Physical Sciences and Mathematics Commons^™

Petrophysical And Empirical And Theoretical Rock Physics Modeling For The Moki Formation In Two Fields In The Taranaki Basin, New Zealand, Deniz Yener

Dissertations, Master's Theses and Master's Reports

This work consists of conventional petrophysical analysis and sonic response determination from empirical relations, rock physics modelling, and fluid substitution for six wells in the Moki formation of New Zealand’s Taranaki Basin. The project composed of three parts encompassing conventional log analysis, rock-physics modeling using empirical and theoretical approaches, and finally rock-physics modeling for shaley sands using semi-empirical adaptations to Gassmann fluid substitution. Finally, comparisons are made between results for the different wells, based on their depths and mineralogy.

The first part of this study is presented as a petrophysical analysis, including crossplot analysis, conventional 3-mineral identification approach, and determination …

Investigation Of The Resistance To Demagnetization In Bulk Rare-Earth Magnets Comprised Of Crystallographically-Aligned, Single-Domain Crystallites With Modified Intergranular Phase, Jie Li

Dissertations, Master's Theses and Master's Reports

The research presented in this dissertation investigates whether an increased coercivity of Neodymium-Iron-Boron (Nd2Fe14B) based bulk magnets at elevated temperature (160°C), which is now only obtainable by substituting ~7wt% dysprosium (Dy) for a portion of neodymium (Nd), can be achieved through specific microstructural modifications with decreased Dy concentrations. The approach is to reduce the size of individual crystallographically-aligned grains in the magnet so that each grain can only support a single magnetic domain and to simultaneously dilute the Nd-Fe inter-granular phase present in conventional magnets with a non-Fe-containing, Nd-rich phase (Nd-Cu alloy) in an attempt to partially magnetically isolate the …

Numerical Modeling Of Ambient Noise Seismic Interferometry, Simisola M. Arogundade

Dissertations, Master's Theses and Master's Reports

CO₂ sequestration involves storing CO₂ in a deep geological formation and may help to mitigate the increasing emission of carbon. To monitor the migration of injected fluid in the reservoir, seismic observations may be used to observe changes in reflection character. Conventional methods to image the subsurface, using active seismic measurements, with man-made sources, have been applied at a few test sites, and the use of passive measurements, with natural sources, has been considered as a probable cost-efficient method to monitor CO₂ migration and leakage. This numerical modeling study examines the use of seismic interferometry to retrieve …

Comparisons Of Seismic Interferometry By Cross Correlation, Deconvolution, And Cross Coherence, Haitao Cao

Dissertations, Master's Theses and Master's Reports

Ambient noise seismic interferometry (ANSI) has been applied widely for geophysical investigations including earthquake tomography, civil engineering and seismic exploration purposes. Comparing this approach with the traditional active seismic survey, the application of ANSI is cost effective, environmentally friendly and easily repeatable. Conventional seismic interferometry by cross correlating wavefields recorded at different receivers has already obtained fruitful results.

Even though the application of seismic interferometry (SI) by cross correlation has been successful, different methods for the processing workflow such as cross coherence and deconvolution have been conducted in an effort to improve the resolution. While these three methods have been …

Cave Detection Using Seismic Methods At Madison Blue Spring State Park, Madison County, Florida, Charles Breithaupt

Dissertations, Master's Theses and Master's Reports

Locating caves and quantifying their geometries has significant importance in aquifer characterization, sinkhole mitigation, and contaminant transport monitoring. Several geophysical methods have been used for cave detection with limited success, but no reliable solution has been found. New developments in seismic techniques, however, show promising results indicating that cave voids may be more accurately detected.

We evaluated the capability of several seismic techniques to detect caves by collecting new seismic data over a known conduit connected to Madison Blue Spring, in northern Florida. These analyses validated the abilities of diffracted surface waves to detect water-filled caves by viewing these data …

Spectrophotometric Analysis Of Urinary Iodine In 18-22 Year-Old Women In Central Minnesota, Haley Chatelaine

All College Thesis Program, 2016-2019

Iodine is an overlooked but incredibly important micronutrient, especially with regard to early fetus development. The United States does not mandate salt iodization, so widely consumed processed foods are not likely to contain iodized salt, which may potentially put the population at risk for developing iodine deficiencies. Therefore, the purpose of this study is to correspond iodine intake to iodine status and establish effective methods for determining a relationship between the two. Subjects (n=23) completed a food survey and supplied 50mL urine samples to compare an estimated average daily iodine intake based on foods over the course of a week …

