Physical Sciences and Mathematics Commons^™

A Bi-Encoder Lstm Model For Learning Unstructured Dialogs, Diwanshu Shekhar

Electronic Theses and Dissertations

Creating a data-driven model that is trained on a large dataset of unstructured dialogs is a crucial step in developing a Retrieval-based Chatbot systems. This thesis presents a Long Short Term Memory (LSTM) based Recurrent Neural Network architecture that learns unstructured multi-turn dialogs and provides implementation results on the task of selecting the best response from a collection of given responses. Ubuntu Dialog Corpus Version 2 (UDCv2) was used as the corpus for training. Ryan et al. (2015) explored learning models such as TF-IDF (Term Frequency-Inverse Document Frequency), Recurrent Neural Network (RNN) and a Dual Encoder (DE) based on Long …

Generalized Spatiotemporal Modeling And Causal Inference For Assessing Treatment Effects For Multiple Groups For Ordinal Outcome., Soutik Ghosal

Electronic Theses and Dissertations

This dissertation consists of three projects and can be categorized in two broad research areas: generalized spatiotemporal modeling and causal inference based on observational data. In the first project, I introduce a Bayesian hierarchical mixed effect hurdle model with a nested random effect structure to model the count for primary care providers and understand their spatial and temporal variation. This study further enables us to identify the health professional shortage areas and the possible impacting factors. In the second project, I have unified popular parametric and nonparametric propensity score-based methods to assess the treatment effect of multiple groups for ordinal …

Bayesian Analytical Approaches For Metabolomics : A Novel Method For Molecular Structure-Informed Metabolite Interaction Modeling, A Novel Diagnostic Model For Differentiating Myocardial Infarction Type, And Approaches For Compound Identification Given Mass Spectrometry Data., Patrick J. Trainor

Electronic Theses and Dissertations

Metabolomics, the study of small molecules in biological systems, has enjoyed great success in enabling researchers to examine disease-associated metabolic dysregulation and has been utilized for the discovery biomarkers of disease and phenotypic states. In spite of recent technological advances in the analytical platforms utilized in metabolomics and the proliferation of tools for the analysis of metabolomics data, significant challenges in metabolomics data analyses remain. In this dissertation, we present three of these challenges and Bayesian methodological solutions for each. In the first part we develop a new methodology to serve a basis for making higher order inferences in metabolomics, …

Information Theoretic Thresholding Techniques Based On Particle Swarm Optimization., Surina Surina

Electronic Theses and Dissertations

In this dissertation, we discuss multi-level image thresholding techniques based on information theoretic entropies. In order to apply the correlation information of neighboring pixels of an image to obtain better segmentation results, we propose several multi-level thresholding models by using Gray-Level & Local-Average histogram (GLLA) and Gray-Level & Local-Variance histogram (GLLV). Firstly, a RGB color image thresholding model based on GLLA histogram and Tsallis-Havrda-Charv'at entropy is discussed. We validate the multi-level thresholding criterion function by using mathematical induction. For each component image, we assign the mean value from each thresholded class to obtain three segmented component images independently. Then we …

Plasma Based Synthesis And Surface Modification Of Graphene., Rong Zhao

Electronic Theses and Dissertations

Graphene, an atom thick layer of carbon, has attracted intense scientific interest due to its exceptional electrical, mechanical and chemical properties. Especially, it provides a perfect platform to explore the unique electronic properties in absolute two-dimension. Pristine graphene possesses zero band gap and weakens its competitiveness in the field of semiconductors. In order to induce a band gap and control its semiconducting properties, functionalization and doping are two of the most feasible methods. In the context of functionalization, large area monolayer graphene synthesized by chemical vapor deposition was subjected to controlled and sequential fluorination using radio frequency plasma while monitoring …

Developments In Multivariate Post Quantum Cryptography., Jeremy Robert Vates

Electronic Theses and Dissertations

Ever since Shor's algorithm was introduced in 1994, cryptographers have been working to develop cryptosystems that can resist known quantum computer attacks. This push for quantum attack resistant schemes is known as post quantum cryptography. Specifically, my contributions to post quantum cryptography has been to the family of schemes known as Multivariate Public Key Cryptography (MPKC), which is a very attractive candidate for digital signature standardization in the post quantum collective for a wide variety of applications. In this document I will be providing all necessary background to fully understand MPKC and post quantum cryptography as a whole. Then, I …

