Physical Sciences and Mathematics Commons^™

Nitrogen Cycling During A Period Of Environmental Change, Kaizad Patel

Electronic Theses and Dissertations

Natural and anthropogenic disturbances have altered the N cycle on the regional to global scale. Although numerous studies have examined the effects of chronic atmospheric N deposition on ecosystem processes, less is known about intra-annual variability of these processes, or how these responses might be altered under conditions of changing climate. The work described in this dissertation focuses on the effects of a changing chemical and physical climate, particularly terrestrial N processes (a) during Maine’s changing winters, and (b) in response to chronic elevated N additions.

Subnivean winter soil processes were examined at the Dwight B. DeMerritt Forest (DBDF) and …

Retreat Of The Antarctic Ice Sheet In The Southern Ross Embayment From Records At Amundsen And Liv Glaciers, Southern Transantarctic Mountains, Jillian Pelto

Electronic Theses and Dissertations

The Antarctic Ice Sheet contains ~58 m of global sea-level equivalent and thus its future behavior under global warming is of pressing concern. Examination of past ice-sheet behavior during periods of warming climate can afford insight useful for predicting future sea-level rise. This study focuses on a major unanswered question - namely, the cause of Antarctic Ice Sheet retreat following the last glaciation. Documenting the timing and nature of this deglaciation is crucial to understand the mechanisms behind ice-sheet behavior. Here, I examine how the marine portions of the ice sheet responded to the major warming that occurred at the …

Towards An Efficient, Scalable Stream Query Operator Framework For Representing And Analyzing Continuous Fields, John Whittier

Electronic Theses and Dissertations

Advancements in sensor technology have made it less expensive to deploy massive numbers of sensors to observe continuous geographic phenomena at high sample rates and stream live sensor observations. This fact has raised new challenges since sensor streams have pushed the limits of traditional geo-sensor data management technology. Data Stream Engines (DSEs) provide facilities for near real-time processing of streams, however, algorithms supporting representing and analyzing Spatio-Temporal (ST) phenomena are limited.

This dissertation investigates near real-time representation and analysis of continuous ST phenomena, observed by large numbers of mobile, asynchronously sampling sensors, using a DSE and proposes two novel stream …

Three Examples Of Mondoromy Groups, Alice A. Wise

Electronic Theses and Dissertations

This thesis illustrates the notion of the Monodromy group of a global analytic function through three examples. One is a relatively simple finite example; the others are more complicated infinite cases, one abelian and one non-abelian, which show connections to other parts of mathematics.

Principles And Guidelines For Advancement Of Touchscreen-Based Non-Visual Access To 2d Spatial Information, Hari Prasath Palani

Electronic Theses and Dissertations

Graphical materials such as graphs and maps are often inaccessible to millions of blind and visually-impaired (BVI) people, which negatively impacts their educational prospects, ability to travel, and vocational opportunities. To address this longstanding issue, a three-phase research program was conducted that builds on and extends previous work establishing touchscreen-based haptic cuing as a viable alternative for conveying digital graphics to BVI users. Although promising, this approach poses unique challenges that can only be addressed by schematizing the underlying graphical information based on perceptual and spatio-cognitive characteristics pertinent to touchscreen-based haptic access. Towards this end, this dissertation empirically identified a …

Understanding Student Development Of Science Literacy Skills In An Undergraduate Environmental Science Course, Molly Picillo

Electronic Theses and Dissertations

Educators are expected to instill a variety of skills in their students that are necessary to be competent citizens of society. One such set of skills, science literacy skills, broadly encompass the ability of an individual to evaluate reliability of data and information and critically analyze and interpret them (Gormally Brickman, Hallar, & Armstrong, 2009). These skills are utilized in everyday decision-making and given their pertinence, there is a need for citizens to be scientifically literate. Thus, educators need tools and assessments to help students develop these skills and analyze their science literacy. The aim of this study was to …

Structure And Thermodynamics Of Polyglutamine Peptides And Amyloid Fibrils Via Metadynamics And Molecular Dynamics Simulations, Riley Workman

