Physical Sciences and Mathematics Commons^™

A Determination Of The Surface Tension Of Bismuth, Cadmium, Tin, And Lead, Edward Mckee Chandler

Masters Theses

"Various methods have been employed for the determination of surface tension including capillary rise, drop weight, maximum bubble pressure, sessile drops on flat surfaces, sessile bubbles formed underneath flat surfaces, and the shape of pendent drops. Each method is subject to characteristic advantages and disadvantages. Only two of these will be discussed. The method of maximum bubble pressure allows the formation of a fresh surface for every bubble but does not permit the study of a given sample over a period of time. The sessile drop in direct contrast, allows the observation of the same sample over any period of …

A Grazing Incidence Vacuum Grating Spectrograph For Far Ultra Violet Spectroscopy, Lawrey Huber Chapin

Masters Theses

"Spectroscopy, in the region of the far ultraviolet from 100 Angstroms to 1000 Angstroms, requires special equipment and techniques, inasmuch as these wavelengths are highly absorbed by air. Many gases have resonant frequencies corresponding to the wavelengths mentioned and hence absorption bands appear in the spectrograms obtained by using spectrographs for the visible region. One solution of the problem of obtaining data in this region is to construct a spectrograph from which all intervening gas molecules have been removed, thus eliminating the absorbing material. A vacuum of 10⁻⁴ mm. of mercury is necessary to reduce the absorption to a value …

The Reflection Coefficient At The Truncated Corner Of A Rectangular Wave Guide, John Raymond Barcroft

Masters Theses

"The term wave guide refers to a hollow conducting tube (usually of rectangular or circular cross section) filled with a dielectric (or vacuum) and used for the transmission of electromagnetic waves. We shall consider the guide to be bounded by a perfect conductor and to be filled with a lossless homogeneous isotropic dielectric (or vacuum). The electromagnetic wave in the guide must of course satisfy Maxwell's equation. It must also satisfy the boundary condition that there be no tangential component of electric field at the surface of the conductor. If the electromagnetic waves traveling along the guide meet a discontinuity …

An Ecological Study Of The Foraminifera Of Mason Inlet, North Carolina, Daniel N. Miller Jr.

Masters Theses

"Mason Inlet. North Carolina is a lagoonal marsh area with warm-temperate water, the salinity ranging from fresh to salt water. Nine collecting stations comprise an ecological gradient across the environment.

Forty-two species of foraminifera are recorded from the inlet, ranging in their affinities from brackish water to open-sea facies. Several extensions of range are recorded both northward and southward.

Substratum conditions apparently control the distribution of foraminifera within the inlet. Clean, fine sand provided the largest faunal populations. A depauperate assemblage was found in an inorganic, argillaceous substratum. The largest population of arenaceous forms was found at the channel through …

Geology Of The Crystal Mine, Hardin County, Illinois, John Amsden Emery

Masters Theses

"The study of the geology and mineralization of the Crystal Mine was undertaken at the suggestion of Mr. Dodson G. Gibson of the Crystal Fluorspar Company, who allowed access to the mine and its records for this purpose. The problem was to develop a system of prospecting the so-called bedded-replacement fluorspar deposits of Hardin County, Illinois. It is believed that an economically feasible method has been developed. This method involves not only the actual finding of fluorspar, but also serves as a guide in revealing structural trends suggestive of mineralization.

The fluorspar deposits of the Crystal Mine are representative of …

Ammonium And Alkylammonium Salts Of Carboxylic Acids As Characterizing Derivatives, Hal Gilbert Lankford

Masters Theses

"One of the methods widely used to establish the identity and purity of an organic compound is to prepare various derivatives, the properties of which have been reported in the literature. The object of this investigation was to prepare ammonium and alkylammonium salts of carboxylic acid and determine their utility as characterization derivatives. Should these salts meet the requirements of a satisfactory derivative, they would be particularly valuable from a standpoint time, since they are generally very quickly formed"--Introduction, page 1.

