Physical Sciences and Mathematics Commons^™

A Privacy Framework For Decentralized Applications Using Blockchains And Zero Knowledge Proofs, David Gabay

FIU Electronic Theses and Dissertations

With the increasing interest in connected vehicles along with electrification opportunities, there is an ongoing effort to automate the charging process of electric vehicles (EVs) through their capabilities to communicate with the infrastructure and each other. However, charging EVs takes time and thus in-advance scheduling is needed. As this process is done frequently due to limited mileage of EVs, it may expose the locations and charging pattern of the EV to the service providers, raising privacy concerns for their users. Nevertheless, the EV still needs to be authenticated to charging providers, which means some information will need to be provided …

Evaluating The Impact Of Proactive Care Management With Idstrat, D.J. Donahue, Lauren Staples

Published and Grey Literature from PhD Candidates

This purpose of this study is to quantify potential cost savings and member care improvements as a result of engagement through BlueCross BlueShield of Tennessee’s (BCBST) Identification and Stratification (IDStrat) process. Commercial members engaged in clinical management that were identified through IDStrat were compared to commercial members identified through other means across several metrics including per-member, per-month (PMPM) cost and physician visits. Members identified by IDStrat experienced a statistically significant 7% greater reduction in costs after being engaged when compared with those identified by other methods. Members identified by IDStrat also experienced a significant reduction in emergency room visits after …

Fate Of The Organophosphate Insecticide, Chlorpyrifos, In Leaves, Soil, And Air Following Application, Supta Das, Kimberly J. Hageman, Madeleine Taylor, Sue Michelsen-Heath, Ian Stewart

Chemistry and Biochemistry Faculty Publications

A field study was conducted to further our understanding about the fate and transport of the organophosphate insecticide, chlorpyrifos, and its degradation product, chlorpyrifos oxon. Leaf, soil and air sampling was conducted for 21 days after chlorpyrifos application to a field of purple tansy (Phacelia tanacetifolia). Air samples were collected using a high-volume air sampler (HVAS) and seven battery-operated medium-volume active air samplers placed around the field and on a 500-m transect extending away from the field. Chlorpyrifos was detected every day of the sampling period in all matrices, with concentrations decreasing rapidly after application. Chlorpyrifos oxon was …

Authentication Usability Methodology, Jean-Baptiste Subils

USF Tampa Graduate Theses and Dissertations

Nowadays many systems require end users to authenticate themselves. Authentication is one of the security activities that end users perform the most. Thus, the usability of this security feature plays a major role in the proper utilization and adoption of a novel authentication method.

This dissertation presents coauthentication, a novel authentication system. Many authentication methods and protocols exist, but passwords remain the predominant authentication method used. Coauthentication is presented here in detail in several possible variations and their associated protocols, with performance comparisons.

This dissertation also presents a framework to evaluate authentication methods in terms of usability.

A large body …

A Gpu-Based Framework For Parallel Spatial Indexing And Query Processing, Zhila Nouri Lewis

USF Tampa Graduate Theses and Dissertations

Support for efficient spatial data storage and retrieval have become a vital component in almost all spatial database systems. Previous work has shown the importance of using spatial indexing and parallel computing to speed up such tasks. While GPUs have become a mainstream platform for high-throughput data processing in recent years, exploiting the massively parallel processing power of GPUs is non-trivial. Current approaches that parallelize one query at a time have low work efficiency and cannot make good use of GPU resources. On the other hand, many spatial database applications are busy systems in which a large number of queries …

Molecular Properties Are A Primary Control On The Microbial Utilization Of Dissolved Organic Matter In The Ocean, Yuan Shen, Ronald Benner

