Physical Sciences and Mathematics Commons^™

How To Select A Model If We Know Probabilities With Interval Uncertainty, Vladik Kreinovich

Departmental Technical Reports (CS)

Purpose: When we know the probability of each model, a natural idea is to select the most probable model. However, in many practical situations, we do not know the exact values of these probabilities, we only know intervals that contain these values. In such situations, a natural idea is to select some probabilities from these intervals and to select a model with the largest selected probabilities. The purpose of this study is to decide how to most adequately select these probabilities.

Design/methodology/approach: We want the probability-selection method to preserve independence: If, according to the probability intervals, the two …

If Everything Is A Matter Of Degree, Why Do Crisp Techniques Often Work Better?, Miroslav Svitek, Olga Kosheleva, Vladik Kreinovich

Departmental Technical Reports (CS)

Numerous examples from different application domain confirm the statement of Lotfi Zadeh -- that everything is a matter of degree. Because of this, one would expect that in most -- if not all -- practical situations taking these degrees into account would lead to more effective control, more effective prediction, etc. In practice, while in many cases, this indeed happens, in many other cases, "crisp" methods -- methods that do not take these degrees into account -- work better. In this paper, we provide two possible explanations for this discrepancy: an objective one -- explaining that the optimal (best-fit) model …

Inkjet-Printed Electrochemical Sensors For Lead Detection, Annatoma Arif

Open Access Theses & Dissertations

This PhD dissertation research has developed a simple, miniaturized, sensitive, selective, reproducible, and disposable 3D (inkjet printed – additive manufacturing technology) gold (Au) plated electrochemical sensor (ECS) on shape memory polymer (SMP) for aqueous lead detection. This technology has shown promising performance in the application of electrochemical sensing (lead (II) detection) due to increased effective electrode surface area (7.25 mm^2 ± 0.15 mm^2) despite miniaturizing lateral surface area (4.19 mm^2). The design, fabrication processes, optimization including bismuth functionalization, evaluation, uncertainty analysis, and cost analysis of the novel SMP based inkjet printed Au plated sensor have been delineated in this manuscript …

Continuous Risk Assessment For Large-Scale Cyber Systems, Adeel A. Malik

Open Access Theses & Dissertations

Cyberspace, with its multiple forms of device integration, is rapidly evolving and introducing loopholes within the cyber infrastructure, which creates opportunities for attackers. Despite the presence of network security devices such as firewalls, anti-virus, intrusion detection, and prevention systems, network intrusions still occur due to vulnerabilities within organizational assets or socially engineered cyber attacks. The lack of information about threats, vulnerabilities, and threat actors often leaves cyber defenders on a wild goose chase, making it critical to evaluate network security to mitigate adversarial threats periodically.

Various risk assessment frameworks, third-party tools, and online databases containing comprehensive threat information have been …

A Dft Analysis And Simple Hamiltonian Modeling Of A Molecular System Employed For Experimental Evidence Of Quantum Teleportation, Pedro Ulises Medina Gonzalez

Open Access Theses & Dissertations

Radical ion pairs (RIPs) have been used to demonstrate quantum teleportation in molecular systems for applications in quantum information science. Covalent organic donor-acceptor (D-A) molecules can produce RIPs through photo-induced charge transfer and an additional radical (R) molecule makes quantum teleportation possible. We present the electronic structure and analyze charge transfer excited states of a recently studied [1] D-A-R molecular system using density functional theory. The distances between donor-acceptor and donor-radical are about 12.9 \AA $\,$ and 21.9 \AA, respectively. The excitation energies are calculated using the perturbative delta-SCF method and agree with other conventional excited-state methods and experimental reference …

Robust Penalized Density Power Divergence Regression With Scad Penalty For High Dimensional Data Analysis, Maxwell Kwesi Mac-Ocloo

Open Access Theses & Dissertations

Amidst the exponential surge in big data, managing high-dimensional datasets across diverse fields and industries has emerged as a significant challenge. Conventional statistical methods struggle to handle their complexity, making analysis intricate. In response, we've formulated a robust estimator tailored to counter outliers and heavy-tailed errors. Our approach integrates the SCAD penalty into the Density Power Divergence method, effectively reducing insignificant coefficients to zero. This enhances analysis precision and result reliability.We benchmark our robust and penalized model against existing techniques like Huber, Tukey, LASSO, LAD, and LAD-LASSO. Employing both simulated and UCI machine learning repository datasets, we assess method performance …