X-Ray Structure And Properties Of The Ferrous Octaethylporphyrin Nitroxyl Complex, Nagabhushanam Kundakarla, Sergey V. Lindeman, Hafiz Md. Rahman, Michael D. Ryan

Chemistry Faculty Research and Publications

The preparation and characterization of the iron octaethylporphyrin nitroxyl ion, [Fe(OEP)(NO)⁻], is reported. The complex was synthesized by the one-electron reduction of Fe(OEP)(NO) using anthracenide as the reducing agent. The compound was isolated as the potassium (2.2.2)cryptand salt. The anion was characterized using X-ray analysis with visible and infrared spectroscopy. The spectral features of the iron nitroxyl complex were consistent with previous literature reports. The important structural changes upon reduction were a significant decrease in the Fe–N–O bond angle from 142° to 127° and an increase in the N–O bond length from that in the starting nitrosyl moiety. …

One-Pot Synthesis Of Biocompatible Silver Nanoparticle Composites From Cellulose And Keratin: Characterization And Antimicrobial Activity, Chieu D. Tran, Franja Prosenc, Mladen Franko, Gerald Benzi

Chemistry Faculty Research and Publications

A novel, simple method was developed to synthesize biocompatible composites containing 50% cellulose (CEL) and 50% keratin (KER) and silver in the form of either ionic (Ag⁺) or Ag⁰ nanoparticles (Ag⁺NPs or Ag⁰NPs). In this method, butylmethylimmidazolium chloride ([BMIm⁺Cl^–]), a simple ionic liquid, was used as the sole solvent and silver chloride was added to the [BMIm⁺Cl^–] solution of [CEL+KER] during the dissolution process. The silver in the composites can be maintained as ionic silver (Ag⁺) or completely converted to metallic silver (Ag …

A Flipped Classroom Redesign In General Chemistry, Scott Reid

Chemistry Faculty Research and Publications

The flipped classroom continues to attract significant attention in higher education. Building upon our recent parallel controlled study of the flipped classroom in a second-term general chemistry course (J. Chem. Educ., 2016, 93, 13–23), here we report on a redesign of the flipped course aimed at scaling up total enrollment while keeping discussion sizes small (i.e.,students), and maintaining equivalent contact hour load for faculty and workload for students. To that end, the course format featured lecture contact pushed outside of the classroom in the form of video lectures (mean duration 13 minutes) paired with online …

Reactivity Of (3-Methylpentadienyl)Iron(1+) Cation: Late-Stage Introduction Of A (3-Methyl-2z,4-Pentadien-1-Yl) Side Chain, Subhabrata Chaudhury, Shukun Li, William A. Donaldson

Chemistry Faculty Research and Publications

The 3-methyl-2Z,4-pentadien-1-yl sidechain is found in various sesquiterpenes and diterpenes. A route for the late stage introduction of this functionality was developed which relies on nucleophilic attack on the (3-methylpentadienyl)iron(1+) cation, followed by oxidative decomplexation. This methodology was applied to the synthesis of the proposed structure of heteroscyphic acid A methyl ester. Realization of this synthesis led to a correction of the proposed structure.

Sol-Gel Assembly Of Metal Nanostructures Into Metallic Gel Frameworks And Their Applications, Xiaonan Gao

Theses and Dissertations

The advent of nanoscience and nanotechnology has sparked many research forefronts in the creation of materials with control over size, shape, composition, and surface properties.^1,2 However, for most of the applications, nanoscale materials need to be assembled into functional nanostructures that exhibit useful and controllable physical properties. Therefore, numerous efforts on the assembly of nanoparticles (NPs) using organic ligands, polymers and polyelectrolytes have been reported.^3,4 However, the interactions between NPs are mediated by intervening ligands, which are detrimental to charge transport and limit the thermal stability. Hence, developing a new method to produce solid …

Versatile Synthesis Of Transition Metal Phosphides: Emerging Front-Runners For Affordable Catalysis, April C. Mattei

Theses and Dissertations

Transition metal phosphide materials have found themselves at the forefront of research revolving around energy applications. Due to the vast range of properties possessed by marginally different phase compositions, binary and ternary metal phosphides are utilized as catalysts, semi-conductors and magnetocaloric materials along with many others. These attractive properties, which are highly phase dependent, call for a versatile and cost effective synthesis route for various phosphide materials without sacrificing properties important at the nanoscale such as particle size and morphology.

