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2018

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Articles 2971 - 3000 of 13646

Full-Text Articles in Physical Sciences and Mathematics

Parametric Study Of The Rossby Wave Instability In A Two-Dimensional Barotropic Disk. Ii. Nonlinear Calculations, Tomohiro Ono, Takayuki Muto, Kengo Tomida, Zhaohuan Zhu Aug 2018

Parametric Study Of The Rossby Wave Instability In A Two-Dimensional Barotropic Disk. Ii. Nonlinear Calculations, Tomohiro Ono, Takayuki Muto, Kengo Tomida, Zhaohuan Zhu

Physics & Astronomy Faculty Research

Vortices in protoplanetary disks have attracted attention since the discovery of lopsided structures. One of the possible mechanisms for producing vortices is the Rossby wave instability (RWI). In our previous work, we have performed detailed linear stability analyses of the RWI with various initial conditions. In this paper, we perform numerical simulations of the vortex formation by the RWI in two-dimensional barotropic disks using the Athena++ code. As initial conditions, we consider axisymmetric disks with a Gaussian surface density bump of various contrasts and half-widths. Perturbations grow as expected from the linear stability analyses in the linear and weakly nonlinear …

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Simultaneous Rayleigh-Scatter And Sodium Resonance Lidar Temperature Comparisons In The Mesosphere-Lower Thermosphere, Leda Sox, Vincent B. Wickwar, Tao Yuan, Neal R. Criddle Aug 2018

Simultaneous Rayleigh-Scatter And Sodium Resonance Lidar Temperature Comparisons In The Mesosphere-Lower Thermosphere, Leda Sox, Vincent B. Wickwar, Tao Yuan, Neal R. Criddle

All Physics Faculty Publications

The Utah State University (USU) campus (41.7°N, 111.8°W) hosts a unique upper atmospheric observatory that houses both a high-power, large-aperture Rayleigh lidar and a Na lidar. For the first time, we will present 19 nights of coordinated temperature measurements from the two lidars, overlapping in the 80–110 km observational range, over one annual cycle (summer 2014 to summer 2015). This overlap has been achieved through upgrades to the existing USU Rayleigh lidar that increased its observational altitude from 45–95 to 70–115 km and by relocating the Colorado State Na lidar to the USU campus. Previous climatological comparisons between Rayleigh and …

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Using Strong Laser Fields To Produce Antihydrogen Ions, Christopher Michael Keating Aug 2018

Using Strong Laser Fields To Produce Antihydrogen Ions, Christopher Michael Keating

Dissertations and Theses

We provide estimates of both cross section and rate for the stimulated attachment of a second positron into the (1s2 1Se) state of the H+ ion using Ohmura and Ohmura's (1960 Phys. Rev. 118 154) effective range theory, Reiss's strong field approximation (1980 Phys. Rev. A 22, 1786), and the principle of detailed balancing. Our motivation for producing H+ ion include its potential to be used as an intermediate state in bringing antihydrogen to ultra-cold (sub-mK) temperatures required for a variety of studies, which include both spectroscopy and the probing of the gravitational interaction of …

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Understanding The Death Of Massive Stars Using An Astrophysical Transients Observatory, Peter W. Roming, Eddie Baron, Amanda J. Bayless, Volker Bromm, Peter J. Brown, Michael W. Davis, Anastasia Fialkov, Brian Fleming, Kevin France, Chris L. Fryer, Thomas K. Greathouse, Jed J. Hancock, D. Andrew Howell, Andrew J. Levan, Abraham Loeb, Raffaella Margutti, Mark L. Mcconnell, Paul T. O'Brien, Julian P. Osborne, Daniel A. Perley, Eric M. Schlegel, Rhaana L. C. Starling, Nial R. Tanvir, Mark Tapley, Patrick A. Young, Bing Zhang Aug 2018

Understanding The Death Of Massive Stars Using An Astrophysical Transients Observatory, Peter W. Roming, Eddie Baron, Amanda J. Bayless, Volker Bromm, Peter J. Brown, Michael W. Davis, Anastasia Fialkov, Brian Fleming, Kevin France, Chris L. Fryer, Thomas K. Greathouse, Jed J. Hancock, D. Andrew Howell, Andrew J. Levan, Abraham Loeb, Raffaella Margutti, Mark L. Mcconnell, Paul T. O'Brien, Julian P. Osborne, Daniel A. Perley, Eric M. Schlegel, Rhaana L. C. Starling, Nial R. Tanvir, Mark Tapley, Patrick A. Young, Bing Zhang

