Physical Sciences and Mathematics Commons^™

Gas Chromatography Of Hydrogen-Deuterium Mixtures, Paul Payson Hunt

Doctoral Dissertations

Introduction: In recent years the gas chromatographic method has found widespread applications, chiefly for analytical purposes. This method is principally employed for the separation, identification, and quantitative determination of volatile compounds. It is potentially of great value for the quantitative determination of mixtures of the hydrogen isotopes. The development of a rapid, convenient, and inexpensive method for the analysis of the hydrogen isotopes would be a valuable addition to many laboratories, especially those where a mass spectrograph is unavailable. This problem was undertaken in an attempt to develop further the chromatographic method for the separation and quantitative determination of hydrogen …

The Chelation Of Cu(Ii) With 1, 3-Bis(Tris(Hydroxymethyl)Methylamino)-2-Propanol And 1, 3-Bis (2-Hydroxyethylamino)-2-Propanol, David Andrew Jackson Jr.

Master's Theses

The chelating agent 1, 3-bis(2-hydroxyethylamino)-2-propanol dihydro­chloride was prepared and preliminary examinations of the Cu(ll) and Fe(lll) complexes were carried out spectrophotometrically. This dihydrochloride as well as 1, 3 bis(tris(hydroxymethyl)methylamino)-2-propanol dihydrochloride. were converted from the chloride salts to their corresponding ammonium bases. The conversion was carried out by passing an aqueous solution of each chloride salt through an ion exchange column containing Amberlite XE-78 resin.

Solutions of these bases were standardized for use in potentiometric titration&. Each ammonium base was titrated with standard perchloric acid at 20°C, 30°C, and 40°C. The dissociation constants. were calculated using these data. Aqueous solutions of …

Preparation Of Elemental Boron And Measurement Of Its Emittance At Incandescent Temperatures, Claude P. Talley

Master's Theses

The normal spectral emittance at 0. 65 microns of elemental boron specimens was measured at incandescent temperatures by the hollow-tube method, This was made possible by depositing boron onto thin-walled hollow tubes of graphite and molybdenum. An approximate value of the total hemispherical emittance for boron was also obtained. The deposition of boron was accomplished by chemical vapor plating with boron tribromide and hydrogen. The boron produced was characterized in several ways.

The Development Of Nickel Electrodeposits On Copper Monocrystals As Studied With The Electron Microscope, Lucille Burnett Garmon

Master's Theses

Important theoretical and experimental developments in the field of electrocrystallization on single crystals are briefly reviewed and new data presented. The deposition of nickel from a Watts-type bath onto electrolytically polished mono crystals of copper is the system chosen for study. Various aspects of the structural changes in the deposit with increasing thickness are considered. The electron microscope is the main tool employed and the deposit is studied by detaching it from the basis metal as well as by the use of surface replicas. Short backgrounds in crystallography and electron microscopy are included.

A Chromatographic Study Of The Polyphenols In Cured Tobacco, Marvin Dennis Edmonds

Master's Theses

The object of this project was to isolate, separate, and identify the polyphenols in tobacco. Following this, the aim was to develop a method for the quantitative determination of the major polyphenols in tobacco.

Existing methods for the determination of polyphenols in tobacco involve lengthy procedures which are concerned with one or two of the polyphenols rather than the· complete class of compounds. The methods consist of exhaustive extraction procedures, lengthy chromatographic procedures and numerous methods of identification.

Extensive research on the determination of polyphenols by chromatography has been carried out in the field of tobacco and in other fields. …

3-Amino-2,5-Dihydroxy-5-Sulfo-Benzoic Acid, Hideo Tomomatsu

University of the Pacific Theses and Dissertations

It seems possible that efforts to discover essential chemical differences which might exist between normal and malignant cells will eventually reveal the secret of cancer and thereby lead to new approaches to safer and more selective chemotherapy.