The primary focus outlined in the work of this dissertation pertains to a versatile wet chemical synthesis capable of producing …

Identifying Parameters For Robust Network Growth Using Attachment Kernels: A Case Study On Directed And Undirected Networks, Ahmed F. Abdelzaher

Theses and Dissertations

Network growing mechanisms are used to construct random networks that have structural behaviors similar to existing networks such as genetic networks, in efforts of understanding the evolution of complex topologies. Popular mechanisms, such as preferential attachment, are capable of preserving network features such as the degree distribution. However, little is known about such randomly grown structures regarding robustness to disturbances (e.g., edge deletions). Moreover, preferential attachment does not target optimizing the network's functionality, such as information flow. Here, we consider a network to be optimal if it's natural functionality is relatively high in addition to possessing some degree of robustness …

A Study Of The Effect Of Harvesting On A Discrete System With Two Competing Species, Rebecca G. Clark

Theses and Dissertations

This is a study of the effect of harvesting on a system with two competing species. The system is a Ricker-type model that extends the work done by Luis, Elaydi, and Oliveira to include the effect of harvesting on the system. We look at the uniform bound of the system as well as the isoclines and perform a stability analysis of the equilibrium points. We also look at the effects of harvesting on the stability of the system by looking at the bifurcation of the system with respect to harvesting.

Optimal Control And Its Application To The Life-Cycle Savings Problem, Tracy A. Taylor

Theses and Dissertations

Throughout the course of this thesis, we give an introduction to optimal control theory and its necessary conditions, prove Pontryagin's Maximum Principle, and present the life-cycle saving under uncertain lifetime optimal control problem. We present a very involved sensitivity analysis that determines how a change in the initial wealth, discount factor, or relative risk aversion coefficient may affect the model the terminal depletion of wealth time, optimal consumption path, and optimal accumulation of wealth path. Through simulation of the life-cycle saving under uncertain lifetime model, we are not only able to present the model dynamics through time, but also to …

Marine Ecoregion And Deepwater Horizon Oil Spill Affect Recruitment And Population Structure Of A Salt Marsh Snail, Steven C. Pennings, Scott Zengel, Jacob Oehrig, Merryl Alber, T. Dale Bishop, Donald R. Deis, Donna Devlin, A. Randall Hughes, John J. Hutchens, Jr., Whitney M. Kiehn, Caroline R. Mcfarlin, Clay L. Montague, Sean P. Powers, C. Edward Proffitt, Nicholle Rutherford, Camille L. Stagg, Keith Walters

University Faculty and Staff Publications

Marine species with planktonic larvae often have high spatial and temporal variation in recruitment that leads to subsequent variation in the ecology of benthic adults. Using a combination of published and unpublished data, we compared the population structure of the salt marsh snail, Littoraria irrorata, between the South Atlantic Bight and the Gulf Coast of the United States to infer geographic differences in recruitment and to test the hypothesis that the Deepwater Horizon oil spill led to widespread recruitment failure of L. irrorata in Louisiana in 2010. Size-frequency distributions in both ecoregions were bimodal, with troughs in the distributions consistent …

Interference Energy Spectrum Of The Infinite Square Well, Mordecai Waegell, Yakir Aharonov, Taylor Lee Patti

Mathematics, Physics, and Computer Science Faculty Articles and Research

Certain superposition states of the 1-D infinite square well have transient zeros at locations other than the nodes of the eigenstates that comprise them. It is shown that if an infinite potential barrier is suddenly raised at some or all of these zeros, the well can be split into multiple adjacent infinite square wells without affecting the wavefunction. This effects a change of the energy eigenbasis of the state to a basis that does not commute with the original, and a subsequent measurement of the energy now reveals a completely different spectrum, which we call the interference energy spectrum of …

Mathematical Frameworks For Consciousness, Menas C. Kafatos, Ashok Narasimhan

Mathematics, Physics, and Computer Science Faculty Articles and Research

If Awareness is fundamental in the universe, mathematical frameworks are better suited to reveal its fundamental aspects than physical models. Awareness operates through three fundamental laws which apply at all levels of reality and is characterized by three universal powers. We explore and summarize in general terms mathematical formalisms that may take us as close as possible to conscious awareness, beginning with the primary relationships between the observer with the observed, using a Hilbert space approach. We also examine insights from category theory, and the calculus of indications or laws of forms. Mathematical frameworks as fundamental languages of our interaction …