Physics & Astronomy Faculty Research

The death of massive stars, manifested as gamma-ray bursts and core-collapse supernovae, critically influence how the universe formed and evolves. Despite their fundamental importance, our understanding of these enigmatic objects is severely limited. We have performed a concept study of an Astrophysical Transient Observatory (ATO) that will rapidly facilitate an expansion of our understanding of these objects. ATO combines a very wide-field X-ray telescope, a near-infrared telescope, a multi-mode ultraviolet instrument, and a rapidly slewing spacecraft to realize two primary goals: (1) characterize the highest-redshift massive stars and their environments, and (2) constrain the poorly understood explosion mechanism of massive …

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Concentration Of Atmospheric Ammonia From Kenyon College Monitoring Station, Vivian Ezeh, David Heithaus, Simon Garcia, Matthew F. Rouhier Aug 2018

Concentration Of Atmospheric Ammonia From Kenyon College Monitoring Station, Vivian Ezeh, David Heithaus, Simon Garcia, Matthew F. Rouhier

Simon Garcia

Kenyon College is hosting an ammonia (NH3) monitoring station as part of the National Atmospheric Deposition Program (NADP). The Kenyon College (OH32) site is one of six locations around the state of Ohio.

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Investigation Of Chaos In Biological Systems, Navaneeth Mohan Aug 2018

Investigation Of Chaos In Biological Systems, Navaneeth Mohan

Electronic Thesis and Dissertation Repository

Chaos is the seemingly irregular behavior arising from a deterministic system. Chaos is observed in many real-world systems. Edward Lorenz’s seminal discovery of chaotic behavior in a weather model has prompted researchers to develop tools that distinguish chaos from non-chaotic behavior. In the first chapter of this thesis, I survey the tools for detecting chaos namely, Poincaré maps, Lyapunov exponents, surrogate data analysis, recurrence plots and correlation integral plots. In chapter two, I investigate blood pressure fluctuations for chaotic signatures. Though my analysis reveals interesting evidence in support of chaos, the utility such an analysis lies in a different direction …

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Occupancy And Habitat Use By Six Species Of Forest Ungulates On Tiwai Island, Sierra Leone, Kathryn R. Mccollum, Emily Belinfante, April L. Conway, John P. Carroll Aug 2018

Occupancy And Habitat Use By Six Species Of Forest Ungulates On Tiwai Island, Sierra Leone, Kathryn R. Mccollum, Emily Belinfante, April L. Conway, John P. Carroll

School of Natural Resources: Faculty Publications

Forest ungulates in West Africa are common bushmeat species and are subject to habitat degradation through deforestation. Based on historical data, there are possibly 12 species of forest Bovidae and Tragulidae found in eastern Sierra Leone. We used camera trapping to assess occupancy by forest ungulates on and around a small protected area, Tiwai Island, Sierra Leone. We then assessed habitat over two field seasons during 2008–2011 for those species where we had sufficient numbers of detections. We detected 6 of 12 potential species and obtained enough data to further assess the habitat of two species. Species detected included the …

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The Influence Of Conversational Agent Embodiment And Conversational Relevance On Socially Desirable Responding, Ryan M. Schuetzler, Justin Scott Giboney, G. Mark Grimes, Jay F. Nunamaker Jr. Aug 2018

The Influence Of Conversational Agent Embodiment And Conversational Relevance On Socially Desirable Responding, Ryan M. Schuetzler, Justin Scott Giboney, G. Mark Grimes, Jay F. Nunamaker Jr.

