Physical Sciences and Mathematics Commons^™

Synthesis, Co-Polymerisation And Electrochemical Evaluation Of Novel Ferrocene-Pyrrole Derivatives, Mary Deasy, Eithne Dempsey, Geok Hong Soon, Oliver Worsfold

Articles

New ferrocene derivatives, ((4-(1H-pyrrol-1-yl)phenoxy)carbonyl) ferrocene (4) and (6-(4-(1H-pyrrol-1-yl)phenoxy)hexyl) ferrocene (7) were synthesised, characterised and electrochemically evaluated as redox active films formed via anodic oxidation with pyrrole. Thin film studies were conducted and films formed from both compounds resulted in a stable Fe ^II/III redox couple with E^o = 0.04V and 0.36V vs. Ag/Ag⁺ for (7) and (4) respectively. Both potential sweeping and chronocoulometry were employed for film formation with the former resulting in controllable, reproducible film deposition. Growth conditions and solution concentrations were varied in the case of both compounds in order to assess …

Colorado's Large Snow Events' Impact On Tree Ring Growth And Dillon Reservoir, Katrina Leona Marzetta

Electronic Theses and Dissertations

Meteorological observations from 1894 through 2010 suggest that 17 historically large snow events occurred in the mountains of Colorado within Denver's water supply region. Of these 16 events, 14 can be identified in precipitation sensitive tree ring records as positive climatic pointer years. If these storms were to occur today, they would have the potential to fill reservoirs in Denver Water's supply system, even after years of sustained drought. These "drought busters" have the potential to refill Dillon Reservoir by increasing average yearly inflow up to 146% of the previous year's inflow. Such drought busters can help Denver recover from …

Trends In Heavy-Duty Diesel Emissions And Analyses Of Colorado's Light-Duty Vehicle Inspection And Maintenance Program, Brent G. Schuchmann

Electronic Theses and Dissertations

Emission trends are reported and discussed resulting from the multi-year study of Heavy-Duty Diesel Vehicles (HDDV) at the Port of Los Angeles and at a weigh station in Peralta also in the L.A. basin. Remote sensing data were also collected from the Port of Houston and compared to the data from California. As part of San Pedro Bay Ports Clean Air Action Plan (CAAP) to fast track the turnover rate of cleaner trucks, many truck operators have been subject to modifying their trucks, or have purchased new trucks, with more advanced control technologies to reduce exhaust particulate matter (PM) and …

A Study Of Transient Variations In Cosmic Ray Proton Intensities Using Bess-Polar I Data, Neeharika Thakur

Electronic Theses and Dissertations

The intensities of galactic cosmic rays are modulated upon entering the heliosphere. These variations, defined as solar modulations, are classified as long-term or transient modulations based on their durations.

Studies have correlated the transient variations with the characteristics of the solar wind and the interplanetary magnetic field. Therefore, studies of transients augment our understanding of physical processes in the interplanetary medium. Processes causing transient variations may also induce geomagnetic storms. Precise measurements of cosmic ray fluxes during a transient phenomenon will have immense use in validating models of space weather prediction.

BESS (Balloon-borne Experiment with a Superconducting Spectrometer), a US-Japanese …

Approximate Transversals Of Latin Squares, Jon Kyle Pula

Electronic Theses and Dissertations

A latin square of order n is an n by n array whose entries are drawn from an n-set of symbols such that each symbol appears precisely once in each row and column. A transversal of a latin square is a subset of cells that meets each row, column, and symbol precisely once.

There are many open and difficult questions about the existence and prevalence of transversals. We undertake a systematic study of collections of cells that exhibit regularity properties similar to those of transversals and prove numerous theorems about their existence and structure. We hope that our results …

Water-Soluble Bis(1,10-Phenanthroline) Octanedioate Cu2+ And Mn2+ Complexes With Unprecedented Nano And Picomolar In Vitro Cytotoxicity: Promising Leads For Chemotherapeutic Drug Development, Andrew Kellett, Mark O'Connor, Malachy Mccann, Orla Howe, Alan Casey, Pauraic Mccarron, Kevin Kavanagh, Mary Mcnamara, Sean Kennedy, Donald May, Philip Skell, Denis O'Shea, Michael Devereux

Articles

Dinuclear Cu^II and Mn^II bis-phenanthroline octanedioate complexes exhibit rapid, unprecedented nano and picomolar in vitro cytotoxicity against colorectal cancer lines and are less toxic than cisplatin when examined in vivo. The complexes are potent generators of cellular reactive oxygen species, avid DNA binders and induce O₂ dependent cleavage of DNA. The Cu(II) complex was found to have self-cleaving nuclease activity.

