Physical Sciences and Mathematics Commons^™

Factors Associated With Loss To Follow-Up Among Hiv-Infected Patients At An Urban, Hospital-Based Outpatient Hiv Clinic, Timothy J. Friel Md, Anthony Nerino, Lynn Nagel, J D'Aversa, Anthony Strobel, Dorothy Faulkner Phd

Department of Medicine

No abstract provided.

Rapid Door To Balloon Time In The Treatment Of Acute St- Elevation Myocardial Infarction Meaningfully Reduces Overall Hospital Stay, Amit N. Nanavati Md, Nainesh Patel Md, Bruce Feldman Do, J Patrick Kleaveland Md, Orlando E. Rivera Rn, David A. Cox Md

Department of Medicine

No abstract provided.

Atr-Ftir Studies On The Kinetics Of Dimethylarsinic Acid (Dma) Surface Complexation With Iron(Oxyhydr)Oxides, Julia Tofan-Lazar Miss

Theses and Dissertations (Comprehensive)

Dimethylarsinic acid (DMA) is an organoarsenical compound that, along with monomethylarsonic acid, poses a health and an environmental risk, and a challenge to the energy industry. Little is known about the surface chemistry of DMA at the molecular level with materials relevant to geochemical environments and industrial sectors. The surface chemistry of phosphorus and arsenic compounds in their organic and inorganic forms is of great interest due to its role in controlling their transport, bioaccessibility and speciation. This thesis reports the first in-situ and surface-sensitive rapid kinetic studies on the adsorption and desorption of DMA to and from Fe-(oxyhydr)oxide films …

Density Functional Theory Calculations On Hydrated Dimethylarsinic Acid And Iron Oxide Clusters, Adrian Adamescu

Theses and Dissertations (Comprehensive)

Dimethylarsinic Acid (DMA) or (CH₃)₂AsO₂H is an important organoarsenical compound detected in arsenic speciation studies of environmental samples and synthesized during pyrolysis of oil shale. DMA was used historically as a herbicide on large agricultural fields and can be detected in the leachates of landfills rich in waste containing arsenic such as glass, alloys, and semiconductors, as well as biologically pre-treated municipal solid waste. Under certain soil conditions DMA can become bio-available and has the potential to be recycled to more toxic inorganic forms of arsenic. Bioavailability of DMA is largely controlled by the …

Synthesis And Investigation Of The Liquid Crystalline Properties Of Polycyclic Aromatic Hydrocarbons, Joseph A. Paquette

Theses and Dissertations (Comprehensive)

In this thesis, the synthesis and liquid crystalline properties of a series of novel substituted dibenz[a,c]anthracenes is reported. Specifically, a series of hexaalkoxydibenz[a,c]anthracenes were prepared and found not to exhibit a mesophase. In contrast, when substituents are introduced on the aromatic core, columnar mesophases are observed over broad temperature ranges. A series substituted derivatives was prepared and their mesomorphic properties compared. In general, electron-withdrawing substituents promote broad mesophase temperature ranges, as do larger substituents. The liquid crystalline phase is a result of the electronic effects, size and shape of the substituents in the 10 and 13 positions.

We also synthesized …

Laboratory Methods For The Advancement Of Wastewater Treatment Modeling, Holly E. Gray

Theses and Dissertations (Comprehensive)

To achieve the low levels of total phosphorus required in wastewater treatment plant effluent all chemical forms of phosphorus should be removed. The most refractory phosphorus in terms of removal is so-called “organic phosphorus”. This thesis explores potential relationships between dissolved organic matter and organic phosphorus and methods of removing organic phosphorus from waste water. Fluorescence spectroscopy will be used to characterize dissolved organic matter (DOM) in wastewater. The fluorescent DOM will then be monitored throughout the various wastewater treatment plants to investigate any changes throughout the treatment train. Correlations between fluorophore concentrations (concentrations determined for the different classifications of …

Shoreline Changes In Point Pelee, Canada: An Airphoto-Based Analysis, Abdullah Bamasoud

Theses and Dissertations (Comprehensive)

Shoreline retreat has significant consequences for Point Pelee National Park’s (PPNP) ecological and economic systems. In this study, the shoreline changes of PPNP are examined in terms of their rates, their relationship to natural and anthropogenic influences, and methods for predicting shoreline positions.