Immobilization Of Gold Nanoparticles On Nitrided Carbon Fiber Ultramicroelectrodes By Direct Reduction, George Affadu-Danful

Electronic Theses and Dissertations

Due to enhanced properties such as large surface area-to-volume ratio, metal nanoparticles are often employed as catalysts for various applications. However, most studies involving nanoparticle catalysts have been conducted on collections of particles rather than single nanoparticles. Results obtained for ensemble systems can be difficult to interpret due to variations in particle loading and interparticle distance, which are often challenging to control and characterize. In this study, two immobilization strategies for incorporating gold nanoparticles (AuNPs) on carbon fiber ultramicroelectrodes (UMEs) were compared with the goal of extending these techniques to nanoelectrodes for studies of single AuNPs. Both layer-by-layer deposition of …

Comparing Laser Assisted Pulling And Chemical Vapor Deposition Methods In The Fabrication Of Carbon Ultramicro- And Nanoelectrodes, Theophilus Neequaye

Electronic Theses and Dissertations

Ultramicroelectrodes (UMEs) (limiting dimensions <~25 μm) and nanoelectrodes (<~100 nm) exhibit enhanced electrochemical properties compared to macroscopic electrodes. Their small sizes and enhanced properties make them well-suited for various interesting and important applications such as measuring redox-active species in nonaqueous solvents, studying intermediates of fast electrochemical reactions, and investigating electrochemical and electrocatalytic properties of single nanoparticles. While UMEs are commercially available, nanoelectrode fabrication is still largely confined to research labs. Various methods for constructing nanoelectrodes have been reported and continue to be developed, but most require considerable expertise, and comparisons between different fabrication processes are lacking. In this work, a comparison of laser-assisted pulling and chemical vapor deposition (CVD) methods of electrode fabrication is made with the aim of optimizing production of carbon nanoelectrodes for single nanoparticle electrochemical measurements. By examining effects of pulling parameters, post-pulling treatments, and CVD processing, electrodes as small as ~50 nm were successfully produced.

The 2-Domination Number Of A Caterpillar, Presley Chukwukere

Electronic Theses and Dissertations

A set D of vertices in a graph G is a 2-dominating set of G if every vertex in V − D has at least two neighbors in D. The 2-domination number of a graph G, denoted by γ₂(G), is the minimum cardinality of a 2- dominating set of G. In this thesis, we discuss the 2-domination number of a special family of trees, called caterpillars. A caterpillar is a graph denoted by P_k(x₁, x₂, ..., x_k), where x_i is the number of leaves attached to the ith vertex …

Distribution Of A Sum Of Random Variables When The Sample Size Is A Poisson Distribution, Mark Pfister

Electronic Theses and Dissertations

A probability distribution is a statistical function that describes the probability of possible outcomes in an experiment or occurrence. There are many different probability distributions that give the probability of an event happening, given some sample size n. An important question in statistics is to determine the distribution of the sum of independent random variables when the sample size n is fixed. For example, it is known that the sum of n independent Bernoulli random variables with success probability p is a Binomial distribution with parameters n and p: However, this is not true when the sample size …

Clustering Mixed Data: An Extension Of The Gower Coefficient With Weighted L2 Distance, Augustine Oppong

Electronic Theses and Dissertations

Sorting out data into partitions is increasing becoming complex as the constituents of data is growing outward everyday. Mixed data comprises continuous, categorical, directional functional and other types of variables. Clustering mixed data is based on special dissimilarities of the variables. Some data types may influence the clustering solution. Assigning appropriate weight to the functional data may improve the performance of the clustering algorithm. In this paper we use the extension of the Gower coefficient with judciously chosen weight for the L2 to cluster mixed data.The benefits of weighting are demonstrated both in in applications to the Buoy data set …

Hydrolysis Of Cellulose And Biomass Using Blue Molybdenum, Farouk Awudu

Electronic Theses and Dissertations

Hydrolysis of cellulosic biomass is an important and ongoing subject of research due to generating precursors for biofuel synthesis. This work involves hydrolysis of microcrystalline cellulose and Arundo donax to glucose. Methods for acid hydrolysis include the use of sulfuric acid, phosphomolybdic acid, blue molybdenum using low concentrations at 40-100 °C. For comparison purposes, enzymatic hydrolysis was also carried out using cellulase. Products were quantified by measuring total organic carbon and reducible sugars using dinitrosalicylic acid. Use of phosphomolybdic acid, blue molybdenum and sulfuric acid even at 6.0 M did not increase the amount of glucose compared to using water …

T-De Vries Algebra, Nawal Alznad

Electronic Theses and Dissertations

The main point of this dissertation is to introduce the action on de Vries algebra by a topological monoid and we denoted the resulting category by dVT. In order to reach our goal, we started with introducing new proofs for some well known results in the category of flows. Then, we studied the Generalized Smirnov's Theorem for flows. After we studied the new category (dVT), we were able to provide a new way to construct the Čech-stone flow compactification of a given flow. Finally, we developed the co-free T-de Vries algebra for a special case.