Low Temperature Epitaxial Growth Of Ge Quantum Dot On Si (100) - (2×1) By Femtosecond Laser Excitation, Ali Oguz Er, Wei Ren, Hani E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

Low temperature epitaxy of Ge quantum dots on Si (100) - (2×1) by femtosecond pulsed laser deposition under femtosecond laser excitation was investigated. Reflection high-energy electron diffraction and atomic force microscopy were used to analyze the growth mode and morphology. Epitaxial growth was achieved at ∼70 °C by using femtosecond laser excitation of the substrate. A purely electronic mechanism of enhanced surface diffusion of the Ge adatoms is proposed. © 2011 American Institute of Physics. [doi:10.1063/1.3537813]

Faulting And Stress Distribution In The Bolu Pull-Apart Basin (North Anatolian Fault Zone, Turkey): The Significance Of New Dates Obtained From The Basin Fill, Ergun Gökten, Ramazan Demi̇rtaş, Volkan Özaksoy, Erdal Herece, Baki̇ Varol, Uğur Temi̇z

Turkish Journal of Earth Sciences

The Bolu Basin in northwestern Turkey, situated in the western part of the North Anatolian Fault Zone (NAFZ), displays the neotectonic features of a pull apart basin. The long axis of the basin extends east-west, parallel to the fault zone and Bolu city, situated in the central part of this basin, was extensively damaged during the 17 August 1999 M= 7.4 and 12 November 1999 M= 7.2 earthquakes. The master strand of the North Anatolian Fault Zone cuts through the basin close to its southern edge and movement on this strand has caused tilting of the basin floor towards the …

Geology And Correlation Of The Mersin Mélanges, Southern Turkey, Patrice Moix, Laurent Beccaletto, Olivier Masset, Heinz W. Kozur, Paulian Dumitrica, Daniel Vachard, Rossana Martini, Gerard Stampfli

Turkish Journal of Earth Sciences

Our paper aims to give a thorough description of the infra-ophiolitic mélanges associated with the Mersin ophiolite. We propose new regional correlations of the Mersin mélanges with other mélange-like units or similar series, located both in southern Turkey and adjacent regions. The palaeotectonic implications of the correlations are also discussed. The main results may be summarized as follows: the infra-ophiolitic mélange is subdivided into two units, the Upper Cretaceous Sorgun ophiolitic mélange and the Ladinian-Carnian Hacialanı mélange. The Mersin mélanges, together with the Antalya and Mamonia domains, are represented by a series of exotic units now found south of the …

Short Note On The Use Of Neotectonic And Palaeotectonic Nomenclature, Douwe J.J. Van Hinsbergen

Turkish Journal of Earth Sciences

The terms 'palaeotectonic' and 'neotectonic' are entrenched in the literature of Anatolian geology, used to subdivide the tectonic history before and after the last major tectonic change, which is frequently linked to the Arabia-Eurasia collision and the onset of westward Anatolian escape along the North Anatolian Fault Zone. This short note, however, illustrates that many different authors use different definitions for the age and cause of onset, and style of 'neotectonics', leading to needless confusion in Turkish geological literature. In addition, in recent years it has become common practice to use the neotectonic period as a stratigraphic correlation tool, leading …

First Records Of Late Devonian Entomozoacean Ostracods In North-Western Turkey, Ati̇ke Nazi̇k, Helga Groos-Uffenorde