A Determination Of The Surface Tension Of Tin In The Solid State, Charles Merton Rice

Masters Theses

"Many studies have been made on the surface tension of metals but almost exclusively in the liquid state. Information on metals in the solid state is needed in pure physics to test theories of cohesion and in physical metallurgy to explain sintering. The common approach to the problem of surface tension in the solid state is to hang a weight on a thin wire or leaf of metal and then heat this weighted sample to a temperature at which flow is appreciable. The shrinkage or stretch of the sample is then a measure of the surface tension. Of the recent …

Plateau Characteristics Of Geiger Counters With Respect To Different Gas Mixtures And Pressures, Ralph E. Lee

Masters Theses

"The section of a Geiger Counter is characterized by the so-called plateau curve. In this curve the counting rate of a given counter is plotted as a function of voltage, when the gas which it contains and the radiation to which it is exposed are both kept the same. These curves are characterized by a rapid rise beyond the starting potential (potential at which the counter begins to respond) until a more or less flat region is reached. This flat region is called the plateau of the curve. The slope and width of the plateau curve are dependent upon the …

Application Of Electrical Prospecting Methods To Two Types Of Sulphide Ore Deposits, Robert Van Nostrand

Masters Theses

"Although certain types of sulphide ores, especially those near the surface of the earth, lend themselves very well to electrical prospecting methods, quite the opposite is true of the extensive deposits of the type found in the Mississippi River Valley. The purpose of this investigation was to discover additional facts concerning two distinct types of sulphide ores, and therefrom to develop a new technique which would be applicable to prospecting for the lead and zinc deposits found in the Mississippi Valley"--Introduction, page 1.

Geology And Mineralization Of The Minerva Mine No. 1, Hardin County, Illinois, Matthew Peter Nackowski

Masters Theses

"This study originally was undertaken to describe the witherite identified in specimens collected at the Minerva Oil Company Mine No. 1, Hardin County, Illinois. The original specimens of witherite were collected on October 25, 1948, by Charles E. Tothill, while on a senior trip through the fluorspar mine. The witherite was identified by Dr. O. R. Grawe, Chairman of the Geology Department, Missouri School of Mines, Rolla, Missouri, to whom the specimens were presented. Dr. Grawe suggested that the writer visit the southern Illinois fluorspar area to determine the occurrence and distribution of the witherite. This mineral had been described …

Radioactivity Of The Pre-Cambrian Section Of The Bourbon, Missouri, Well Core By Measurement Of The Total Hard Gamma Radiation, Paul E. Damon

Masters Theses

"In December of 1947 Mr. Robert Van Nostrand and the writer became interested in the problem of the distribution of natural radioactivity and the applications of radioactivity to geology. A cooperative survey of the literature on the subject was undertaken. Later the writer decided to follow up the survey with a research project. Consultations with Dr. Z. V. Harvalik of the Missouri School of Mines Physics Department, and Dr. E. L. Clark and Mr. O. M. Bishop of the Missouri Geological Survey, followed. The nature of the project was evolved when Dr. Clark, with the consent of the U. S. …

The Determination Of The Surface Tension Of Benzyl Ether, Sze-Kwei Min

Masters Theses

"The accurate determination of surface tension is of importance in the investigation of theories of surface structure, the structure of liquids, molecular cohesion, in the study of colloids, especially in physiological work, and in various lines of technical chemistry. The two methods most commonly used for determining surface tension are the capillary rise method and the drop weight method. The theory of the former is simple, but its technique is difficult. Its use in some cases is the cause of errors as high as 30%, due to its inapplicability to certain classes of substance, and is much more sensitive to …

Reduction Of Beryllium Compounds With Magnesium, Pei Wang

Masters Theses

"The purpose of this research was to investigate the thermal reduction of beryllium compounds and to devise a method to estimate the metallic beryllium content in the final product"--Introduction, page 1.

Geology Of The Berryman Area, Washington County, Missouri, Jack Alexander James

Masters Theses

"Purpose and scope - The are discussed in this thesis was selected because of recent exploration for lead within this region and because of the need for more detailed information of the structure and geologic history of the area. The work constitutes part of a program of geologic mapping by the Missouri Geological Survey and Water Resources to complete the mapping of a strip of quadrangles extending across the Ozark Uplift from Rolla eastward to the Mississippi River"--Introduction, page 1.

Hysteresis Loss Of Supermalloy At Different Temperatures, Chester Ray Holland

Masters Theses

"The object of this investigation was to measure the hysteresis loss of supermalloy at different temperatures, and to see if temperature had any effect on hysteresis loss and permeability. The maximum magnetizing current was held constant for all temperatures"--Introduction, page 1.

