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2023

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Articles 61 - 90 of 12566

Full-Text Articles in Physical Sciences and Mathematics

Reliable Emergency Rescue Model Of Uavs Based On Blockchain, Mengyao Du, Kai Xu, Miao Zhang, Xiang Fu, Quanjun Yin Dec 2023

Reliable Emergency Rescue Model Of Uavs Based On Blockchain, Mengyao Du, Kai Xu, Miao Zhang, Xiang Fu, Quanjun Yin

Journal of System Simulation

Abstract: Natural disasters may unpredictably disrupt ground communication infrastructure and transportation systems, and UAVs emergency response can deal with such uncertainties and highly dynamic scenarios. Aiming at the robustness requirements of decentralized rescue systems. UAV emergency rescue chain (UERChain) based on blockchain technology is proposed. By deploying UAV backbone nodes within a layered local network, the smart contracts for managing reputation considering UAV social relationships are designed. The blockchain is employed as a trust mechanism to realize the trustworthy interactions among distributed UAVs. Experimental results show that, UERChain has higher robustness, and within controllable resource constraints, the reputation management and …


Automatic Target Recognition Of Substation 3d Scene For Digital Twin, Qian Tu, Jun Li, Dongliang Fan, Qi Kong, Jie Shen Dec 2023

Automatic Target Recognition Of Substation 3d Scene For Digital Twin, Qian Tu, Jun Li, Dongliang Fan, Qi Kong, Jie Shen

Journal of System Simulation

Abstract: In order to improve the accuracy of automatic target recognition and promote the effect on substation operation and maintenance, automatic target recognition of substation 3D scene for digital twin is proposed. The automatic target recognition model for the three dimensional scene of the substation is constructed. The perception module of the model is used to collect the real-time status data of substation, and the communication module is used to transmit the data to digital twin modules. This module, based on the received data information, realizes the deep fusion and panoramic mapping of substation information through the knowledge base constructed …


Urban Uav Path Planning Based On Improved Beetle Search Algorithm, Qingqing Yang, Minyi Deng, Yi Peng Dec 2023

Urban Uav Path Planning Based On Improved Beetle Search Algorithm, Qingqing Yang, Minyi Deng, Yi Peng

Journal of System Simulation

Abstract: An improved SABAS is proposed to improve the safety and path smoothing of UAV missions in urban multi-obstacle environments and to obtain the shortest path. The algorithm no longer completely depends on the difference of odor concentration between the left and the right tentacles of beetle when exploring the path for position update. Instead, it makes full use of the strong searching ability of BAS algorithm, and introduces the annealing algorithm to add the neighborhood position solution of the next position, and finally selects the next best position from the neighborhood position solution. Metropolis criterion of annealing algorithm is …


Reducing Food Scarcity: The Benefits Of Urban Farming, S.A. Claudell, Emilio Mejia Dec 2023

Reducing Food Scarcity: The Benefits Of Urban Farming, S.A. Claudell, Emilio Mejia

Journal of Nonprofit Innovation

Urban farming can enhance the lives of communities and help reduce food scarcity. This paper presents a conceptual prototype of an efficient urban farming community that can be scaled for a single apartment building or an entire community across all global geoeconomics regions, including densely populated cities and rural, developing towns and communities. When deployed in coordination with smart crop choices, local farm support, and efficient transportation then the result isn’t just sustainability, but also increasing fresh produce accessibility, optimizing nutritional value, eliminating the use of ‘forever chemicals’, reducing transportation costs, and fostering global environmental benefits.

Imagine Doris, who is …


Optimized Scheduling Of Distribution Network With Distributed Generation Based On Coronavirus Herd Immunity Optimizer Algorithm, Xiaomeng Wu, Rongze Yuan, Yingliang Li, Qi Zhu Dec 2023

Optimized Scheduling Of Distribution Network With Distributed Generation Based On Coronavirus Herd Immunity Optimizer Algorithm, Xiaomeng Wu, Rongze Yuan, Yingliang Li, Qi Zhu

