Physical Sciences and Mathematics Commons^™

Development Of Electrochemical Sensors Suitable For In Vivo Detection For Neurotransmitters, Mengjia Hu

Graduate Theses and Dissertations

The electrochemical method of redox cycling was exploited to achieve new discoveries in neurotransmitter detection and to advance its suitability toward in vivo use. Redox cycling has advantages in signal amplification, selectivity of species based on their electrochemical reaction mechanisms, and limited or no background subtraction. Distinction of dopamine from norepinephrine in a mixture with an electrochemical method at unmodified electrodes was demonstrated for the first time in vitro. This ability resulted from a series of fundamental studies of redox cycling behavior of the catecholamines (dopamine, norepinephrine and epinephrine) using different electrode configurations. Taking advantage of the ECC’ mechanism associated …

Linear Trend Analysis: Implications For A Structural Fracture System And Applications Of Subsurface Fluid Migration, Northwest Arkansas And Eastern Oklahoma, Loren Labusch

Graduate Theses and Dissertations

Lineaments are mappable, simple or composite linear or curvilinear features of the Earth’s surface longer than one mile, which differ from the patterns of adjacent features and are presumed to reflect subsurface phenomenon such as faults and fractures. The usage of the term refers to the description Lattman published in 1958 and was the foundation for work by MacDonald in 1977, which is the basis for this project. Remote sensing techniques have provided a valuable means to analyze lineaments on a large scale in a relatively short time in comparison to field mapping methods. The products of such fracture studies …

Hardware Trojan Detection Via Golden Reference Library Matching, Lucas Weaver

Graduate Theses and Dissertations

Due to the proliferation of hardware Trojans in third party Intellectual Property (IP) designs, the issue of hardware security has risen to the forefront of computer engineering. Because of the miniscule size yet devastating effects of hardware Trojans, few detection methods have been presented that adequately address this problem facing the hardware industry. One such method with the ability to detect hardware Trojans is Structural Checking. This methodology analyzes a soft IP at the register-transfer level to discover malicious inclusions. An extension of this methodology is presented that expands the list of signal functionalities, termed assets, in addition to introducing …

Field Observations And Computer Modeling Of Tornado-Terrain Interaction And Its Effects On Tornado Damage And Path, Nawfal Shihab Ahmed

Graduate Theses and Dissertations

Tornado forces on structures have been a research focus for the past decades, and some comparisons have been made to distinguish between straight boundary layer (SBL) wind and tornado wind forces on specific structures. However, very little attention has been paid to terrain effects on tornado damage and path. Available damage investigation data for four tornado locations (Joplin-2011, Tuscaloosa-2011, Parish-2011 and Mayflower-2014) is utilized to explore terrain effects on tornado damage and path. Google Earth, site visits and aerial images are employed to study the influence of terrain on an extent of damage and path variation. Additionally, a three dimensional …

Investigating Mineral Stability Under Venus Conditions: A Focus On The Venus Radar Anomalies, Erika Kohler

Graduate Theses and Dissertations

Radar studies of the surface of Venus have identified regions with high radar reflectivity concentrated in the Venusian highlands: between 2.5 and 4.75 km above a planetary radius of 6051 km, though it varies with latitude. Previous research has proposed several theories on the source of these anomalies, including increased surface roughness, metallic materials with higher dielectric constants, or ferroelectric materials. Prior work suggests several processes that could be the origin of these anomalies, such as surface-atmospheric interactions or low lying clouds or fog. Alternatively, these anomalies could result from a semi-metallic compound trapped at the cooler conditions in the …

Topics In The Detection Of Gravitational Waves From Compact Binary Inspirals, Shasvath Jagat Kapadia

Graduate Theses and Dissertations

Orbiting compact binaries - such as binary black holes, binary neutron stars and neutron star-black hole binaries - are among the most promising sources of gravitational waves observable by ground-based interferometric detectors. Despite numerous sophisticated engineering techniques, the gravitational wave signals will be buried deep within noise generated by various instrumental and environmental processes, and need to be extracted via a signal processing technique referred to as matched filtering.