Water Quality Land Cover Change And Water Quality In Wetlands At The City Of Gresham, Or, Evelyn Barajas, Michael Gonzalez

altREU Projects

The City of Gresham, Oregon has implemented constructed wetlands around the area as an attempt to collect, filter, and purify water from different sources such as rain, agricultural waste, and domestic waste. We focused our research on three different facilities: Columbia Slough Water Quality Facility (CSWQF), Fairview Creek Water Quality Facility, and Brookside Water Quality Facility. For each of these, we conducted tests and looked at the concentration levels for nitrogen and phosphorus nutrients such as NH3-N (ammonium), NO3-N (nitrate), TKN (total Kjeldahl nitrogen), O-PO4 (phosphate), and Total P (total phosphorus), as well as heavy metals like Total Cu (total …

Late Jurassic Paleogeography Of The U.S. Cordillera From Detrital Zircon Age And Hafnium Analysis Of The Galice Formation, Klamath Mountains, Oregon And California, Usa, Kathleen D. Surpless, Ryan Wayne Alford, C. Barnes, A. Yoshinobu, Natalee E. Weis

Geosciences Faculty Research

The Upper Jurassic Galice Formation, a metasedimentary unit in the Western Klamath Mountains, formed within an intra-arc basin prior to and during the Nevadan orogeny. New detrital zircon U-Pb age analyses (N = 11; n = 2792) yield maximum depositional ages (MDA) ranging from ca. 160 Ma to 151 Ma, which span Oxfordian to Kimmeridgian time and overlap Nevadan contractional deformation that began by ca. 157 Ma. Zircon ages indicate a significant North American continental provenance component that is consistent with tectonic models placing the Western Klamath terrane on the continental margin in Late Jurassic time. Hf isotopic analysis of …

Synthesis And Reactivity Of Heteroatom Embedded Cycloalkynes In Spaac, Nickel Catalyzed Alkylarylation Of Alkenes, And Carbofluorination Of Alkynes, Namrata Khanal

Chemistry and Chemical Biology ETDs

Part I covers Chapters 1, 2, and 3

cycloaddition reactions, that is utilized in biorthogonal chemistry. This metal free version The strain promoted azide-alkyne cycloaddition (SPAAC) reaction is one of the popular 1,3-dipolar of click reaction offers advantage over copper catalyzed click reaction. Since it eliminates the use of copper that is toxic to cells, it is considered favorable for biocompatible reaction. Due to the increased reactivity with dipoles without the use of metal catalyst, cycloalkynes, in particular cyclooctynes, have been employed as the biorthogonal reagent in biorthogonal chemical reaction for the study of a biological processes in vivo. The …

Proceedings Of The 2023 Berry Summer Thesis Institute, University Of Dayton. University Honors Program

Proceedings of the Berry Summer Thesis Institute

Thanks to a gift from the Berry Family Foundation and the Berry family, the University Honors Program launched the Berry Summer Thesis Institute in 2012. The institute introduces students in the University Honors Program to intensive research, scholarship opportunities and professional development. Each student pursues a 12-week summer thesis research project under the guidance of a UD faculty mentor. This contains the product of the students' research.

Contents:

• “How Porous Materials Affect the Boundary-Layer Transition of Hypersonic Flight Vehicles” (Megan C. Sieve)
• “Ultra-Stretchable, Self-Healing, DLP 3D-Printed Elastomers for Damage-Resistant Soft Robots: A Review” (Robert M. A. Drexler)
• “Extrapolation of Scalar …

Nutrient Dynamics Of Freshwater Estuarine Sediments Disturbed By Dredging, Ryan Allan John Roekle

Theses and Dissertations

This study examined the nutrient environment of sediments in the Milwaukee River estuary and the dynamics of those nutrients during simulated disturbance experiments within the context of large-scale dredging remediation. Surface sediments were collected from throughout the Milwaukee estuary (including river, harbor, and nearshore stations) by PONAR, centrifuged to separate porewater (interstitial water) from solid material, and filtered to further isolate and stabilize dissolved material. Porewaters were analyzed for dissolved nutrients including ammoniacal nitrogen (AN), nitrate, nitrite, and soluble reactive phosphorus (SRP). Surface sediment porewaters within the estuary were often highly enriched in AN and SRP, which were often 10-2000x …

Benthic Algal And Macroinvertebrate Response To The Removal Of Dreissenid Mussels In The Nearshore Zone Of Lake Michigan, Tyler Alexander Kunze

