Physical Sciences and Mathematics Commons^™

Synergistic Effect Of Acylpyrazolone Integrated With Multiwalled Carbon Nanotubes On The Electrochemical Analysis Of Ascorbic Acid, Emi Norzehan Mohamad Mahbob, Mohamad Syahrizal Ahmad, Illyas Md Isa, Norhayati Hashim, Anwar Ul-Hamid, Mohamad Idris Saidin, Suyanta Suyanta, Sofian Ibrahim

Makara Journal of Science

Square wave voltammetry, cyclic voltammetry, chronocoulometry, and electrochemical impedance spectroscopy were employed to assess ascorbic acid’s electrochemical behavior in multiwalled carbon nanotubes (MWCNTs)/carbon paste electrode (CPE) modified by 1-phenyl-3-methyl-4-metafluorobenzoyl-5-pyrazolone (HPMmFBP). The ascorbic acid’s irreversible oxidation peak appeared at approximately 0.5 V. The shifting of the peak potential at the pH range of 6.0–8.4 showed the involvement of protons in the ascorbic acid oxidation. Moreover, the shifting of the peak potential with scan rate in the range of 0.07–0.4 V/s confirmed that the oxidation reaction was irreversible. Under optimized conditions, the oxidative peak current showed linear dependence on the ascorbic acid’s …

Investigating Channel Narrowing And Nonnative Vegetation Encroachment In Three Dryland Rivers, Casey Pennock, Benjamin Miller, Phaedra Budy

Browse all Datasets

Water development and the proliferation of invasive riparian vegetation has led to widespread habitat loss and simplification of rivers in the western United States, contributing to the imperilment of native fishes. Here, we quantify channel narrowing and vegetation encroachment, which are conspicuous indicators of riverine habitat degradation, along approximately 400 km of three dryland tributaries of the upper Colorado River. To accomplish this, we conducted a comparative analysis of aerial photographs from historical (1930s) and contemporary (2010s or 2020s) time periods and utilized Light Detection and Ranging (LiDAR) data and Object-Based Image Analysis (OBIA) to determine contemporary canopy cover of …

Size Limits And Fission Channels Of Doubly Charged Noble Gas Clusters, Ianessa Stromberg, Stefan Bergmeister, Lisa Ganner, Fabio Zappa, Paul Scheier, Olof Echt, Elisabeth Gruber

Faculty Publications

Small, highly charged liquid droplets are unstable with respect to spontaneous charge separation when their size drops below the Rayleigh limit or, in other words, their fissility parameter X exceeds the value 1. The absence of small doubly charged atomic cluster ions in mass spectra below an element-specific appearance size n_a has sometimes been attributed to the onset of barrierless fission at X = 1. However, more realistic models suggest that n_a marks the size below which the rate of fission surpasses that of competing dissociative channels, and the Rayleigh limit of doubly charged van der Waals clusters …

Preserving Linguistic Diversity In The Digital Age: A Scalable Model For Cultural Heritage Continuity, James Hutson, Pace Ellsworth, Matt Ellsworth

Faculty Scholarship

In the face of the rapid erosion of both tangible and intangible cultural heritage globally, the urgency for effective, wide-ranging preservation methods has never been greater. Traditional approaches in cultural preservation often focus narrowly on specific niches, overlooking the broader cultural tapestry, particularly the preservation of everyday cultural elements. This article addresses this critical gap by advocating for a comprehensive, scalable model for cultural preservation that leverages machine learning and big data analytics. This model aims to document and archive a diverse range of cultural artifacts, encompassing both extraordinary and mundane aspects of heritage. A central issue highlighted in the …

Data Supporting Research On Personalized Learning Paths, Sean Mochocki, Mark Reith

Faculty Publications

Personalized Learning Paths (PLPs) are a key application of Artificial Intelligence in E-Learning. In contrast to regular Learning Paths, they return a unique sequence of learning materials identified as meeting the individual needs of the students. In the literature, PLPs are often created from knowledge graphs, which assist with ordering topics and their associated learning materials. Knowledge graphs are typically directed and acyclic, to capture prerequisite relationships between topics, though they can also have bidirectional edges when these prerequisite relationships are not necessary. This data package provides a primarily un-directed knowledge graph, with associated repository of open-source learning materials that …