Journal of System Simulation

Abstract: Following the large-scale entry of distributed new energy into the network, the uncertainty factor of the distribution network increases significantly, and the difficulty of reactive power optimization scheduling increases accordingly. Traditional optimization solutions have many limitations and shortcomings, and a dynamic reactive power optimization scheme for active distribution networks based on a multi-scenario approach is proposed. The mathematical modeling is carried out separately for the uncertainty of new energy and load, and the multi-scenario method is used to transform the uncertainty problem into a deterministic problem. A mathematical model is constructed on the distribution network side to pursue the …


Research On Network Public Opinion Propagation Model Of Major Epidemics Under Cross-Infection Of Double Emotions, Yaming Zhang, Yanyuan Su, Guiru Zhao, Xiaoyu Guo Dec 2023

Research On Network Public Opinion Propagation Model Of Major Epidemics Under Cross-Infection Of Double Emotions, Yaming Zhang, Yanyuan Su, Guiru Zhao, Xiaoyu Guo

Journal of System Simulation

Abstract: Major epidemics provoke a variety of netizens' emotions. To some degree, the interaction of netizens' intense emotions determine the development direction of public opinion. Considering the complexity and dual emotional contagion, the impact of emotional factors in network public opinion is quantified to three dimensions indicators, emotional enhancement, differences and conversion rates. SIPINR public opinion propagation model is constructed. The equilibrium points and the transmission threshold are estimated and the stability is proved. The law of network public opinion propagation during major epidemics is revealed through numerical simulation. The results show that the dual emotional contagion would lead to …


Development Of Several Typical Virtual Reality Fusion Technologies, Qiqi Feng, Zhiming Dong, Wencheng Peng, Yi Dai, Bingshan Si Dec 2023

Development Of Several Typical Virtual Reality Fusion Technologies, Qiqi Feng, Zhiming Dong, Wencheng Peng, Yi Dai, Bingshan Si

Journal of System Simulation

Abstract: Virtual reality fusion can realize the two-way interaction, mapping and linkage between virtual world and physical world, which attracts the attention of countries in the world. In order to sort out and make statistics on concept connotation, academic status and application of the related new technologies, digital twin, cyber-physical systems, metaverse and live-virtual-constructive simulation are taken as representatives. The comparison on the development process, functional characteristics, target trends, etc. is carried out.


Task Scheduling For Internet Of Vehicles Based On Deep Reinforcement Learning In Edge Computing, Xiang Ju, Shengchao Su, Chaojie Xu, Beibei He Dec 2023

Task Scheduling For Internet Of Vehicles Based On Deep Reinforcement Learning In Edge Computing, Xiang Ju, Shengchao Su, Chaojie Xu, Beibei He

Journal of System Simulation

Abstract: Aiming at the offloading and execution of delay-constrained computing tasks for internet of vehicles in edge computing, a task scheduling method based on deep reinforcement learning is proposed. In multi-edge server scenario, a software-defined network-aided internet of vehicles task offloading system is built. On this basis, the task scheduling model of vehicle computation offloading is given. According to the characteristics of task scheduling, a scheduling method based on an improved pointer network is designed. Considering the complexity of task scheduling and computing resource allocation, the deep reinforcement learning algorithm is used to train the pointer network. The vehicle offloading …


Application Of Improved Path Tracking Algorithm In Robot Slam, Qian Li, Ye Tao, Hui Li Dec 2023

Application Of Improved Path Tracking Algorithm In Robot Slam, Qian Li, Ye Tao, Hui Li

Journal of System Simulation

Abstract: Mapping is an important part of automated logistics. At present, SLAM is widely used. However, in large-scale scenes, errors are accumulated because robots often repeatedly measure and scan the region edge, which makes it impossible to quickly build a high-precision and complete map. An autonomous mapping method based on auxiliary path tracking is proposed, in which the given initial sketch is grid denoised and the auxiliary path is fitted and improved by multi segment cubic polynomial. The improved pure pursuit algorithm is used to guide the robot to build the map and improve the total distance and time of …


Unrelated Parallel Machine Scheduling With Additional Resource And Learning Effect, Youlian Zheng, Deming Lei Dec 2023

Unrelated Parallel Machine Scheduling With Additional Resource And Learning Effect, Youlian Zheng, Deming Lei

