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Articles 2701 - 2730 of 4195

Full-Text Articles in Physical Sciences and Mathematics

Valuation Of Over-The-Counter (Otc) Derivatives With Collateralization, Leon Guerrero Jan 2013

Valuation Of Over-The-Counter (Otc) Derivatives With Collateralization, Leon Guerrero

Electronic Theses and Dissertations

Collateralization in over-the-counter (OTC) derivatives markets has grown rapidly over the past decade, and even faster in the past few years, due to the impact of the recent financial crisis and the particularly important attention to the counterparty credit risk in derivatives contracts. The addition of collateralization to such contracts significantly reduces the counterparty credit risk and allows to offset liabilities in case of default. We study the problem of valuation of OTC derivatives with payoff in a single currency and with single underlying asset for the cases of zero, partial, and perfect collateralization. We assume the derivative is traded …


Dynamic Feedback Pulse Shaping For High Power Chirped Pulse Amplification System, Dat Nguyen Jan 2013

Dynamic Feedback Pulse Shaping For High Power Chirped Pulse Amplification System, Dat Nguyen

Electronic Theses and Dissertations

The topic of this proposal is the development of high peak power laser sources with a focus on linearly chirped pulse laser sources. In the past decade chirped optical pulses have found a plethora of applications such as photonic analog-to-digital conversion, optical coherence tomography, laser ranging, etc. This dissertation analyzes the aforementioned applications of linearly chirped pulses and their technical requirements, as well as the performance of previously demonstrated parabolic pulse shaping approaches. The experimental research addresses the topic of parabolic pulse generation in two distinct ways. First, pulse shaping technique involving a time domain approach is presented, that results …


Dynamical Invariants And The Fluid Impulse In Plasma Models, Martin Michalak Jan 2013

Dynamical Invariants And The Fluid Impulse In Plasma Models, Martin Michalak

Electronic Theses and Dissertations

Much progress has been made in understanding of plasmas through the use of the MHD equations and newer models such as Hall MHD and electron MHD. As with most equations of fluid behavior, these equations are nonlinear, and no general solutions can be found. The use of invariant structures allows limited predictions of fluid behavior without requiring a full solution of the underlying equations. The use of gauge transformation can allow the creation of new invariants, while differential geometry offers useful tools for constructing additional invariants from those that are already known. Using these techniques, new geometric, integral and topological …


Sediment Impact On The Formation Of Hypoxic Waters In The Northern Gulf Of Mexico: A Synthesis Of Sediment Texture, Composition, Erodibility And Transport, Rangley Claude Mickey Jan 2013

Sediment Impact On The Formation Of Hypoxic Waters In The Northern Gulf Of Mexico: A Synthesis Of Sediment Texture, Composition, Erodibility And Transport, Rangley Claude Mickey

Electronic Theses and Dissertations

Annual hypoxic events have been found to occur over the past several decades in the northern Gulf of Mexico (nGOM) and have prompted researchers to begin studying the mechanisms that control hypoxia formation so they may advise policy makers on the appropriate mitigating responses. This has led to the development of 3-dimensional modeling systems that incorporate marine physical, biological, geological, and chemical processes that may impact the formation and duration of hypoxic regimes in the nGOM. This study used field, laboratory, and modeling techniques to examine how sediment may be eroded from the seabed and where/how it is transported across …


Femtosecond Filament Interaction As A Probe For Molecular Alignment, Erik Mckee Jan 2013

Femtosecond Filament Interaction As A Probe For Molecular Alignment, Erik Mckee

Electronic Theses and Dissertations

Femtosecond laser filamentation is a highly nonlinear propagation mode. When a laser pulse propagates with a peak power exceeding a critical value Pcr (5 GW at 800 nm in air), the Kerr effect tends to collapse the beam until the intensity is high enough to ionize the medium, giving rise to plasma defocusing. A dynamic competition between these two effects takes place leaving a thin and weakly ionized plasma channel in the trail of the pulse. When an ultrafast laser pulse interacts with molecules, it will align them, spinning them about their axis of polarization. As the quantum rotational wave …


On The Capillary Electrophoresis Of Monohydroxy Metabolites Of Polycyclic Aromatic Hydrocarbons And Its Application To The Analysis Of Biological Matrices, Gaston Knobel Jan 2013