Efficient Removal Of Chemical Organic Demand And Total Organic Carbon From Leachate Using Heterogeneous Fenton Catalyst Based On Activated Carbon, Amar Idir, Mounir Ziati, Mohamed Bouzid

Emirates Journal for Engineering Research

Organic components contained in leachates resulting from decomposition of waste are difficult to degrade. Leachate volume and its composition vary depending on biogeochemistry of site type of deposited residues, and the age of sanitary landfill. The present study aims to develop efficient heterogeneous Fenton oxidation of organic matter, expressed in terms of chemical organic demand (COD) and total organic carbon (TOC) of leachate using the newly synthesized iron-modified activated carbon. The characterization of catalyst revealed that the Fe(II) was successfully introduced onto the original activated carbon (AC) and diversified the material’s surface morphology and elemental compounds. The heterogeneous Fenton oxidation …

A Cohomological Perspective To Nonlocal Operators, Nicholas White

Honors Theses

Nonlocal models have experienced a large period of growth in recent years. In particular, nonlocal models centered around a finite horizon have been the subject of many novel results. In this work we consider three nonlocal operators defined via a finite horizon: a weighted averaging operator in one dimension, an averaging differential operator, and the truncated Riesz fractional gradient. We primarily explore the kernel of each of these operators when we restrict to open sets. We discuss how the topological structure of the domain can give insight into the behavior of these operators, and more specifically the structure of their …

New Ways To Improve Dispersibility Of Nanotubes: Approaching From The Formation Of Silicon Nanoparticles By High Energy Reactive Ball Milling (Herbm) In Polar Solvents, Julie P. Vanegas, Yolanda V. Gutierrez, Joaquin Rivera, Juan García Jr.

Research Symposium

Background: This research aims to synthesize stable silicon nanoparticles using different molar ratios of N-Cyclohexyl-2-pyrrolidone (CHP) and Silicon to demonstrate if there is any significance towards the production of effective nanotubes. To determine this, the synthesized nanoparticles will be characterized by scanning electron microscopy (SEM), UV visible absorption spectroscopy, and photoluminescence spectroscopy (PL).

Methods: 50 Mg of silicon wafer are added with differing ratios of ligand (CHP), 5mL of water, and 3 steel iron balls into a ball milling vial. Vials are then placed into a ball milling apparatus for 7 cycles or 3.5 hours. Once the cycles are complete, …

Mathematically Modeling How Trapping Regimes That Target Specific Crayfish Life Stages Impact Removal Efficacy, Rini Pattison

Seaver College Research And Scholarly Achievement Symposium

The red swamp crayfish, Procambarus clarkii, is an invasive species introduced into several streams within the Santa Monica Mountains (SMM) in Southern California. Crayfish predation decimates native aquatic species. Thus, the Mountains Restoration Trust (MRT) and Environmental Restoration Group have worked to remove crayfish through regular trapping in Malibu Creek.

To aid conservation efforts, former SURB students William Milligan and Dev Patel developed mathematical models of crayfish removal efficacy. Milligan created a differential equation model of how crayfish removal affects local newt populations. Patel expanded Milligan’s crayfish model by creating a discrete model of the crayfish life cycle that newly …

Poleward Moving Auroral Forms And Magnetic Reconnection, Gasia Excel, Gerard Fasel, Julia Johnson, Jordana Xu, Parker Para, Amiel Silbol, Rachel Rodriguez, John Mann

Seaver College Research And Scholarly Achievement Symposium

Magnetic reconnection on the dayside magnetosphere is one of the main mechanisms for the solar wind to transfer energy and momentum to the terrestrial environment. This process is assumed to be most effective when the interplanetary magnetic field (IMF) is southward. Poleward moving auroral forms (PMAFs) have been identified in past studies as ionospheric signatures of magnetic reconnection on the dayside. The PMAFs occurring for the positive/(negative) IMF y-component first expanded westward(dawn)/eastward(dusk) before propagating poleward. This PMAF study presents a comprehensive set of events where the initial brightening moves through a pre-existing dayside auroral arc westward(dawn)/eastward(dusk) when the IMF y-component …