Theses and Dissertations

Dreissenid mussels (Dreissena polymorpha and Dreissena rostriformis bugensis) have changed the fundamental community structure and biogeochemical processes of the Lake Michigan nearshore zone. There is evidence that dreissenids promote the nuisance growth of benthic algae, especially Cladophora sp. In addition, benthic macroinvertebrates have benefitted from the presence of dreissenid mussels due to the increased structural complexity along with greater nutrient availability in the benthos. These effects of the dreissenid mussel invasion are well documented; however, little is known about how these systems respond to the removal of dreissenid mussels from a once-populated area. Therefore, it is important to further our …

The Vanishing Discount Method For Stochastic Control: A Linear Programming Approach, Brian Hospital

Theses and Dissertations

Under consideration are convergence results between optimality criteria for two infinite-horizon stochastic control problems: the long-term average problem and the $\alpha$-discounted problem, where $\alpha \in (0,1]$ is a given discount rate. The objects under control are those stochastic processes that arise as (relaxed) solutions to a controlled martingale problem; and such controlled processes, subject to a given budget constraint, comprise the feasible sets for the two stochastic control problems.

In this dissertation, we define and characterize the expected occupation measures associated with each of these stochastic control problems, and then reformulate each problem as an equivalent linear program over a …

Collapsibility And Z-Compactifications Of Cat(0) Cube Complexes, Daniel L. Gulbrandsen

Theses and Dissertations

We extend the notion of collapsibility to non-compact complexes and prove collapsibility of locally-finite CAT(0) cube complexes. Namely, we construct such a cube complex $X$ out of nested convex compact subcomplexes $\{C_i\}_{i=0}^\infty$ with the properties that $X=\cup_{i=0}^\infty C_i$ and $C_i$ collapses to $C_{i-1}$ for all $i\ge 1$.

We then define bonding maps $r_i$ between the compacta $C_i$ and construct an inverse sequence yielding the inverse limit space $\varprojlim\{C_i,r_i\}$. This will provide a new way of Z-compactifying $X$. In particular, the process will yield a new Z-boundary, called the cubical boundary.

Non-Hyperbolic Right-Angled Coxeter Groups With Menger Curve Boundary, Cong He

Theses and Dissertations

We find a class of simplicial complexes as nerves of non-hyperbolic right-angled Coxetergroups, with boundary homeomorphic to the Menger curve. The nerves are triangulations of compact orientable surfaces with boundary. In particular, the nerves are non-graphs.

Distribution And Habitat Associations Of The Georgia Satyr (Neonympha Areolatus) In Arkansas, Kristi Patterson

ATU Theses and Dissertations 2021 - Present

The Georgia satyr (Neonympha areolatus) is a small sedentary butterfly that is rare in Arkansas. Currently, the exact locations of this butterfly in Arkansas are unknown, along with the habitat characteristics associated with their presence. In order to determine these unknowns, I completed 104 surveys across seven different wildlife management areas in southern Arkansas. Pollard-Yates transects were conducted at each study site, and weather variables were recorded before each survey. Vegetation surveys were also completed at each site, and where each Georgia satyr was identified. Generalized linear models (GLM) were created to identify what parameters are important for …

Characteristics Of Refractivity And Sea State In The Marine Atmospheric Surface Layer And Their Influence On X-Band Propagation, Douglas Matthew Pastore

Electronic Theses and Dissertations

Predictions of environmental conditions within the marine atmospheric surface layer (MASL) are important to X-band radar system performance. Anomalous propagation occurs in conditions of non-standard atmospheric refractivity, driven by the virtually permanent presence of evaporation ducts (ED) in marine environments. Evaporation ducts are commonly characterized by the evaporation duct height (EDH), evaporation duct strength, and the gradients below the EDH, known as the evaporation duct curvature. Refractivity, and subsequent features, are estimated in the MASL primarily using four methods: in-situ measurements, numerical weather and surface layer modeling, boundary layer theory, and inversion methods.

The existing refractivity estimation techniques often assume …

Design Of A Resonant Optical Cavity For Imaging Magneto-Optically Active Thin Film Samples, Cody Robert Brelage

Graduate Theses - Physics and Optical Engineering

This document describes the design and fabrication of an optical resonator system to investigate magneto-optic properties of thin film samples. This system uses an open-air optical resonator to enable photons to make multiple passes through each thin film and thus increase the magnitude of the Faraday rotation that each sample imposes onto the light that exits the system. This system promises many future experiments to study the magneto-optic properties of thin film and nano-particle samples. Using an optical resonator to enhance Faraday rotation should enable an improved signal-to-noise ratio in taking measurements and images with a photodetector.