One objective of this study is to find that part of this molecule that causes it to concentrate in the tumor and thence make a smaller size compound which has similar concentration characteristics to tumor as tetracycline. For this purpose, an attempt was made in this study to synthesize the right side ring of Chlorotetracycline, the structure of which is shown below. [see …

Feeding Pickled Wheat To Pigs, Department Of Agriculture, Western Australia

Journal of the Department of Agriculture, Western Australia, Series 4

INQUIRIES are frequently received from farmers asking whether it is safe to feed pickled wheat to pigs, and if so, the quantities which would be suggested.

Until very recently there was no experimental information on the safety or possible dangers of these wheat pickling agents, but feeding trials completed last year at the Animal Health and Nutrition Laboratory, Nedlands, have provided some of the answers to these questions.

Weed Research. 7. Weed Control Around The Yard, Geoffrey A. Pearce

Journal of the Department of Agriculture, Western Australia, Series 4

MANY farmers and city householders have weed problems around houses and sheds which can be readily overcome by treatment with appropriate herbicides.

The risk from fire through weeds and unslightly growth can easily be removed and an area free of any plant growth can be maintained with little effort for a considerable period.

Some Results With Nitrogen Fertiliser On Cereals At Esperance Plain Research Station, William John Toms

Journal of the Department of Agriculture, Western Australia, Series 4

ON newly-cleared land at Esperance Plain Research Station the use of sulphate of ammonia on cereals has proved profitable over a number of seasons.

The response to sulphate of ammonia varies markedly with the season.

Oxygen Permeability Of Free Paint Films, Janice I. Kellerman

Masters Theses

"As early as the mid 1800’s investigations were performed on the gas passage through rubber, but it is only comparatively recently that plastic polymeric materials have come into prominence. One interesting aspect of much experimentation begun was that of permeability, and it was soon evident that, in general, polymeric materials have extremely low permeability of gases. This is, in essence, the basis for use of plastics as packaging materials, balloons, and in many other designs and fabrications where it is desirous and/or necessary to exclude air.

There are several variables which must be taken into consideration in the evaluation of …

Tetracycline-7-Boronic Acid, William Denham Rhoads

University of the Pacific Theses and Dissertations

The objective of this study is the preparation of a tetracycline-boron-10 derivative which is stable under biological conditions. The boron-10 should then provide a concentration of material capable of accepting thermal neutrons, thus producing localized high-energy alpha radiation. The fact that the tetracyclines are not retained by normal tissue should remove the danger of destruction of this tissue.

Preparation And Ultra-Violet Absorption Studies Of Leucocyanides Of The Triarylmethane Dyes, Arthur Katzakian Jr.

University of the Pacific Theses and Dissertations

No abstract provided.

List Of Registered Fertilisers : 1959-60, H G. Cariss

Journal of the Department of Agriculture, Western Australia, Series 4

TN accordance with the provisions of the Fertilisers Act, 1928-1955, it is required that—with the exception of bulk sales to a manufacturer and those made in accordance with a buyer's written prescription—all fertilisers sold are required to be registered annually, the registration year being from November 1 to October 31 following.

The list of fertilisers registered for the year commencing November 1, 1959, is set out herewith in tabular form.

The Dielectric Strength Of Some Anti-Corrosive Paints, John Harvey Gustafson

Masters Theses

"Metals undergo chemical reaction with nonmetallic elements of their surroundings to produce compounds which are either oxides or salts. These corrosion products, as they are called, may accelerate, impede, or have no influence on the course of further corrosion. It is unfortunate that iron, the metal of greatest use to man, receives very little protection from its corrosion products. There are no easy or inexpensive means of prevention of this corrosion and at best the reactions can only be controlled. One method of control is the use of anti-corrosive paints. Their protection is produced by placing an inert, continuous, and …

Spectroscopic Studies Of Metal-Cyanide Complexes, Roy L. Mccullough

Chemistry and Chemical Biology ETDs

Part 1: Infrared and Visible Absorption Studies of Cyanide Complexes of Ni(II) in Aqueous Solution

Part 2: An Analysis of the Infrared Vibrational Spectra of the Tetracyanonickelate(II) Ion in the Solid State

In this work, further evidence has been collected establishing the existence of a new ionic species in solutions of sodium tetracyanonickelate(II) and sodium cyanide. Contrary to the literature, however, this work shows that the species is [Ni(CN)₅]^-3 rather than [Ni(CN)₆]^-4.

