Physical Sciences and Mathematics Commons^™

The Internal Chemical Shift - A Key To Bonding In Aromatic Molecules. 2. Substituent Effects On The Carbon-13 Magnetic Resonance Spectra Of The 1,4-Disubstituted Benzenes, Donald W. Beistel, W. Dan Edwards

Chemistry Faculty Research & Creative Works

Carbon-13 magnetic resonance shifts were determined for six families of 1,4-disubstituted benzenes. Linear least-squares correlations between the internal shifts of the families suggest an additivity relationship for 13C substituent effects at all four nonidentical ring carbons and at the α position when one of the substituents has a central carbon. The correlation of 1H and 13C shifts for these compounds is also linear, implying that the additivity relationships derived in a previous 1H study can be generalized to 13C.

Planning A Kinetic And Mechanistic Study With Cerium (Iv), Samir B. Hanna, Robert R. Kessler, André Merbach, Steve Ruzicka

Chemistry Faculty Research & Creative Works

No abstract provided.

Comment On "Clustering Of Water On Hydrated Protons In A Supersonic Free Jet Expansion", James L. Kassner, Donald E. Hagen

Physics Faculty Research & Creative Works

No abstract provided.

Surface Electromagnetic Wave Mode And Field Analysis In A Metal-Metal-Oxide-Air System With Damping, C. A. Ward, Ralph William Alexander, Robert John Bell

Physics Faculty Research & Creative Works

An Explanation is Provided for the Surface Electromagnetic Wave (SEW) Energy Ejection from a Thin Film at the Longitudinal and Transverse Optical-Phonon Frequencies of the Film Material. Field Ratio Calculations Identify Previously Discussed Metal-Metal-Oxide-Air SEW Modes as Those Expected from the Berreman Configuration, and It is Shown that Greenler Technique High-Incidence-Angle-Reflectance Data on the Same System May Be Similarly Interpreted. © 1976 the American Physical Society.

The Magnification Factor For Sodium Chloride Liesegang Circles Established With An Aerosol Centrifuge, O. Preining, Josef Podzimek, P. Yue

Physics Faculty Research & Creative Works

Sodium chloride particles deposited on a gelatin film containing silver nitrate form in a humid environment clearly visible dark brown reaction spots (Liesegang circles) after development in u.v.-light. The size of these reaction spots depends on the mass of NaCl in the particles. To establish the spot size vs particle size relation, particles produced by nebulising NaCl-solutions and sea water were sampled in an aerosol centrifuge. The location of deposition yields the aerodynamic diameter of the particle, and the spot size is measured microscopically. In this way the spot size vs aerodynamic diameter relation is established experimentally in the so …

Areal Geology, Brecciation, And Mineralization In The Trout Creek Area, Park And Chaffee Counties, Colorado, Barry Plin Mercer

Masters Theses

"The principle purpose of this thesis research has been to map rock types in an area selected for its occurrence of lead-zinc mineralization, and particularly to examine the character and origin of breccias present in the Leadville Limestone. The thesis area is located in Colorado along the east flank of the southernmost Mosquito Range, bounded by Buffalo Peaks Volcanic field on the north and Trout Creek on the south. Units mapped include the Sawatch Quartzite (Cambrian), Manitou Limestone (lower Ordovician), Harding Sandstone (middle Ordovician), Fremont Limestone (upper Ordovician), Parting Quartzite (Devonian), Dyer Dolomite (Devonian), and Leadville Limestone (Mississippian). The Leadville …

Surface Electromagnetic Waves With Damping. I. Isotropic Media, G. S. Kovener, Ralph William Alexander, Robert John Bell

Physics Faculty Research & Creative Works

Surface-Electromagnetic-Wave Dispersion Curves Are Usually Calculated using a Simple Equation Derived from Maxwell's Equations and Boundary Conditions. When Complex Dielectric Functions Are Used for the Two Media, the Component of the Propagation Vector Along the Surface, Kx, Becomes Infinite as the Frequency Approaches the Surface Polariton Frequency Ωs If Ω is Considered Complex and Kx is Real. on the Other Hand, If Kx is Considered Complex and Ω Real, the Dispersion Curves Bend Back Toward Smaller Kx as Ω Approaches Ωs. We Have Previously Demonstrated that Both Types of Behavior Can Be Obtained from Attenuated-Total-Reflection Measurements of Silver. We Now …