Reservoir Characterization Of The Utica Shale Play Using Well Log Data In Columbiana, Ohio, Tyler L. West

Electronic Theses and Dissertations

The Ordovician Utica shale play is rapidly developing throughout the Appalachian Basin. The play is a mixed carbonate-siliciclastic system that grades from primarily carbonates at its base in the Lexington/Trenton limestones into primarily shale within the Utica shale. As of January 2021, it is the third highest-producing dry shale gas play in the contiguous U.S., although it is known to produce wet gas and oil in various parts of the basin. In addition to being an unconventional reservoir, the Utica shale, an informal unit in Ohio where the main fairway is located, is a known source rock for much of …

A Statewide Evaluation Of Fuel Treatment Effectiveness In Altering Wildfire Outcomes On Public Lands In Utah, Jamela Charmaine Thompson

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Fuel treatments are land management activities that reduce living and dead flammable materials on the landscape to mitigate undesirable wildfire behavior and effects. Common treatments in the western United States include mechanical methods such as thinning and mastication, prescribed burns, and chemical methods, such as herbicide application. Treatments usually have multiple objectives, including reducing fire intensity, protecting natural and cultural resources, slowing or disrupting a potential future fire’s path, supporting ecosystem health, and reestablishing low to mid severity fire cycles in ecosystems. Although treatments can potentially modify fire behavior and ecological health, they generally cannot prevent fires from igniting, eliminate …

Comparative Study Of Clustering Techniques On Eye-Tracking In Dynamic 3d Virtual Environments, Scott Johnson

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Eye-tracking has been used for decades to understand how and why an individual focuses on particular objects, areas, and elements of space. A vast body of knowledge exists on how eye-tracking is measured. However, historically, eye-tracking has been predominately studied using 2D environments, with limited work in 3D environments. The purpose of this study is to identify which methods most accurately represent the areas that have captured the participant’s visual attention within a 3D dynamic environment. This will be completed by evaluating different clustering methods of fixations using a customized virtual reality tool that collects eye-tracking data. There exist several …

Using Stable Water Isotopes And Radiogenic Strontium Isotopes To Trace Water And Its Salinity Sources In Pecos And Colorado River Basins In Texas, Nuria Valeria Andreu Garcia

Open Access Theses & Dissertations

Water stable isotope ratios (Deuterium/hydrogen 2H/1H and Oxygen 18O/16O ratios) and radiogenic strontium isotope ratios (87Sr/86Sr) have been widely used to trace various hydrologic processes and understand surface-groundwater interactions for watershed and critical zone studies. Our project aimed to trace the water and salinity sources in the Colorado and Pecos Rivers, two major rivers that provide essential water resources for water-stressed parts of Texas. In our study, we collected water samples from 25 locations during July (monsoon season), December 2021 (dry season), and May 2022 (pre-monsoon season) along the Pecos and Colorado rivers from central Texas to the Gulf of …

Removal Of Nonylphenols From Water And Wastewater Using Alginate-Activated Carbon Beads, Angelica Araly Chacon

Open Access Theses & Dissertations

The presence of contaminants of emerging concern (CECs) have been affecting water quality in recent years. The United States Environmental Protection Agency (U.S EPA) defines CECs as toxic chemicals without regulatory status and with adversely impact on the wildlife and people. Among the CECs, nonylphenols (NPs) are frequently found in all water systems and are categorized as endocrine-disrupting compounds (EDCs) due to their ability to mimic hormones causing reproductive and developmental effects in humans and animals. The main sources of discharge and distribution of NPs into the environment are wastewater treatment plants (WWTPs) which are not designed to remove them. …

Electrochemical Approaches To Life-Support Resources In Space Missions And Nuclear Technologies: Hydrogen Peroxide And Uranium Films, Armando Manuel Pena-Duarte

Open Access Theses & Dissertations

Space race has developed several technological advances that have achieved and continue to achieve the success of space missions in the aerospace timeline. Currently, the number of space technical and scientific innovations is still growing––demanding new materials and developments for extreme performing applications of fuel cells, batteries, supercapacitors, and systems of nuclear energy. Space missions require life-support solutions, auto-sustainable closed-loop living environments, cleaning and sanitizing solutions against pathogens, and safe nuclear-based resources of energy––with fissile materials with well-controlled dimensions within the core fuel elements. Likewise, to guarantee safety conditions, reduce costs, and facilitate operational logistics, space missions must reduce their …

Density Functional Theory Study Of Dopant Incorporation Into Gamma-Uo3, Nicholas James Wilson

