Physical Sciences and Mathematics Commons^™

Characterization And Evaluation Of Catalytic Activity Of Small Molecule Copper Complexes For Metallopolymer Design, Brenda Lu

Master's Theses

Catalysis is one of the driving forces in designing greener chemical processes for essential real-world applications. Enzymes, Nature’s catalysts, are known for their high selectivity, use of readily available metals and reagents, and ability to work under physiological conditions; three important qualities that synthetic chemists would like to mimic in their small molecule metal catalysts. Though most small molecule metal catalysts fall short of enzyme-like activity, we hypothesize that using a polymer scaffold as a secondary coordination sphere mimic around the metal complex will affect the microenvironment (steric and electronic) and enable enzyme-like activity. Previously, we synthesized ligand precursors and …

Climate Long-Term Trends Impacting Wheat Production Systems In Kansas, Octavia M.M. Tavares, Fábio Marin, Romulo Lollato, Bruno C. Pedreira

Kansas Agricultural Experiment Station Research Reports

Winter wheat production is of major importance in Kansas. The purpose of the study was to verify the evidence of climate change in a long-term weather data series from Wellington and Parsons, KS, to understand whether climate change has been affecting yield production.

Annual Summary Of Weather Data For Parsons - 2022, Matthew Sittel

Kansas Agricultural Experiment Station Research Reports

This report includes the annual summary of precipitation and temperatures from 2022 at the research locations represented in the 2023 Southeast Research and Extension Center Agricultural Research Report.

Field Station Weather Reports, E. Adee, M. Sittel

Kansas Agricultural Experiment Station Research Reports

This report includes the annual summary of precipitation and temperatures from 2022 at the research locations represented in the 2023 Field Research Report and further details about the Kansas River Valley locations and the east central Kansas locations.

Recent Climate Change Influence On Flood Magnitude And Frequency, Channel Widening, And Bar Deposition In Big River, Missouri Ozarks, Patrick Saulys

MSU Graduate Theses

Climate and land use can control the flood regime of a river and regulate channel form and size over periods of decades to centuries. Recent climate change has increased rainfall intensity and flood magnitude/frequency in many watersheds in the midwestern United States. Thus, river channels affected by more frequent and larger floods are expected to respond by increasing width (or depth) by fluvial erosion to accommodate larger peak discharges. This hypothesis was evaluated along 186 km of the Big River in southeast Missouri by analysis of historical aerial photography, precipitation studies, and United States Geological Survey (USGS) flow gage records. …

Sensor Relationship Inference In Single Resident Smart Homes Using Time Series, Samuel Nack

MSU Graduate Theses

Determining sensor relationships in smart environments is complex due to the variety and volume of time series information they provide. Moreover, identifying sensor relationships to connect them with actuators is difficult for smart home users who may not have technical experience. Yet, gathering information on sensor relationships is a crucial intermediate step towards more advanced smart home applications such as advanced policy generation or automatic sensor configuration. Therefore, in this thesis, I propose a novel unsupervised learning approach, named SeReIn, to automatically group sensors by their inherent relationships solely using time series data for single resident smart homes. SeReIn extracts …

Optimizing Soluble Recombinant Expression Of The Aedes Aegypti Early Trypsin Protease, Neomi Millan

Master's Theses

The female Aedes aegypti mosquito is a primary vector for the transmission of blood–borne viral pathogens such as Chikungunya, Zika, Yellow Fever, and Dengue. The female mosquito will become infected with these pathogens through the uptake of a blood meal from an infected host. The midgut digestive enzymes are required to digest the blood meal to obtain necessary nutrients needed for the completion of the gonotrophic cycle. Blood meal digestion is biphasic and digestive enzymes are expressed at different time points after uptake of a blood meal. The focus of this study is on an early phase protease known as …

Bosons In Anti De Sitter Spacetime, Thi Khanh Linh Pham

Master's Theses

I am extremely grateful to Dr. Kassahun Betre for his support and guidance throughout my thesis journey. His wisdom, knowledge, and encouragement have been invaluable to me. His willingness to take me on making this project and the collaborative friendship is the highlight of my master’s program. Many thanks to Dr. Curtis Asplund and Dr. Ehsan Khatami for participating on my committee and with regard to their valuable feedback on my thesis draft, ensuring the completion of this work. Finally, I am grateful to my family for their unwavering love and all the support and absolute patience over the years …