Absorption In The Infrared Of Surface Electromagnetic Waves By Adsorbed Molecules On A Copper Surface, K. Bhasin, D. Bryan, Ralph William Alexander, Robert John Bell

Physics Faculty Research & Creative Works

Experimental Observations Have Been Made for the First Time that Surface Electromagnetic Wave (SEW) Spectroscopy Can Be Used to Measure the Infrared Spectra of Adsorbed Molecules and Very Thin Films on Metal Surfaces. using a Tunable CO2 Laser (9.2-10.8 Μm Wavelength), the 975 and the 1037 Cm-1 Resonances of 5-25 Å Thick Physiosorbed Benzene on Copper Were Observed. Broadening of These Resonances for the Thinnest Layers of Benzene Was Observed. Also SEW Spectroscopy and Ellipsometry Were Used to Study Thin Films of Cellulose Acetate (15-75 Å) on Copper. Further, It Was Shown that Film Thicknesses Determined by SEW Spectroscopy Are …

Radiative Lifetimes Of Some Group Ii Ions By The Hanle Effect In A Fast-Flowing Helium Afterglow, F. H.K. Rambow, Laird D. Schearer

Physics Faculty Research & Creative Works

Radiative lifetimes of the first P322 state of Mgu, Cau, Znu, Sru, Cdu, and Bau are reported as measured by the Hanle effect in a fast-flowing helium afterglow. They are, respectively, 3.65(0.12), 6.61(0.30), 2.4(0.3), 6.64(0.10), 2.86(0.25), 6.78(0.40) in units of 10-9 sec. The ions in the afterglow are created by Penning ionization of the neutral metal atoms, thus providing a steady-state, field-free region for observation. Comparisons are made with measurements by other methods, and discrepancies are discussed. © 1976 The American Physical Society.

The Martensite Transformation, Manfred Wuttig, Tetsuro Suzuki

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.

Note On Amorphous Magnetic Materials, Louis H. Lund

Physics Faculty Research & Creative Works

No abstract provided.

Numerical Simulation Of A Widely Used Cloud Nucleus Counter., Darryl J. Alofs, J. C. Carstens

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The Performance of the Conventional Horizontal Plate Thermal Diffusion Chamber as a Cloud Nucleus Counter Was Studied. Numerical Calculations Were Performed in Order to Follow the Simultaneous Drop Growth and Sedimentation in the Spatially and Temporally Nonuniform Supersaturation Field. the Effect of Nuclei Distribution and Smallest Detectable Drop Size Were Investigated. the Results Indicate Order of Magnitude Uncertainty in the Count at 0. 1% Supersaturation, and a Factor of 2 Uncertainty at 1. 0% Supersaturation.

Part I. Thermodynamic Acidities Of Substituted Phenylacetylenes. Part Ii. Mercury Accumulation In Trout Of Southern Missouri, Eric T. Lloyd

Masters Theses

"PART I: THERMODYNAMIC ACIDITIES OF SUBSTITUTED PHENYLACETYLENES The thermodynamic acidities (pKa) of phenylacetylene and several para substituted phenylacetylenes in methanol were determined at 25ºC. These acidity constants were determined using a quenching technique which involves converting the phenylacetylenic anion, present at equilibrium as sodium phenylacetylide, to the tritium labelled carbon acid. By liquid scintillation counting techniques, the concentration of the anion was determined and the pKa of the phenylacetylene compound calculated. The resulting pKa's are: p-nitrophenylacetylene, 17.98, p-bromophenylacetylene, 18.10, p-fluorophenylacetylene, 18.14, phenylacetylene, 18.50, and p-methylphenylacetylene, 18.60. The effect of a substituent in the para position on the relative acidities is …

Geology, Mineralogy, And Fluid Inclusion Geothermometry Of The El Paso Gold Mine, Cripple Creek, Colorado, Charles Albon Lane