Dayside Pulsating Diffuse Aurora And The Interplanetary Magnetic Field, Thomas Lewer, Gerard J. Fasel, Maxwell Fargo, Ethan Swonger, S. Lee, Aidan Hulbert, Owen Bradley, Arman Manookian, Tommy Cleaveland, B. Yonano, John Mann, F. Sigernes, D. Lorentzen

Seaver College Research And Scholarly Achievement Symposium

Changes in the interplanetary magnetic field (IMF) orientation can affect pulsations in the dayside aurora. It has been reported that multiple dayside arcs(Pc 5 band) were replaced by diffuse pulsating aurora (Pc 3-4 band) when the IMF turned northward. Dayside green (557.7 nm emission) pulsating aurora had been reported to occur between 0800 and 1100 MLT (0500-0800 UT) in patches. The pulsations are normally associated with Pc 3-5 range. This statistical study examines pulsating green aurora using ground-based optical data are obtained from the Kjell Henriksen Observatory (KHO) in Longyearbyen, Svalbard (GEO: N, E; AACGM: N, E). All-Sky Camera images …

X-Currents And Extreme Brightening Events, Abrielle Tio An Mei Wang, Gerard J. Fasel, Audrey Daucher, Makena Swenski, Andrea Black, John Mann, Maame Osei-Tutu

Seaver College Research And Scholarly Achievement Symposium

The solar-terrestrial interaction is a dynamic process which manifests itself in the ionosphere. Interplanetary (IP) shocks or solar wind dynamic pressure pulses can generate enhanced brightening in dayside aurora. Foreshock transients are capable of inducing pressure changes, larger in magnitude than solar wind pressure pulses, which also contribute to intensifying dayside aurora. These pressure variations can accelerate particles into the ionosphere, generating field- aligned currents that produce magnetic impulse events and enhanced dayside auroral activity with periods of increased brightening. This study presents several dayside auroral brightening events which are not associated with IP shocks or solar wind dynamic pressure …

Coomassie Brilliant Blue Dye As A Method For Analyzing Fracture Markings In Bone, Abigail Hoffmeister, David Harutunyan, Matthew Aizawa, Everett Baker, Brandon Mendoza, Chase Freeman, Siran Iskanian

Seaver College Research And Scholarly Achievement Symposium

Coomassie Brilliant Blue Dye is a dye commonly used to stain proteins. Because of its ability to adhere to proteins, this research has focused on perfecting a method of dyeing a fractured flat bone in order to most accurately observe and analyze fracture markings within the trabecular layer. Stereoscopic microscopy was the chosen technique of analysis for this research because of its proven effectiveness in glass and ceramic fractography to observe varying depths. In order to most effectively apply stereoscopic microscopy to this research, the following variables were manipulated to maximize color contrast in the trabecular layer in order to …

Deep Learning Can Be Used To Classify And Segment Plant Cell Types In Xylem Tissue, Reem Al Dabagh, Benjamin Shin, Sean Wu, Fabien Scalzo, Helen Holmlund, Jessica Lee, Chris Ghim, Samuel Fitzgerald, Marinna Grijalva

Seaver College Research And Scholarly Achievement Symposium

Studies of plant anatomical traits are essential for understanding plant physiological adaptations to stressful environments. For example, shrubs in the chaparral ecosystem of southern California have adapted various xylem anatomical traits that help them survive drought and freezing. Previous studies have shown that xylem conduits with a narrow diameter allows certain chaparral shrub species to survive temperatures as low as -12 C. Other studies have shown that increased cell wall thickness of fibers surrounding xylem vessels improves resistance to water stress-induced embolism formation. Historically, these studies on xylem anatomical traits have relied on hand measurements of cells in light micrographs, …

Historical Perspectives In Volatility Forecasting Methods With Machine Learning, Zhiang Qiu, Clemens Kownatzki, Fabien Scalzo, Eun Sang Cha