Cirrus Microphysical Properties And The Controlling Factors Using A Machine Learning Approach, Derek D. Ngo

Master's Theses

Cirrus clouds are located at high altitudes and are composed of ice crystals. The unique location of cirrus clouds and their large variability in-cloud microphysical properties allow them to have either warming or cooling effects on Earth’s surface and affect the Earth’s energy budget on a global scale. The examination of cirrus radiative effects is further complicated by multiple factors affecting their formation and evolution, including the effects of thermodynamic, dynamic, aerosol, and chemical tracer variables. In this work, we developed a composite aircraft-based in-situ observation dataset based on seven National Science Foundation (NSF) and five NASA flight campaigns that …

Cloud Phase Distribution At A Global-Scale And The Governing Factors Using Satellite And In-Situ Airborne Observations, Dao Wang

Master's Theses

Cloud thermodynamic phase distributions play a crucial role in accurately representing cloud radiative effects and feedback in a changing climate. The partitioning of cloud thermodynamic phases (ice, liquid, and mixed phase) significantly influences Earth's surface temperature and its ability to mitigate the impact of global warming. Satellite-based cloud phase data are frequently used for the evaluation of global climate models, yet validation of them against in-situ observations is still lacking. This study examines global cloud phase distributions and their determinant factors by validating three satellite-based cloud phase products against an extensive in-situ airborne dataset. CALIPSO exhibits the most similar ice …

The Potential And Limitations Of Conversational Agents For Chronic Conditions And Well-Being, Ekaterina Uetova, Lucy Hederman, Robert J. Ross, Dympna O'Sullivan

Articles

Conversational agents are becoming more common in the health and wellness domains in part due to assumptions regarding potential improvements in individuals’ outcomes. This paper presents initial findings from a review of conversational agent use in healthcare for chronic conditions and well-being. A search of the literature was performed on electronic databases PubMed, ACM Digital Library, Scopus and IEEE Xplore. Studies were included if they were focused on chronic disorder management, disease prevention or lifestyle change and if systems were tested on target user groups. This paper investigates the health domains, the user profiles and reasons why conversational agents may …

Analysis Of Laminar Flow Patterns In Milifluidic Devices, Brian Leger

Honors Theses

This research centers around a millifluidic device designed for the analysis of flowing chemical reactions that may happen too quickly to be analyzed by traditional spectroscopic methods. The device works by combining two simple concepts: fluid flows a certain distance over time and chemical reactions progress over time. Combining these allows for the correlation of reaction progress and distance through the device. Since the flow within the device is laminar, there is friction along the walls of the channel that creates a flow profile that elongates over time. The details of the flow were previously unknown but are necessary if …

Stochastic Optimization To Reduce Aircraft Taxi-In Time At Igia, New Delhi, Rajib Das, Saileswar Ghosh, Rajendra Desai, Pijus Kanti Bhuin, Stuti Agarwal

International Journal of Aviation, Aeronautics, and Aerospace

Since there is an uncertainty in the arrival times of flights, pre-scheduled allocation of runways and stands and the subsequent first-come-first-served treatment results in a sub-optimal allocation of runways and stands, this is the prime reason for the unusual delays in taxi-in times at IGIA, New Delhi.

We simulated the arrival pattern of aircraft and utilized stochastic optimization to arrive at the best runway-stands allocation for a day. Optimization is done using a GRG Non-Linear algorithm in the Frontline Systems Analytic Solver platform. We applied this model to eight representative scenarios of two different days. Our results show that without …

Explorations Of A Topology Constructed On The Maximal Ideals Of A Boolean Algebra, Abbigal Moos

Dissertations and Theses

The primary purpose of this thesis is to construct a topology on the collection of maximal ideals of a distributive and complemented lattice using the hull-kernel methodology. Through the construction of this topological space, we discovered that the space is compact, zero-dimensional, and Hausdorff. Next, we looked at the properties of some lattices, namely the power set of a finite set ordered by inclusion and the set of all positives divisors for some arbitrary integer ordered by divisibility. Whenever these lattices were both distributive and complemented, we constructed a topology on the collection of maximal ideals of the lattices using …