Masters Theses

"The Cripple Creek district consists of a deeply- eroded, breccia-filled volcanic subsidence basin. Subsidence of the basin occurred along fissures formed by fracturing during the Laramide orogeny. The material filling the crater probably developed first as fissure flows. Erosion of the volcanics formed the material now filling the basin. Volcanic activity was accompanied by intrusion of numerous sills, dikes, and stocks of several different rock types into the breccia and surrounding granite, punctuated by occasional explosive activity. The majority of the mines in the district lie within the volcanic center; however, a few important ones, most notably the El Paso …

Computer Manpower In The United States - Supply And Demand, John Wesley Hamblen

Computer Science Faculty Research & Creative Works

At a time when new departments of computer science, data processing, information science, information systems, etc. are being created and existing departments are trying to grow and compete with more established disciplines for scarce resources, it seems imperative that we attempt to keep abreast of the needs of industry and government for the graduates of these programs. This need must be monitored and matched against the production of graduates at all appropriate levels. The author has assembled extensive data on the latter over the past eight years while at the Southern Regional Education Board in Atlanta, GA (USA) during the …

The P-Nitrobenzyl System. Iv. Base-Induced Transformations In P-Nitrobenzyl Chloride, Bromide, Iodide, Tosylate, And Sulfonium Salts, Samir B. Hanna, Paul H. Ruehle

Chemistry Faculty Research & Creative Works

No abstract provided.

Saturation Effects In A Tunable Coherent Near-Infrared Source, Israel L. Tyler, R. (Ralph) W. Alexander, R. (Robert) J. (John) Bell

Physics Faculty Research & Creative Works

A Saturation Effect in a Tunable Infrared Source Utilizing Four-Wave Parametric Conversion in Potassium Vapor is Reported and is Shown to Be the Result of Parasitic Oscillations. a Hundredfold Increase over Previously Attained Power Levels Has Been Affected Via Elimination of These Oscillations.

Radiative Lifetime Of The B ²Σˉ State Of Ch, Richard A. Anderson, Jerry Peacher, David M. Wilcox

Physics Faculty Research & Creative Works

The radiative lifetimes of the N'=3 to 15 rotational states of the v'=0 level of the B ²Σ^- state of CH were measured. Emission lines were observed to N'=15, but no lines above this rotational state were observed. This result agrees with previous studies. The lifetimes of all rotational states were between 300 and 400 ns. Previous measurements have indicated that the N'=15 level might have a lifetime as short as 100 ns.

High-Frequency Dielectric Measurements On Electro-Optic Single Crystals, J. R. Teague, R. R. Rice, Robert Gerson

Physics Faculty Research & Creative Works

A slotted line was used to measure the high-frequency dielectric constant and loss tangent of several electro-optic crystals useful for wide-band laser modulator applications. Dielectric measurements were made at 0.1, 0.3, 1.0, and 2.0 GHz.

Intrinsic Viscosity Of Stiff Dumbbells From Time Correlation Functions, Gerald Wilemski

Physics Faculty Research & Creative Works

The intrinsic viscosity of a suspension of stiff dumbbells is evaluated by a time correlation function method. The required moments of the internal coordinates are calculated directly from the diffusion equation, without explicit evaluation of the Green's function. For the rigid dumbbell, the correct high frequency limit is obtained, disposing of recent doubts over this possibility. The interplay of dumbbell stiffness and shearing frequency is also illustrated.

Energy And Angular Distribution Of Electrons Ejected From Helium By Fast Protons And Electrons: Theory And Experiment, Steven Trent Manson, Larry H. Toburen, Don H. Madison, Nikolaus Stolterfoht

Physics Faculty Research & Creative Works

A comprehensive study of the angular and energy distributions of electrons ejected in collisions of fast electrons and protons with He is presented. New experimental results for 300-keV, 1-MeV, and 5-MeV proton impact are reported along with theoretical results for 2-keV electron impact and 100-keV, 300-keV, 1-MeV, and 5-MeV proton impact. The theoretical results, based upon Born approximation with Hartree-Slater initial discrete and final continuum wave functions, show excellent agreement with experimental electron-impact results. Serious discrepancies are found between theory and experiment in the angular distribution of ejected electrons for forward angles for 100- and 300-keV proton impact; the discrepancies …

Some Comments On Correlation-Function Formulas For Polymer Intrinsic Viscosity, Walter H. Stockmayer, Gerald Wilemski, Hiromi Yamakawa, Genzo Tanaka

Physics Faculty Research & Creative Works

No abstract provided.