Turkish Journal of Earth Sciences

Entomozoacean ostracods (pelagic socalled fingerprint-ostracods) have recently been observed for the first time in Upper Devonian sediments of the Darlık B Section from the İstanbul region, north-western Turkey. These new assemblages consist of Entomoprimitia nitida, Entomoprimitia sartenaeri, Entomoprimitia concentrica, Franklinella calcarata, Waldeckella erecta?, Rabienella n. sp. c, aff. reichi sensu Rabien & Rabitz 1958, Rabienella reichi, Richterina (Volkina) zimmermanni and Nehdentomis pseudorichterina and can be dated as Late Frasnian Entomoprimitia sartenaeri Zone (= variostriata Zone sensu Rabien 1954). These entomozoacean ostracods indicate a faunal relationship with Germany (Rhenish Schiefergebirge, Harz Mountains, Thuringia), Poland (Holy Cross Mountains), N France-Belgium (Ardennes), Volgo-Ural …

A New Species Of Angariid Gastropod From The Early Thanetian Of The Haymana-Polatlı Basin, Turkey, İzzet Hoşgör, Yavuz Okan

Turkish Journal of Earth Sciences

A new trochoidean species, Angaria calvii n. sp., from the early Thanetian of the Kırkkavak Formation (Haymana-Polatlı Basin, Palaeocene) in central Anatolia, is described and placed in the family Turbinidae. Previously, the oldest Cenozoic Angaria was recorded from the Early Palaeocene (Danian) in France (Paris Basin). In this paper, we report the second discovery of the oldest angariid specimens from the Thanetian sediments of the Tethys realm, a stratigraphic position which is supported by the foraminiferal-red alga assemblages at this locality.

Integrated Oligocene−Lower Miocene Larger And Planktonic Foraminiferal Biostratigraphy Of The Kahramanmaraş Basin (Southern Anatolia, Turkey), Uğraş Işik, Aynur Hakyemez

Turkish Journal of Earth Sciences

An integrated biostratigraphical analysis based on the larger and planktonic foraminifera from three sections provides a well-defined zonal scheme of the Oligocene-Lower Miocene successions in the Kahramanmaraş Basin. The planktonic foraminiferal zonation is based on a combination of standard (P) and Mediterranean (MMi) zonal schemes and consists of Turborotalia ampliapertura (P19), Globigerina angulisuturalis-Paragloborotalia opima opima (P21), Globigerina ciperoensis (P22) biozones spanning the Upper Rupelian-Chattian interval and Globoquadrina dehiscens-Globigerinoides altiaperturus (MMi 2a), Globigerinoides altiaperturus-Catapsydrax dissimilis (MMi 2b) and Globigerinoides trilobus (MMi 3) biozones in the Upper Aquitanian-Burdigalian interval. The larger foraminiferal zonation of the studied successions has been established by means …

New Data On The Dasycladales From The Lower Eocene Of Seyitgazi Region, Eskişehir, Central Turkey, Rajka Radoicic, Nazi̇re Erdem

Turkish Journal of Earth Sciences

An association of Dasycladalean algae is identified from the Lower Eocene (Ilerdian-Cuisian) of the Seyitgazi area, Western Anatolia. The association consists mostly of the genus Belzungia Morellet and Anatolia n. gen. This is the first discovery of such a rich and diversified dasycladalean flora with Belzungia in the Eocene of Central Tethys. The genus Belzungia is represented by four species: Belzungia terquemi Morellet, B. silvestrii (Pfender), B. bella (Ju Ying) Radoicic and B. pfenderae n. sp. Belzungia articles consist of whorls characterized by an assemblage of laterals, in the transversal section of which, the primary laterals are distally enlarged (sub-triangular …

Geodynamic Significance Of The Early Triassic Karaburun Granitoid (Western Turkey) For The Opening History Of Neo-Tethys, Cüneyt Akal, Osman Ersi̇n Koralay, Osman Candan, Oberhaensli Roland, Fukun Chen

Turkish Journal of Earth Sciences

The Karaburun Peninsula, which is considered part of the Anatolide-Tauride Block of Turkey, contains clastic and carbonate sequences deposited on the northern margin of Gondwana. The Palaeozoic clastic sequence, which is intruded by the Early Triassic granitoid and tectonically overlies a Mesozoic mélange sequence, can be divided into three subunits: a lower clastic subunit consisting of a sandstone-shale alternation, an upper clastic subunit consisting of black chert-bearing shales, sandstone and conglomerate, and a Permo-Carboniferous carbonate subunit. The lower Triassic Karaburun I-type granitoid has a high initial ^8^7Sr/^8^6Sr ratio (0.709021-0.709168), and low ^1^4^3Nd/^1^4^4Nd ratio (0.512004-0.512023) and \epsilonNd (-5.34 to -5.70) isotopic …