Faculty Publications

The global ocean sequesters a large amount of reduced carbon in dissolved organic molecules that can persist for centuries to millennia. The persistence of dissolved organic carbon (DOC) in the deep ocean has been attributed to inherently refractory molecules and to low concentrations of molecules, but the relative roles of molecular properties and molecular concentrations remain uncertain. We investigate both of these possibilities using bioassay experiments with unfiltered seawater collected from five depths (50–1500 m) at the Bermuda Atlantic Time-Series Study site. The microbial utilization of compositionally distinct forms of seawater DOC at in situ and elevated concentrations was determined. …

Biochar Enhances Nitrous Oxide Reduction In Acidic But Not In Near-Neutral Ph Soil, Engil Isadora Pujol Pereira, Jerome Lechot, Rafaela Feola Conz, Abmael Da Silva Cardoso, Johan Six

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

We quantified nitrous oxide (N2O) fluxes and total denitrification (N2O + N2) in an acidic (Ferralsol) and a near-neutral pH soil (Cambisol) to determine whether biochar’s alkalinization effect could be the mechanism inducing potential reductions in N2O fluxes. In Ferralsol, decreases in N2O emissions and in the N2O to N2O + N2 ratio were observed in both biochar and lime treatments. In Cambisol, neither biochar nor lime decreased N2O emissions, despite significantly increasing soil pH. The abundance and community structure of nosZ gene-bearing microorganisms indicated that gene abundances did not explain biochar effects, but a higher diversity of nosZ gene-bearing …

From The Human To The Planetary: Speculative Futures Of Care, Miriam Ticktin

Publications and Research

This is largely a theoretical, speculative essay that takes on the question of what ‘care’ looks like at a moment when climate change is increasingly taking center stage in public and political discussions. Starting with two new practices, namely, humanitarian care for nonhumans and One Health collaborations, I seek to determine what forms of political care can incorporate the well-being of future generations and future iterations of the earth. After an exploration of One Health as an approach to planetary care, I ask what its parts enable us to think, despite its limitations; I focus on the new human-nonhuman assemblages …

Investing In The New Blue Economy: The Changing Role Of International Development Organizations In Catalyzing Private Sector Investment In Support Of Regional Strategic Action Programmes For The Sustainable Development Of Coasts And Oceans, Ryan Whisnant, Veerle Vandeweerd

Journal of Ocean and Coastal Economics

Over the last 20 years, governments sharing common coastal and ocean ecosystems have developed and agreed on concrete regional action programs to stop and, in some cases, reverse a trend of deteriorating coastal and ocean resources. Implementation of these action programs requires significant investments by the public and private sectors alike, with the potential for substantial economic growth and enhanced social well-being. For this to happen, new institutional arrangements, technologies, and financial vehicles and asset classes are needed to mainstream innovative “blue economy” projects that have the potential to transition economies and communities to more sustainable development paths.

This paper …

Court Record In The Age Of Artificial Intelligence, Fredric I. Lederer

Popular Media

No abstract provided.

Inferring A Consensus Problem List Using Penalized Multistage Models For Ordered Data, Philip S. Boonstra, John C. Krauss

The University of Michigan Department of Biostatistics Working Paper Series

A patient's medical problem list describes his or her current health status and aids in the coordination and transfer of care between providers, among other things. Because a problem list is generated once and then subsequently modified or updated, what is not usually observable is the provider-effect. That is, to what extent does a patient's problem in the electronic medical record actually reflect a consensus communication of that patient's current health status? To that end, we report on and analyze a unique interview-based design in which multiple medical providers independently generate problem lists for each of three patient case abstracts …

A Three-Dimensional Rna Motif Mediates Directional Trafficking Of Potato Spindle Tuber Viroid From Epidermal To Palisade Mesophyll Cells In Nicotiana Benthamiana, Jian Wu, Neocles B. Leontis, Craig L. Zirbel, David M. Bisaro, Biao Ding