Journal of System Simulation

Abstract: To solve unrelated parallel machine scheduling problem(UPMSP) with additional resource and learning effect, a dynamical artificial bee colony(DABC) algorithm is proposed to minimize the makespan. A new representation and decoding process is given and two initial bee swarms are constructed. A swarm evaluation method is applied to dynamically decide employed bee swarms and onlooker bee swarms. Employed bee phase and onlooker bee phase are implemented in different ways to increase exploration ability. The experimental results show that the new strategies of DABC are effective and reasonable, and can obtain results with better convergence, average value and stability, which d …


Research And Development Of Simulation Training Platform For Multi-Agent Collaborative Decision-Making, Cheng Cheng, Zhijie Chen, Ziming Guo, Ni Li Dec 2023

Research And Development Of Simulation Training Platform For Multi-Agent Collaborative Decision-Making, Cheng Cheng, Zhijie Chen, Ziming Guo, Ni Li

Journal of System Simulation

Abstract: Reinforcement learning simulation platform can be an interactive and training environment for reinforcement learning. In order to make the simulation platform compatible with the multi-agent reinforcement learning algorithms and meet the needs of simulation in military field, the similar processes in multi-agent reinforcement learning algorithms are refined and a unified interface is designed to embed and verify different types of deep reinforcement learning algorithms on the simulation platform and to optimize the back-end service of the simulation platform to accelerate the training process of the algorithm model. The experimental results show that, by unifing the interface, the simulation platform …


Data Simulation Testing Framework For Complex Process Equipment Software, Jinkun Zhang, Longfei Shi, Chi Hu, Hao Zhang, Yonghui Yang Dec 2023

Data Simulation Testing Framework For Complex Process Equipment Software, Jinkun Zhang, Longfei Shi, Chi Hu, Hao Zhang, Yonghui Yang

Journal of System Simulation

Abstract: Due to the complex task, tight coupling, strict timing, and a large amount of interchange data, the technical threshold of automated testing of bus communication equipment software is high, and the implementation is difficult. The ideas of data-driven testing and keyword-driven testing are introduced, and a data simulation testing framework is proposed. Configuration rules are formulated and implemented in the framework. Testers can simulate peripheral data for complex process equipment software and implement automated testing by only focusing on the task analysis, and configuring interchange data and keywords. There is no need to develop test scripts, which reduces the …


Airport Operational Efficiency Evaluation Based On Combined Weighting-Topsis Model, Jie Hu, Fan Bao Dec 2023

Airport Operational Efficiency Evaluation Based On Combined Weighting-Topsis Model, Jie Hu, Fan Bao

Journal of System Simulation

Abstract: In order to improve the scientificity and comprehensiveness of the airport operational efficiency evaluation, a new method based on the combined weighting-TOPSIS model is proposed. From 4 dimensions of stand operational efficiency, passenger boarding efficiency, aircraft taxiing efficiency, and coordination efficiency, a new airport operational efficiency evaluation system consisting of 11 indicators, such as flight approach rate, corridor bridge turnover rate, stand change ratio, etc., are constructed. G1 method and entropy weight method are implemented respectively to calculate the subjective and objective weights of the evaluation indicators, and the combined weights are calculated by minimizing the deviation of subjective …


Simulation On High-Speed Train Carriage Evacuation Considering Passengers Moving To Adjacent Carriages, Zuoan Hu, Tian Zeng, Yidong Wei, Yi Ma Dec 2023

Simulation On High-Speed Train Carriage Evacuation Considering Passengers Moving To Adjacent Carriages, Zuoan Hu, Tian Zeng, Yidong Wei, Yi Ma

Journal of System Simulation

Abstract: To study the influence of passengers moving to adjacent carriages on high-speed train carriages' evacuation, a cellular automata model considering export selection is established. Taking the CR400BF second-class carriage as the research object, some analytical indexes such as evacuation efficiency, number of conflicts and the congestion degree are used to study the effect of passengers moving to adjacent carriages on carriage evacuation, and the passenger seat distribution, the number of passengers transferred from adjacent carriages and the opening door modes of adjacent carriages are discussed. The simulation results show that the discretized seat distribution reduces the times of conflicts …


Research And Design Of Etc Simulation Platform For Expressway, Fumin Zou, Feng Guo, Sijie Luo, Lüchao Liao, Nan Li, Yue Xing Dec 2023

Research And Design Of Etc Simulation Platform For Expressway, Fumin Zou, Feng Guo, Sijie Luo, Lüchao Liao, Nan Li, Yue Xing