On The Capillary Electrophoresis Of Monohydroxy Metabolites Of Polycyclic Aromatic Hydrocarbons And Its Application To The Analysis Of Biological Matrices, Gaston Knobel

Electronic Theses and Dissertations

Polycyclic aromatic hydrocarbons (PAH) are a class of environmental pollutants consisting of a minimum of two fused aromatics rings originating from the incomplete combustion of organic matter and/or anthropogenic sources. Numerous possible anthropogenic and natural sources make the presence of PAH ubiquitous in the environment. The carcinogenic nature of some PAH and their ubiquitous presence makes their chemical analysis a topic of environmental and toxicological importance. Although environmental monitoring of PAH is an important step to prevent exposure to contaminated sites, it provides little information on the actual uptake and subsequent risks. Parent PAH are relatively inert and need metabolic …


Climate Change Impacts On Rainfed Corn Production In Malawi, Kondwani Msowoya Jan 2013

Climate Change Impacts On Rainfed Corn Production In Malawi, Kondwani Msowoya

Electronic Theses and Dissertations

Agriculture is the mainstay of the economy in Malawi and accounts for 40% of the Gross Domestic Product (GDP) and 90% of the export revenues. Corn (maize) is the major cereal crop grown as staple food under rainfed conditions, covers over 92% of the total agricultural area, and contributes 54% of the caloric intake. Corn production is the principle occupation and major source of income for over 85% of the total population in Malawi. Issues of hunger and food insecurity for the entire nation are associated with corn scarcity and low production. Global warming is expected to cause climate change …


Developing A Group Decision Support System (Gdss) For Decision Making Under Uncertainty, Soroush Mokhtari Jan 2013

Developing A Group Decision Support System (Gdss) For Decision Making Under Uncertainty, Soroush Mokhtari

Electronic Theses and Dissertations

Multi-Criteria Decision Making (MCDM) problems are often associated with tradeoffs between performances of the available alternative solutions under decision making criteria. These problems become more complex when performances are associated with uncertainty. This study proposes a stochastic MCDM procedure that can handle uncertainty in MCDM problems. The proposed method coverts a stochastic MCDM problem into many deterministic ones through a Monte-Carlo (MC) selection. Each deterministic problem is then solved using a range of MCDM methods and the ranking order of the alternatives is established for each deterministic MCDM. The final ranking of the alternatives can be determined based on winning …


Metrology Of Volume Chirped Bragg Gratings Recorded In Photo-Thermo-Refractive Glass For Ultrashort Pulse Stretching And Compressing, Christopher Lantigua Jan 2013

Metrology Of Volume Chirped Bragg Gratings Recorded In Photo-Thermo-Refractive Glass For Ultrashort Pulse Stretching And Compressing, Christopher Lantigua

Electronic Theses and Dissertations

Chirped Bragg gratings (CBGs) recorded in photo-thermo-refractive (PTR) glass provide a very efficient and robust way to stretch and compress ultra-short laser pulses. These gratings offer the ability to stretch pulses from hundreds of femtoseconds, to the order of 1 ns and then recompress them. However, in order to achieve pulse stretching of this magnitude, 100 mm thick CBGs are needed. Using these CBGs to both stretch, and re-compress the pulse thus requires propagation through 200 mm of optical glass. This therefore demands perfect control of the glass homogeneity, as well as the holographic recording process of the CBG. In …


Extensions Of S-Spaces, Bernd Losert Jan 2013

Extensions Of S-Spaces, Bernd Losert

Electronic Theses and Dissertations

Given a convergence space X, a continuous action of a convergence semigroup S on X and a compactification Y of X, under what conditions on X and the action on X is it possible to extend the action to a continuous action on Y . Similarly, given a Cauchy space X, a Cauchy continuous action of a Cauchy semigroup S on X and a completion Y of X, under what conditions on X and the action on X is it possible to extend the action to a Cauchy continuous action on Y . We answer the first question for some …


Trace Contaminant Control: An In-Depth Study Of A Silica-Titania Composite For Photocatalytic Remediation Of Closed-Environment Habitat Air, Janelle Coutts Jan 2013

Trace Contaminant Control: An In-Depth Study Of A Silica-Titania Composite For Photocatalytic Remediation Of Closed-Environment Habitat Air, Janelle Coutts