Electronic Theses and Dissertations

Aggregation of polyglutamine (polyQ)-rich polypeptides in neurons is a marker for nine neurodegenerative diseases. The molecular process responsible for the formation of polyQ fibrils is not well understood and represents a growing area of study. To enable development of treatments that could interfere with aggregation of polyQ peptides, it is crucial to understand the molecular mechanisms by which polyQ peptides aggregate into fibrils. Many experimental techniques have been employed to probe polyQ aggregation, however, observations from these studies have not lead to a unified understanding of the properties of these systems, instead yielding competing, fragmented theories of polyQ aggregation. This …

Economics Of Managing Loblolly Pine Plantations For Increased Wildlife Biodiversity, Melissa Griffith

Electronic Theses and Dissertations

The goal of this thesis was to identify the differences between the costs incurred and revenues gained from managing loblolly pine (Pinus taeda) plantations in East Texas for strictly timber production or a combination of timber production and wildlife biodiversity. Management regimes evaluated had varying planting densities, thinning frequency and intensities, prescribed burn intervals, and site indices. Economic analyses used to evaluate management regimes over a range of nonindustrial private landowner (NIPF) alternative rates of return (ARRs) and site indexes were net present worth, land expectation value, and equal annual annuity. These economic analyses demonstrated that altering management …

The Hilbert-Huang Transform: A Theoretical Framework And Applications To Leak Identification In Pressurized Space Modules, Kenneth R. Bundy

Electronic Theses and Dissertations

Any manned space mission must provide breathable air to its crew. For this reason, air leaks in spacecraft pose a danger to the mission and any astronauts on board. The purpose of this work is twofold: the first is to address the issue of air pressure loss from leaks in spacecraft. Air leaks present a danger to spacecraft crew, and so a method of finding air leaks when they occur is needed. Most leak detection systems localize the leak in some way. Instead, we address the identification of air leaks in a pressurized space module, we aim to determine the …

Mechanistic Studies Of Reducible Metal Oxides As Hydrodeoxygenation Catalysts, Akbar Mahdavi Shakib

Electronic Theses and Dissertations

Hydrodeoxygenation of phenol to benzene using ruthenium supported titania catalysts strongly varies depending on the support crystal structure and preparation conditions. Here, we performed spectroscopic characterization of titania supports to identify the surface impurities common to commercial and synthesized titania samples using a variety of spectroscopic methods. Sulfate impurities were detected for the commercial anatase samples and a procedure for their elimination was proposed so that inactive catalysts gained reactivity. Surface hydroxyls of different TiO2 samples (anatase, rutile, and pyrogenic) were identified using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments performed on vigorously cleaned surfaces and a facet-specific assignment …

Biomass Based Monomers For Synthesis Of Renewably Sourced Polymers, Anushka E. Vithanage

Electronic Theses and Dissertations

Limited fossil resources have raised research focus on synthesizing novel, sustainable polymers and renewably sourcing existing petroleum based polymers. This work presents the synthesis and ring opening polymerization (ROP) of a new functionalized lactone monomer, methoxy-δ-hexalactone (MDHL), to yield a functionalized polyester (polyMDHL). MDHL can be renewably sourced from hydroxymethylfurfural, a renewable platform chemical. MDHL was synthesized from methyl cyclopentanone-2-carboxylate by a five-step synthesis with a global yield of 23%. ROP of MDHL was conducted with benzyl alcohol initiator, catalyzed by diphenyl phosphate. 1H Nuclear Magnetic Resonance spectroscopy verified polyMDHL chemical structure. Targeting higher molecular weights for polyMDHL by increasing …

Chemically Cross-Linked Polysaccharide-Based Hydrogels Via Thiol-Norbornene Reaction As Sustainable Biomaterials, Nayereh Dadoo

Electronic Theses and Dissertations

Hydrogels are 3D polymeric networks with high water content and are widely being investigated for biomedical applications such as tissue engineering. Polysaccharides have been used to fabricate hydrogels due to their natural abundance, biocompatibility, and immunogeniety. Additionally, polysaccharide-based hydrogels can provide mechanical and biological cues similar to those of the natural environments. In this work, thiol-norbornene chemistry was used to fabricate polysaccharide-based hydrogels including hyaluronic acid (HA), carboxymethyl cellulose (CMC), and cellulose nanofibrils (CNFs). Hydrogels with tunable physical and mechanical properties were achieved. The properties of these hydrogels were spatiotemporally modified by photopatterning. Also, high stem cell viability was achieved …

