Physical Sciences and Mathematics Commons^™

Electrodeposited Cobalt-Phosphorous-Derived Films As Competent Bifunctional Catalysts For Overall Water Splitting, Nan Jiang, Bo You, Meili Sheng, Yujie Sun

Chemistry and Biochemistry Faculty Publications

One of the challenges to realize large-scale water splitting is the lack of active and low-cost electrocatalysts for its two half reactions: H2 and O2 evolution reactions (HER and OER). Herein, we report that cobalt-phosphorous-derived films (Co-P) can act as bifunctional catalysts for overall water splitting. The as-prepared Co-P films exhibited remarkable catalytic performance for both HER and OER in alkaline media, with a current density of 10 mAcm¢2 at overpotentials of ¢94 mV for HER and 345 mV for OER and Tafel slopes of 42 and 47 mV/dec, respectively. They can be employed as catalysts on both anode and …

Introduction Effort, Climate Matching And Species Traits As Predictors Of Global Establishment Success In Non-Native Reptiles, Peter J. Mahoney, Karen H. Beard, Andrew M. Durso, Aimee G. Tallian, Arin Lexine Long, Ryan J. Kindermann, Nicole E. Nolan, Daniel Kinka, Harrison E. Mohn

Biology Faculty Publications

Non-native reptiles are often detrimental to native communities and ecosystems and can be extremely difficult to manage once established. Thus, there is considerable interest in predicting the likelihood of establishment of nonnative reptiles. We assessed three hypotheses describing possible factors contributing to the successful establishment of introduced reptiles in an effort to better identify potential invaders.

Aligning Public Participation To Stakeholders’ Sustainability Literacy—A Case Study On Sustainable Urban Development In Phoenix, Arizona, Matthew Cohen, Arnim Wiek, Braden Kay, John Harlow

Earth and Environmental Sciences Publications

In public planning processes for sustainable urban development, planners and experts often face the challenge of engaging a public that is not familiar with sustainability principles or does not subscribe to sustainability values. Although there are calls to build the public’s sustainability literacy through social learning, such efforts require sufficient time and other resources that are not always available. Alternatively, public participation processes may be realigned with the sustainability literacy the participants possess, and their capacity can modestly be built during the engagement. Asking what tools might successfully align public participation with participants’ sustainability literacy, this article describes and evaluates …

Single And Multiple Objective Biomass-To-Biofuel Supply Chain Optimization Considering Environmental Impacts, Claudia Evangelina Valles Sosa

Open Access Theses & Dissertations

Bioenergy has become an important alternative source of energy to alleviate the reliance on petroleum energy. Bioenergy offers diminishing climate change by reducing Green House Gas Emissions, as well as providing energy security and enhancing rural development. The Energy Independence and Security Act mandate the use of 21 billion gallons of advanced biofuels including 16 billion gallons of cellulosic biofuels by the year 2022. It is clear that Biomass can make a substantial contribution to supply future energy demand in a sustainable way. However, the supply of sustainable energy is one of the main challenges that mankind will face over …

Investigation Of The Natural Degradation Of Selected Endocrine Disrupting Compounds In Wastewater, Toni Carrick

Open Access Theses & Dissertations

Endocrine disrupting compounds (EDCs) are a class of compounds that are of concern for their potentially adverse effects on fish, wildlife, and humans. They can cause developmental and reproductive anomalies at concentrations in the low ppb to ppt levels. Studies have shown the primary route of exposure of EDCs within the environment is through the discharge of effluent wastewater. Removal efficiencies of wastewater treatment plants have been studied extensively, however, in rural or developing areas, which often lack secondary or tertiary wastewater treatment, little is known about the stability of these compounds and the rate at which they degrade in …

Improving Software Quality And Productivity Leveraging Mining Techniques: [Summary Of The Second Workshop On Software Mining, At Ase 2013], Ming Li, Hongyu Zhang, David Lo, Lucia Lucia