Studies Of Surface Films Formed By Adsorption Of Polar Organic Molecules On Activated Metal Surfaces, Roy Leo Bennett

Doctoral Dissertations

The investigation of adsorption has been a valuable aid in under­ standing the properties of metal surfaces. The surface of a metal differs from the interior of the material due to unsatisfied valence forces which impart an affinity for adsorbed materials. This high sur­face energy is illustrated by the fact that when two clean metal sur­faces are placed in contact, that is, when there is no intervening adsorbed film, cold welding results. The resulting bond is equivalent to the bonding in the rest of the metal. This has been demonstrated by Bowden and Young,l who showed that mere contact of …

Colorado "Rush To The Rockies Centennial" Spectroscopy Conference

Rocky Mountain Conference on Magnetic Resonance

Program from the Colorado "Rush to the Rockies Centennial" Spectroscopy Conference, sponsored by the Rocky Mountain Spectroscopy Society. Held in Denver, Colorado, August 10-11, 1959.

An In Situ Method For Alteration Of Catalytic Activity By Generation Of A Reactant On The Surface Of The Catalyst, Clyde Dunn Alley

Doctoral Dissertations

In many researches dealing with catalysis there are properties of the catalyst that are attributed to the effect of hydrogen on the surface of the catalyst. The interpretations of the effect of hydrogen on the catalyst surface range from statements which indicate that surface hydrogen is necessary for the reactions to proceed to statements that surface hydrogen is a poison on the reaction. A clearly interpreted picture of the role of hydrogen at the present time is not available.

Rearrangements Of The Benzilic Acid Type; Preparation And Use Of Dialkali Metal Adducts Of Aromatic Ketones., Stanley Selman

Doctoral Dissertations

Introduction: The benzilic acid rearrangement is the base-catalyzed transformation of an α-diketone to the salt of an α-hydroxy acid. This rearrangement can be effected in aromatic, semi-aromatic (o-quinones), in alicyclic, and aliphatic, as well as in heterocyclic α-diketones. Examples of the rearrangement in the above type compounds are illustrated in equations 1-6.

The Cytochrome Composition Of Bacillus Subtilis And Bacillus Megaterium, John Harvey Mangum

Theses and Dissertations

A spectroscopic and enzymatic investigation of the cytochromes of B. megaterium and B. subtilis was conducted. Attempts were made to isolate and characterize the individual cytochromes as well as to determine the locale of such activities as cytochrome c oxidase, DPNH oxidase, succinic dehydrogenase, cytochrome c reductase and diaphorse. Only two methods proved effective in liberating the cytochromes; disruption of the cells with sonic osillations and grinding tlhe cells with alumina. These procedures caused a fragmentation of the cell membrane. It was found that the entire cytochrome complement of these two bacteria was bound intimately to particles which most likely …

Substituted Triphenyl Tetrazolium Chlorides, Lawrence Donald Hanback

Master's Theses

The work in this thesis is a continuation of a project started at the University of Richmond in 1952 by A. G. Richardson under the directorship of Dr. J. S. Pierce and Dr. George z.Williams, Director of Clinical Pathology, National Institutes of Health, Bethesda, Maryland.

The purpose of the research was to prepare triphenyl tetrazolium salts, substituted, particularly in the ortho and para positions, with various electron accepting and electron donating groups. It was hoped that these substitutions would impart enough differences in the properties of the compounds so as to allow d etection of certain biological reactions. The tetrazolium …

Part I: The Catalytic Hydrogenation Of Nitro Compounds Over Supported Rhodium In Acetic Acid; Part Ii: The Exchange Of Deuterium Gas And Methanol In The Presence Of Raney Nickel, Burch Byron Stewart

Doctoral Dissertations

An improved effusiometry apparatus for analyzing hydrogen and deuterium mixtures was constructed and utilized to study the exchange reaction of deuterium with methanol over Raney nickel catalyst.

The exchange reaction was zero order with respect to deuterium pressure and pseudo-zero order with respect to methanol concentration. The apparent activation energy was found to be 3.5 kcal./mole. The specific reaction rate was 2.9 1. mm. min.^-1 g.^-1.