Rediscovering The Interpersonal: Models Of Networked Communication In New Media Performance, Alicia Champlin

Electronic Theses and Dissertations

This paper examines the themes of human perception and participation within the contemporary paradigm and relates the hallmarks of the major paradigm shift which occurred in the mid-20th century from a structural view of the world to a systems view. In this context, the author’s creative practice is described, outlining a methodology for working with the communication networks and interpersonal feedback loops that help to define our relationships to each other and to media since that paradigm shift. This research is framed within a larger field of inquiry into the impact of contemporary New Media Art as we experience it. …

Comparison Of A Modified And Traditional Rapid Infiltration Basin For Treatment And Control Of Nutrients In Wastewater Effluent, Jessica Cormier

Electronic Theses and Dissertations

Rapid infiltration basins (RIB) have been historically used in Florida for groundwater recharge, effluent disposal, or a combination of both. However, this technique has proven ineffective in providing nitrogen control unless the RIB is modified in some manner. In this study, a traditional RIB was compared to a modified RIB constructed with manufactured biosorption activated media (BAM) to evaluate nitrate removal from reclaimed water. The RIBs are used for reclaimed and excess storm water disposal. Few, if any, studies have been published where BAM-modified RIBs have been used for this purpose. In this work, a mixture of clay, tire crumb, …

Analysis Of Nucleus Properties Of The Enigmatic Comet 29p/Schwassmann-Wachmann 1, Charles Schambeau

Electronic Theses and Dissertations

We present results from a continuing effort to understand activity drivers for the enigmatic Comet 29P/Schwassmann-Wachmann 1 (SW1). SW1 has been of interest since its discovery almost 100 years ago because of its nearly continuous, quiescent activity beyond the water-sublimation line and its highly variable, outburst activity while receiving a nearly constant insolation due to its low eccentricity orbit. These characteristics make SW1 a useful target for investigating both distant cometary activity drivers and also cometary outburst behavior. We approach answering these questions through a detailed analysis of SW1; first by measuring nucleus properties required for a more accurate nucleus …

Room Temperature Operation Of Quantum Cascade Lasers Monolithically Integrated Onto A Lattice-Mismatched Substrate, Rowel Go

Electronic Theses and Dissertations

Quantum Cascade Lasers (QCLs) are semiconductor devices that, currently, have been observed to emit radiation from ~ 2.6 μm to 250 μm (1 to 100 terahertz range of frequencies.) They have established themselves as the laser of choice for spectroscopic gas sensing in the mid-wavelength infrared (3-8 μm) and long-wavelength infrared (8-15 μm) region. In the 4-12 μm wavelength region, the highest performing QCL devices, in terms of wall-plug efficiency and continuous wave operation, are indium phosphide (InP) based. The ultimate goal is to incorporate this InP-based QCL technology to silicon (Si) substrate since most opto-electronics are Si-based. The main …

High Dynamic Range Optical Devices And Applications., Elijah Robert Jensen

Electronic Theses and Dissertations

Much of what we know about fundamental physical law and the universe derives from observations and measurements using optical methods. The passive use of the electromagnetic spectrum can be the best way of studying physical phenomenon in general with minimal disturbance of the system in the process. While for many applications ambient visible light is sufficient, light outside of the visible range may convey more information. The signals of interest are also often a small fraction of the background, and their changes occur on time scales so quickly that they are visually imperceptible. This thesis reports techniques and technologies developed …

A Glacial History Of Roberts Massif, Central Transantarctic Mountains, Antarctica, Using Cosmogenic 3he, 10be, And 21ne Surface Exposure Ages, Alexandra M. Balter

Electronic Theses and Dissertations

Ice-free areas at high elevation in the central Transantarctic Mountains preserve moraines and drift deposits that delineate the former thickness and extent of the East Antarctic Ice Sheet (EAIS); cosmogenic exposure ages on these features indicate when the ice sheet was as or more extensive than today. Approximately 30 existing cosmogenic-nuclide exposure ages from scattered locations within these deposits suggest that some moraines and drift sheets are at least 5 Ma old. Those ages imply that the age range of these deposits may span warm periods during the Miocene and Pliocene, during which the EAIS is hypothesized to have been …

Developing Optimization Techniques For Logistical Tendering Using Reverse Combinatorial Auctions, Jennifer Kiser