Binary Nucleation. I. Theory Applied To Water-Ethanol Vapors, Gerald Wilemski

Physics Faculty Research & Creative Works

A quantitative study of nucleation in vapor mixtures of ethanol and water near 273°C is presented. First, Reiss' theory of binary nucleation is reexamined. The theory is modified slightly in order to yield the proper limit for homogeneous nucleation in a one-component system. Moreover, a corrected expression for the equilibrium concentration of mixed clusters is derived. Calculations of the critical vapor activities needed to produce a visible condensate are presented and compared with the results of Flood's cloud chamber experiments. The agreement is only fair, but qualitative accord is found.

Binary Nucleation. Ii. Time Lags, Gerald Wilemski

Physics Faculty Research & Creative Works

The role of the time lag needed to attain steady state nucleation in binary vapors is discussed. Under appropriate conditions it is possible to obtain both a large predicted rate of binary nucleation and a large time lag. In this circumstance, homogeneous nucleation of the more concentrated component may be the predominant process. It is of obvious importance to the experimentalist to differentiate between these possibilities. Approximate formulas for the time lags are developed, and representative calculations for the ethanol-water system are reported.

Double Beta Decay Of ¹²⁸Te, Edward W. Hennecke, Oliver Manuel, Dwarka D. Sabu

Chemistry Faculty Research & Creative Works

The half-life of ¹²⁸Te relative to the half-life of ¹³⁰Te has been found to be t12128t12130=(1.59±0.05)×10³ by measurement of the ββ-decay products, ¹²⁸Xe and ¹³⁰Xe, in a geologically old (2.4×10⁹ yr) telluride ore. These results yield an upper limit on the lepton nonconservation parameter, η≤0.8×10^-4. RADIOACTIVITY ββ-decay ¹²⁸Te; measured T_1/2=1.5×1024 yr; deduced η≤0.8×10^-4. Detected excess ¹²⁸Xe in old Te ore.

Differential Cross Sections For Elastic And Inelastic Scattering Of 15-100-Kev Li⁺ By He, John T. Park, Victor Pol, James E. Lawler, Jacob M. George, Judith E. Aldag, John W. Parker, Jerry Peacher

Physics Faculty Research & Creative Works

Sets of energy-loss spectra for Li⁺ incident on He that were taken at a series of scattering angles were used to calculate differential cross sections. Differential cross sections are given for elastic scattering and for excitation of the He (n=2) states. The differential cross section is also given for excitation of states corresponding to a 60-eV energy loss. These inelastic differential cross sections exhibit maxima at scattering angles greater than zero. The velocity dependence of the cross sections can be compensated by displaying the elastic data in ρ-vs-τ plots and the inelastic data in ρ-vs-E^3/2θ plots. When …

Univalence Of Derivatives Of Functions Defined By Gap Power Series, S. M. Shah, S. Y. Trimble

Mathematics and Statistics Faculty Research & Creative Works

No abstract provided.

A Coefficient Inequality For Convex Univalent Functions, S. Y. Trimble

Mathematics and Statistics Faculty Research & Creative Works

A short proof of formula presented is given for normalized convex univalent functions. © 1975, American Mathematical Society.

On Functional Equations Related To Mielnik's Probability Spaces, C. F. Blakemore, Caslav V. Stanojevic

Mathematics and Statistics Faculty Research & Creative Works

It is shown that the method used by C. V. Stanojevic to obtain a characterization of inner product spaces in terms of a Mielnik probability space of dimension 2 does not admit a generalization to dimension n > 2. © 1975 American Mathematical Society.

Tertiary Welded Tuffs Of The Ryan Spring Area, Needle Range, Beaver County, Utah, Peter Carlyle Rauch

Masters Theses

"The Needle Range of southwestern Utah is composed of Paleozoic sediments overlain by a thick sequence of Tertiary volcanic rocks primarily of the welded tuff class. The area has undergone at least four stages of post-eruptive structural deformation. The most significant stage is that which formed the range by normal Basin and Range type faulting. The faults strike northwest and tilt the volcanic layers northeast.

The volcanic section is composed primarily of the Needles Range Formation (Oligocene) overlain by the Isom Formation and underlain by several flows and ash flows, one of which has been tentatively correlated to the Escalante …