Matched filtering requires large banks of signal templates that are faithful representations of the true gravitational waveforms produced by astrophysical binaries. The accurate and efficient production of templates is thus crucial …

Identification Of Biomarkers For The Overall Survival Of Ovarian Cancer Patients, Kristi Mai

Graduate Theses and Dissertations

Rapid advance in sequencing technology has led to genome-wide analysis of genetic and epigenetic features simultaneously, making it possible to understand the biological mechanisms underlying cancer initiation and progression. However, how to identify important prognostic features poses a great challenge for both statistical modeling and computing. In this thesis, a network-based approach is applied to the Cancer Genome Atlas (TCGA) ovarian cancer data to identify important genes related to the overall survival of ovarian cancer patients. In the first step, a stepwise correlation-based selector is used to reduce the dimensionality of TCGA data, by filtering out a large number of …

Quantifying, Assessing, And Mitigating Methane Emissions From Super-Emitters In The Oil And Gas Supply Chain, David Richard Lyon

Graduate Theses and Dissertations

Methane emissions from the oil and gas (O&G) supply chain reduce potential climate benefits of natural gas as a replacement for other fossil fuels that emit more carbon dioxide per energy produced. O&G facilities have skewed emission rate distributions with a small fraction of sites contributing the majority of emissions. Knowledge of the identity and cause of these high emission facilities, referred to as super-emitters or fat-tail sources, is critical for reducing supply chain emissions. This dissertation addresses the quantification of super-emitter emissions, assessment of their prevalence and relationship to site characteristics, and mitigation with continuous leak detection systems. Chapter …

Impact Of Extreme Summer Temperatures On Bridge Structures, Ryan Hagedorn

Graduate Theses and Dissertations

Climate change and its effect on weather in the United States is a well-documented phenomenon. In particular, extreme heat waves have become more intense, more frequent, and longer lasting, especially in the southern United States. As with much of America’s transportation infrastructure, prestressed concrete bridge girders experience the effects of these heat waves. Uneven heating of optimized bridge girder sections results in large non-linear temperature gradients. In this study, temperature was monitored in three different AASHTO I-girders to determine the vertical and transverse temperature gradients in a pre-deck placement condition. It was determined that the current design standard, which uses …

Algal Wastewater Treatment And Biofuel Production: An Assessment Of Measurement Methods, And Impact Of Nutrient Availability And Species Composition, John F. Chamberlin

Graduate Theses and Dissertations

In order to move towards a more sustainable future, human civilization will need to decrease its impacts on air and water quality and minimize consumption of fossil fuels. Using algae for wastewater treatment and biofuel production offers one approach to progress towards these goals simultaneously. Algae are capable of removing nutrients from wastewater and carbon dioxide from the air, and the biomass formed in that process can be used to generate a wide-range of products including fertilizer or fuels that could power combustion engines, power plants, or zero-emission fuel cell vehicles. Using wastewater for biofuel production has the potential to …

Spread Trading In Corn Futures Market, Ryan D. Napier

Graduate Theses and Dissertations

The non-linear relationship between old crop – new crop year spreads in corn futures market and stock-to-use (S-U) ratios published by the United States Department of Agriculture is analyzed. Using a non-linear logarithmic smooth transition regression (LSTR) model, we capture asymmetric market behaviors in high and low S-U regimes. Capturing this relationship and understanding the non-linear aspects of the relationship is of interest of grain merchandizers and speculators in the market. A spread trading strategy is simulated for the sample period, January 1985 through April 2015, to determine if the non-linear relationship is a profitable arbitrage opportunity in the market.

A Method Comparison And Stressor-Response Experimental Study Of Nitrogen And Phosphorus Impacts To Periphyton In Ozark Streams, Ashley Renee Rodman

Graduate Theses and Dissertations

Stream bioassessment is important for understanding algal-nutrient relationships and the development of scientifically defensible numeric nutrient criteria. However, multiple methods of periphyton data collection are currently used, and little is known about the comparability of resulting datasets. Literature also suggests other factors besides nutrients (i.e. variable grazing, light, and flow) can confound algal-nutrient relationships. A one-year method comparison study and 31-day algal biomass-nutrient manipulative experiment were conducted in the southern Ozarks of Arkansas. The method comparison study was implemented using two common bioassessment procedures (whole-surface and delimiter-reduced periphyton removal) to assess the potential for combining datasets. During the manipulative experiment, …