Seaver College Research And Scholarly Achievement Symposium

Volatility forecasting in the financial market plays a pivotal role across a spectrum of disciplines, such as risk management, option pricing, and market making. However, volatility forecasting is challenging because volatility can only be estimated, and different factors influence volatility, ranging from macroeconomic indicators to investor sentiments. While recent works suggest advances in machine learning and artificial intelligence for volatility forecasting, a comprehensive benchmark of current statistical and learning-based methods for such purposes is lacking. Thus, this paper aims to provide a comprehensive survey of the historical evolution of volatility forecasting with a comparative benchmark of key landmark models. We …

Machine Learning Prediction Of Photoluminescence In Mos2: Challenges In Data Acquisition And A Solution Via Improved Crystal Synthesis, Ethan Swonger, John Mann, Jared Horstmann, Daniel Yang

Seaver College Research And Scholarly Achievement Symposium

Transition metal dichalcogenides (TMDCs) like molybdenum disulfide (MoS2) possess unique electronic and optical properties, making them promising materials for nanotechnology. Photoluminescence (PL) is a key indicator of MoS2 crystal quality. This study aimed to develop a machine-learning model capable of predicting the peak PL wavelength of single MoS2 crystals based on micrograph analysis. Our limited ability to consistently synthesize high-quality MoS2 crystals hampered our ability to create a large set of training data. The project focus shifted towards improving MoS2 crystal synthesis to generate improved training data. We implemented a novel approach utilizing low-pressure chemical vapor deposition (LPCVD) combined with …

Mechanistic Investigation Of C—C Bond Activation Of Phosphaalkynes With Pt(0) Complexes, Roberto M. Escobar, Abdurrahman C. Ateşin, Christian Müller, William D. Jones, Tülay Ateşin

Research Symposium

Carbon–carbon (C–C) bond activation has gained increased attention as a direct method for the synthesis of pharmaceuticals. Due to the thermodynamic stability and kinetic inaccessibility of the C–C bonds, however, activation of C–C bonds by homogeneous transition-metal catalysts under mild homogeneous conditions is still a challenge. Most of the systems in which the activation occurs either have aromatization or relief of ring strain as the primary driving force. The activation of unstrained C–C bonds of phosphaalkynes does not have this advantage. This study employs Density Functional Theory (DFT) calculations to elucidate Pt(0)-mediated C–CP bond activation mechanisms in phosphaalkynes. Investigating the …

La1-Xsrxcoo3 Perovskite Nanomaterial: Synthesis, Characterization, And Its Biomedical Application, Adhira Tippur, Anyet Shohag, Luke Franco, Ahmed Touhami, Swati Mohan, Mohammed Uddin

Research Symposium

Early cancer detection is paramount for effective treatment and potential cures. This research explores the application of perovskite materials, specifically Sr2+-doped Lanthanum Cobaltite (La1-xSrxCoO3) nanomaterials, in cancer detection, with a focus on rats as an experimental model. The ferroelectric nature of these materials, synthesized through a combination of sol-gel and molten-salt processes, was examined at varying Sr2+ doping levels (1-20 wt%). Rigorous characterization, employing X-ray diffraction and scanning electron microscopy, confirmed the uniform morphology of nano cubes, laying the foundation for subsequent investigations. The magnetic properties of the perovskite nanoparticles were probed, suggesting their potential as a diagnostic tool for …

High Energy Approximation For Monte Carlo Event Generator, A. N. Ismailova, Yu. L. Parfenova, P. G. Sharov, D. M. Janseitov

Eurasian Journal of Physics and Functional Materials

Analysis of the nuclear physics experiment often requires Monte Carlo simulation of the detector setup. Such kind of simulations often requires a quite advanced model of nuclear interaction. In this work we describe application of Monte Carlo simulation in the nuclear physic experiment, and discuss on example of elastic scattering how to apply well known High Energy Approximation (or Glauber model) to Monte Carlo simulation of the experimental setup.