Deep Learning Approaches For Automatic Colorization, Super-Resolution, And Representation Of Volumetric Data, Sudarshan Devkota

Graduate Thesis and Dissertation 2023-2024

This dissertation includes a collection of studies that aim to improve the way we represent and visualize volume data. The advancement of medical imaging has revolutionized healthcare, providing crucial anatomical insights for accurate diagnosis and treatment planning. Our first study introduces an innovative technique to enhance the utility of medical images, transitioning from monochromatic scans to vivid 3D representations. It presents a framework for reference-based automatic color transfer, establishing deep semantic correspondences between a colored reference image and grayscale medical scans. This methodology extends to volumetric rendering, eliminating the need for manual intervention in parameter tuning. Next, it delves into …

A Systematic Review Of Cryptocurrencies Use In Cybercrimes, Kieran B D Human

Graduate Thesis and Dissertation 2023-2024

Cryptocurrencies are one of the most prominent applications of blockchain systems. While cryptocurrencies promise many features and advantages, such as decentralization, anonymity, and ease of access, those very features can be abused. For instance, as documented in various recent works, cryptocurrencies have been frequently abused in many different forms of cybercrime. Despite the plethora of works on measuring and understanding the abuse of cryptocurrencies in the digital space, there has been no work on systemizing this knowledge by comprehensively understanding those contributions, contrasting them based on their merit, and understanding the gap in this research space.

This thesis initiates the …

Optimizing Deep Neural Networks Performance: Efficient Techniques For Training And Inference, Ankit Sharma

Graduate Thesis and Dissertation 2023-2024

Recent advances in computer vision tasks are mainly due to the success of large deep neural networks. The current state-of-the-art models have high computational costs during inference and suffer from a high memory footprint. Therefore, deploying these large networks on edge devices remains a serious concern. Furthermore, training these over-parameterized networks is computationally expensive and requires a longer training time. Thus, there is a demand to develop techniques that can efficiently reduce training costs and also be able to deploy neural networks on mobile and embedded devices. This dissertation presents practices like designing a lightweight network architecture and increasing network …

Dna Capture And Translocation Through Nanopore, Swarnadeep Seth

Graduate Thesis and Dissertation 2023-2024

This thesis investigates DNA dynamics and translocation through nanopores using Brownian dynamics (BD) simulations, offering insights into sequencing technologies, DNA marker detection, and accurate barcoding utilizing solid-state nanopore platforms. First, we in silico study the intricate process of capture and translocation in a single nanopore. Our simulation reveals a high probability of hairpin loop formation during the capture process. However, attaching a charged tag to one end of DNA improves multi-scan rates and enhances unidirectional translocations. We use modulating voltage biases to multi-scan a lambda-phage dsDNA with oligonucleotide flap markers (tags) through a single and double nanopore system. Our study …

Evaluating Gizzard Shad Dorosoma Cepedianum And Threadfin Shad D. Petenense Populations In Two Kentucky Reservoirs Recently Invaded With Silver Carp Hypophthalmichthys Molitrix, Nathan Klein

Murray State Theses and Dissertations

Gizzard Shad Dorosoma cepedianum and Threadfin Shad D. petenense are ecologically important fish species found in many reservoirs throughout the southeastern United States, such as Kentucky Lake and Lake Barkley. One current challenge that Gizzard Shad and Threadfin Shad may face in these two reservoirs is competition with the invasive Silver Carp Hypophthalmichthys molitrix. However, quantifying the effects of this competition may be difficult because of limited baseline population data for Gizzard Shad and Threadfin Shad in these two reservoirs. Gizzard Shad and Threadfin Shad were collected by boat electrofishing and surface trawling in cove and main channel locations …

Local Or Import? A Compositional Analysis Of Aztec Ritual Ceramics In The Tuxtlas Frontier, Veracruz, Mexico, Matthew T. Meyer

Murray State Theses and Dissertations

At the time of Spanish Contact in the early 16th Century the western Tuxtlas region formed part of the Aztec imperial frontier in the southern Gulf lowlands. The most apparent material manifestation of this imperial connection was Aztec-style Texcoco-Molded Censers, recovered primarily from sites that served local centralizing functions. While rare, these symbols may provide valuable information on the dynamics of frontier politics and the relations between this region and the distant core to which they were sending tax payments. Initial consideration of this adopted imperial style implies political linkages, but the mechanisms of introduction, knowledge transmission, imperial versus local …