Geology And Tectonic Emplacement Of Eclogite And Blueschists, Biga Peninsula, Northwest Turkey, Firat Şengün, Erdi̇nç Yi̇ği̇tbaş, İsmai̇l Onur Tunç

Turkish Journal of Earth Sciences

The Biga Peninsula in northwestern Anatolia is a tectonic mosaic, comprising different tectonic units, representing the Sakarya Continent and oceanic assemblages of different origin and ages. The Çamlıca metamorphic association, a member of this orogenic mosaic in the westernmost part of the peninsula, is subdivided into three formations, from bottom to top; the Andıktaşı formation, the Dedetepe formation, and the Salihler formation. Eclogite-facies metamorphic rocks occur as tectonic slices within schist-marble intercalations of the Dedetepe formation. These slices, about 2 km long and 500 m wide, include two different rock types; (i) quartz-mica schists, and (ii) metabasite lenses with eclogite/blueschist …

Sphalerite Associated With Pyrrhotite-Chalcopyrite Ore Occurring In The Kotana Fe-Skarn Deposit (Giresun, Ne Turkey): Exsolution Or Replacement, Emi̇n Çi̇ftçi̇

Turkish Journal of Earth Sciences

The Kotana prospect is located about 30 km south of Giresun (NE Turkey). The ore mineralization is a Fe-skarn occurring within the low-grade pre-Lower Jurassic Pınarlar metamorphics, consisting of marble-phyllite intruded by the Upper Cretaceous-Eocene Aksu biotite monzogranite. The principal primary ore minerals include pyrrhotite and magnetite along with minor pyrite (I) and chalcopyrite, accompanied by trace sphalerite. Sphalerite is closely associated with chalcopyrite and to a lesser extent with hexagonal pyrrhotite. Secondary ore minerals include pyrite (II), marcasite, martite, hematite, goethite, lepidocrocite, and intermediate Fe-oxides-hydroxides. Gangue minerals are mainly calcite and quartz. Oxidation of the primary sulphides resulted in …

Lagrangian Prediction And Correlation Analysis With Eulerian Data, Mi̇ne Çağlar, Taylan Bi̇lal, Leonid Piterbarg

Turkish Journal of Earth Sciences

A velocity field obtained from the ocean surface by high-frequency radar is used to test Lagrangian prediction algorithms designed to evaluate the position of a particle given its initial position and observations of several other simultaneously released particles. The problem is motivated by oceanographic applications such as search and rescue operations and spreading pollutants, especially in coastal regions. The prediction skill is essentially determined by temporal and spatial covariances of the underlying velocity field. For this reason correlation analysis of both Lagrangian and Eulerian velocities was carried out. Space covariance functions and spectra of the velocity field are also presented …

Geophysical Variations During The Total Solar Eclipse In 2006 In Turkey, Abdullah Ateş, Aydin Büyüksaraç, Özcan Bektaş

Turkish Journal of Earth Sciences

It has been observed that some geophysical parameters could be changed during a solar eclipse. We have therefore measured gravity and magnetic fields during solar eclipses. We also measured the gravity field during the previous eclipse on the 11^t^h of August, 1999. Gravity measurements on the 29^t^h of March, 2006 are compared with previous gravity measurements at the same location during the eclipse on the 11^t^h of August, 1999. Both showed the same behaviour during the eclipses. Gravity measurements showed fluctuations during both eclipses. A decrease in the intensity of the magnetic field was observed. Low-pass filtered magnetic data show …

The North Anatolian Fault On The Hersek Peninsula, Turkey: Its Geometry And Implications For The 1999 İzmit Earthquake Rupture Propagation, Özgür Kozaci, Erhan Altunel, Scott Lindvall, Charles Brankman, William Lettis