Information Systems and Quantitative Analysis Faculty Publications

Conversational agents (CAs) are becoming an increasingly common component in a wide range of information systems. A great deal of research to date has focused on enhancing traits that make CAs more humanlike. However, few studies have examined the influence such traits have on information disclosure. This research builds on self-disclosure, social desirability, and social presence theories to explain how CA anthropomorphism affects disclosure of personally sensitive information. Taken together, these theories suggest that as CAs become more humanlike, the social desirability of user responses will increase. In this study, we use a laboratory experiment to examine the influence of …

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An Investigation Into The Adduct Forming Potential Of Drugs Of Abuse With Peptides And Proteins, Richard Allen Gilliland Aug 2018

An Investigation Into The Adduct Forming Potential Of Drugs Of Abuse With Peptides And Proteins, Richard Allen Gilliland

FIU Electronic Theses and Dissertations

Hemoglobin and serum albumin, two prevalent proteins in human blood, contain unbound cysteine thiol moieties, creating a nucleophilic site with the potential for covalent modification by reactive chemical species. These covalent modifications, called “adducts”, are stable entities that accumulate during acute and chronic exposure and remain covalently bound for the life-span of the protein. Despite their current use as exposure markers for a variety of compounds, the use of adducts in assessing exposure to drugs of abuse has not yet been explored. The goal of this work was to examine the in vitro adduct forming capability of selected drugs of …

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A New Lower Actinopterygian Fish From The Upper Mississippian Bluefield Formation Of West Virginia, Usa, Kathryn Mickle Aug 2018

A New Lower Actinopterygian Fish From The Upper Mississippian Bluefield Formation Of West Virginia, Usa, Kathryn Mickle

College of Life Sciences Faculty Papers

The Upper Mississippian Bluefield Formation of the Mauch Chunk Group in southeastern West Virginia is known for its preservation of a variety of invertebrate taxa and early tetrapod trackways, but no lower actinopterygian remains have been formally described from these Carboniferous rocks. Here, the first lower actinopterygian fish is described from the Bluefield Formation of West Virginia. This fish is represented by a nearly complete articulated specimen with a three-dimensional snout and an unobstructed view of the gular and branchiostegal region. This new taxon is defined by a unique set of characters, which include features of the snout, circumorbital series, …

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Techniques For Improved Space Object Detection Performance From Ground-Based Telescope Systems Using Long And Short Exposure Images, David J. Becker Aug 2018

Techniques For Improved Space Object Detection Performance From Ground-Based Telescope Systems Using Long And Short Exposure Images, David J. Becker

Theses and Dissertations

Space object detection is of great importance in the highly dependent yet competitive and congested space domain. Detection algorithms employed play a crucial role in fulfilling the detection component in the space situational awareness mission to detect, track, characterize and catalog unknown space objects. Many current space detection algorithms use a matched filter or a spatial correlator on long exposure data to make a detection decision at a single pixel point of a spatial image based on the assumption that the data follows a Gaussian distribution. This research focuses on improving current space object detection algorithms and developing new algorithms …

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The Importance Of Solvent Effects On The Mechanism Of The Pfeiffer Effect, Jamie Lunkley, Ngoc Nguyen, Kristina Tuminaro, Dana Margittai, Gilles Muller Aug 2018

The Importance Of Solvent Effects On The Mechanism Of The Pfeiffer Effect, Jamie Lunkley, Ngoc Nguyen, Kristina Tuminaro, Dana Margittai, Gilles Muller

Faculty Publications, Chemistry

The Pfeiffer effect is observed when an optically active compound such as an amino acid is introduced to a solution containing a labile racemic metal complex, and an equilibrium shift is obtained. The “perturbation” results in an excess of one enantiomer over the other. The shift is a result of a preferential outer sphere interaction between the introduced chiral species and one enantiomeric form (Λ or ∆) of a labile metal complex. Speculations regarding the mechanism of the Pfeiffer effect have attributed observations to a singular factor such as pH, solvent polarity, or numerous other intermolecular interactions. Through the use …

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Ultralow Frequency Electrodynamics Of Magnetosphere-Ionosphere Interactions Near The Plasmapause During Substorms, Anatoly V. Streltsov, Evgeny V. Mishin Aug 2018

Ultralow Frequency Electrodynamics Of Magnetosphere-Ionosphere Interactions Near The Plasmapause During Substorms, Anatoly V. Streltsov, Evgeny V. Mishin