Determination Of Phase Boundaries And Diffusion Coefficients Of Copper In Spinel Cucr2se4 And Delafossite Cucrse2 By Galvanostatic Intermittent Titration Technique (Gitt), A. O. Onishenko, E. A. Suslov, M. S. Postnikov, A. S. Shkvarin, A. N. Titov, A. I. Merentsov

Eurasian Journal of Physics and Functional Materials

Cux CrSe2 materials can exist in the form of delafossite with a layered structure and exhibit multiferroic properties, or in the form of spinel and exhibit ferromagnetic properties, depending on the copper concentration. The stability of both forms of Cux CrSe2 has been studied with regards to defectivity in the copper sublattice. The boundaries of the Cux CrSe2 homogeneity regions for the delafossite- like structure and for the cubic spinel CuCr2Se4 were determined by coulometric titration at room temperature. Analysis of the time dependence of cell polarization allowed us to estimate the diffusion coefficients in these materials

Study Of The Effect Of Combined Reinforcement And Modification Of Epoxy Resin With Rubbers On The Impact Strength Of Carbon Fiber-Reinforced Plastic, M. N. Meiirbekov, M. B. Ismailov, A. K. Kenzhegulov, L. M. Mustafa, I. B. Tashmukhanbetova

Eurasian Journal of Physics and Functional Materials

The effect of modified epoxy resin with polyurethane, silicone, and butadiene rubber and combined reinforcement with fiberglass and Kevlar on the strength properties of carbon fiber-reinforced plastic was studied. It was found that when rubber is introduced into the composition of the epoxy resin, polyurethane, and combined reinforcement according to the carbon fiber/Kevlar scheme in a ratio of 10:10 leads to an increase in impact strength by 42% to 273 kJ/m2 and compressive strength increases by 35% to 575 MPa

Luminescence And Creation Of Electron-Hole Trapping Centers In Alkali Metal Sulfates Activated By Pb2+ Impurity, T. N. Nurakhmetov, R. K. Shamieva, Zh. M. Salikhodzha, N. I. Temirkulova, T. T. Alibay, B. M. Sadykova, B. N. Yussupbekova, A. A. Kabdulkak

Eurasian Journal of Physics and Functional Materials

The nature of the impurity emission and the process of creating intrinsic and impurity electron-hole trapping centers were studied by spectroscopic and thermal activation methods in Na2SO4 - Pb and K2SO4 - Pb phosphors. The combined radiative electronic state is formed from intrinsic SO3− 4 - SO− 4 and impurity Pb+ - SO− 4 electron-hole trapping centers in UV-irradiated phosphors with a photon en- ergy of 6.2 eV at 80 K. Emissions of 3.2 eV and 3.6 eV resulting from irradiation with photons with an energy of 6.2 eV are associated with intracenter transitions of 3p1 - 1s0 in Pb2+ …

Concentration Polarization And Ionic Conductivity Of Nanocomposite Thermoelectric Materials K0.01cu1.94s, K0.02cu1.94s, K0.03cu1.94s, M. M. Kubenova, M. Kh. Balapanov, K. A. Kuterbekov, B. Akhmetgaliev, R. Kh. Ishembetov, R. F. Almukhametov, M. Zeleev, A. M. Kabyshev, K. Zh. Bekmyrza, R. Alina, R. E. Kondakirov, M. K. Kenzhebek

Eurasian Journal of Physics and Functional Materials

The paper presents experimental results of concentration polarization and ionic conductivity of nanocom- posite thermoelectric materials K0.01Cu1.94S , K0.02Cu1.94S , K0.03Cu1.94S . According to X-ray phase analysis, the synthesized samples are monoclinic jarleite Cu1.93÷1.97S with an admixture of oxygen ox- ide Cu2S and monoclinic chalcocyte. High values of total ionic conductivity are observed, ranging from 0.86 to 1.5 Cm/cm. The lowest ionic conductivity (0.86 Cm/cm at 355 ◦ C) is observed for alloy K0.02Cu1.94S . In addition, it was found that with an increase in the concentration of potassium in the studied materials, ionic conductivity tends to decrease, activation energy …