Mathematics and Statistics Faculty Publications

Potato spindle tuber viroid (PSTVd) is a circular non-coding RNA of 359 nucleotides that replicates and spreads systemically in host plants, thus all functions required to establish an infection are mediated by sequence and structural elements in the genome. The PSTVd secondary structure contains 26 Watson-Crick base-paired stems and 27 loops. Most of the loops are believed to form three-dimensional (3D) structural motifs through non-Watson-Crick base pairing, base stacking, and other local interactions. Homology-based prediction using the JAR3D online program revealed that loop 27 (nucleotides 177-182) most likely forms a 3D structure similar to the loop of a conserved hairpin …

Quartz Crystal Microbalance Based Sensors For Detection And Discrimination Of Volatile Organic Compounds Using Ionic Materials, Stephanie R. Vaughan

LSU Doctoral Dissertations

Volatile organic compounds (VOCs) are prevalent in everyday life, ranging from household chemicals, naturally occurring scents from common plants and animals, to industrial-scale chemicals. Many of these VOCs are known to cause adverse health and environmental effects and require regulation to prevent pollution. Detecting VOCs plays a critical role in food quality control, environmental quality control, medical diagnostics, and explosives detection. Thus, development of adequate sensing devices for detection and discrimination of VOCs is of great importance. In recent years, use of quartz crystal microbalance (QCM) based sensor arrays for analyses of VOCs has attracted significant interest. Detection of VOCs …

Lorentz- And C P T -Violating Standard Model Extension In Chiral Perturbation Theory, Brett Altschul, Matthias R. Schindler

Faculty Publications

Lorentz and CPT violation in hadronic physics must be tied to symmetry violations at the underlying quark and gluon level. Chiral perturbation theory provides a method for translating novel operators that may appear in the Lagrange density for color-charged parton fields into equivalent forms for effective theories at the meson and baryon levels. We extend the application of this technique to the study of Lorentzviolating and potentially CPT-violating operators from the minimal standard model extension. For dimension-4 operators, there are nontrivial relations between the coefficients of baryon-level operators related to underlying quark and gluon operators with the same Lorentz structures. …

Thioenamide Synthesis Inspired By Peptide Macrocycles, Joshua Allen Lutz

LSU Doctoral Dissertations

Despite advances in medicine, antibiotic resistance threatens to return once preventable diseases to the human population. The microbisporicins are 24-amino acid antibiotic peptides belonging to the lantibiotic class, which pathogens have been slow to develop resistance. The uncommon post-translational modification S-[(Z)-2-aminovinyl]-D-cysteine (AviCys) is likely crucial to their activity, and appears in a small number of other peptides with compelling biological activities. Total synthesis of an AviCys-containing peptide has eluded the chemical community.

The primary challenge of AviCys synthesis is the construction of a thioenamide functional group. We demonstrate that acid-promoted reactions between an amide and …

Hasasia: A Python Package For Pulsar Timing Array Sensitivity Curves, J. S. Hazboun, J. D. Romano, Tristan L. Smith

Physics & Astronomy Faculty Works

No abstract provided.

Development Of A Tunable Platform For The Study Of Geomacromolecular Matrices Using Controlled Radical Polymerization, Arjun Pandey

LSU Doctoral Dissertations

Soil is an important environmental component, and the study of soil processes have many practical implications such as improvement in agriculture, mitigation of climate change etc. The widespread use of Agricultural Chemicals (ACs) in modern agriculture has resulted in adverse effects in environment and human health mostly through contamination into food and water sources. Study of fate, bioavailability, and transport of ACs involves molecular level understanding of their interactions with soil. This can be challenging due to complex and heterogeneous nature of soil. One common approach used is the correlation of macroscopic properties of soil, (e.g. sorption) with empirical parameters …

Multimodal Emotion Recognition Using 3d Facial Landmarks, Action Units, And Physiological Data, Diego Fabiano

USF Tampa Graduate Theses and Dissertations

To fully understand the complexities of human emotion, the integration of multiple physical features from different modalities can be advantageous. Considering this, this thesis presents an approach to emotion recognition using handcrafted features that consist of 3D facial data, action units, and physiological data. Each modality independently, as well as the combination of each for recognizing human emotion were analyzed.