Electronic Theses and Dissertations

In business-to-business logistical sourcing events, companies regularly use a bidding process known as tendering in the procurement of transportation services from third-party providers. Usually in the form of an auction involving a single buyer and one or more sellers, the buyer must make decisions regarding with which suppliers to partner and how to distribute the transportation lanes and volume among its suppliers; this is equivalent to solving the optimization problem commonly referred to as the Winner Determination Problem. In order to take into account the complexities inherent to the procurement problem, such as considering a supplier’s network, economies of scope, …

Warning Confidence And Perceptions Of Lava Flow Hazard Diversion Strategies At Kīlauea And Mauna Loa Volcanoes, Hawai‘I, Ashleigh Reeves

Electronic Theses and Dissertations

The 2014-15 lava flow crisis at Kīlauea volcano, Hawai‘i and post-September 2015 elevated unrest at adjacent Mauna Loa volcano provided opportunities to assess households’ psychological and behavioral responses to different levels of volcanic activity. Weused the Protective Action Decision Model to examine stakeholder perceptions and confidence in warnings, in addition toattitudes toward lava flow mitigation strategies, such as diversion by berms and bombing, and people’s acceptance of additional risk to personal property in exchange for protecting important elements of their community, such as schools, major roads, electrical substation, and shopping centers. Respondents’ confidence in events important in decision-making during emergencies …

Synthesis And Characterization Of Zinc(Ii) Dipyrrin Photosensitizers, Norah Alqahtani

Electronic Theses and Dissertations

Photocatalytic carbon dioxide reduction transforms CO2 to useful chemicals and fuels, reducing CO2 emissions and making fossil fuels more renewable. Due to a lack of earthabundant sensitizers, we want to design new earth-abundant sensitizers to go with the many known carbon dioxide reduction catalysts. Zn(II) dipyrrin complexes strongly absorb visible light, but their excited state properties have not been widely studied. To investigate their photophysical properties, two Zn dipyrrin complexes, with and without heavy atoms, were synthesized and characterized by NMR and mass spectrometry. The photophysical properties of the two complexes were measured in polar and non-polar solvents, particularly fluorescence …

Evaluation Of Drug-Loaded Gold Nanoparticle Cytotoxicity As A Function Of Tumor Tissue Heterogeneity., Hunter Allan Miller

Electronic Theses and Dissertations

The inherent heterogeneity of tumor tissue presents a major challenge to nanoparticle-medicated drug delivery. This heterogeneity spans from the molecular to the cellular (cell types) and to the tissue (vasculature, extra-cellular matrix) scales. Here we employ computational modeling to evaluate therapeutic response as a function of vascular-induced tumor tissue heterogeneity. Using data with three-layered gold nanoparticles loaded with cisplatin, nanotherapy is simulated with different levels of tissue heterogeneity, and the treatment response is measured in terms of tumor regression. The results show that tumor vascular density non-trivially influences the nanoparticle uptake and washout, and the associated tissue response. The drug …

Improving The Accuracy Of Mobile Touchscreen Qwerty Keyboards, Amanda Kirk

Electronic Theses and Dissertations

In this thesis we explore alternative keyboard layouts in hopes of finding one that increases the accuracy of text input on mobile touchscreen devices. In particular, we investigate if a single swap of 2 keys can significantly improve accuracy on mobile touchscreen QWERTY keyboards. We do so by carefully considering the placement of keys, exploiting a specific vulnerability that occurs within a keyboard layout, namely, that the placement of particular keys next to others may be increasing errors when typing. We simulate the act of typing on a mobile touchscreen QWERTY keyboard, beginning with modeling the typographical errors that can …

Fuel Specific Emissions Trends For In-Use Medium And Heavy-Duty Vehicle Fleets In California, Molly J. Haugen

Electronic Theses and Dissertations

New heavy-duty vehicle regulations have caused significant reductions in hazardous air pollutants, such as particulate matter (PM) and nitrogen oxides (NO_x), due to better engine management and utilization of advanced after-treatment systems. The University of Denver has collected data for gaseous and PM emission measurements from on-road heavy-duty vehicles (HDVs). The On-Road Heavy-Duty Vehicle Emissions Measurement System (OHMS) collected fuel specific emission information on individual HDVs of in-use fleets at two California locations in the spring of 2013, 2015 and 2017. These complimentary fleets, studied over multiple years, produced 7,075 measurements of gaseous and particle emission data providing …