Bayesian Structural Time Series Methods For Modeling Cattle Body Temperature In Heat-Stressed Animals, Lacey Quandt

Murray State Theses and Dissertations

Climate change has had devastating effects globally, most commonly talked about during natural disasters and rising temperatures. Notably, the climate concern is turning towards agriculture and livestock. With rising temperatures, the prolonged amount of heat stress put on animals, specifically cattle, is becoming more apparent. Heat stress has been linked to a reduction in cattle growing and fattening, feed intake, productivity, reproduction, and fertility; increased heart rates and respiration; changes in behavior; and mortality in severe cases. There are abatement strategies put in place to lower heat stress in cattle, such as improvements in shading and cooling, nutritional management, and …

Temporal Neural Team Formation With Negative Sampling, Seyed Sobhan Dashti

Electronic Theses and Dissertations

Predicting future successful teams of experts who can synergistically work in concert with each other and en masse cover a set of required skills of a degree necessary for the achievement of the desired outcome is challenging due to several reasons, including 1) the magnitude of the pool of plausible expert candidates with diverse backgrounds and skills, and 2) the drift and variability of collaborative ties of experts and their level of expertise in each area in time. Prior works in team formation have neglected the fact that experts’ skill, interests, and collaborative ties change over time. We can categorize …

Biallelic Mutations In P4htm Cause Syndromic Obesity, Sadia Saeed, Lijiao Ning, Alaa Badreddine, Muhammad Usman Mirza, Mathilde Boissel, Roohia Khanam, Jaida Manzoor, Qasim M. Janjua, Waqas I. Khan, Bénédicte Toussaint, Emmanuel Vaillant, Souhila Amanzougarene, Mehdi Derhourhi, John F. Trant, Anna-Maria Siegert, Brian Y.H. Lam, Giles S.H. Yeo, Layachi Chabraoui, Asmae Touzani, Abhishek Kulkarni, I. Sadaf Farooqi, Amélie Bonnefond, Muhammad Arslan, Philippe Froguel

Chemistry and Biochemistry Publications

We previously demonstrated that 50% of children with obesity from consanguineous families from Pakistan carry pathogenic variants in known monogenic obesity genes. Here, we have discovered a novel monogenetic recessive form of severe childhood obesity using an in-house computational staged approach. The analysis included whole-exome sequencing data of 366 children with severe obesity, 1,000 individuals of the Pakistan Risk of Myocardial Infarction Study (PROMIS) study, and 200,000 participants of the UK Biobank to prioritize genes harboring rare homozygous variants with putative effect on human obesity. We identified five rare or novel homozygous missense mutations predicted deleterious in five consanguineous families …

A New Look At The Origin Of N-S Trending Young Basins Of Western Anatolia, Ömer Feyzi Gürer

Bulletin of the Mineral Research and Exploration

In the western Anatolia, the tectonic regime transitioned from crustal shortening to extension during Late Cenozoic time and evidence of this event was imprinted on basement lithologies and N-S and E-W oriented two distinct basin sub-types. Here, we examined the exhumation mechanism of the Menderes massif that forms the basement of these basins from a different perspective. The N-S oriented basins overlying different basement rock types were re-evaluated based on new evidence that has potential to put new constrains for interpreting the tectonic evolution of the area. Unroofing of the Menderes Massif must have developed due to compressional core complex. …

Evaporate Salt Exploration By Two Dimensional (2d) Seismic Reflection Method: Ankara- Polatlı Region, Türkiye, Recep Güney, Zeynep Rezzan Özerk, Erdener Izladi, Salih Erden, Esra Ak, Erdi Apatay, Erdoğan Eryilmaz, Batuğhan Yikmaz, Sami Aytaç Özdemi̇r, Sermet Gündüz, Tuğçe Can, İmam Çeli̇k, Abdullah Gürer, Sinem Aykaç, Muzaffer Özgü Arisoy, Esra Burcu Köse, Büşra Bihter Demi̇rci̇