This analysis includes the use of principal component analysis to determine which dimensions of the feature vector are most important for emotion recognition. The proposed features are shown to be able to be used to accurately recognize emotion and that …

Chemical Synthesis Of Oligosaccharides From Human Milk, Mithila Dulanjalee Bandara Weerasooriya Mudiyanselage

Dissertations

Human milk oligosaccharides (HMO) are a family of structurally related glycans that are highly abundant in breast milk. Oligosaccharide fraction is the third largest solid component in human milk after lactose and lipids. There is an accumulating evidence that HMO can provide significant benefits to the breast-fed infants. However, understanding of the exact HMO functions is still incomplete due to the lack of individual compounds in sufficient quantities. Therefore, development of expeditious strategies for the chemical synthesis of HMO has been increasingly important. Among all the methods available for oligosaccharide synthesis, armed-disarmed strategy introduced by Fraser-Reid is based on chemoselective …

Topological Bound States For Quantum Charges, Yakir Aharonov, Ismael L. Paiva, Jeff Tollaksen, Mordecai Waegell

Mathematics, Physics, and Computer Science Faculty Articles and Research

We discuss how, in appropriately designed configurations, solenoids carrying a semifluxon can be used as topological energy barriers for charged quantum systems. We interpret this phenomenon as a consequence of the fact that such solenoids induce nodal lines in the wave function describing the charge, which on itself is a consequence of the Aharonov-Bohm effect. Moreover, we present a thought experiment with a cavity where two solenoids are sufficient to create bound states.

Investigation Of Subsurface Stratigraphy And Groundwater Dynamics In The Mississippi River Delta, An Li

LSU Doctoral Dissertations

The Mississippi River Delta (MRD) is socioeconomically important to the state of Louisiana and the United States. Various types of land-water system data have been collected in the MRD. However, very few efforts have been made to utilize these datasets in modeling regional stratigraphy and groundwater dynamics in the MRD, especially for the upper 50 m of the depth. In this interval of depth, the Mississippi River and surrounding interdistributary bays intensively interact with the groundwater system. The lack of knowledge in regional stratigraphy and groundwater dynamics hinder an understanding of how hydrogeological setting affects processes such as surface-groundwater interaction, …

Visualization And Quantitation Of Radioiodine Distribution In Silver Zeolite Cartridges, Daniel Dimarco

LSU Master's Theses

Iodine 131 is a major fission product released during a nuclear incident. This isotope provides a serious health hazard for humans and the environment, therefore nuclear power plants must monitor releases using air sampling. The air sampling is accomplished using air filter cartridges using silver zeolite as a filter media. During an emergency situation, silver zeolite is useful for its affinity to I-131 without adsorbing other radioactive gases. After leaving the plume, these cartridges are counted in a low background area. This measurement does not take into account the distribution of radioiodine in the cartridge. This study explores two methods …

An Optimal Upper Bound On The Tail Probability For Sums Of Random Variables, Iosif Pinelis

Iosif Pinelis

No abstract provided.

High Functional Diversity Of Contaminated Soils From Liberty State Park, Nina M. Goodey

Sustainability Seminar Series

Urban brownfields present an opportunity to study the functioning of degraded ecosystems. We investigated the soils of Liberty State Park in Jersey City, New Jersey, which once supported a major rail yard and port facility with docks for shipping cargo to New York City. ICP-MS and pyrolysis-GC-MS studies were used to show that our study site is contaminated with heavy metals and organic contaminants, including polycyclic aromatic hydrocarbons. We used fluorescence spectroscopy to measure soil enzymatic function at multiple locations within the brownfield and found the following types of sites: 1.) hotspots with high heavy metal concentrations and high extracellular …

Galaxy And Mass Assembly: A Comparison Between Galaxy-Galaxy Lens Searches In Kids/Gama, Shawn Knabel, Benne Holwerda