Fluid Release During Eclogite Formation, North Qaidam Terrane, Western China, Jake M. Meyer

All Master's Theses

Ultrahigh-pressure (UHP, depths ≳100 km) eclogite samples from the Dulan area of the North Qaidam Terrane, western China, preserve evidence of fluid release along a prograde pressure-temperature (P-T) path. Eclogite sample D126A, Grt + Omp + Qtz + Zo + Amp + Phe + minor Rt + Hem, contains garnet porphyroblasts that preserve strong Ca zoning, recording higher core values (Grs₃₄), lower inner mantle values (Grs₂₅), increasing outer mantle values (Grs₂₈), and lower rim values (Grs₂₆). Isochemical phase diagrams (pseudosections), assuming H₂O saturation, produce a P-T path constrained by multiple …

Applications Of Computational Geometry And Computer Vision, Joseph Lemley

All Master's Theses

Recent advances in machine learning research promise to bring us closer to the original goals of artificial intelligence. Spurred by recent innovations in low-cost, specialized hardware and incremental refinements in machine learning algorithms, machine learning is revolutionizing entire industries. Perhaps the biggest beneficiary of this progress has been the field of computer vision. Within the domains of computational geometry and computer vision are two problems: Finding large, interesting holes in high dimensional data, and locating and automatically classifying facial features from images. State of the art methods for facial feature classification are compared and new methods for finding empty hyper-rectangles …

Rapid Orbit Refinement Of Potential Near-Earth Objects And Recovery Of Nearly Lost Asteroids, Austin Lantz Caughey

Theses and Dissertations

The Minor Planet Center alerts researchers about potential discoveries of new Near-Earth Objects (NEOs) on their NEO Confirmation Page (NEOCP). Most of these are indeed previously unstudied objects, which must be studied very promptly while initial predictions of their motions are still accurate. My thesis project has focused on the observation of these bodies, and the submission of their measured positions to the MPC within a few hours of observation. Data has been obtained using the Skynet Robotic Telescope Network, including the R-COP telescope in Perth, Australia; the PROMPT 3 telescope in La Serena, Chile; and Yerkes Observatory in Williams …

Hydrological Drought Analysis For Seven North Georgia Watersheds (1970-2000), Jessica L. Taylor

Theses and Dissertations

Drought is a prolonged reduction in precipitation which may result in significant effects on local ecosystems, watersheds, and water sources, with the potential to have negative impacts on human populations. Normalized indexes can be used to characterize drought magnitudes and frequencies using historical data records on temperature, rainfall, snowpack, soil moisture, streamflow, and/or other water supply indicators. This study examined the applicability of two drought indices: Standardized Precipitation Index (SPI) and Streamflow Drought Index (SDI). The SPI and SDI estimate the magnitude of observed rainfall (SPI) and discharge (SDI) deviations from the longterm average. In this study, SPI and SDI …

Fuzzy Decision Tree-Based Inference System For Liver Disease Diagnosis, Himaja Sivaraju

Theses and Dissertations

Medical diagnosis can be challenging because of a number of factors. Uncertainty in the diagnosis process arises from inaccuracy in the measurement of patient attributes, missing attribute data and limitation in the medical expert’s ability to define cause and effect relationships when there are multiple interrelated variables. Given this situation, a decision support system, which can help doctors come up with a more reliable diagnosis, can have a lot of potential. Decision trees are used in data mining for classification and regression. They are simple to understand and interpret as they can be visualized. But, one of the disadvantages of …

Mangrove Enhancement As A Climate Change Adaptation Strategy In The Republic Of The Marshall Islands (Rmi): Potential Ecosystem Service Shifts Following Colonization, Andrew S. Harwood

Environmental Science and Management Professional Master's Project Reports

The ability of Small Island Developing States (SIDS) and Pacific Island communities to adapt to the increasing sea-levels, storm surge, saltwater intrusion, and other threats posed by global climate change is critical to the survival of many of these local communities as well as their cultures (LivingIslands.org). One of the world’s most striking examples of a nation at great risk is the Republic of the Marshall Islands (RMI) in the central Pacific Ocean. Due to a combination of factors, including the country’s extremely low elevation above sea-level (an average of 2 meters) and lack of adequate structures to provide safety …