Polarized Bow Shock Nebulae Reveal Features Of The Winds And Environments Of Massive Stars, Manisha Shrestha

Electronic Theses and Dissertations

Massive stars strongly affect their surroundings through their energetic stellar winds during their lifetime and through their energetic deaths as supernovae. When a stellar wind interacts with the local interstellar medium (ISM), if the relative velocity between wind and ISM is supersonic, then a stellar wind bow shock is formed. Bow shocks and related density enhancements produced by the winds of massive stars moving through the interstellar medium provide important information regarding the motions of the stars, the properties of their stellar winds, and the characteristics of the local medium. Since bow shock nebulae are aspherical structures, light scattering within …

The Expected Number Of Patterns In A Random Generated Permutation On [N] = {1,2,...,N}, Evelyn Fokuoh

Electronic Theses and Dissertations

Previous work by Flaxman (2004) and Biers-Ariel et al. (2018) focused on the number of distinct words embedded in a string of words of length n. In this thesis, we will extend this work to permutations, focusing on the maximum number of distinct permutations contained in a permutation on [n] = {1,2,...,n} and on the expected number of distinct permutations contained in a random permutation on [n]. We further considered the problem where repetition of subsequences are as a result of the occurrence of (Type A and/or Type B) replications. Our method of enumerating the Type A replications causes double …

Factorization In Integral Domains., Ryan H. Gipson

Electronic Theses and Dissertations

We investigate the atomicity and the AP property of the semigroup rings F[X; M], where F is a field, X is a variable and M is a submonoid of the additive monoid of nonnegative rational numbers. In this endeavor, we introduce the following notions: essential generators of M and elements of height (0, 0, 0, . . .) within a cancellative torsion-free monoid Γ. By considering the latter, we are able to determine the irreducibility of certain binomials of the form Xπ − 1, where π is of height (0, 0, 0, . . .), in the monoid domain. Finally, …

3d-Printed Fluidic Devices And Incorporated Graphite Electrodes For Electrochemical Immunoassay Of Biomarker Proteins, Abdulhameed Alabdulwaheed

Electronic Theses and Dissertations

Biomarkers are measurable indicators of health status or disease state that can be used for diagnosis and may help guide patient treatment strategies. Enzyme-linked immunosorbent assays (ELISA) and other many clinical techniques currently used for measuring biomarker proteins lack sensitivity, demand high analysis cost, are often not well-suited for measuring multiple biomarkers in a single sample, and require long analysis times. Here, we demonstrate simple, low-cost 3D-printed flow-through devices with integrated electrodes modified with gold nanoparticles (AuNPs) for electrochemical immunoassays of S100B, a biomarker protein related to conditions like skin cancer and brain injuries. Flow-through devices are fabricated from photocurable-resin …

Surface Entropy Of Shifts Of Finite Type, Dennis Pace

Electronic Theses and Dissertations

Let χ be the class of 1-D and 2-D subshifts. This thesis defines a new function, H_S : χ x R → [0,∞] which we call the surface entropy of a shift. This definition is inspired by the topological entropy of a subshift and we compare and contrast several structural properties of surface entropy to entropy. We demonstrate that much like entropy, the finiteness of surface entropy is a conjugacy invariant and is a tool in the classification of subshifts. We develop a tiling algorithm related to continued fractions which allows us to prove a continuity result about surface …

Developing A Femtosecond Stimulated Raman Spectroscopy Experiment For Solid State Materials, Daniel Hammerland

Electronic Theses and Dissertations

Femtosecond Stimulated Raman Spectroscopy (FSRS) is a ultrafast spectroscopy technique first implemented by chemists to understand isomerization and other ultrafast molecular morphology changes by resolving vibrational dynamics[1, 2, 3]. FSRS has an unparalleled temporal and spectral resolution [4, 1, 5, 6] that arises as a result of a clever combination of picosecond and femtosecond pulses. However, despite this capability, FSRS has yet to be applied to modern materials in condensed matter physics. This thesis explores the design and implementation of FSRS to study two-dimensional materials in order to measure their quantum confined vibrational dynamics on utlrafast time scales.