Posters-at-the-Capitol

Strong gravitational lenses are cases where a distant background galaxy is located directly behind a massive foreground galaxy, whose gravity causes the light from the background galaxy to bend around the foreground galaxy. In addition to being visually stunning, these rare events are useful laboratories for furthering our understanding of gravity and cosmology and to determine properties, such as the mass and dark matter content, of the lensing galaxies themselves. The trouble is finding enough of these strong gravitational lenses for further study. The immensity of the catalogs being collected by state-of-the-art telescopes requires equally innovative methods for interpreting that …

Determination Of Cannabinoids, Cathinones, And Synthetic Fentanyls Using Wastewater-Based Epidemiology, Catherine O'Rourke, Bikram Subedi

Posters-at-the-Capitol

Unregulated new psychoactive substances (NPS) in “pure” or “preparation” forms are designed to mimic the effects of controlled substances, and are introduced and reintroduced in the market as a cheap substitute for established regulated drugs in quick succession to loophole the law enforcement efforts on combating drugs. For example, carfentanil, a synthetic opioid activates the opioid receptors similar to morphine but it is astoundingly potent compared to a typical drug of abuse (100 times more potent than fentanyl and 10,000 times more powerful than morphine). Based on the cost- and time-intensive forensic analysis, National Drug Early Warning System reported the …

A Terrestrial Reconstruction Of Gona, Ethiopia Before And During The African Humid Period, Marie N. White, Gary E. Stinchcomb

Posters-at-the-Capitol

The African Humid Period (AHP) resulted in more humid conditions across Northern and Eastern Africa from 15 to 5 thousand years ago (ka). This wetter climate affected flora, fauna and the Homo sapiens living in East Africa. The lack of terrestrial paleoenvironmental reconstructions is a problem in East Africa, especially during the AHP, where most are done utilizing lacustrine or marine proxies. In the case of Gona, Ethiopia, terrestrial proxies are desired due to the rich archaeological and fossil concentrations that occur in the area. Paleosols provide more direct, localized reconstructions that provide context for these finds. This study utilizes …

Magnetocaloric Effect Near Room Temperature In Quintenary And Sextenary Heusler Alloys, Benjamin D. White, R. I. Barabash, O. M. Barabash, I. Jeon, M. B. Maple

All Faculty Scholarship for the College of the Sciences

An inverse magnetocaloric effect is studied in Ni₂Mn_1+xX_1-x-type Heusler alloys. Principally known for their shape-memory properties, these alloys also exhibit significant entropy and temperature changes (ΔS and ΔT_Ad, respectively) under adiabatic conditions when a modest magnetic field is applied. We investigated the impact on magnetocaloric properties of introducing substantial chemical disorder on the X-site (X = Si, Ga, In), of replacing Ni with nonmagnetic Ag, and of replacing a small amount of Mn with Gd. While a reduction in ΔS is observed in the first two cases, we observe a significant enhancement …

Chemistry And Biochemistry News, Georgia Southern University

Department of Chemistry and Biochemistry News (2015-2023)

• SERMACS 2019 - Chemistry on the Coast

Samarium-Activated La2hf2o7 Nanoparticles As Multifunctional Phosphors, Santosh K. Gupta, Maya Abdou, Jose P. Zuniga, Alexander A. Puretzky, Yuanbing Mao

Chemistry Faculty Publications and Presentations

Recent developments in the field of designing novel nanostructures with various functionalities have pushed the scientific world to design and develop high-quality nanomaterials with multifunctional applications. Here, we propose a new kind of doped metal oxide pyrochlore nanostructure for solid-state phosphor, X-ray scintillator, and optical thermometry. The developed samarium-activated La2Hf2O7 (LHOS) nanoparticles (NPs) emit a narrow and stable red emission with lower color temperature and adequate critical distance under near-UV and X-ray excitations. When the LHOS NPs are exposed to an energetic X-ray beam, the Sm3+ ions situated at the symmetric environment get excited along with those located at the …