Publications

Ultra low frequency (ULF) electromagnetic waves have been regularly observed by the CRRES, Cluster, and Van Allen Probes satellites near the plasmapause during substorms. Frequently, the small-scale waves are detected together with a large-scale quasi-stationary electric field collocating with mesoscale plasma flows penetrating into the plasmasphere. These observations suggest that the plasmapause plays an important role in the conversion of the kinetic energy of energetic particles moving toward the Earth from the reconnection site in the magnetotail into a large-scale electric field. The field penetrates along the magnetic field into the ionosphere and generates small-scale, shear Alfvén waves and field-aligned …

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Synchrotron Radiation From Electrons With A Pitch-Angle Distribution, Yuan-Pei Yang, Bing Zhang Aug 2018

Synchrotron Radiation From Electrons With A Pitch-Angle Distribution, Yuan-Pei Yang, Bing Zhang

Physics & Astronomy Faculty Research

In most astrophysical processes involving synchrotron radiation, the pitch-angle distribution of the electrons is assumed to be isotropic. However, if electrons are accelerated anisotropically, e.g., in a relativistic shock wave with an ordered magnetic field or in magnetic reconnection regions, the electron pitch angles might be anisotropic. In this Letter, we study synchrotron radiation from electrons with a pitch-angle distribution with respect to a large-scale uniform magnetic field. Assuming that the pitch-angle distribution is normal with a scatter of σ p and that the viewing direction is where the pitch-angle direction peaks, we find that for electrons with a Lorentz …

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Stylolites Cathodoluminescence Under Cross Polarized Light, Katherine Dvorak Aug 2018

Stylolites Cathodoluminescence Under Cross Polarized Light, Katherine Dvorak

The Hilltop Review

Devil's Gate limestone under cathodoluminescence. Bright yellow and orange areas are calcite and the bright blue indicates trace minerals along the solution seam. Trace minerals left in the seam are heavy metals and other silicate minerals.

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Totality In Carbondale, Grant Haynes Aug 2018

Totality In Carbondale, Grant Haynes

The Hilltop Review

August 21 was one of the high points of 2017. That day a total solar eclipse tracked over much of the continental U.S. An early morning train ride brought me to Carbondale Illinois, the location of the eclipses longest duration. As totality neared clouds obscured this amazing celestial wonder, but they soon parted, and I was able to get a few spectacular photos of the eclipse, this one with the clouds that almost ruined it, is my favorite.

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Predicting Impacts Of Chemicals From Organisms To Ecosystem Service Delivery: A Case Study Of Endocrine Disruptor Effects On Trout, Valery E. Forbes, Steve Railsback, Chiara Accolla, Bjorn Birnir, Randall J.F. Bruins, Virginie Ducrot, Nika Galic, Kristina Garber, Bret C. Harvey, Henriette I. Jager, Andrew Kanarek, Robert Pastorok, Richard Rebarber, Pernille Thorbek, Chris J. Salice Aug 2018

Predicting Impacts Of Chemicals From Organisms To Ecosystem Service Delivery: A Case Study Of Endocrine Disruptor Effects On Trout, Valery E. Forbes, Steve Railsback, Chiara Accolla, Bjorn Birnir, Randall J.F. Bruins, Virginie Ducrot, Nika Galic, Kristina Garber, Bret C. Harvey, Henriette I. Jager, Andrew Kanarek, Robert Pastorok, Richard Rebarber, Pernille Thorbek, Chris J. Salice

Department of Mathematics: Faculty Publications

We demonstrate how mechanistic modeling can be used to predict whether and how biological responses to chemicals at (sub)organismal levels in model species (i.e., what we typically measure) translate into impacts on ecosystem service delivery (i.e., what we care about). We consider a hypothetical case study of two species of trout, brown trout (Salmo trutta; BT) and greenback cutthroat trout (Oncorhynchus clarkii stomias; GCT). These hypothetical populations live in a high-altitude river system and are exposed to human-derived estrogen (17α‑ethinyl estradiol, EE2), which is the bioactive estrogen in many contraceptives. We use the individual based model in STREAM …

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First Observed Temporal Development Of A Noctilucent Cloud Ice Void, Linda Megner, Jacek Stegman, Pierre-Dominique Pautet, Michael J. Taylor Aug 2018