Turkish Journal of Earth Sciences

The western termination of the 1999 İzmit earthquake still remains as an intriguing problem for researchers and the people residing around the Sea of Marmara. There have been numerous offshore mapping and modelling studies performed in the Gulf of İzmit. However, the main debate about the western termination of the 1999 İzmit surface rupture is linked to the Hersek Peninsula and corresponding fault geometry. We focused our efforts at resolving the fault geometry on the Hersek Peninsula by applying geological mapping, geomorphic analyses, palaeoseismic trenching and geophysical surveys. Our studies reveal that the North Anatolian Fault forms a restraining stepover …

Palaeoseismological Investigations On The Karadere Segment, North Anatolian Fault Zone, Turkey, Aynur Di̇kbaş, Hüsnü Serdar Akyüz

Turkish Journal of Earth Sciences

The Karadere segment of the North Anatolian Fault (NAF) is the easternmost part that ruptured during the 17 August 1999 İzmit earthquake (Mw 7.4). It has a different orientation, at N65°E to other segments which have a nearly E-W trend, and lesser dextral displacement, with maximum 2.3 m in contrast with 5.2 m in the ruptured neighbouring western segment. Two palaeoseismological trenches, at Kazimiye and Karadere sites, were excavated on the central part of the Karadere segment to determine the timing of past earthquakes. Excavation of the Kazimiye site revealed the occurrence of five past events since the 4th century …

The 6 September 2009 Mw5.4 Earthquake In Eastern Albania – Fyrom Border: Focal Mechanisms, Slip Model, Shakemap, Anastasia Kiratzi

Turkish Journal of Earth Sciences

On 6 September 2009 (GMT 21:49) a moderate Mw5.4 earthquake sequence burst at the eastern border of Albania with the Former Yugoslav Republic of Macedonia (FYROM). The main shock was located ~6 km north of the epicentre of the 30 November 1967 Mw6.2 Dibra (or Debar) earthquake, which caused loss of life and considerable damage to buildings. We use broad band waveforms recorded by the Hellenic Unified Seismic Network (HUSN), which receives real-time waveforms from the neighbouring networks, to compute focal mechanisms, obtain the slip model and derive the Shake Map of the mainshock. The focal mechanisms of 18 of …

Upper Jurassic Reefs From The Russian Western Caucasus: Implications For The Eastern Black Sea, Li Guo, Stephen J. Vincent, Vladimir Lavrishchev

Turkish Journal of Earth Sciences

Exposures of Upper Jurassic reef outcrops in the Russian western Caucasus provide excellent field analogues for possible reef-complex reservoir targets imaged on seismic reflection data from the northern Shatskiy Ridge, eastern Black Sea. The reefs at outcrop can be generally grouped into coral-dominated, siliceous sponge-microbialite and microbialite types. Coral-dominated reefs occur as isolated patchy and massive forms, and can be subdivided into higher-diversity and low-diversity types. The former developed at shallow-water platform margins and in platform interiors, whilst the latter occurred in deeper-water mid-shelf settings. Siliceous sponge-microbialite and microbialite reefs occur as lenses and mounds that were restricted to deeper-water …

Growth-Invariant Meristic Characters Tools To Reveal Phylogenetic Relationships In Nummulitidae (Foraminifera), Johann Hohenegger

Turkish Journal of Earth Sciences

Morphological characters that are restricted to a few growth-independent characters (such as the embryonic apparatus of nummulitids) or measurements at arbitrarily chosen growth stages (such as the second whorl in planispiral tests) do not adequately explain the phylogenetic relationships of fossil forms. Molecular-genetic investigations enlighten phylogenetic relations, but have two main disadvantages. First, they are restricted to living forms, and second, these relations are based on an extremely small part of the DNA and never on developmental and structural genes that regulate morphology. Morphometric methods based on growth-invariant characters allow modelling the test shape for each growth stage and thus …

The Role Of The Palaeogene Adriatic Carbonate Platform In The Spatial Distribution Of Alveolinids, Katica Drobne, Vlasta Cosovic, Alan Moro, Damir Buckovic

Turkish Journal of Earth Sciences

Sediments of the Palaeogene Adriatic carbonate platform, a distinctive palaeogeographic unit, are today exposed along the eastern Adriatic coast for a distance of 800 km and a width of 100-130 km. The large number of identified alveolinid species (69) from the Early Ypresian (Ilerdian) to the Bartonian record the dynamics of their evolution, with emphasis on the following: (1) great species diversity and great abundance in the middle Ilerdian (SBZ 7-8) followed by a sharp decline in occurrences at the Ilerdian/Cuisian transition; (2) a diversity boom in the late Ypresian (late Cuisian, SBZ 11-12) and (3) an abrupt decrease in …