Statistical Analysis Of Fluvial Channel Belts, Kyle Ryan Spencer

Graduate Theses and Dissertations

As meandering rivers laterally migrate over time, they build channel belts. The accumulation of all previous flow paths creates the channel belt. To better understand these ancient rivers, modern river systems are being mapped to find statistical relationships between current flow path and the channel belt of river systems. It is important to examine a wide range of systems in terms of age, size, and location. The rivers are being mapped using an ImageJ, interpretations from Saucier (1994) and Google Earth. Three channel belt morphologies are mapped for 15 modern channel belts; the width of the river in relation to …

Geospatial Analysis Of Droughts, Rice And Wheat Production, And Agrarian Vulnerability: A District-Level Study Of The Self-Calibrated Palmer Drought Severity Index In India, Aaron Michael Shew

Graduate Theses and Dissertations

Droughts have affected more people than any other natural disaster in the last century, causing billions in economic damages and millions of deaths. As the Sea Surface Temperatures (SST) have heated in the Indian Ocean, drought patterns across South Asia have changed; the Indian monsoon has become more volatile and less predictable. In this study, monthly self-calibrated Palmer Drought Severity Index (sc-PDSI) data for the time period between 1950 and 2009 were interpolated to India’s districts; then the data were analyzed for changes in frequency and severity. The data were further evaluated using Anselin’s Local Moran’s I Statistic to elicit …

Wayne E. Sabbe Arkansas Soil Fertility Studies 2015, Nathan A. Slaton

Arkansas Agricultural Experiment Station Research Series

Rapid technological changes in crop management and production require that the research efforts be presented in an expeditious manner. The contributions of soil fertility and fertilizers are major production factors in all Arkansas crops. The studies described within will allow producers to compare their practices with the university’s research efforts. Additionally, soil-test data and fertilizer sales are presented to allow comparisons among years, crops, and other areas within Arkansas.

Dissolved Oxygen Monitoring In Kings River And Leatherwood Creek, Eric Cummings, Erin E. Scott, Marty Matlock, Brian E. Haggard

Technical Reports

The Clean Water Act (CWA) establishes the basic structure used to regulate water quality. Under the CWA, States are required to assess water bodies relative to water‐quality standards and designated beneficial uses and then to submit lists of impaired bodies every other year to the US Environmental Protection Agency (USEPA). In 2015, at least 4,800 water bodies were listed as impaired by dissolved oxygen across the US (USEPA, 2015). Aquatic species like fish and macroinvertebrates depend on adequate dissolved oxygen for survival. Low dissolved oxygen can lead to fish kills, reduced aquatic diversity, and nuisance smells from anaerobic conditions – …

Journal Of The Arkansas Academy Of Science - Volume 70 2016, Academy Editors

Journal of the Arkansas Academy of Science

No abstract provided.

Constituent Loads And Trends In The Upper Illinois River Watershed And Upper White River Basin, Erin E. Scott, Zach P. Simpson, Brian E. Haggard

Technical Reports

Water chemistry can greatly influence the quality of surface waters and affect the ability for streams and rivers to meet their designated use(s). In Arkansas, many streams and rivers were placed on the 2008 303(d) list of impaired water bodies due to excess levels of nutrients, chlorides, sulfates, and sediments (ADEQ, 2008). These constituents continue to be listed as the potential cause for water‐quality impairments through the most recent draft 303(d) list (ADEQ, 2014). The Arkansas Non‐Point Source (NPS) Management Program wants to reduce poll‐ utant loading from the landscape and improve water quality, where funding for projects is targeted …

A Step In The Right Direction: Streambank Restoration Efforts At The Botanical Garden Of The Ozarks, Dylan S. Milholen, Madison Brown, Steven Thao, Lisa S. Wood

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

The Botanical Garden of the Ozarks (BGO) is a unique destination in Northwest Arkansas that draws more than 80,000 visitors a year. While the BGO manages low-input practices, run-off from pesticide application and synthetic fertilizers containing phosphorus and nitrogen are of concern to water quality, habitat, and overall ecological interactions of the BGO streambanks and adjacent Hilton Creek, which flows directly into Lake Fayetteville. One way to reduce pollution to waterbodies is through the use of riparian buffers. This project sought to establish a riparian buffer immediately adjacent to a portion of Hilton Creek in an effort to improve ecological …