First Observed Temporal Development Of A Noctilucent Cloud Ice Void, Linda Megner, Jacek Stegman, Pierre-Dominique Pautet, Michael J. Taylor

All Physics Faculty Publications

Noctilucent clouds are ice clouds that appear high in the atmosphere, about 80 km above the summer pole. By observing them we have learned a lot about the remote and inaccessible region where they form. Recently, a satellite borne instrument discovered nearly circular ice-free regions within the clouds, denoted as “ice voids.” The origin of these voids is a mystery—we do not know what causes the clouds to disappear in large circular areas. So far these voids have only been observed from satellites, which only can take pictures of the clouds when they pass above once every 1.5 hr—longer than …

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Compressive Direct Imaging Of A Billion-Dimensional Optical Phase Space, Samuel H. Knarr, Daniel J. Lum, James Schneeloch, John C. Howell Aug 2018

Compressive Direct Imaging Of A Billion-Dimensional Optical Phase Space, Samuel H. Knarr, Daniel J. Lum, James Schneeloch, John C. Howell

Mathematics, Physics, and Computer Science Faculty Articles and Research

Optical phase spaces represent fields of any spatial coherence and are typically measured through phase-retrieval methods involving a computational inversion, optical interference, or a resolution-limiting lenslet array. Recently, a weak-values technique demonstrated that a beam's Dirac phase space is proportional to the measurable complex weak value, regardless of coherence. These direct measurements require raster scanning through all position-polarization couplings, limiting their dimensionality to less than 100 000 [C. Bamber and J. S. Lundeen, Phys. Rev. Lett. 112, 070405 (2014)]. We circumvent these limitations using compressive sensing, a numerical protocol that allows us to undersample, yet efficiently measure, high-dimensional phase spaces. …

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Auxetics Abounding, Ciprian S. Borcea, Ileana Streinu Aug 2018

Auxetics Abounding, Ciprian S. Borcea, Ileana Streinu

Computer Science: Faculty Publications

Auxetic behavior refers to lateral widening upon stretching. Although a structural origin for this rather counterintuitive type of deformation was often suggested, a theoretical understanding of the role of geometry in auxetic behavior has been a challenge for a long time. However, for structures modeled as periodic bar-and-joint frameworks, including atom-and-bond frameworks in crystalline materials, there is a complete geometric solution which opens endless possibilities for new auxetic designs. We construct a large family of three-dimensional auxetic periodic mechanisms and discuss the ideas involved in their design.

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High-Dimensional Isotope Relationships, Yuyang He Aug 2018

High-Dimensional Isotope Relationships, Yuyang He

LSU Doctoral Dissertations

High-dimensional isotope relationships describes the relationships of two or more element or position-specific (PS) elements in the same molecule or ion. It provides us more powerful tools to study reaction mechanisms and dynamics. Chapter 1 is about dual or multiple stable isotope relationship on δ-δ (or δ'-δ') space. While temporal data sampled from a closed-system can be treated by a Rayleigh Distillation Model (RDM), spatial data should be treated by a Reaction-Transport Model (RTM). Here we compare the results of a closed-system RDM to a RTM for systems with diffusional mass transfer by simulating the trajectories on nitrate's δ'18 …

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Acetylcholinesterase Biosensor Platform Based On Bp2000 For The Detection Of Carbaryl, Ming-Han Zhang, Jun-Qiao Jiang, Jun-Jie Ge, Wei Xing Aug 2018

Acetylcholinesterase Biosensor Platform Based On Bp2000 For The Detection Of Carbaryl, Ming-Han Zhang, Jun-Qiao Jiang, Jun-Jie Ge, Wei Xing

Journal of Electrochemistry

With the purpose of providing a new method for carbaryl (a pesticide) detection, on the basis of the principle that acetylcholinesterase (AChE) activity can be restrained by carbaryl, an AChE biosensor platform based on BP2000 (as a fixation) was constructed by dropping method. As a result, it revealed that AChE immobilized on BP2000 maintained its catalytic activity for acetylcholine (ATCl), and due to the introduction of the BP2000 material, the effective electrochemical surface area of the modified electrode was enlarged. In addition, the electrochemical oxidation at the modified electrode occurred at low potential (0.630 V) accompanied by proton transmission. The …