D-Fens: Dns Filtering & Extraction Network System For Malicious Domain Names, Jeffrey Spaulding

Electronic Theses and Dissertations

While the DNS (Domain Name System) has become a cornerstone for the operation of the Internet, it has also fostered creative cases of maliciousness, including phishing, typosquatting, and botnet communication among others. To address this problem, this dissertation focuses on identifying and mitigating such malicious domain names through prior knowledge and machine learning. In the first part of this dissertation, we explore a method of registering domain names with deliberate typographical mistakes (i.e., typosquatting) to masquerade as popular and well-established domain names. To understand the effectiveness of typosquatting, we conducted a user study which helped shed light on which techniques …

Novel Relative Spontaneous Ignition Temperature Determination Using Carbon Dioxide Onset With Sta/Ir, Antonio David Trevino

Electronic Theses and Dissertations

Simultaneous thermal analysis, coupled with infrared spectroscopy (STA/IR), was utilized to monitor the evolution of gaseous products during the thermal degradation of samples from Triadica sebifera (Chinese tallow), Ligustrum sinense (Chinese privet), and Ilex vomitoria (yaupon) plants. Identification of carbon dioxide was successful with a spectral match of 90.2 percent and further used in the determination of relative spontaneous ignition temperature, or RSIT. The RSIT value during the growing season for Chinese tallow, Chinese tallow stem, Chinese privet, and Yaupon were 208.4°C, 250.3°C, 210.1°C, and 232.3°C respectively. During the dormant seasons, the values for Chinese tallow stem, Chinese privet, and …

Wald Confidence Intervals For A Single Poisson Parameter And Binomial Misclassification Parameter When The Data Is Subject To Misclassification, Nishantha Janith Chandrasena Poddiwala Hewage

Electronic Theses and Dissertations

This thesis is based on a Poisson model that uses both error-free data and error-prone data subject to misclassification in the form of false-negative and false-positive counts. We present maximum likelihood estimators (MLEs), Fisher's Information, and Wald statistics for Poisson rate parameter and the two misclassification parameters. Next, we invert the Wald statistics to get asymptotic confidence intervals for Poisson rate parameter and false-negative rate parameter. The coverage and width properties for various sample size and parameter configurations are studied via a simulation study. Finally, we apply the MLEs and confidence intervals to one real data set and another realistic …

Fault-Adjacent Damage At The Base Of The Seismogenic Zone And Seismic Anisotropy Of Fold Structures, Won Joon Song

Electronic Theses and Dissertations

While earthquakes represent a major hazard to life and property, there are a number of open questions about how earthquake faults operate at depth, and how the energy released by earthquakes travels as elastic waves through Earth’s complexly deformed crustal rocks. The aims of my dissertation are to explore (a) the extent of co-seismic damage in an ancient earthquake fault exhumed from great depths, (b) the deformation processes and mechanics of the fault at depth during earthquake cycles, and (c) the role of different rock structures in determining the velocities of seismic waves.

When tectonic plates collide, deformation tends to …

Frequency And Temperature Dependence Of Shear Wave Speed With Rheological Properties In A Micellar Fluid, E. G. Sunethra K. Dayavansha

Electronic Theses and Dissertations

Wormlike micellar fluids, which flow when subjected to long-term stresses, are mechanically viscoelastic over shorter durations and can support shear waves. These fluids are birefringent under shear, allowing the study of shear wave propagation using both optical and acoustic modalities. Microstructural phase transitions of the micelles are temperature dependent and can manifest as sharp changes in the shear wave speed as a function of temperature. In this work, the behavior of shear waves in a fluid consisting of hexadecyltrimethylammonium bromide (CTAB) and sodium salicylate (NaSal) combined in a 5:3 ratio in a 200 mM concentration is studied. The temperature-dependent microstructural …