Where East Meets West: Phylogeography Of The High Arctic North American Brant Goose, Robert E. Wilson, W. Sean Boyd, Sarah A. Sonsthagen, David H. Ward, Preben Clausen, Kathryn M. Dickson, Barwolt S. Ebbinge, Gudmundur A. Gudmundsson, George K. Sage, Jolene R. Rearick, Dirk V. Derksen, Sandra L. Talbot

School of Natural Resources: Faculty Publications

Genetic variation in Arctic species is often influenced by vicariance during the Pleistocene, as ice sheets fragmented the landscape and displaced populations to low-and high-latitude refugia. The formation of secondary contact or suture zones during periods of ice sheet retraction has important consequences on genetic diversity by facilitating genetic connectivity between formerly isolated populations. Brant geese (Branta bernicla) are a maritime migratory waterfowl (Anseriformes) species that almost exclusively uses coastal habitats. Within North America, brant geese are characterized by two phenotypically distinct subspecies that utilize disjunct breeding and wintering areas in the northern Pacific and Atlantic. In the …

Embedding Information Literacy Practices In An Upper Division Chemistry Lab Class At A University In The United States Of America, Christopher Randles, Matilynn Lamm, Katy A. Miller

Faculty Scholarship and Creative Works

This poster discusses the implementation of information literacy into an upper division inorganic chemistry lab and the strategies employed to develop students’ information literacy in the laboratory course.

Butte Priority Soils Operable Unit Grove Gulch Sedimentation Bay 100% Remedial Design, Josh Bryson

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

The Impact Of Data Preparation And Model Complexity On The Natural Language Classification Of Chinese News Headlines, Torrey J. Wagner, Dennis Guhl, Brent T. Langhals

Faculty Publications

Given the emergence of China as a political and economic power in the 21st century, there is increased interest in analyzing Chinese news articles to better understand developing trends in China. Because of the volume of the material, automating the categorization of Chinese-language news articles by headline text or titles can be an effective way to sort the articles into categories for efficient review. A 383,000-headline dataset labeled with 15 categories from the Toutiao website was evaluated via natural language processing to predict topic categories. The influence of six data preparation variations on the predictive accuracy of four algorithms was …

Ex-Vivo Hippocampus Segmentation Using Diffusion-Weighted Mri, Haoteng Tang, Siyuan Dai, Eric M. Zou, Guodong Liu, Ryan Ahearn, Ryan Krafty, Michel Modo, Liang Zhan

Computer Science Faculty Publications and Presentations

The hippocampus is a crucial brain structure involved in memory formation, spatial navigation, emotional regulation, and learning. An accurate MRI image segmentation of the human hippocampus plays an important role in multiple neuro-imaging research and clinical practice, such as diagnosing neurological diseases and guiding surgical interventions. While most hippocampus segmentation studies focus on using T1-weighted or T2-weighted MRI scans, we explore the use of diffusion-weighted MRI (dMRI), which offers unique insights into the microstructural properties of the hippocampus. Particularly, we utilize various anisotropy measures derived from diffusion MRI (dMRI), including fractional anisotropy, mean diffusivity, axial diffusivity, and radial diffusivity, for …

Birkhoff Summation Of Irrational Rotations: A Surprising Result For The Golden Mean, Heather Moore

University Honors Theses

This thesis presents a surprising result that the difference in a certain sums of constant rotations by the golden mean approaches exactly 1/5. Specifically, we focus on the Birkhoff sums of these rotations, with the number of terms equal to squared Fibonacci numbers. The proof relies on the properties of continued fraction approximants, Vajda's identity and the explicit formula for the Fibonacci numbers.

Spectroscopic End Point Detection With An Electron Beam Evaporator, Ryan Mcgraw

University Honors Theses

Spectroscopic end point detection is a common tool used for measuring slope changes in wavelength intensity. Using algorithms able to apply this concept, coatings will be able to be dynamically measured in real time and stopped at the appropriate level to ensure process uniformity. It is currently applied to reductive processes such as etching, where the surface will start to be eaten away, creating a plasma. When the entire amount of a material on a substrate has been eaten away, the plasma will change color as it is beginning to etch a different material. Using a spectrometer, this point where …