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Complex Coordination Silver Electrocrystallization Mechanism On Glassy Carbon Electrode Surface, Shuai-Shuai Huang, Cheng Liu, Lei Jin, Fang-Zu Yang, Zhong-Qun Tian, Shao-Min. Zhou Aug 2018

Complex Coordination Silver Electrocrystallization Mechanism On Glassy Carbon Electrode Surface, Shuai-Shuai Huang, Cheng Liu, Lei Jin, Fang-Zu Yang, Zhong-Qun Tian, Shao-Min. Zhou

Journal of Electrochemistry

Cyclic voltammetry and potential step methods were successfully used to study the electrochemical crystallization mechanism of silver deposition on glassy carbon electrode (GCE) in the practical cyanide-free silver plating electrolyte containing composite complexing agents. Scharifker-Hill (SH) theory was used to fitting the experimental data. The results showed that the electrodeposition of silver is a diffusion controlled irreversible electrode process according to three-dimensional instantaneous nucleation mechanism. When the step potential shifted from -750 mV to -825 mV, the peak deposition current Im was increased, while the induced nucleation time tm shortened. The calculated kinetic parameters showed that the diffusion coefficient (D) …

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Electrochemical Performances Of Neodymium Doped Lead Dioxide Composite Anode, Hong-Hui Wang, Ming-Jie Ma, Jie Feng, Huang-Ya Kang, Wen-Jie Huang Aug 2018

Electrochemical Performances Of Neodymium Doped Lead Dioxide Composite Anode, Hong-Hui Wang, Ming-Jie Ma, Jie Feng, Huang-Ya Kang, Wen-Jie Huang

Journal of Electrochemistry

Neodymium (Nd) doped titanium (Ti)-based lead dioxide (PbO2) composite anode was prepared by electrodeposition. The surface morphologies and crystal structures of the as-prepared anodes were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) technique, respectively. The electrochemical performances of PbO2-Nd anode were studied by electrochemical impedance spectroscopy, linear sweep voltammetry and cyclic voltammetry. Additionally, the electrocatalytic activity and durability of PbO2-Nd anode were investigated through the degradation of simulative refractory organic wastewater of phenol. The results showed that Nd doping made the PbO2 anode surface structure dense and uniform with smaller …

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Assemblies And Properties Of Asymmetric Supercapacitors Based On Wo3/Carbon Cloth, Wen-Ke Shao, Lei Zhao, Chao Liu, Yan-Ying Dong, Yuan-Jie Zhu, Qiu-Fan Wang Aug 2018

Assemblies And Properties Of Asymmetric Supercapacitors Based On Wo3/Carbon Cloth, Wen-Ke Shao, Lei Zhao, Chao Liu, Yan-Ying Dong, Yuan-Jie Zhu, Qiu-Fan Wang

Journal of Electrochemistry

The demand for a new generation of flexible, portable, and high-capacity power sources increases rapidly with the development of advanced wearable electronic devices. One dimensional (1D) nanowires structures have been demonstrated as one of the most ideal electrode materials in energy storage systems due to their advantages in both micorstructures and their high surface areas. Here we report a simple process for large-scale fabrication of self-standing composite film electrodes composed of WO3 nanorods on carbon cloth. In order to improve the energy density of supercapacitor, we assembled an asymmetric supercapacitor using WO3 nanorods and activated carbon cloth as …

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Brief Account On The Editorial Board Conference Of Journal Of Electrochemistry Aug 2018

Brief Account On The Editorial Board Conference Of Journal Of Electrochemistry

Journal of Electrochemistry

No abstract provided.

