journal of Physics

CuAlS_2 thin films of thicknesses 118 \pm 5 nm were deposited on glass substrates using chemical bath deposition technique. The details of the preparation method are well described. The method is relatively simple and is easily controlled and sufficient to produce large area and good adherence to the substrate films. Effect of annealing temperature T_a on the structure, and optical properties of CuAlS_2 films were investigated. The structures of the films were studied by X-ray diffraction and FTIR spectrophotometer. The optical properties of the films were ascertained by UV-VIS spectrophotometer (wavelengths ranging between 300 and 900 nm). The optical transmittance …

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Landscape Values As A Determinant In Geotourism Development: A Case Study Of Utah, Usa, E. Papińska, Elzbieta Białkowska-Jelińska Jan 2010

Landscape Values As A Determinant In Geotourism Development: A Case Study Of Utah, Usa, E. Papińska, Elzbieta Białkowska-Jelińska

School of Geosciences Student Publications

The state of Utah is located in west-central United States. The area of 219 887 km2is populated by 2.8 million people (in 2009). Population density is relatively low: 12 persons per square km. The main reasons for low population density are unfavourable natural conditions. The most important are topography and climate. Utah’s landscape diversity is a consequence of a variety of terrain types. For that reason, there are 5 national parks (Zion, Bryce, Capitol Reef, Arches and Canyonlands), national monuments, and other lower rank protected areas established in Utah. Each of these places, characterized by unique types of …

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A Dynamic Physical Model For Soil Temperature And Water In Taylor Valley, Antarctica, H. W. Hunt, Andrew G. Fountain, Peter T. Doran, Hassan J. Basagic Jan 2010

A Dynamic Physical Model For Soil Temperature And Water In Taylor Valley, Antarctica, H. W. Hunt, Andrew G. Fountain, Peter T. Doran, Hassan J. Basagic

Geography Faculty Publications and Presentations

We developed a simulation model for terrestrial sites including sensible heat exchange between the atmosphere and ground surface, inter- and intra-layer heat conduction by rock and soil, and shortwave and longwave radiation. Water fluxes included snowmelt, freezing/thawing of soil water, soil capillary flow, and vapour flows among atmosphere, soil, and snow. The model accounted for 96-99% of variation in soil temperature data. No long-term temporal trends in soil temperature were apparent. Soil water vapour concentration in thawed surface soil in summer often was higher than in frozen deeper soils, leading to downward vapour fluxes. Katabatic winds caused a reversal of …

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Modern C, O, And H Isotope Composition Of Speleothem And Dripwater From Modrič Cave, Eastern Adriatic Coast (Croatia), Maša Surić, Zvjezdana Roller-Lutz, Magda Mandić, Ines Krajcar Bronić, Mladen Juračić Jan 2010

Modern C, O, And H Isotope Composition Of Speleothem And Dripwater From Modrič Cave, Eastern Adriatic Coast (Croatia), Maša Surić, Zvjezdana Roller-Lutz, Magda Mandić, Ines Krajcar Bronić, Mladen Juračić

International Journal of Speleology

Modrič Cave is a shallow horizontal cave situated in the middle of the eastern Adriatic coast (Croatia). The cave entrance is located 120 m from the coast at an altitude of 32 m above sea level, and due to its position on the SW slope of the Dinaridic mountain range, a Mediterranean climatic influence is dominant. Due to the stable environmental conditions [(15.6 ± 0.1) °C] Modrič Cave was recognized as a potential site for detailed palaeoclimatic studies. Isotope analyses of modern carbonate speleothems, rain and dripwater were conducted in order to evaluate the isotopic equilibrium conditions. The δ18O composition …

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Origins Of The Extragalactic Background At 1mm From A Combined Analysis Of The Aztec And Mambo Data In Goods-N, Kyle Penner, Alexandra Pope, Edward Chapin, Thomas Greve, Frank Bertoldi, Mark Brodwin, Ranga-Ram Chary, Christopher Conselice, Kristen Coppin, Mauro Giavalisco, David Hughes, Rob Ivison, Thushara Perera, Douglas Scott, Kimberly Scott, Grant Wilson Jan 2010