Management Plan For Western Painted Turtle (Chrysemys Picta Belli) At Fairview Creek Headwaters, Ashley Smithers

Environmental Science and Management Professional Master's Project Reports

Western painted turtles (Chrysemys picta belli) are found occupying Fairview Creek Headwaters (FCH) in Gresham, Oregon. This urban stream contains a large wetland with an adjacent butte, all managed by the City of Gresham. This management plan addresses the preferred habitat and population of turtles at the site. A habitat delineation of the site revealed specific locations where habitat improvements could take place as well as areas of already beneficial habitat. Two site plans were prepared showing areas of the site that could be enhanced with nesting habitat as well as additional aquatic habitat and basking habitat. A habitat study …

Oxyhalogen-Sulfur Chemistry: Kinetics And Mechanism Of Oxidation Of N-Acetylthiourea By Aqueous Bromate And Acidified Bromate, Kudzanai Chipiso, Wilbes Mbiya, Thai Tran, Reuben H. Simoyi

Chemistry Faculty Publications and Presentations

The oxidation of N-acetylthiourea (ACTU) by acidic bromate has been studied by observing formation of bromine in excess bromate conditions. The reaction displays an induction period before formation of bromine. The stoichiometry of the reaction was determined to be 4:3: 4BrO 3 – +3(CH 3 CO)NH(NH 2 )C=S+3H 2 O®4Br – +3(CH 3 CO)NH(NH 2 )C=O+3SO 4 2– +6H + (A) with a complete desulfurization of ACTU to its urea analogue. In excess bromate conditions the stoichiometry was 8:5: 8BrO 3 – + 5(CH 3 CO)NH(NH 2 )C=S + H 2 O ® 4Br 2 + 5(CH 3 CO)NH(NH 2 …

Electrochemistry-Coupled To Mass Spectrometry In Simulation Of Metabolic Oxidation Of Methimazole: Identification And Characterization Of Metabolites, Kudzanai Chipiso, Reuben H. Simoyi

Chemistry Faculty Publications and Presentations

Methimazole (MMI), an antithyroid drug, is associated with idiosyncratic toxicity. Reactive metabolites resulting from bioactivation of the drug have been implicated in these adverse drug reactions. Mimicry of enzymatic oxidation of MMI was carried out by electrochemically oxidizing MMI using a coulometric flow-through cell equipped with a porous graphite working electrode. The cell was coupled on-line to electrospray ionization mass spectrometry (EC/ESI-MS). ESI spectra were acquired in both negative and positive modes. In acidic medium, ESI spectral analysis showed that the dimer was the main product, while in neutral and basic media, methimazole sulfenic acid, methimazole sulfinic acid and methimazole …

The Production And Manipulation Of Nonseparable Spin-Orbit Modes Of Light Under Hong-Ou-Mandel Interference Conditions, Maggie E. Lankford

Senior Independent Study Theses

No abstract provided.

From Fantasy To Virtual Reality: An Exploration Of Modeling, Rigging And Animating Characters For Video Games, Sarah K. Williams

Senior Independent Study Theses

In the last few decades video games have quickly become one of the most popular forms of entertainment around the world. This can be linked to the improvement of computer systems and graphics which now allow for authentic and highly detailed computer generated characters. This project examines how these characters are modeled and developed. The examination of game characters entails a brief history of video games and their aesthetics. The foundations of character design are discussed and 3D modeling of a character is explored in detail. Finally, rigging or skeleton placement is investigated in order to animate the characters designed …

Global And Regional Assessments Of Unsustainable Groundwater Use In Irrigated Agriculture, Danielle S. Grogan

Doctoral Dissertations

Groundwater is an essential input to agriculture world-wide, but it is clear that current rates of groundwater use are unsustainable in the long term. This dissertation assesses both current use of groundwater for country- to global-scale agriculture, and looks at the future of groundwater. The focus is on 1) quantifying food directly produced as a result of groundwater use across spatially-varying agricultural systems, 2) projecting future groundwater demands with consideration of climate change and human decision-making, and 3) understanding the system dynamics of groundwater re-use through surface water systems. All three are addressed using a process-based model designed to simulate …