The rates of shoreline change are analyzed for the period 1959-2004 using ortho-airphotos. The eastern shoreline of the Park exhibited varying recession in both rising and falling Lake Erie water level, especially in the Northeast Beach, where it averaged -3.14 m˖y-1. The western shoreline of the Park generally exhibited accretion and had an inverse relationship with Lake …

A Greener Synthesis Of 2-Aminochromenes In Ionic Liquid And Evaluation Of Their Antiproliferative Activities, M. Sudershan Rao, Bhupender S. Chhikara, Rakesh Tiwari, Amir Nasrolahi Shirazi, Keykavous Parang, Anil Kumar

Pharmacy Faculty Articles and Research

An improved simple and facile synthesis of chromene derivatives by employing threecomponent one-pot condensation reaction of β-naphthol, aromatic aldehydes, and malononitrile in ionic liquids is described.

Quantitative Analysis Of Some Important Metals And Metalloids In Tobacco Products By Inductively Coupled Plasma-Mass Spectrometry (Icp-Ms), Syed Ghulam Musharraf, Muhammad Shoaib, Amna Jabbar Siddiqui, Muhammad Najam-Ul-Haq, Aftab Ahmed

Pharmacy Faculty Articles and Research

Background: Large scale usage of tobacco causes a lot of health troubles in human. Various formulations of tobacco are extensively used by the people particularly in developing world. Besides several toxic tobacco constituents some metals and metalloids are also believed to pose health risks. This paper describes inductively coupled plasma-mass spectrometric (ICP-MS) quantification of some important metals and metalloids in various brands of smoked, sniffed, dipped and chewed tobacco products.

Results: A microwave-assisted digestion method was used for sample preparation. The method was validated by analyzing a certified reference material. Percentage relative standard deviation (% R.S.D.) between recovered …

Pegylated Silicon Nanowire Coated Silica Microparticles For Drug Delivery Across Intestinal Epithelium, Vuk Uskoković, Phin-Peng Lee, Laura Walsh, Kathleen Fischer, Tejal Dasai

Pharmacy Faculty Articles and Research

Composite particles made by growing nanoscopic silicon wires from the surface of monodispersed, microsized silica beads were tested in this study for their ability to affect the integrity and permeability of an epithelial cell layer. Polyethylene glycol (PEG) is known to sterically stabilize particles and prevent protein binding; as such, it is a routine way to impart in vivo longevity to drug carriers. The effect of the silica beads, both with and without silicon nanowires and PEG, on the disruption of the tight junctions in Caco-2 cells was evaluated by means of: (a) analysis of the localization of zonula occludens-1 …

A New, Simple, Green And One-Pot Four-Component Synthesis Of Bare And Poly(Α, Γ, L-Glutamic Acid) Capped Silver Nanoparticles, Magdalena Stevanović, Igor Savanović, Vuk Uskoković, Srečo D. Škapin, Ines Bračko, Uroš Jovanović, Dragan Uskoković

Pharmacy Faculty Articles and Research

A simple and green chemical method has been developed to synthesize stable bare and capped silver nanoparticles based on the reduction of silver ions by glucose and capping by poly(α,γ,Lglutamic acid) (PGA). The use of ammonia during synthesis was avoided. PGA has had a dual role in the synthesis and was used as a capping agent to make the silver nanoparticle more biocompatible and to protect the nanoparticles from agglomerating in the liquid medium. The synthesized PGA-capped silver nanoparticles in the size range 5–45 nm were stable over long periods of time, without signs of precipitation. Morphological examination has shown …

Dynamic Light Scattering And Microelectrophoresis: Main Prospects And Limitations, Vuk Uskoković

Pharmacy Faculty Articles and Research

Microelectrophoresis based on the dynamic light scattering (DLS) effect has been a major tool for assessing and controlling the conditions for stability of colloidal systems. However, both the DLS methods for characterization of the hydrodynamic size of dispersed submicron particles and the theory behind the electrokinetic phenomena are associated with fundamental and practical approximations that limit their sensitivity and information output. Some of these fundamental limitations, including the spherical approximation of DLS measurements and an inability of microelectrophoretic analyses of colloidal systems to detect discrete charges and differ between differently charged particle surfaces due to rotational diffusion and particle orientation …

Simulated Associating Polymer Networks, Joris Billen

CGU Theses & Dissertations

Telechelic associating polymer networks consist of polymer chains terminated by endgroups that have a different chemical composition than the polymer backbone. When dissolved in a solution, the endgroups cluster together to form aggregates. At low temperature, a strongly connected reversible network is formed and the system behaves like a gel. Telechelic networks are of interest since they are representative for biopolymer networks (e.g. F-actin) and are widely used in medical applications (e.g. hydrogels for tissue engineering, wound dressings) and consumer products (e.g. contact lenses, paint thickeners).