Lower Mississippian Chert Development, Southern Midcontinent Region, J. M. Cains, A. Potra, E. D. Pollock

Journal of the Arkansas Academy of Science

The Lower Mississippian Boone Formation is a chert-bearing, fossiliferous limestone typically 100-115m. thick forming the Springfield Plateau across the tri-state region of northwestern Arkansas, southwestern Missouri, and northeastern Oklahoma. The Boone represents the maximum flooding, highstand, and regressive intervals of a single, third order transgressive-regressive carbonate cycle bounded by regional unconformities. Two types of chert occur in this formation, and provide the basis for subdivision of the Boone into informal lower and upper members in northern Arkansas. The lower Boone represents early Osagean maximum flooding conditions and consists of calcisiltites with interbedded dark, nodular chert. This chert exhibits compaction phenomena …

Early Cementation Of The Short Creek Oolite Member, Boone Formation (Osagean, Lower Mississippian), Northern Arkansas, K. A. Jayne, A. K. Chandler, W. L. Manger

Journal of the Arkansas Academy of Science

The Short Creek Oolite is the only formally named member of the Boone Formation in northern Arkansas. It lacks bedding features, and oolith concentrations that would suggest a shoal environment, and it occurs at variable stratigraphic horizons within the upper Boone Formation consistent with episodic deposition as grainflow slurries. As with modern oolite examples, such as Joulters Cays, Bahamas, the Short Creek preserves numerous intraclasts, and at least one large olistolith indicating an early cementation history.

Comparison Of The Elemental Geochemistry Of The Arkansas Novaculite And The Boone Chert In Their Type Regions, Arkansas, J. Philbrick, E. Pollock, A. Potra

Journal of the Arkansas Academy of Science

The name Arkansas Novaculite was proposed by A.H. Purdue, 1909 to replace the name Arkansas Stone assigned by L. S. Griswold, 1892, but deemed too generic, to an interval of Early Devonian-Early Mississippian, very fine-grained, even textured, siliceous sedimentary rock famous for use as whetstones. The interval is exposed along the margins of the Benton Uplift, south flank of the Ouachita Mountains, west-central Arkansas, where it reaches a maximum thickness of 243.8 m (800 ft). The Arkansas Novaculite comprises informal lower and upper members characterized by massive beds of nearly pure novaculite, separated by a shale-bearing middle member that spans …

Water-Quality Effects On Phytoplankton Species And Density And Trophic State Indices At Big Base And Little Base Lakes, Little Rock Air Force Base, Arkansas, June Through August, 2015, L. J. Driver, B. G. Justus

Journal of the Arkansas Academy of Science

Big Base and Little Base Lakes are located on Little Rock Air Force Base, Arkansas, and their close proximity to a dense residential population and an active military/aircraft installation make the lakes vulnerable to water-quality degradation. The U.S. Geological Survey (USGS) conducted a study from June through August 2015 to investigate the effects of water quality on phytoplankton species and density and trophic state in Big Base and Little Base Lakes, with particular regard to nutrient concentrations. Nutrient concentrations, trophic-state indices, and the large part of the phytoplankton biovolume composed of cyanobacteria, indicate eutrophic conditions were prevalent for Big Base …

Impact Of Climate Variations On Soybean Yield In Eastern Arkansas: 1960-2014, J. W. Magugu, S. Feng, Q. Huang, K. Luthra

Journal of the Arkansas Academy of Science

Climate is the major factor affecting crop production; therefore, various agro-meteorological indicators have been frequently used to evaluate the impact of climate on crop production. In this study, we examined the temporal variations of agrometeorological indicators (growing degree days, total precipitation, dry spells and drought indices) during 1960-2014 and their impact on soybean yields in East Arkansas. Results show an increasing trend in growing degree days (GDDs) and dry spells, though the total precipitation during the soybean growing season remained nearly unchanged during the study period. Generally, GDDs and dry spells show a strong correlation with yields. We also evaluated …

A Bond Length – Bond Valence Relationship For Carbon – Nitrogen Bonds, C. Harris, F. D. Hardcastle