Journal of System Simulation

Abstract: It is difficult to quantitatively calculate and display the real-time traffic situation of expressway ETC system, and there is no simulation system for ETC to optimize the operating situation. A simulation system based on ETC data in proposed, in witch there are three key algorithms. ETC data feature extraction algorithm provides the feature of generating simulation data for the simulation platform. The improved multitask scheduling algorithm has the computing ability of multitasks in simulation environment. The algorithm of expressway traffic flow control strategy provides the decision index for traffic flow control on the way. The experimental results show that …


Research On Digital Twin Data Modeling And Evaluation Method Of Automated Container Terminal, Guoxuan Xu, Daofang Chang, Jiaqi Li, Qiang Ling Dec 2023

Research On Digital Twin Data Modeling And Evaluation Method Of Automated Container Terminal, Guoxuan Xu, Daofang Chang, Jiaqi Li, Qiang Ling

Journal of System Simulation

Abstract: To make full use of the massive operation data of automated container terminals and further realize the digital and intelligent transformation of terminals driven by digital twin, a method for digital twin data modeling and effect verification and evaluation of automated container terminals is proposed. The application framework and operation mechanism based on digital twin are studied. Based on the data processing logic of digital twin framework, a method of terminal operation process evolution and dynamic data modeling based on digital twin is proposed. To verify whether the data could meet the effective operation of the digital twin, a …


Modeling And Simulation On Production Logistics Of Intelligent Workshop Manufacturing System Based On Efsm, Liuzhen Li, Chao Jin, Tingyu Lin, Yaoqin Zhu Dec 2023

Modeling And Simulation On Production Logistics Of Intelligent Workshop Manufacturing System Based On Efsm, Liuzhen Li, Chao Jin, Tingyu Lin, Yaoqin Zhu

Journal of System Simulation

Abstract: The production logistics mode of manufacturing industry is developing rapidly, on which the modeling and simulation can provide the decision support for the design, analysis and transformation of manufacturing system. A description of the entity elements in intelligent workshop manufacturing system is given according to the classification of "human machine material environment rule". A production and logistics componentized EFSM model is created on the basis of EFSM and componentized modeling ideas. The modeling process for multi-job production in smart shop and the component model instantiation methodology are elaborated. The simulation running through the automatic conversion of EFSM-DEVS model and …


Research On 3d Object Detection Method With Cross-Module Attention, Renjie Xu, Xiaoming Zhang, Chen Wang, Peng Wu Dec 2023

Research On 3d Object Detection Method With Cross-Module Attention, Renjie Xu, Xiaoming Zhang, Chen Wang, Peng Wu

Journal of System Simulation

Abstract: To address the issue of feature loss that occurs during the extraction and transmission of target features in 3D object detection tasks using point cloud data, this study proposes an object detection method based on cross-module attention. This method incorporates a channel attention module and a spatial attention module to enhance the crucial feature information. Through feature transformation, the features from different stages of the attention module are connected to mitigate the loss of features during the extraction and transmission process. To tackle the problem of inadequate detection performance in target detection networks for objects of different scales, a …


Accelerated Iron Valence Cycling In Fenton System Using Activated Hydrogen Enhanced By Mil-100(Fe) Modified By Nano-Pd0 Particle, Yun-Dong Wang, Yi-Jun Chen, Mei-Na Cheng, Xin Liu Dec 2023

Accelerated Iron Valence Cycling In Fenton System Using Activated Hydrogen Enhanced By Mil-100(Fe) Modified By Nano-Pd0 Particle, Yun-Dong Wang, Yi-Jun Chen, Mei-Na Cheng, Xin Liu

Turkish Journal of Chemistry

In this paper, a novel Fenton reaction system which was called MHACF-MIL-100(Fe) was constructed. In this system, based on active hydrogen-accelerated FeIII reduction, the hydroxyl radical was continuously produced with a trace amount of total iron. The MIL-100(Fe) modified with the nano-Pd0 particle could be used to activate the H2. Under normal temperature and pressure, the target organic pollutants, such as sulfamethazine and 4-chloro phenol, could be degraded fast. In the condition of initial aqueous solution pH 3, 2 g L–1 dosage of MIL-100(Fe) catalyst loaded with nano-Pd0, Pd/MIL-100(Fe), 20 mM 30 wt% hydrogen peroxide, 25 μM ferrous chloride and …