In this thesis such systems are studied by means of a molecular dynamics/Monte Carlo …

Study Of Vortex Ring Dynamics In The Nonlinear Schrödinger Equation Utilizing Gpu-Accelerated High-Order Compact Numerical Integrators, Ronald Meyer Caplan

CGU Theses & Dissertations

We numerically study the dynamics and interactions of vortex rings in the nonlinear Schrödinger equation (NLSE). Single ring dynamics for both bright and dark vortex rings are explored including their traverse velocity, stability, and perturbations resulting in quadrupole oscillations. Multi-ring dynamics of dark vortex rings are investigated, including scattering and merging of two colliding rings, leapfrogging interactions of co-traveling rings, as well as co-moving steady-state multi-ring ensembles. Simulations of choreographed multi-ring setups are also performed, leading to intriguing interaction dynamics.

Due to the inherent lack of a close form solution for vortex rings and the dimensionality where they live, efficient …

Characterizing Dissolved Organic Matter And Cu2+, Zn2+, Ni2+, And Pb2+ Binding In Salt Water And Implications For Toxicity, Rachael L. Diamond

Theses and Dissertations (Comprehensive)

The binding of metal to dissolved organic matter in aquatic environments is important in controlling the bioavailability and potential toxicity of metals such as Zn²⁺, Pb²⁺, Ni²⁺ and Cu²⁺. The purpose of this research is to: (i) quantify binding capacity to different sources of marine organic matter at environmentally relevant concentrations; (ii) test fluorescence quenching and voltammetric method for use in seawater conditions and; (iii) compare predicted speciation parameters with toxicological observations in the same samples.

Information regarding the solubility of copper and copper compounds is important for risk assessment and can be …

Toward Solving The Cosmological Constant Problem By Embedding, Roman V. Buniy, Thomas W. Kephart

Mathematics, Physics, and Computer Science Faculty Articles and Research

The typical scalar field theory has a cosmological constant problem. We propose a generic mechanism by which this problem is avoided at tree level by embedding the theory into a larger theory. The metric and the scalar field coupling constants in the original theory do not need to be fine-tuned, while the extra scalar field parameters and the metric associated with the extended theory are fine-tuned dynamically. Hence, no fine-tuning of parameters in the full Lagrangian is needed for the vacuum energy in the new physical system to vanish at tree level. The cosmological constant problem can be solved if …

An Interpolation Problem For Functions With Values In A Commutative Ring, Daniel Alpay, Haim Attia

Mathematics, Physics, and Computer Science Faculty Articles and Research

It was recently shown that the theory of linear stochastic systems can be viewed as a particular case of the theory of linear systems on a certain commutative ring of power series in a countable number of variables. In the present work we study an interpolation problem in this setting. A key tool is the principle of permanence of algebraic identities.

Exceptional-Point Dynamics In Photonic Honeycomb Lattices With Pt Symmetry, Hamidreza Ramezani, Tsampikos Kottos, Vassilios Kovanis, Demetrios N. Christodoulides

Physics and Astronomy Faculty Publications and Presentations

We theoretically investigate the flow of electromagnetic waves in complex honeycomb photonic lattices with local PT symmetries. Such PT structure is introduced via a judicious arrangement of gain and loss across the honeycomb lattice, characterized by a gain and loss parameter γ. We found a class of conical diffraction phenomena where the formed cone is brighter and travels along the lattice with a transverse speed proportional to √γ.

Importing Democracy: Promoting Participatory Decision Making In Russian Forest Communities, Maria Tysiachniouk, Errol E. Meidinger

Contributions to Books

Published in Environmental Democracy Facing Uncertainty, Cécilia Claeys & Marie Jacqué, eds.

This paper describes how the World Wildlife Fund for Nature (WWF) jump-started democratic institutions in Russian rural communities to create a basis for social, environmental, and economic modernization within the Russian forestry sector. In Russia’s post-soviet markets and institutions, a host of multinational companies and large transnational environmental organizations sought to promote the restructuring of Russia’s legal and economic infrastructure and active subsidiaries in Russia. In order for modern forestry approaches to be imported, management practices that had developed in the West needed to be adapted to Russia’s …

Personality Type Differences Between Ph.D. Climate Researchers And The General Public: Implications For Effective Communication, C. Susan Weiler, Jason K. Keller, Christina Olex

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Effectively communicating the complexity of climate change to the public is an important goal for the climate change research community, particularly for those of us who receive public funds. The challenge of communicating the science of climate change will be reduced if climate change researchers consider the links between personality types, communication tendencies and learning preferences. Jungian personality type is one of many factors related to an individual’s preferred style of taking in and processing information, i.e., preferred communication style. In this paper, we demonstrate that the Jungian personality type profile of interdisciplinary, early career climate researchers is significantly different …

The New Publishing Scene And The Tenure Case: An Administrator’S View, Daniele C. Struppa

Mathematics, Physics, and Computer Science Faculty Articles and Research

No abstract provided.