Open Access Theses & Dissertations

Uranium trioxide (UO3) is a stable uranium oxide found throughout the nuclear fuel cycle. The γ-UO3 phase is of particular interest as the most stable at ambient conditions. As such, the γ-UO3 structure was selected for a theoretical investigation into the incorporation of metal dopants for nuclear intentional forensics applications. The two lattice types of this phase, tetragonal (I41/amd) and orthorhombic (Fddd), were investigated and found to be energetically identical, and as such the smaller tetragonal structure was selected for doping. Three transition metal dopants (Cr, Fe, and Ni) were incorporated into the structure interstitially and substitutionally at a total …

Growth Of Purple Sulfur Bacteria Allochromatium Vinosum On Solid Phase Metal Sulfides As Sulfur And Electron Sources, Hugo Alarcon

Open Access Theses & Dissertations

Purple sulfur bacteria (PSB) are photosynthetic microorganisms known for their vital roles in geochemical cycles, especially the sulfur cycle, within anoxic photic environments. PSB are also key contributors to the nitrogen, carbon, and oxygen cycles. This study focuses on the autotrophic growth of Allochromatium vinosum, a model strain of PSB, that utilize solid-phase metal sulfides (MS) as both sulfur and electron donors. Through characterizing the growth profiles of A. vinosum on pyrite (FeS2), nickel sulfide (NiS), and iron monosulfide (FeS) nanoparticles, respectively, and investigating the bacteria-MS interaction mechanisms, this work expands our current knowledge of the metabolic capabilities and flexibility …

Partial Auto-Correlation Of Low Magnitude Earthquakes From The 2016 Iris Aray In Grant County, Oklahoma, Alex Christopher Eddy

Open Access Theses & Dissertations

The Anadarko Basin in is a seismically active basin that spans central and western Oklahoma into Kansas. In June and July of 2016, the IRIS Community Wavefield Experiment array was deployed for approximately a month, recording over 300 earthquakes. Using 4 of these earthquakes and an east â?? west array of 129 Fairfield Nodal Z-land 3C nodes, I present a novel application of correlation. These four earthquakes with a ML of 2.8-3.0 represent a varied azimuthal distribution and are between 9 and 40km from the array and have a frequency peak at approximately 10 Hz.

As a proof of concept, …

Quantifying The Contribution Of Atmospheric And Land Surface Characteristics To The Prediction Of Sub-Pixel Scale Surface Soil Moisture In The Jornada Experimental Range Through Interpretable Machine Learning, Stephanie Nicole Marquez

Open Access Theses & Dissertations

This study presents machine learning-based approaches for understanding and predicting plot-scale soil moisture's spatial variability using hydrometeorological and biogeophysical data from in-situ, multi-sensor and remote sensing sources. The high-resolution input features include numerical and categorical data such as land surface temperature, ground albedo, 1-day, 1-week and 2-week antecedent precipitation, soil type, land cover type, distance to nearest vegetation individual, terrain slope and elevation, and normalized differenced vegetation index (NDVI). Soil moisture measurements are collected within a 3 km x 3 km desert grid with Campbell Scientific Hydrosense II-12 soil moisture sensors and validated with a gravimetric method of measuring volumetric …

Interdisciplinary Approach To Understanding Stakeholder Reasoning And Decision-Making For Water, Katalina Salas

Open Access Theses & Dissertations

On a global scale, humanity is compelled to address complex or â??wickedâ?? resource-related issues in the face of accelerating environmental change. In our work, we use the term wicked problem to refer to an issue that has multiple potential solutions and involves various stakeholders. The paths to reach resource sustainability under environmental uncertainty are difficult to identify, plausible outcomes remain uncertain, and tradeoffs required by any path chosen are challenging to understand. Environmental sustainability issues may involve perspectives from multiple stakeholders (i.e., scientists, policymakers, community members, and industry), often leading to conflicting interests and cultural misalignments that trigger the need …

The Influence Of Allostery Governing The Changes In Protein Dynamics Upon Substitution, Joseph Hess

All Dissertations

The focus of this research is to investigate the effects of allostery on the function/activity of an enzyme, human immunodeficiency virus type 1 (HIV-1) protease, using well-defined statistical analyses of the dynamic changes of the protein and variants with unique single point substitutions ¹. The experimental data¹ evaluated here only characterized HIV-1 protease with one of its potential target substrates. Probing the dynamic interactions of the residues of an enzyme and its variants can offer insight of the developmental importance for allosteric signaling and their connection to a protein’s function. The realignment of the secondary structure elements can …