Synthesis Of Silane- And Quaternary Ammonium-Bearing Copolymers And Application As A Coating Resin On Cotton Fabric, Ayşe Marti̇n, Nazgül Güler, İlknur Yerli̇, Hande Hançer, Tüli̇n Özbek, Tarik Eren Dec 2023

Synthesis Of Silane- And Quaternary Ammonium-Bearing Copolymers And Application As A Coating Resin On Cotton Fabric, Ayşe Marti̇n, Nazgül Güler, İlknur Yerli̇, Hande Hançer, Tüli̇n Özbek, Tarik Eren

Turkish Journal of Chemistry

In this study, silane and quaternary ammonium functional methacrylate monomers were synthesized and used to construct a copolymer using an emulsion polymerization technique to control the reaction rate. The copolymer was then designed using different ratios of silane and quaternary ammonium groups to investigate the relationship between the structure and properties. The presence of the ethoxy silane group in the copolymer series provided covalent bonding through the silanol group onto cotton fabric. The presence of cationic groups also helped to cover the fabric surface. After coating the cotton textile fabric, the resistance of the dye on the fabric surface to …


Polypyrrole Fabricated Laponite Rd Conductive Nanocomposites: Influence Of Grafting Efficiency On Structural And Conductive Properties, Shafiq Ur Rehman, Shaista Taimur, Asif Raza, Tariq Yasin Dec 2023

Polypyrrole Fabricated Laponite Rd Conductive Nanocomposites: Influence Of Grafting Efficiency On Structural And Conductive Properties, Shafiq Ur Rehman, Shaista Taimur, Asif Raza, Tariq Yasin

Turkish Journal of Chemistry

In the present work novel conductive organic-inorganic nanocomposites were produced by grafting of pyrrole monomer onto silanized Laponite RD utilizing emulsion graft polymerization. Influence of some important factors like concentration of monomer, initiator and surfactant were investigated on grafting efficiency. Grafting of polypyrrole chains onto modified Laponite RD was verified by Fourier transform infrared spectroscopy (FT-IR). Scanning electron microscope (SEM) revealed the spherical particles of nanocomposite with average diameter of 271.5 nm. XRD pattern showed that molecular framework of pure polypyrrole almost remains same in nanocomposite. Surface area and pore volume of Laponite RD, measured by Brunauer-Emmett-Teller (BET) analysis, was …


Phytochemical Investigation On The Aerial Parts Of Veratrum Versicolor F. Viride Nakai And Their Biological Activities, Seong Su Hong, Jae Yeon Lee, Yeon Woo Jeong, Ji Eun Lee, Yun-Hyeok Choi, Wonsik Jeong, Eun-Kyung Ahn, Chun Whan Choi, Il Ho Ahn, Joa Sub Oh Dec 2023

Phytochemical Investigation On The Aerial Parts Of Veratrum Versicolor F. Viride Nakai And Their Biological Activities, Seong Su Hong, Jae Yeon Lee, Yeon Woo Jeong, Ji Eun Lee, Yun-Hyeok Choi, Wonsik Jeong, Eun-Kyung Ahn, Chun Whan Choi, Il Ho Ahn, Joa Sub Oh

Turkish Journal of Chemistry

Veratrum spp. have traditionally been used in folk medicine to treat various pathologies. In this study, nine compounds, comprising one simple phenolic compound (1), three stilbenoids (2–4), and five flavonoids (5–9), were isolated from the aerial parts of Veratrum versicolor f. viride Nakai. The structures of these compounds were elucidated by spectroscopic analyses and comparison with reported data. Together, all reported compounds were isolated from V. versicolor f. viride for the first time in the study. Among them, two flavone aglycone tricetins (7 and 9) have never been isolated from the genus Veratrum or the family Melanthiaceae. The ethanol extract …


Extraction/Transportation Of Co2+ Metal Ions With Bis(2-Ethylhexyl) Phosphate Dissolved In Kerosene Using A Multidropped Liquid Membrane Technique, Volkan Demi̇rel, Ramazan Donat Dec 2023

Extraction/Transportation Of Co2+ Metal Ions With Bis(2-Ethylhexyl) Phosphate Dissolved In Kerosene Using A Multidropped Liquid Membrane Technique, Volkan Demi̇rel, Ramazan Donat