Journal of the Arkansas Academy of Science

In a recent study, Pauling’s relationship between bond length and valence was derived along with a definition for his fitting parameter b that incorporates the orbital exponents for each atom contributing to the bond of interest. The values of b for various bonds, including C-N bonds, were calculated using the orbital exponent data. In this study, Pauling’s correlation between bond length and bond valence, as well as his valence sum rule, were used with the recently-derived definition for b in order to produce a relationship specifically applicable to C-N bonds. The resulting equation was checked against published x-ray diffraction data …

Electron Shock Waves With A Large Current Behind The Shock Front, H. D. Newberry, M. Hemmati, H. D. Moore, K. Ledbetter, M. W. Bowman

Journal of the Arkansas Academy of Science

The propagation of breakdown waves in a gas, which is primarily driven by electron gas pressure, is described by a one-dimensional, steady-state, three-component (electrons, ions, and neutral particles) fluid model. We consider the electron gas partial pressure to be much larger than that of the other species and the waves to have a shock front. Our set of equations consists of the equations of conservation of the flux of mass, momentum, and energy coupled with Poisson’s equation. This set of equations is referred to as the electron fluid dynamical equations. In this study we are considering breakdown waves propagating in …

Lithologic Character Of The Paleozoic Sandstone Succession, Southern Ozark Region, Arkansas, And Missouri, E. C. Bello

Journal of the Arkansas Academy of Science

Sandstones comprise nearly half of the Paleozoic (Upper Cambrian-Middle Pennsylvania) lithostratigraphic succession in the southern Ozark region of northern Arkansas and southern Missouri. They record five distinct, but related intervals characterized by 1) Upper Cambrian arkoses resting unconformably on Precambrian granite; 2) Lower Ordovician reworked subarkoses, sublitharentites, and quartzites; 3) Lower Ordovician to Lower Mississippian reworked orthoquartzites; 4) Upper Mississippian first cycle sandstones with few metamorphic rock fragments (mrfs); 5) Lower Pennsylvanian (Morrowan) first cycle sandstones with common mrfs and Middle Pennsylvanian (Atokan) first cycle sandstones with common to abundant mrfs. These sandstones accumulated on a gently sloping cratonic platform …

Plain Facts About Anthropogenic Global Climate Change And Warming: A Review, M. K. Cleaveland

Journal of the Arkansas Academy of Science

Anthropogenic global climate change (AGC) is proceeding rapidly. The proximate cause is the greenhouse effect of carbon dioxide, methane and other greenhouse gases (GHG), which have rapidly accumulated in the atmosphere from burning fossil fuels and other human activities. Measurements of incoming and outgoing radiation have verified the warming imbalance. Effects manifest themselves in accelerating sea level rise and diminishment of the cryosphere. This has already created climatic refugees and water stress, and will destroy coastal infrastructure. It also impacts ecosystems and biodiversity in many ways. To avoid catastrophic effects, fossil fuel use must cease and carbon sinks must be …

Impacts Of Man-Made Structures On Avian Community Metrics In 4 State Parks In Northwestern Arkansas, R. D. Keith, B. Grooms, R. E. Urbanek

Journal of the Arkansas Academy of Science

Avian community metrics often differ between areas with no human disturbance and areas with high levels of human disturbance. However, the relationships between avian community metrics and smaller-scale disturbances are not as clear. Our goal was to investigate if avian abundance, richness, evenness, and diversity differed in areas with and without small-scale human developments. We used fixed-radius 50-m avian point counts to compare points which contained a man-made structure (n = 47), such as a picnic area, road, or campsite to those that did not contain a man-made structure (n = 181) at 4 state parks in Arkansas during 18 …

Sedimentation In The Upper Reaches Of Lake Ouachita, J. A. Patton

Journal of the Arkansas Academy of Science

Lake Ouachita in west-central Arkansas is the largest man-made reservoir in the state. The lake was created by the U.S. Army Corps of Engineers (USACE) in 1953 for the purposes of hydropower, flood control, and recreation. Although Lake Ouachita is widely known for its high water clarity near Blakely Dam, little is known about the volume and ultimate fate of sediments that enter the lake from two primary tributaries: the North and South Forks of the Ouachita River. This project utilized a dual-frequency echo sounding system in combination with geographic information system and statistical analysis to calculate an average post-impoundment …