Review Of The Mathematical Language Of Quantum Theory: From Uncertainty To Entanglement, Matthew S. Leifer

Mathematics, Physics, and Computer Science Faculty Articles and Research

A book review of The Mathematical Language of Quantum Theory: From Uncertainty to Entanglement by Teiko Heinosaari and Mario Ziman.

A New Karren Feature: Hummocky Karren, Lukas Plan, Christa Renetzeder, Rudolf Pavuza, Wilfried Körner

International Journal of Speleology

Karren are small-scale landforms on karst surfaces and many types have been described so far. Here we present an apparently new feature which was found on the Hochschwab karst massive in the Northern Calcareous Alps of Austria. So far only few outcrops each having less than 1 m² within a very restricted area have been found. Morphometric analysis reveals that the karren consist of a randomly distributed, dispersed assemblage of small hummocks and depressions in between. The mean distance between neighbouring hummocks is 4 to 5 cm and the mean height is 0.85 cm. Longitudinal sections are gently sinuous. The …

Swimming Performance Of Epigeal And Hypogeal Species Of Characidae, With An Emphasis On The Troglobiotic Stygichthys Typhlops Brittan & Böhlke, 1965, Francisco Alexandre Costa Sampaio, Paolo Santos Pompeu, Hersília De Andrade E Santos, Rodrigo Lopes Ferreira

International Journal of Speleology

Swimming performance of fish constitutes a good ecophysiological tool to evaluate the ability of species to use different types of habitats. In order to understand how the swimming performance is related to the hydraulic environment, we compared the critical velocity of five fish (Characidae): Stygichthys typhlops (groundwater troglobiotic); Piabina argentea and Bryconamericus stramineus (riverine); Hemigrammus marginatus (generalist, found in rivers and floodplains) and Psellogrammus kennedyi (lacustrine). Swimming speed tests were performed in a respirometer-type apparatus. Total body length was the variable that best explained the maximum speed attained by all species under study. The critical swimming speed values (in body …

Scientific Drilling Of Speleothems – A Technical Note, Christoph Spötl, David Mattey

International Journal of Speleology

This short article provides detailed descriptions of custom-made and commercially available hand-held drilling gear and options for water-flushing units specifically designed to obtained good-quality core material from speleothems even in remote cave regions. We use small-diameter (6-7 mm) diamond drill bits to obtain aliquots of calcite (as little as a few hundreds of milligram) from the interior of the basal part of in-situ stalagmites. These small cores are used to date the onset of stalagmite growth and occasionally to obtain other compositional information. Larger diameter drill bits produce cores 25-32 mm in diameter and up to 1.3 m in length …

Cover: Volume 41, Issue 1

International Journal of Speleology

No abstract provided.

Diversity And Community Assembly Patterns Of Epigean Vs. Troglobiont Spiders In The Iberian Peninsula, Pedro Cardoso

International Journal of Speleology

Cave-obligate organisms usually have smaller ranges and their assemblages have higher beta diversity than their epigean counterparts. Phylogenetic and functional diversity is usually low in cave communities, leading to taxonomic and functional disharmony, with entire groups missing from the subterranean realm. The objective of this work is to compare range, beta diversity, phylogenetic and functional diversity, taxonomic and functional disharmony of epigean versus troglobiont spiders in the Iberian Peninsula.

The median extent of occurrence was found to be 33 times higher for epigean than for cave species. Beta diversity was significantly higher for troglobiont assemblages. Cave assemblages present lower phylogenetic …

Cora – A Dedicated Device For Carbon Dioxide Monitoring In Cave Environments, Marc Luetscher, Felix Ziegler

International Journal of Speleology

High resolution time-series of cave CO₂ fluctuations are increasingly demanded to quantify calcite precipitation processes. CORA, an energy-efficient NDIR-device, has been specifically developed for the long-term monitoring of carbon dioxide in remote cave environments. To allow comparison between different cave sites, changes in air pressure and temperature are compensated for using dedicated probes. Laboratory experiments demonstrate that CORA’s precision is adapted to the analysis of spatially and temporally variable CO₂ regimes and therefore suitable for a large number of applications. Data obtained with 12 independently calibrated instruments are reproducible within 3% (1σ). The two-point calibration function is validated …

Book Review: Karst Evolution In The South Mediterranean Area – Environmental Impact On Human Life And Civil Planning, Leonardo Piccini

International Journal of Speleology

No abstract provided.

World Karst Science Reviews

International Journal of Speleology

No abstract provided.