Bulletin of the Mineral Research and Exploration

The presence of the evaporate salt zone in Ankara-Polatlı region has been determined by the drillings. It is thought to be the largest reserve in Türkiye. The seismic reflection method was used to determine the top-bottom levels of the zone; its depth; its thickness and extent boundaries; the horstgraben structures; base depth and tectonic movements affecting the study area. Data were collected on three seismic lines. The near-surface tomographic velocity sections were compatible with the top-of-the-zone depth observed in the drillings. As a result of the study, the depth and thickness of the top-bottom of the zone were determined along …

Just Transition Litigation In Latin America: An Initial Categorization Of Climate Litigation Cases Amid The Energy Transition, Maria Antonia Tigre, Lorena Zenteno, Marlies Hesselman, Natalia Urzola, Pedro Cisterna-Gaete, Riccardo Luporini

Sabin Center for Climate Change Law

Just transition litigation is a novel field representing a sub-set of climate change litigation cases that is under-researched and studied. The report provides a novel comparative analysis of legal developments found in 20 just transition litigation cases in four Latin American countries and questions whether initiatives for achieving energy transformation in the region may have erred in failing to consider key just transition principles or dimensions, leading applicants to bring legal cases to claim their rights or demand more just solutions. The cases found – limited to the energy sector – not only question decarbonization policies or projects (in typical …

Accelerating A Software Defined Satnav Receiver Using Multiple Parallel Processing Schemes, Logan Reich, Sanjeev Gunawardena, Michael Braasch

Faculty Publications

Excerpt: Satnav SDRs present many benefits in terms of flexibility and configurability. However, due to the high bandwidth signals involved in satnav SDR processing, the software must be highly optimized for the host platform in order to achieve acceptable runtimes. Modules such as sample decoding, carrier replica generation, carrier wipeoff, and correlation are computationally intensive components that benefit from accelerations.

Atmospheric Meteorological Effects On Forecasting Daily Lightning Occurrence At Cape Canaveral Space Force Station, Jon Saul [*], Torrey J. Wagner, Eric G. Mbonimpa, Brent T. Langhals

Faculty Publications

As the Cape Canaveral Space Force Station and Kennedy Space Center increase their launch rate, any process that could assist in the automation of the currently-manual lightning forecast would be valuable. This work examines the possibility of machine-learning assistance with the daily lighting forecast which is produced by the 45th Weather Squadron. A dataset consisting of 34 lightning, pressure, temperature and windspeed measurements taken from 334 daily weather balloon (rawinsonde) launches in the timeframe 2012-2021 was examined. Models were created using recursive feature elimination on logistic regression and XGClassifier algorithms, as well as Bayesian and bandit optimization of neural network …

Modification Of Hyaluronic Acid To Enable Click Chemistry Photo-Crosslinking Of Hydrogels With Tailorable Degradation Profiles, Ciara Buckley

Articles

Hyaluronic acid (HA) is a naturally occurring mucopolysaccharide that, due to its inherent bioactivity and extracellular matrix-like structure, has the potential to be utilised extensively in tissue engineering. However, this glycosaminoglycan lacks the properties required for cellular adhesion and photo-crosslinking by UV light, which significantly hinders this polymers applicability. This research presents a method for modifying hyaluronic acid via thiolation and methacrylation to generate a novel photo-crosslinkable polymer with improved physicochemical properties, biocompatibility and the potential to customize biodegradability according to the ratio of monomers used. A decrease in stiffness proportional to increasing thiol concentration was observed when testing the …

Antibiotic Susceptibility Of Proteus Mirabillis That Isolates Of Diabetic Foot Ulcers In Al- Diwaniyah Hospital, Aseel Hussein Jaber, Suaad A. Fazaa Almiyah

Al-Qadisiyah Journal of Pure Science

The current study have been included 250 samples diabetic foot ulcer patients attending in Al-Diwaniyah Teaching Hospital and private clinics at a period of study from beginning October 2021 to February 2022, Isolates were identified by morphological form on blood agar and macConkey agar, traditional biochemical tests and then confirmed by Vitek 2 system. The result of bacterial culture have been recorded that only 80 samples had positive result to P. mirabilis formed (32%) of this result. Prevalence of P. mirabilis isolates in male more than female (34.78%) and (28.57%) respectively, after then were determination of antibiotics susceptibility pattern of …