Early Oligocene Larger Foraminiferal Biostratigraphy Of The Qom Formation, South Of Uromieh (Nw Iran), Mohsen Yazdi Moghadam

Turkish Journal of Earth Sciences

The marine strata of the Qom Formation south of Uromieh (Baranduz) yielded a moderately diverse larger benthic foraminiferal fauna resembling the fauna already described from European marine sequences. The fauna allowed the author to correlate the larger foraminiferal assemblage of northwestern Iran with the standard shallow benthic zonation. The assemblage is dominated by hyaline and porcellaneous forms including Operculina, Nummulites, Neorotalia, Penarchaias, Victoriella, Peneroplis, Praerhapydionina, Spirolina, Halkyardia, Planorbulina, Dendritina, Borelis and Bullaveolina. This faunal assemblage is also accompanied by coralline alga Subterraniphyllum thomasii. The presence of Nummulites cf. fichteli and N. cf. vascus in the absence of Lepidocyclina allows correlation …

Stratigraphy And Larger Foraminifera Of The Middle Eocene To Lower Oligocene Shallow-Marine Units In The Northern And Eastern Parts Of The Thrace Basin, Nw Turkey, György Less, Ercan Özcan, Aral Okay

Turkish Journal of Earth Sciences

The shallow-marine Eocene Soğucak Limestone and Oligocene Ceylan Formation were studied in the northern and eastern parts of the Thrace Basin with detailed biometric analysis of the full spectrum of larger benthic foraminifera (mainly nummulitids and orthophragmines). This allows us to establish a high-resolution biostratigraphy in the context of the shallow benthic zonation (with SBZ zones) of the Tethyan Palaeogene since larger foraminiferal assemblages show a very strong Western Tethyan affinity. Only two species (Heterostegina armenica and Orbitoclypeus haynesi) are unknown so far to the west of the Thrace Basin. The age of particular larger foraminiferal sites is determined based …

Estimating The Efficacy Of Mild Heating Processes Taking Into Account Microbial Non-Linearities: A Case Study On The Thermisation Of A Food Simulant, Vasilis Valdramidis, Brijesh Tiwari, Patrick Cullen, Alain Kondjoyan, Jan Van Impe

Articles

Traditional and novel approaches for the calculation of the heat treatment efficiency are compared in this work. The Mild Heat value (MH-value), an alternative approach to the commonly used sterilisation, pasteurisation and cook value (F, P, C–value), is calculated to estimate the efficiency of a mild heat process. MH-value is the time needed to achieve a predefined microbial reduction at a reference temperature and a known thermal resistant constant, z, for log-linear or specific types of non log-linear microbial inactivation kinetics. An illustrative example is given in which microbial inactivation data of Listeria innocua CLIP 20-595 are used for estimating …

A Break In The Clouds: Towards A Cloud Definition, Chris Rose

Walden Faculty and Staff Publications

This paper discusses the concept of Cloud Computing to achieve a complete definition of what a Cloud is, using the main characteristics typically associated with this paradigm in the literature. More than 20 definitions have been studied allowing for the extraction of a consensus definition as well as a minimum definition containing the essential characteris- tics. This paper pays much attention to the Grid paradigm, as it is often confused with Cloud technologies. We also de- scribe the relationships and distinctions between the Grid and Cloud approaches.

A Generalized Nonlinear Model For The Evolution Of Low Frequency Freak Waves, Jonathan Blackledge

Articles

This paper presents a generalized model for simulating wave fields associated with the sea surface. This includes the case when `freak waves' may occur through an effect compounded in the nonlinear (cubic) Schrodinger equation. After providing brief introductions to linear sea wave models, `freak waves' and the linear and nonlinear Schrodinger equations, we present a unified model that provides for a piecewise continuous transition from a linear to a nonlinear state. This is based on introducing a fractional time derivative to develop a fractional nonlinear partial differential equation with a stochastic source function. In order to explore the characteristics of …