Research Collection School Of Computing and Information Systems

The second International Workshop on Software Mining (Soft-mine) was held on the 11th of November 2013. The workshop was held in conjunction with the 28th IEEE/ACM International Conference on Automated Software Engineering (ASE) in Silicon Valley, California, USA. The workshop has facilitated researchers who are interested in mining various types of software-related data and in applying data mining techniques to support software engineering tasks. During the workshop, seven papers on software mining and behavior models, execution trace mining, and bug localization and fixing were presented. One of the papers received the best paper award. Furthermore, there were two invited talk …

How Wildlife Information, Recreation Involvement And Demographic Characteristics Influence Public Acceptability Of Development, Jessica Espenshade

Graduate College Dissertations and Theses

Increasing development like roads and houses will alter the future landscape of Vermont. Development provides important resources for people and society, but also results in consequences for wildlife and opportunities for recreation. Managing development requires information on the public's acceptability of development and how acceptability is shaped by information on various consequences. In this study, I examined three questions: 1) What is the public's acceptability of development? 2) Does wildlife information influence public acceptability of development and 3) Is the maximum amount of acceptable development influenced by views about wildlife, involvement in recreation, and demographic factors? I surveyed 9,000 households …

Estimating Cost Adjustments Required To Accomplish Target Savings In Chronic Disease Management Interventions: A Simulation Study, Rafael Diaz, Joshua G. Behr, Bruce S. Britton

VMASC Publications

Chronic diseases are persistent ailments that are not preventable or curable with medication or vaccination. Many of the leading chronic conditions in industrialized societies may be related to lifestyle choices. The prevalence of these chronic conditions significantly affects the health, suffering, and longevity of patients. This paper demonstrates the utility of system dynamics as an approach to model and simulate the behavior of key cost factors in the implementation of population health management interventions. The study uses modeling and simulation as an evaluative method to identify potential savings stemming from an intervention within a well-defined population group. The model is …

Potential Of Forages In Crop Diversification And Crop Rotation, Martin H. Entz, Joanne Thiessen Martens

IGC Proceedings (1993-2023)

Redesign of agricultural systems according to ecological principles has been proposed for the development of sustainable systems. We review a wide variety of ecologically-based crop production practices that focus on forage crops in farming systems and discuss their potential role in enhancing the profitability, environmental sustainability and resilience. Crop-livestock systems that most closely mimic natural systems through appropriate integration of diverse components appear to offer the greatest potential benefits. These systems are more energy efficient and combine high productivity with low ecological footprint. Greater understanding of ecological relationships within crop-livestock systems are required to purposefully and proactively redesign agricultural systems …

Evergraze: A Partnership Between Researchers, Farmers And Advisors To Deliver Effective Grassland Management, Warwick B. Badgery, Kate Sargeant, Michael A. Friend, Scott Glyde, Paul Sanford, Ralph Behrendt, Meredith L. Mitchell, Sean Murphy, Angela Avery

IGC Proceedings (1993-2023)

The profitable and sustainable management of livestock production from grassland systems is challenging and it can be difficult to develop a research structure that addresses farmer’s needs and has acceptable rigour and on-ground impact. This paper describes the attributes of research, development and extension (RD&E) programs that are required for a successful partnership between researchers, farmers and advisors. Insights are provided from the EverGraze program that designed, tested and implemented farming systems based on perennial pastures across southern Australia. With this project farmers and advisors were involved in setting research direction, designing experiments, providing strategic guidance over the management of …

Characterization Of Pm2.5 From Residential Woodstove Use For Source Apportionment Application, Virginia M. Porden

Graduate Student Theses, Dissertations, & Professional Papers

Results are presented for the comparative analysis of the PM_2.5 (Particulate Matter <2.5 µm) emissions from an EPA certified and a Traditional style wood stove using western larch. A total of 92 Quartz QMA 47mm filters were collected using a BGI PM_2.5 SSC (Sharp Cut Cyclone) sampler from each stove type and analyzed on a gas chromatograph-mass spectrometer against blank and deuterated internal standards. The results were analyzed using a Welch’s t-test (α > 0.05) to statistically differentiate between stove designs for temperature, mass, levoglucosan, resin acids (abietic and dehydroabietic), and polycyclic aromatic hydrocarbons [PAH] (acenaphthene, anthracene, benz(a)anthracene, pyrene, and retene). There was no statistical difference in levoglucosan PM_2.5 mass fraction between the stove types, yielding a mean levoglucosan fraction of 9.25% and 95% confidence interval of 8.43% …