Turkish Journal of Chemistry

The transport properties of Co2+ ions from the aqueous donor phase to aqueous acceptor phase with the recently developed multidroplet liquid membrane (MDLM) extraction system were studied. This system serves as a continuous process for the transportation of ions and requires fewer reagents for starting and conducting the procedure. Moreover, the procedure results in fewer waste chemicals and mixtures in comparison to traditional extraction methods. During extraction, bis(2-ethylhexyl) phosphate (D2EHPA) was used as a carrier material and 5% potassium thiocyanate (KSCN) solution was used to obtain a colored complex for UV-Vis detection. By means of several experiments, the optimum D2EHPA …


Poly(Vinyl Alcohol)/Zsm-5 Zeolite Mixed Matrix Membranes For Pervaporation Dehydration Of Ethanol And N-Propanol, Ji Ting Wang, Zhen Huang, Ya Tong Zhu, Si Ning Wang Dec 2023

Poly(Vinyl Alcohol)/Zsm-5 Zeolite Mixed Matrix Membranes For Pervaporation Dehydration Of Ethanol And N-Propanol, Ji Ting Wang, Zhen Huang, Ya Tong Zhu, Si Ning Wang

Turkish Journal of Chemistry

In this study, mixed matrix membranes (MMMs) composed of poly(vinyl alcohol) (PVA) and porous ZSM-5 zeolite are thoroughly investigated for concentrating alcohols of ethanol and n-propanol via dewatering pervaporation. The effects of the zeolite content (10–30 wt.%), feed composition (5–30 wt.% water), and feed temperature (50–90 °C) on the pervaporation flux/separation factor and component permeance/selectivity of these MMMs are examined in detail. These MMMs achieve higher separation efficiency and pervaporation flux than their pure PVA counterparts as expected, even if the dehydration results strongly depend on the pervaporation conditions. The disparity in pervaporation performances acquired for different alcohol solutions may …


Bromination And Conversion Of Tetrahydro-1h-Indene To Bisoxirane With A New Approach: Synthesis, Structural Characterization By Spectroscopic And Theoretical Methods, And Biological Analysis Supported By Dft And Docking, Raşi̇t Fi̇kret Yilmaz, Sultan Erkan, Sali̇h Ökten, Ahmet Tutar, Ertan Şahi̇n Dec 2023

Bromination And Conversion Of Tetrahydro-1h-Indene To Bisoxirane With A New Approach: Synthesis, Structural Characterization By Spectroscopic And Theoretical Methods, And Biological Analysis Supported By Dft And Docking, Raşi̇t Fi̇kret Yilmaz, Sultan Erkan, Sali̇h Ökten, Ahmet Tutar, Ertan Şahi̇n

Turkish Journal of Chemistry

In this study, a new method for synthesizing diepoxides is proposed. Tetrahydroindene 1 was brominated with NBS in the presence of LiClO4 and acetic acid, resulting in the formation of dibromodiacetate derivatives 2 and 3. Treatment of compounds 2 and 3 with NaOH in methanol produced a mixture of diepoxides 4 and 5. Additionally, direct bromination of tetrahydro-1H-indene yielded tetrabromo octahydroindene isomers 6 and 7. The structures of the compounds were characterized using spectroscopic techniques such as 1H NMR, 13C NMR, APT, COSY, and XRD. The new method provides an easy and selective route to access epoxides for the synthesis …


Quaternized Chitosan/Pva/Natural Bioactive Agent Electrospun Wound Scaffolds: Production, Characterization, And Investigation Of Release Kinetics, Ezgi Eren Belgin, Cankiz Gi̇zem Deli̇balta Dec 2023

Quaternized Chitosan/Pva/Natural Bioactive Agent Electrospun Wound Scaffolds: Production, Characterization, And Investigation Of Release Kinetics, Ezgi Eren Belgin, Cankiz Gi̇zem Deli̇balta