The Kerr Electro-Optic Effect In Plastic Materials Transmitting Infra-Red Radiation, James Edson Dueker

Masters Theses

"Much work has been done investigating the Kerr Electro-Optic effect and what physical properties of a substance lead to the occurrence of the phenomenon. Information now available indicates a relationship between molecular shape and orientation with the Kerr Effect, hence any added information increases the possibility for finding the exact relationship and the molecular structure of substances. The Kerr Effect, has been used in a number of applications other than for the study of molecular construction of matter. Many applications have been made to form Electro-Optic shutters. This field of work has been increased to include light flash production and …

A Microwave Polarimeter, Alfred E. Schwaneke

Masters Theses

"The dissertation on the following pages may read more like a construction article than an approach to a study of physical phenomena. If so, its purpose is clearly defined. this subject has been studied little from an experimental viewpoint, so one of the main objectives of this writing is to describe the instrument so others may read the article and reproduce this or an equivalent device without a great amount of reading and searching for information on just how to fabricate and mount the parts. No single book or article that I know of covers the inexpensive construction of such …

The Effect Of Spontaneous Crystallization Of Some Inorganic Compounds At The Critical Temperature Of Their Solvents, John William Buttrey

Masters Theses

"For many years the phenomena which occur at the critical temperature of liquids have been investigated. And since 1912, when Laue and other discovered that a beam of x-rays could be made to yield a diffraction pattern by passing it through a crystal, scientists have been attempting to change the x-ray pattern for various crystals by somehow changing the arrangement of the atoms in the crystal lattice. Harvalik has already shown that crystallization occurs when a solvent reaches the critical point and his work indicates that under these conditions of crystallization there is a change in the crystal pattern. The …

The Separation Of The Rare Earths Neodymium And Praseodymium By Precipitation As Chloride, Stanley Milton Kulifay

Masters Theses

"The purpose of this thesis is to provide a means of preparing highly purified samples of neodymium and praseodymium compounds when the material to be refined already exists in a state of approximate purity. The method described cannot be profitably used to purify the individual rare earths without first concentrating them. The process is not intended to be quantitative, for it is a fractional crystallization technique using a concentrated hydrochloric acid medium"--Introduction, page 1.

Geology Of The Ozark-Martin Mine Area, Madison County, Missouri, William Clifton Hayes

Masters Theses

"General descriptions of the region adjacent to the Ozark and Martin Mines of Madison County, Missouri have been included in a number of early publications dealing with the Einstein Silver Mine area, but a detailed geologic map has not been made. It was thought that through detailed mapping and by a detailed analysis of all of the geologic features present, a more definite relationship between mineralization and structure might be determined"--Introduction, Purpose and Scope of Work, page 1.

Geology Of The Einstein-Apex Tungsten Mine Area, Joel B. Pomerene

Masters Theses

"The geological problem existing in the Silver Mine area, the relationship of mineralization to structure, particularly to faulting and jointing, was pointed out to the writer by Prof. O. R. Grawe. Several geologists have made reconnaisance [sic] surveys of the whole region, but so far no detailed geologic map has been published of the immediate area. Prof. Grawe pointed out that such a map would be of value in the better understanding of the area and would be especially useful in the event that another national emergency required the development of all possible sources of tungsten"--Introduction, Selection of the Problem, …

An Investigation Of The Colorimetric Methods For The Determination Of Fluorine By The Zirconium Alizarin Sulfonate Method, William Lewis Break

Masters Theses

"There has been a need for a rapid and an accurate method for the determination of fluorine in its compounds. Both gravimetric and volumetric methods have been studied, but both methods were time consuming or inaccurate or both. Colorimetric methods had been studied before F. Richter developed his method but none had been reported to be as satisfactory as his method. This method was investigated because it was thought that F. Richter's method would be a satisfactory colorimetric determination for fluorine in its compounds"--Introduction, page 1.

A Study Of The Electrolytic Reduction Of Pyrrole, Don Richard Strehlau

Masters Theses

"A review of the chemical literature has shown that electro-organic methods compare favorably with purely chemical methods for certain syntheses belonging to the following general classes of reactions: coupling, oxidation, reactions with halogens, and reductions. Electro-organic methods have been used most successfully in synthesis by reduction. The chief advantage is using electrolytic reduction in preference to a chemical one is that it offers a more exact control of conditions, and consequently should give a higher yield and a purer product. The advantages of the means of reduction suggested an investigation of its use in the synthesis of hydrogenated products of …

Conodonts From The Marathon Basin, Brewster County, Texas, Roy William Graves Jr.