Permutation Invariant Lattices, Lenny Fukshansky, Stephan Ramon Garcia, Xun Sun

Pomona Faculty Publications and Research

We say that a Euclidean lattice in Rⁿ is permutation invariant if its automorphism group has non-trivial intersection with the symmetric group S_n, i.e., if the lattice is closed under the action of some non-identity elements of S_n. Given a fixed element T E S_n, we study properties of the set of all lattices closed under the action of T: we call such lattices T-invariant. These lattices naturally generalize cyclic lattices introduced by Micciancio in [7,8], which we previously studied in [1]. Continuing our investigation, we discuss some basic properties of …

Toeplitz Determinants With Perturbations In The Corners, Albrecht Böttcher, Lenny Fukshansky, Stephan Ramon Garcia, Hiren Maharaj

Pomona Faculty Publications and Research

This paper is devoted to exact and asymptotic formulas for the determinants of Toeplitz matrices with perturbations by blocks of fixed size in the four corners. If the norms of the inverses of the unperturbed matrices remain bounded as the matrix dimension goes to infinity, then standard perturbation theory yields asymptotic expressions for the perturbed determinants. This premise is not satisfied for matrices generated by so-called Fisher-Hartwig symbols. In that case we establish formulas for pure single Fisher-Hartwig singularities and for the Hermitian matrices induced by general Fisher-Hartwig symbols.

Nutrient Movements Through Ruminant Livestock Production Systems, Adegbola T. Adesogan, Jose C. B. Dubeux, Lynn E. Sollenberger

IGC Proceedings (1993-2023)

Considerable attention has been paid to reducing nutrient emissions from ruminant livestock in the last few decades. This area will continue to attract considerable research in the future due to increasing farm sizes in some developed countries as well as the increasing demand for meat and dairy products, particularly in developing countries. This paper discusses the deposition and losses of carbon and nitrogen in soils and plants in grazed and harvested forage systems as well as utilization and losses of both nutrients by ruminants in both systems. The paper also outlines several soil, plant, and animal-focused strategies that can be …

Potential Antineoplastic Structural Variations Of Uracil Mustard (Uramustine) Retaining Cytotoxic Activity And Drug-Likeness Suitable For Oral Administration, Ronald Bartzatt

Chemistry Faculty Publications

Aims: To present 12 new variants of uracil mustard having drug-like properties and cytotoxic functional group, by utilizing uracil mustard (uramustine) as a lead compound. Utilize rigorous substructure and similarity of a molecular scaffold to determine drug like variants. Physicochemical properties determined indicate the variants have favorable drug-likeness.

Study Design: Conduct molecular database search utilizing features of substructure and similarity based upon uracil mustard. Place and Duration of Study: Department of Chemistry, Medicinal Chemistry Study Section, University of Nebraska at Omaha, Omaha Nebraska between January 2015 to March 2015.

Methodology: Uracil mustard consists of the pyrimidine derivative uracil, …

Symmetries And Patterns In Non-Euclidean Settings, Sarah Elizabeth Stoops

Undergraduate Honors Thesis Collection

From the Megalithic Temples of Malta constructed over 5,500 years ago, to the Pyramid of Djoser in Egypt built some 4,700 years ago, to more recent works of architectural wonder such an the Taj Mahal, the testimonials to the innate human genius for creating beauty through symmetry, color, and patterns abound. Evidently, the mathematical underpinnings of many architectural marvels are mostly rooted in the Euclidean Geometry. Now, as marvelous as these monuments are, one may wonder what would be the concepts of beauty and symmetry in a non-Euclidean universe. It turns out that this is not a far-fetched thought. It …

Hyperbolic Geometry With And Without Models, Chad Kelterborn

Masters Theses

We explore the development of hyperbolic geometry in the 18th and early 19th following the works of Legendre, Lambert, Saccheri, Bolyai, Lobachevsky, and Gauss. In their attempts to prove Euclid's parallel postulate, they developed hyperbolic geometry without a model. It was not until later in the 19th century, when Felix Klein provided a method (which was influenced by projective geometry) for viewing the hyperbolic plane as a disk in the Euclidean plane, appropriately named the "Klein disk model". Later other models for viewing the hyperbolic plane as a subset of the Euclidean plane were created, namely the Poincaré disk model, …