Turkish Journal of Chemistry

Quaternized chitosan (HTCC) was synthesized and characterized to increase chitosan solubility. Then HTCC was electrospun with poly (vinyl alcohol) (PVA) and prepared natural bioactive agent (Calendula officinalis) extract was loaded onto fibers for wound scaffold applications. Morphological, structural, and mechanical characterization of the produced wound scaffolds was performed and their in vitro bioactive component release behavior was investigated. As a result, it was observed that the degree of quaternization of chitosan was 0.89, and synthesized HTCC was soluble in acidic, basic, alkaline media and could be electrospun with PVA in the presence of a natural bioactive agent. The presence of …


Optimum Pyrolysis Conditions To Prepare The Most Crystalline Boron Carbide Powder From Boric Acid–Mannitol Complex Ester, Abdullah Devri̇m Pekdemi̇r, Müşerref Önal, Yüksel Sarikaya Dec 2023

Optimum Pyrolysis Conditions To Prepare The Most Crystalline Boron Carbide Powder From Boric Acid–Mannitol Complex Ester, Abdullah Devri̇m Pekdemi̇r, Müşerref Önal, Yüksel Sarikaya

Turkish Journal of Chemistry

A weak acidic complex ester (CE) in solid form was prepared by a condensation reaction between very weak boric acid (BA: H3BO3) and (D)-mannitol (MA: C6H14O6) by the molar ratio of BA/MA = 2. A boron carbide (B4C) precursor was obtained from heating of the CE at 400 °C for 4 h. The precursor was pyrolyzed under argon flow in the interval of 1300–1550 °C for 4 h and at 1400 °C for 1–4 h, respectively. The materials were examined using several techniques such as X-ray diffraction analysis, thermal analysis, scanning electron microscopy, particle size distribution, and nitrogen adsorption/desorption. The …


Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül Dec 2023

Sustainable Graphitic Carbon From Biomass To Be Suitable For Technological Devices, Gökçen Akgül

Turkish Journal of Chemistry

Technological devices are mostly manufactured by conductive and semiconductive materials. As advancement in the last decades, carbon nanomaterials have been explored in electrical/electronic technology due to their unique performances for manufacturing developing, and prudential miniaturized and flexible electrical/electronic devices. In the era of sustainable and clean carbon technology; renewable, alternative, biodegradable, and eco-friendly new carbon resources are required. Biomass could be the answer to offer inspiring carbon allotropes from nature to be suitable for developing electrical/electronic devices. In this article, deriving of the technological carbonaceous material from biomass, studies although they are very limited in the literature on obtaining the …


Exploring The Photocatalytic And Photodynamic Effects Of Bodipy-Linked Titanium Dioxide Nanoparticles, Seda Demi̇rel Topel Dec 2023

Exploring The Photocatalytic And Photodynamic Effects Of Bodipy-Linked Titanium Dioxide Nanoparticles, Seda Demi̇rel Topel

Turkish Journal of Chemistry

This study aimed to investigate the photocatalytic and photodynamic actions of a 2,6-diiodinated-BODIPY (2,6-diI2-Bod) photosensitizer (PS) covalently linked to TiO2 nanoparticles (NPs). The TiO2 NPs were synthesized utilizing the hydrothermal technique, yielding an average particle size of 4–5 nm as ascertained by transmission electron microscopy and 6.4 nm as determined by dynamic light scattering measurements. The integration of the nonsoluble Bod PS to TiO2 NPs provided increased dispersibility in physiological media, making it more applicable to photodynamic therapy applications. Bod-TiO2 NPs exhibited moderate efficiency of 56.9% in singlet oxygen generation. Additionally, the photocatalytic behavior of the TiO2 NPs was evaluated …


Scope And Limitations Of The Preparation Of Xanthones Using Eaton’S Reagent, Johann Bosson Dec 2023

Scope And Limitations Of The Preparation Of Xanthones Using Eaton’S Reagent, Johann Bosson

Turkish Journal of Chemistry

Xanthones comprise a large family of heterocycles displaying fascinating biological properties. Many synthetic protocols have been developed for the preparation of natural and nonnatural xanthone derivatives. Among them, condensation reactions between salicylic acid derivatives and phenol partners are highly desirable. Those reactions can be satisfactorily performed using Eaton’s reagent (P2O5 in CH3SO3H). Despite being highly effective with a variety of substrates, this approach presents limitations that depend on the electronic nature of the reaction precursors. The scope and limitations of the Eaton’s reagent-mediated preparation of xanthones are herein presented and discussed. In short, this approach is limited to the utilization …