Holocene Formation History Of Mud Depocenters On The Continental Shelf In The Gulf Of Cadiz, Southwestern Spain, Mary Lee King

Electronic Theses and Dissertations

Holocene mud accumulation on the continental shelf in northern Gulf of Cadiz, from the Guadalquivir River to the Tinto-Odiel Estuary, is described as two types of mud depocenters (MDCs): a sheet-like prodelta and mud belt. Despite a substantial number of investigations of this continental shelf (Somoza et al., 1997; Hernández-Molina et al., 2000; Lobo et al., 2001; synthesis: Lobo et al., 2015), information on Holocene sediment facies and a robust stratigraphic age model remained unestablished (Lobo et al., 2002; and Lobo and Ridente, 2014). Objectives of this study are to describe the dynamics of MDC formation in a chrono- and …

Hydrodynamic Drivers Of Dissolved Oxygen Variability Within A Highly Developed Tidal Creek In Myrtle Beach, South Carolina, Douglas Matthew Pastore

Electronic Theses and Dissertations

Erosion and water quality degradation have been observed in Singleton Swash in Myrtle Beach, SC, and have been hypothesized to be related to migration of the beach-face channel. Dredging this channel temporarily fixes erosional threats to nearby infrastructure but the effects on water quality are not well understood. It is hypothesized that variations in dissolved oxygen (DO) concentration (used here as a proxy for water quality) within the water column are related to changes in vertical mixing and transport due to oceanic tidal forcing. This study utilizes current meters, pressure sensors, and optical DO probes to measure and study the …

Seasonal Occurrence, Relative Abundance, And Migratory Movements Of Juvenile Sandbar Sharks, Carcharhinus Plumbeus, In Winyah Bay, South Carolina, Caroline Collatos

Electronic Theses and Dissertations

Winyah Bay, located on the coast of South Carolina, is the fourth largest U.S. estuary by discharge rate (Voulgaris et al. 2002), and provides an annually used habitat for juvenile C. plumbeus (Abel et al. 2006, Gary 2009). From May to September 2016 and 2017, we set a total of 303 bottom longlines in middle and lower Winyah Bay to assess sex ratios, size distributions, and catch per unit effort (CPUE), as well as the potential influence of abiotic parameters on CPUE. A subset of eleven juvenile C. plumbeus was tagged with VEMCO (V16-4H) acoustic transmitters to analyze seasonal occurrence, …

Hardbottom Characterization And Relationship To The Geologic Framework In Long Bay, South Carolina, Cathryn J. Wheaton

Electronic Theses and Dissertations

Hardbottom seafloor is a common element among sediment-starved portions of the inner continental shelf along the U.S. Atlantic margin. These areas are characterized by indurated sediment surfaces that are heavily altered by biological and physical processes. Long Bay, in northeastern South Carolina, offers ideal environmental conditions for hardbottom exposure with only patchy Holocene sand deposits, interspersed with extensive hardbottom areas. Here we use high-resolution multibeam bathymetry, CHIRP subbottom profiling and electrical resistivity data, along with surficial sediment samples, hardbottom thin sections, and water column radioisotope (radon-222) analysis to investigate the origin and geologic framework of a region of hardbottom seafloor …

Impact Of Data Selection On The Accuracy Of Atmospheric Refractivity Inversions Performed Over Marine Surfaces, Ian Joseph Matsko

Electronic Theses and Dissertations

Within the Earth’s atmosphere there is a planetary boundary layer that extends from the surface to roughly 1 km above the surface. Within this planetary boundary layer exists the marine atmospheric boundary layer, which is a complex turbulent surface layer that extends from the sea surface to roughly 100 m in altitude. The turbulent nature of this layer combined with the interactions across the air-sea interface cause ever changing environmental conditions within it, including atmospheric properties that affect the index of refraction, or atmospheric refractivity. Variations in atmospheric refractivity lead to many types of anomalous propagation phenomena of electromagnetic (EM) …

Semi-Quantitative Assessment On Winyah Bay's Microplastic Contamination Levels, Samantha Ladewig

Electronic Theses and Dissertations

Although there is much concern globally regarding microplastic contamination in aquatic environments, there is little documentation on microplastic contamination concentrations within South Carolina inland waters and coastal areas. Specifically, Winyah Bay, SC should be of high priority for microplastic contamination evaluations as it is the third largest drainage basin (47,060 km2) and the second largest (157 km2) estuarine system on the east coast of the United States. Today, the general influencing physical factors on microplastic transport are mostly known by the scientific community, however, transport and deposition patterns of microplastics heavily vary by location depending on various physical, chemical, and …