Novel Bodipy Dyes For Dye-Sensitized Solar Cells, Hafsah Klfout

Masters Theses

Dyes-sensitized solar cells (DSCs) are of importance to efficient conversion of solar energy to electricity. The modern version of a DSC is a titanium dioxide nanoparticles-based electrochemical device, in which solar energy is absorbed by dye molecules and electrons from excited dye molecules are injected into the conduction band of titanium dioxide nanoparticle. The electrons are then transported through a network of interconnected TiO₂ particles to the fluorine- tin -oxide layer to the external circuit. In this process dye molecules are crucial to the device's energy conversion efficiency.

Boron-dipyrromethenes, known as BODIPY dyes, show strong absorption in the visible …

The Effects Of Industrial Biomass Gasification Ash As A Soil Amendment On The Earthworm Eisenia Fetida, Michael J. Blackowicz

Masters Theses

Soil application of solid residues from thermal conversion of biomass (i.e. combustion and pyrolysis) has become a topic of interest in recent years. However, there exists a gap in the literature with regard to soil application of gasification residues and their effects on soil health and soil macroorganisms. This study investigates the effects of three different ashes (hardwood oak/hickory, hardwood willow, corn stover), collected from industrial biomass gasification reactors (University of Minnesota Morris, Eastern Illinois University), as a soil amendment on the composting worm Eisenia fetida. Additionally, ash samples were analyzed for total polycyclic aromatic hydrocarbons (PAHs) and potentially toxic …

Morphological And Surface Chemistry Characteristics Of Silica Nanoparticle Based Cryogels From Specific Processing Parameters, Ben Walusiak

Masters Theses

The goal of this research was to determine the effects of processing conditions on the morphology and surface chemistry of silica nanoparticle based cryogels. All processing conditions resulted in a change in morphology or surface chemistry compared to the starting material, CAB-O-SIL HS5 fumed silica. N₂ adsorption isotherms were used to characterize surface area and pore size distributions of fumed silica and silica cryogels. TGA (thermogravimetric analysis) was performed on all samples in order to characterize the adsorbed water and hydroxyl group content of the silica surface. Solid state ²⁹Si NMR was also used to evaluate surface chemistry …

Driftless Area Karst Of Northwestern Illinois And Its Effects On Groundwater Quality, Samuel V. Panno, Walton R. Kelly

Sinkhole Conference 2015

The bedrock aquifer of the Driftless Area of northwestern Illinois is Ordovician-age Galena Dolomite. Previous work by the authors and others showed that the geology and hydrogeology of this area fall well within the definition of karst. Bedrock in the study area has been shown to be extensively fractured and creviced; karst features in the county are dominated by solution-enlarged crevices from 0.4 inches to 3 feet wide within most road cuts and quarries examined. Other karst features include cover-collapse sinkholes ranging from 3 to 25 feet in diameter overlying Galena Dolomite, karst springs and crevice caves. A preliminary evaluation …

Reply To Comment On Origin Of Surface Canting Within Fe3o4 Nanoparticles, Kathryn L. Krycka, Julie A. Borchers, R.A. Booth, Yumi Ijiri, K. Hasz, James J. Rhyne, S.A. Majetich

Faculty & Staff Scholarship

No abstract provided.

A Glance At Tropical Operations And Tropical Linear Algebra, Semere Tsehaye Tesfay

Masters Theses

The tropical semiring is ℝ ∪ {∞} with the operations x ⊕ y = min{x, y}, x ⊕ ∞ = ∞ ⊕ x = x, x ⊙ y = x + y, x ⊙ ∞ = ∞ ⊙ y = ∞. This paper explores how ideas from classical algebra and linear algebra over the real numbers such as polynomials, roots of polynomials, lines, matrices and matrix operations, determinants, eigen values and eigen vectors would appear in tropical mathematics. It uses numerous computed examples to illustrate these concepts and explores the relationship between certain tropical matrices and graph …

Cows And Plows: Science-Based Conservation For Grassland Songbirds In Agricultural Landscapes, Marisa K. Lipsey