Origins Of The Extragalactic Background At 1mm From A Combined Analysis Of The Aztec And Mambo Data In Goods-N, Kyle Penner, Alexandra Pope, Edward Chapin, Thomas Greve, Frank Bertoldi, Mark Brodwin, Ranga-Ram Chary, Christopher Conselice, Kristen Coppin, Mauro Giavalisco, David Hughes, Rob Ivison, Thushara Perera, Douglas Scott, Kimberly Scott, Grant Wilson

Scholarship

We present a study of the cosmic infrared background, which is a measure of the dust obscured activity in all galaxies in the Universe. We venture to isolate the galaxies responsible for the background at 1mm; with spectroscopic and photometric redshifts we constrain the redshift distribution of these galaxies. We create a deep 1.16mm map (sigma ~ 0.5mJy) by combining the AzTEC 1.1mm and MAMBO 1.2mm datasets in GOODS-N. This combined map contains 41 secure detections, 13 of which are new. By averaging the 1.16mm flux densities of individually undetected galaxies with 24um flux densities > 25uJy, we resolve 31--45 per …

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Categorical Approaches To Non-Commutative Fuzzy Logic, Lawrence Stout Jan 2010

Categorical Approaches To Non-Commutative Fuzzy Logic, Lawrence Stout

Scholarship

In this paper we consider what it means for a logic to be non-commutative, how to generate examples of structures with a non-commutative operation * which have enough nice properties to serve as the truth values for a logic. Inference in the propositional logic is gotten from the categorical properties (products, coproducts, monoidal and closed structures, adjoint functors) of the categories of truth values. We then show how to extend this view of propositional logic to a predicate logic using categories of propositions about a type A with functors giving change of type and adjoints giving quantifiers. In the case …

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Computational Micromodel For Epigenetic Mechanisms, Karthika Raghavan, Heather J. Ruskin, Dimitri Perrin, Francois Goasmat, John Burns Jan 2010

Computational Micromodel For Epigenetic Mechanisms, Karthika Raghavan, Heather J. Ruskin, Dimitri Perrin, Francois Goasmat, John Burns

Articles

Characterization of the epigenetic profile of humans since the initial breakthrough on the human genome project has strongly established the key role of histone modifications and DNA methylation. These dynamic elements interact to determine the normal level of expression or methylation status of the constituent genes in the genome. Recently, considerable evidence has been put forward to demonstrate that environmental stress implicitly alters epigenetic patterns causing imbalance that can lead to cancer initiation. This chain of consequences has motivated attempts to computationally model the influence of histone modification and DNA methylation in gene expression and investigate their intrinsic interdependency. In …

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A Mild And Chemoselective Method For The Deprotection Of Tert-Butyldimethylsilyl (Tbdms) Ethers Using Iron(Iii) Tosylate As A Catalyst, Ram Mohan, Jason Bothwell, Veronica Angeles, James Carolan, Margaret Olson Jan 2010

A Mild And Chemoselective Method For The Deprotection Of Tert-Butyldimethylsilyl (Tbdms) Ethers Using Iron(Iii) Tosylate As A Catalyst, Ram Mohan, Jason Bothwell, Veronica Angeles, James Carolan, Margaret Olson

Scholarship

The most common method for the deprotection ofTBDMS ethers utilizes stoichiometric amounts of tetrabutylammonium fluoride, n-Bu4N+F(TBAF), which is highly corrosive and toxic. We have developed a mild and chemoselective method for the deprotection ofTBDMS, TES, and TIPS ethers using iron(III) tosylate as a catalyst. Phenolic TBDMS ethers, TBDPS ethers and the BOC group are not affected under these conditions. Iron(III) tosylate is an inexpensive, commercially available, and non-corrosive reagent.