Masters Theses

"Conodonts were discovered in the limestones of the Marathon region in the Big Bend country, Brewster County, Texas, as a result of field work during the summer of 1939. This was not the first known occurrence of these fossils from this region, however, as King earlier mentioned the occurrence of conodonts in siliceous shales of Devonian age. The discovery of conodonts in the Ordovician and Pennsylvanian limestones of the area had its inception in the attempt to determine whether the Dimple limestone (lower Pennsylvanian) or Maravillas limestone (upper Ordovician) was involved in a fault that was being mapped. These limestones …

Studies On The Quantitative Analysis Of Rhenium And Its Occurrence In The Products Of Molybdenite Processing, Walter Keith Dean

Masters Theses

"There is at the present time no commercially developed source of the metal rhenium in the United States. Since this metal is known to exist in molybdenite, it was felt that a study of the products of the metallurgical processing of this mineral might reveal a source of rhenium that could e developed. The Climax Molybdenum Co. provided a number of samples from their smelter at Langloth, Pennsylvania. Although an improved method for the quantitative estimation of rhenium was recently published, its accuracy was not high and the procedure exacting and time-consuming. These combined factors led to the selection of …

The Volumetric Determination Of Alumina In Clays And Related Materials, David Ferdinand Boltz

Masters Theses

"The primary purpose of this thesis was to develop a direct method for the determination of alumina in certain silicates. The classical gravimetric procedure for the analysis of alumina in clays and related materials has often been regarded as being too lengthy and troublesome, especially when only the percentage of alumina was desired. The correct determination of alumina is undoubtedly one of the most unsatisfactory of the chemical constituents of siliceous materials, and therefore the development of a direct volumetric method for the determination of this constituent was made the main objective of this research, page [1].

Electrolytic Reduction Of Galena In Fused Salt, Peter Simonds

Masters Theses

"A demand has long existed for a method of directly recovering elemental Sulphur, in addition to the Lead, from Galena ore. At the present time, the sulphur of this ore is dissipated in the lead blast furnace as sulphur dioxide fumes. While the fumes are trapped to avoid damage to the vegetation of the surrounding countryside, their concentration is usually too low to make sulphuric acid as a profitable by-product. Thus, contrary to some speculation, the sulphuric acid produces under the circumstances is usually not a true by-product in the money-making sense of the term in many cases, but a …

Consumption And Uses Of Crude Barite And Its Derivatives, Peter Simonds

Masters Theses

"Barite is a widely distributed mineral composed of barium sulphate - BaSO₄. Its most striking feature is its weight - its specific gravity of 4.5 being about twice that of salt and many other of the colorless, transparent and vitreous minerals of its general appearance. The Mineral is usually found in a state of considerable chemical purity. However, small amounts of strontium and calcium sulphates may isomorphously replace the barium salt. Crystals of barytes are orthorhombic; usually very perfectly developed and have a wide variety of forms. The simplest crystals are rhomb-shaped tables bounded by two faces of a basal …

The Reactions Of Acid Halides With Sodium, Magnesium, Zinc And Amalgams, William H. Webb

Masters Theses

"The reactions of acid halides with metals are of interest because there seems to be a possibility of abstracting the halogens from two molecules of the halide, and thereby bringing about a coupling reaction; or the formation of an intermediate organo-metallic compound which would react with another molecule of the acid halide. The result of these reactions should be the formation of diacetyl and acetyl chloride and of dibenzoyl or benzil from benzoyl chloride. This procedure would be far better than the usual procedures for the preparation of these compounds...The results reported in the literature by different workers, on the …

The Catalytic Vapor-Phase Hydrolysis Of Benzene And Toluene, Clemens Raebel Maise

Masters Theses

"The vapor-phase synthesis of organic compounds represents a new field of study which has attracted the attention of investigators only within recent years. However, wide interest is apparent in this field and several processes of commercial importance have already been developed. Hydrolysis is perhaps the newest of all the types of vapor-phase synthesis; the literature consists of little more than a few patents...The vapor-phase hydrolysis of benzene and toluene, therefore, presented an interesting possibility. These two hydrocarbons are considered very stable toward water in the liquid-phase. The purpose of this investigation was to determine to what extent their stability toward …