Graduate Student Theses, Dissertations, & Professional Papers

Temperate grasslands are among earth’s most imperiled ecosystems. In North America, steep declines of endemic songbird populations indicate that grassland loss and degradation may be approaching critical levels. Grasslands are agricultural landscapes largely (~85%) under private ownership with little formal protection status. Remaining bird populations depend on grazing lands that have not been converted to cropland. We combine regional data from a hotspot for grassland bird diversity (northeast Montana, USA; 26,500-km2) with continental data spanning the northern Great Plains (1,000,000-km2) to evaluate how land use and management influence bird distribution and abundance. Regionally, habitat used by seven grassland specialists spanned …

Public Exposure To U.S. Commercial Nuclear Power Plants Induced Disasters, Dean Kyne

Sociology Faculty Publications and Presentations

This study explores the potential risks associated with the 65 U.S.-based commercial nuclear power plants and the distribution of those risks among the populations of both their respective host communities and of the communities located in outlying areas. First, it starts by examining the racial/ethnic composition of the host community populations, as well as the disparities in socioeconomic status that exist, if any, between the host communities and communities located in outlying areas. Second, it utilizes two independent-sample T tests to identify any differences in the sociodemographic compositions of the two areas. Third, it explores regional demographic trends by looking …

Block Design-Based Asynchronous Neighbor Discovery Protocol For Wireless Sensor Networks, Sangil Choi, Wooksik Lee, Teukseob Song, Jong-Hoon Youn

Chemistry Faculty Publications

Neighbor discovery is a significant research topic in wireless sensor networks. After wireless sensor devices are deployed in specific areas, they attempt to determine neighbors within their communication range. This paper proposes a new Block design-based Asynchronous Neighbor Discovery protocol for sensor networks called BAND. We borrow the concept of combinatorial block designs for neighbor discovery. First, we summarize a practical challenge and difficulty of using the original block designs. To address this challenge, we create a new block generation technique for neighbor discovery schedules and provide a mathematical proof of the proposed concept. A key aspect of the proposed …

What Is Answer Set Programming To Propositional Satisfiability, Yuliya Lierler

Computer Science Faculty Publications

Propositional satisfiability (or satisfiability) and answer set programming are two closely related subareas of Artificial Intelligence that are used to model and solve difficult combinatorial search problems. Satisfiability solvers and answer set solvers are the software systems that find satisfying interpretations and answer sets for given propositional formulas and logic programs, respectively. These systems are closely related in their common design patterns. In satisfiability, a propositional formula is used to encode problem specifications in a way that its satisfying interpretations correspond to the solutions of the problem. To find solutions to a problem it is then sufficient to use a …

Collaboration Portal For Researchers At Eastern Illinois University, Fatemeh Khastkhodaardekani

Masters Theses

This thesis addresses a need for an online collaboration environment for the researchers at Eastern Illinois University (EIU). As the solution, it provides a portal for researchers (students and faculties) who wish to explore and collaborate on projects based on ideas from those who may not have the necessary skills. This is considered to help developing projects based on the ideas as well as making teams, and teach different groups of people different perspectives. Therefore, it offers a learning environment. I started off by examining existing tools and methodologies to satisfy this purpose. As the result, the deliverable project is …

Ogden College Of Science & Engineering Newsletter (Winter 2015), Cheryl Stevens, Dean

Ogden College of Science & Engineering Publications

No abstract provided.

A New Design Method For Vanadium Redox Batteries In Renewable Energy Systems, Casey Gibson, Karla G. Morrissey Unversity Of Arkansas, Fayetteville

Inquiry: The University of Arkansas Undergraduate Research Journal

This study investigated the behavior of vanadium redox flow batteries (VRFBs), which are batteries capable of easily switching between charging and discharging modes, making them a suitable option for storing intermittent sources of alternative energies (solar, wind, etc). Since different sizes of the battery provide varying voltages, optimal parameters for a particular home are key for implementation. These parameters, specifically the cell and tank volumes of the battery that are capable of providing consistent on-load voltage, were determined using data from a 13 kW solar array and a medium-sized house. Charge/discharge current values were used to run a mathematical model …