The effects of nitro compounds upon the exchange of deuterium with methanol over Raney nickel were studied. All of the compounds decreased the exchange at very low concentrations and all, except …

Part I: A Study Of The Catalytic Hydrogenation Of Hydroxybenzenes Over Plantinum And Rhodium Catalysts; Part Ii: The Kinetics Of The Acid-Catalyzed Hydrolysis Of The Dimethyl Esters Of Cyclohexanedicarboxylic Acids, Billy Lee Stump

Doctoral Dissertations

Summary: The dimethyl esters of isometric 1,2-, 1,3-, and 1,4-cyclo-hexanedicarboxylic acids have been prepared and the rates of their acid catalyzed hydrolyses in 70 per cent acetone have been determined. All hydrolysis reactions wre run at four temperatures, 25°, 35°, 45°, and 55°. The rate constants for the hydrolyses at each of these temperatures, along with the activation energies for the reactions, have been tabulated in Table IV.

The rates of hydrolysis of the cis-1,3 and trans-1,4 diesters were found to be almost identical. Similarly, the reaction rates of the trans-1,3 and cis-1,4 diesters were found …

A Study Of The Volume Change During The Setting Of Silicic Acid Gel, Richard Joseph Miller

Honors Theses

An investigation of the volume change during the setting of silicic acid gel was made using a precision mercury dilatometer. The effects of varying the silicate and acid concentrations were studies. The heat of neutralization of the acetic acid and sodium silicate was compensated for to prevent any heat expansion in the gel. Also discussed are the theories of the setting of the gel.

Microscopic Radial Lines In Gels, Robert Peter Frosch

Honors Theses

There are many interesting formations which may be prepared in gels. Probably the best known are Liesegang rings, first prepared in the latter nineteenth century and observed previously in such naturally occurring materials as agate. Besides rings periodic radial structures have been observed in gelatin. Some of these radial formations are visible to the naked eye; others may be observed only under a microscope. It is one of the radial formations of the layer type which will be discussed in this paper. For want of a better name the formation to be discussed will simply be referred to as radial …

The Photogalvanic Effect, George Henry Hofmann

Honors Theses

The photogalvantic effect has been studied by relatively few people. Perhaps the largest contribution to the study of this effect has been by E. Rabinowitch while the Massachusetts Institute of Technology and terminated in 1940. At this time Rabinowitch indicated the possibilities in the utilization of solar energy by the photogalvantic effect (1). Presented here is a study of the effect using a modified form of the apparatus used by Rabinowitch. An attempt is made at explaining the results obtained, the advantages and disadvantages of the apparatus used and suggestions are given for improvement. A specific photogalvantic system of high …

Light Scattering By Silicic Acid Gel-Forming Mixtures, Bruce Monroe Manzer

Honors Theses

In this investigation the scattering of light by silicic acid gel-forming mixtures has been studied during the process of gel formation in an effort to extend the work already done on their structure and the mechanism of gel formation. The intensity of the scattered light has been measured by means of Fisher Nefluoro-photometer and an attempt has been made to use the results in explaining the change which the gel-forming mixtures undergo during gel formation.

Studies Of Reductions Of Unsaturated Compounds With Lithium Aluminum Hydride, Robert William Barito

Honors Theses

Our work has involved the reduction of certain alpha-beta unsaturated carbonyl compounds and the reduction of two compounds that did not contain alpha-beta unsaturated carbonyls.

Paper Chromatography Of The Dicarboxylic Acids And The Polyhydric Alcohols, Albert Esposito

Honors Theses

The objective of this work was to develop a paper chromato­graphic technique applicable to the separation and identification of the dicarboxylic acids and the polyhydric alcohols.

A Study Of Aluminum Phosphates Using Infrared Spectroscopy, Michael Miller

Honors Theses

The infrared spectra of aluminum metaphosphate, aluminum pyrophosphate, and the ortho acid phosphates were studies in the 2u to 15u region. The distinct absorption regions of each compound were located. The type of bond which caused the absorption is suggested. The spectra of the aluminum phosphates were found to be very similar to the spectra of other phosphates.