Circulation, Cross-Shelf Exchange, And Blue Mussel (Mytilus Edulis) Population Connectivity In A Complex, Tidally Driven System, Leann M. Conlon

Electronic Theses and Dissertations

Because many marine species have a planktonic larval phase, an understanding of population connectivity (the exchange of individuals among populations) is critical for better understanding their adult populations. However, connectivity depends on both circulation patterns and any interacting biological factors. Of particular importance to organisms originating nearshore is the amount of cross-shelf exchange, as larvae within the slower moving coastal boundary layer experience shorter dispersal distances. I investigated circulation patterns and cross-shelf exchange along the Eastern Maine coast, a region with strong tidal currents and a complex coastline bounded in the offshore direction by a faster moving coastal current. I …

Steric Effects Of Alkyl Ammonium Salts On The Combustion Of Exchanged Smectite Clays, Celeste A. Keith

Electronic Theses and Dissertations

Bomb calorimetry was explored as a new method for determining the cation exchange capacity (CEC) of clays. Smectite clays were modified with several alkyl ammonium salts varying in number of carbons and the spatial orientation of the carbons about the central nitrogen atom. The clays used, standards purchased from the Source Clay Repository, have CECs of 44, 80, 88, and 120 meq/100 g. Theoretically, the combustion energy of the organo-clays should be approximately the same for each salt. Any differences in energy would be due to the different structures of the salts and how they are oriented in the interlamellar …

Environmental Assessment Of Road Brining And Injection Wells For Disposal Of Oil And Gas Liquid Waste, Marissa Madia

Electronic Theses and Dissertations

The dramatic increase in oil and gas drilling operations in Pennsylvania over the last decade has presented a challenge for their wastewater disposal (e.g., flowback, produced water). Currently, these fluids are treated in permitted brine treatment plants or exported out of state to deep injection well facilities. In Pennsylvania, road brining for dust control is permitted for conventional well brines, and permits for three injection wells for unconventional brines are pending. This study focused on water quality impacts due to road brining in Farmington Township (45 samples) and ground and surface water in Grant Township (41 samples) prior to the …

Developing A Risk Assessment Protocol To Quantify Distribution And Uptake Of Persistent Organic Pollutants In Glacial Outflows, Kimberley Rain Miner

Electronic Theses and Dissertations

Pollutants released by industrialized nations between 1960 and 2004 have been transported northward through atmospheric processes and deposited into glaciated alpine ecosystems. Many of these chemicals retain their original structure and are absorbed into the biota thousands of miles away from where they were originally utilized. With a warming climate increasing the melt of alpine glaciers, these glaciers may be introducing growing amounts of toxins into the watershed. While studies have demonstrated the existence of resident pollutants within glaciated ecosystems, no one has developed a risk assessment to identify sources and quantity of risk posed by these compounds when released …

Extraction And Purification Of (E)-Resveratrol From The Bark Of Maine's Native Spruces, Panduka S. Piyaratne

Electronic Theses and Dissertations

Resveratrol is a plant secondary metabolite which protects plants from pathogenic invasions and acts as a remedial agent against injury, stress, and tissue damage by UV radiation. With its characteristic stilbene structure, resveratrol adopts (E) and (Z) isomeric forms. However, the (E) isomer is the most biologically active and abundant form of resveratrol in nature.

(E)- Resveratrol confers a variety of benefits to human health and well-being. Besides its antioxidant activity, the role of (E)-resveratrol as an anti-inflammatory, anti-aging, cardioprotection, and anticancer agent has been a widely explored research interest. …

New Approaches To Mapping Forest Conditions And Landscape Change From Moderate Resolution Remote Sensing Data Across The Species-Rich And Structurally Diverse Atlantic Northern Forest Of Northeastern North America, Kasey R. Legaard

Electronic Theses and Dissertations

The sustainable management of forest landscapes requires an understanding of the functional relationships between management practices, changes in landscape conditions, and ecological response. This presents a substantial need of spatial information in support of both applied research and adaptive management. Satellite remote sensing has the potential to address much of this need, but forest conditions and patterns of change remain difficult to synthesize over large areas and long time periods. Compounding this problem is error in forest attribute maps and consequent uncertainty in subsequent analyses. The research described in this document is directed at these long-standing problems.

Chapter 1 demonstrates …