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Modifications And Electrochemical Properties Of Graphite Fluoride, Liang Zhang, Hong-Mei Zhang, Wei-Hua Wan, Jun-Hua Wei Aug 2018

Modifications And Electrochemical Properties Of Graphite Fluoride, Liang Zhang, Hong-Mei Zhang, Wei-Hua Wan, Jun-Hua Wei

Journal of Electrochemistry

The commercial fluorinated graphite (CFx) was used as the raw material, which was modified by the reduction of hydrazine hydrate (N2H4·H2O). The effects of hydrazine hydrate contents on the electrochemical properties of fluorinated graphite were systematically studied. The crystal phases and electrochemical properties of the modified fluorinated graphite were analyzed by XRD, SEM, EDS, XPS, EIS techniques and constant current discharge measurement. The results showed that the voltage hysteresis response of Lithium-fluorocarbon battery prepared by the modified fluorinated graphite was obviously improved, while the amount of hydrazine hydrate had an important influence …

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Preparations Of Nano-Manganite Loaded Titanium Electocatalytic Membrane Electrode For Phenolic Wastewater Treatment, Le Li, Hong Wang, Rong-Hua Ma, Hong-Sen Hui, Xiao-Ping Liang, Jian-Xin Li Aug 2018

Preparations Of Nano-Manganite Loaded Titanium Electocatalytic Membrane Electrode For Phenolic Wastewater Treatment, Le Li, Hong Wang, Rong-Hua Ma, Hong-Sen Hui, Xiao-Ping Liang, Jian-Xin Li

Journal of Electrochemistry

Nano-manganese oxide loaded on titanium electrocatalytic membrane electrodes (nano-MnOx/Ti) were synthesized bysol-gel method using porous Ti membrane as a substrate and the manganese acetate as a raw material without releasing NOx. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Field-emission scanning electron microscopy (FESEM) were employed to characterize crystal form, valence state and surface morphology of nano-MnOx, respectively. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and chronoamperometry (CA) were used to investigate the electrochemical properties of nano-MnOx electrode. The results indicated that the MnOx catalysts consisted of γ-MnO2 and Mn2 …

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An Aqueous All-Metal Oxide Asymmetric Supercapacitor With High Gravimetric And Volumetric Energy Densities, Jing Xin, Xu Zhang, Wang Wei, Lang Jun-Wei Aug 2018

An Aqueous All-Metal Oxide Asymmetric Supercapacitor With High Gravimetric And Volumetric Energy Densities, Jing Xin, Xu Zhang, Wang Wei, Lang Jun-Wei

Journal of Electrochemistry

Only with both high gravimetric and high volumetric energy densities, can supercapacitors find more extensive applications.In this paper, by making good use of the interesting nanostructures and the high packing densities of RuO2 (nanoshpheres,1.69 g·cm-3) and Co-Ni oxide (nanoflakes, 2.14 g·cm-3), the RuO2//KOH//Co-Ni oxide all-metal oxide asymmetric supercapacitors with high performance were successfully fabricated, which led to the maximum specific capacitance of 217.5 F·g-1 (412.3 F·cm-3) and specific energy density of 61.8 Wh·kg-1 (121 Wh·L-1) in a cell voltage between 0 and 1.5 V in KOH electrolyte. …

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Electrochemical Preparation And Photo-Electro Catalytic Properties Of Flexible Znni/Al-Ldhs/Carbon Fibers Composite, Jing-Jing Tian, Tao Chen, Xing-Chen Bao, Meng-Xu Gao, Ye-Xiao Yu, Si-Yao Peng, Guan-Ping Jin Aug 2018

Electrochemical Preparation And Photo-Electro Catalytic Properties Of Flexible Znni/Al-Ldhs/Carbon Fibers Composite, Jing-Jing Tian, Tao Chen, Xing-Chen Bao, Meng-Xu Gao, Ye-Xiao Yu, Si-Yao Peng, Guan-Ping Jin

Journal of Electrochemistry

In this work, a promising flexible composite consisting of zinc (Zn), nickel (Ni) and aluminum (Al) layered double hydroxide coated carbon fibers (ZnNi/Al-LDHs/CFs) was prepared by electrochemical method with convenient recovery and separation. The structures, morphologies, and photo-electro catalytic properties of ZnNi/Al-LDHs/CFs were characterized by X-ray diffraction, infrared spectroscopy, field emission scanning electron microscopy, inductively coupled plasma atomic emission spectrometry and electrochemical impedance spectroscopy techniques. The excellent photo-electro bifunctional catalytic properties were obtained with the ZnNi/Al-LDHs/CFs composite as compared to that of Zn/Al-LDHs/CFs (photo catalyst) or Ni/Al-LDHs/CFs (electrocatalyst) alone, which could be used in the electro-catalytic oxidations of methanol and …

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