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Bismuth(Iii) Bromide In Organic Synthesis. A Catalytic Method For The Allylation Of Tetrahydrofuranyl And Tetrahydropyranyl Ethers, Ram Mohan, Scott Krabbe, Veronica Angeles Jan 2010

Bismuth(Iii) Bromide In Organic Synthesis. A Catalytic Method For The Allylation Of Tetrahydrofuranyl And Tetrahydropyranyl Ethers, Ram Mohan, Scott Krabbe, Veronica Angeles

Scholarship

A bismuth bromide-catalyzed (10.0 mol %) multicomponent reaction involving the allylation of THF- and THP-ethers, followed by in situ derivatization with acetic anhydride to generate highly functionalized esters has been developed under solvent-free conditions. To the best of our knowledge, this is the first report of a catalytic procedure for the allylation of THF- and THP-ethers to yield ring-opened products.

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Iron(Iii) Tosylate-Catalyzed Deprotection Of Aromatic Acetals In Water, Ram Mohan, Margaret Olson, James Carolan, Michael Chiodo, Phillip Lazzara Jan 2010

Iron(Iii) Tosylate-Catalyzed Deprotection Of Aromatic Acetals In Water, Ram Mohan, Margaret Olson, James Carolan, Michael Chiodo, Phillip Lazzara

Scholarship

The deprotection of aromatic as well as conjugated acetals and ketals in water is catalyzed by iron(III) tosylate (1.0–5.0 mol %). Iron(III) tosylate is an inexpensive and readily available catalyst. The use of water, the most environmentally benign solvent, makes this procedure especially attractive for acetal deprotection.

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High-Resolution Cavity-Enhanced Spectroscopy Of Molecular Ion Beams, Manori Perera, Andrew Mills, Brian Siller, Michael Porambo, Kyle Crabtree, Carrie Kauffman, Holger Kreckel, Benjamin Mccall Jan 2010

High-Resolution Cavity-Enhanced Spectroscopy Of Molecular Ion Beams, Manori Perera, Andrew Mills, Brian Siller, Michael Porambo, Kyle Crabtree, Carrie Kauffman, Holger Kreckel, Benjamin Mccall

Scholarship

Molecular ions play a pivotal role in the chemistry of the interstellar medium due to their high reactivity even at low temperature. To identify these ions in interstellar space, it is essential to obtain high resolution laboratory spectra of potential interstellar ions for comparison to observational data. At the University of Illinois, we are developing a Sensitive, Cooled, Resolved Ion BEam Spectrometer (SCRIBES) that will allow us to obtain high resolution infrared direct absorption spectra of rotationally cold molecular ions in the absence of neutral molecules. This instrument can overcome many of the problems that arise when using other spectroscopic …

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In Your Element: Green Bismuth, Ram Mohan Jan 2010

In Your Element: Green Bismuth, Ram Mohan

Scholarship

No abstract provided.

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Sascha Vitzhum, Jim Browne Jan 2010

Sascha Vitzhum, Jim Browne

Interviews for WGLT

Jim Browne interviews Assistant Professor Sascha Vitzhum about virtual worlds, economics and marketing. (requires RealPlayer)

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Enhancing 3d Lidar Data Handling, Debra Laefer, Michela Bertolotto, Bianca Schoen-Phelan Jan 2010

Enhancing 3d Lidar Data Handling, Debra Laefer, Michela Bertolotto, Bianca Schoen-Phelan

Articles

more evident than in the limited capabilities of Spatial Information Systems (SIS) to manipulate data from aerial Light Detection and Ranging (LiDAR). Currently, multiple software packages are needed to conduct three-dimensional (3D) analysis of LiDAR data. This workflow heavily relies on importing and exporting different file formats, thus potentially losing accuracy and increasing costs. Ideally, all required functionality would be available within a single system. New functionalities in Oracle Spatial combined with our enhanced 3D-indexing for hosting and analysing offer a critical breakthrough in this area.

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