Electronic Theses and Dissertations

This collection of studies focuses on a PCO system for the oxidation of a model compound, ethanol, using an adsorption-enhanced silica-Ti02 composite (STC) as the photocatalyst; studies are aimed at addressing the optimization of various parameters including light source, humidity, temperature, and possible poisoning events for use as part of a system for gaseous trace-contaminant control system in closed-environment habitats. The first goal focused on distinguishing the effect of photon flux (i.e., photons per unit time reaching a surface) from that ofphoton energy (i.e., wavelength) of a photon source on the PCO of ethanol. Experiments were conducted in a bench-scale …


Investigation Of A Novel Magnesium And Acidified Ethanol System For The Degradation Of Persistent Organic Pollutants, Phillip Maloney Jan 2013

Investigation Of A Novel Magnesium And Acidified Ethanol System For The Degradation Of Persistent Organic Pollutants, Phillip Maloney

Electronic Theses and Dissertations

For centuries chemists have sought to improve humankind’s quality of life and address many of society’s most pressing needs through the development of chemical processes and synthesis of new compounds, often with phenomenal results. Unfortunately, there also are many examples where these chemicals have had unintended, detrimental consequences that are not apparent until years or decades after their initial use. There are numerous halogenated molecules in this category that are globally dispersed, resistant to natural degradation processes, bioaccumulative, and toxic to living organisms. Chemicals such as these are classified as persistent organic pollutants (POPs), and due to their negative environmental …


Virtual Interactions With Real-Agents For Sustainable Natural Resource Management, Tyler Pierce Jan 2013

Virtual Interactions With Real-Agents For Sustainable Natural Resource Management, Tyler Pierce

Electronic Theses and Dissertations

Common pool resource management systems are complex to manage due to the absence of a clear understanding of the effects of users’ behavioral characteristics. Non-cooperative decision making based on individual rationality (as opposed to group rationality) and a tendency to free ride due to lack of trust and information about other users’ behavior creates externalities and can lead to tragedy of the commons without intervention by a regulator. Nevertheless, even regulatory institutions often fail to sustain natural common pool resources in the absence of clear understanding of the responses of multiple heterogeneous decision makers to different regulation schemes. While modeling …


Reduced Susceptibility Of Deformation Due To Vibrational And Gravitational Effects On A Focus Variable Adaptive Lens, Victoriya Relina Jan 2013

Reduced Susceptibility Of Deformation Due To Vibrational And Gravitational Effects On A Focus Variable Adaptive Lens, Victoriya Relina

Electronic Theses and Dissertations

Orthodox optical devices, such as lenses, mirrors, and prisms, are composed of solidstate materials, which although well studied and implemented ubiquitously are severely limited in their adaptable properties. An arguably new field of adaptive optics has emerged to further expand photonic manipulation competences of optical components. Fluid-based adaptive optical components were introduced as early as 1968 [1]; such components have the ability to change the shape of their interface surface, thus allowing for a variable curvature profile. The method of manipulation varies greatly, as does the range of surface deformations. A solid-state optical component is affected by system vibration variation …


Photophysical And Photochemical Factors Affecting Multi-Photon Direct Laser Writing Using The Cross-Linkable Epoxide Su-8, Henry Williams Jan 2013

Photophysical And Photochemical Factors Affecting Multi-Photon Direct Laser Writing Using The Cross-Linkable Epoxide Su-8, Henry Williams

Electronic Theses and Dissertations

For the past decade, the epoxy based photoresist SU-8 has been used commercially and in the lab for fabricating micro- and nano-structures. Investigators have studied how processing parameters such as pre- and post-exposure bake temperatures affect the resolution and quality of SU-8 structures patterned using ultraviolet or x-ray lithography. Despite the advances in understanding the phenomena, not all of them have been explored, especially those that are specific to multi-photon direct laser writing (mpDLW). Unlike conventional exposure techniques, mpDLW is an inherently three-dimensional (3D) process that is activated by nonlinear absorption of light. This dissertation reports how several key processing …


Mesoscale Light-Matter Interactions, Kyle Douglass Jan 2013

Mesoscale Light-Matter Interactions, Kyle Douglass

Electronic Theses and Dissertations

Mesoscale optical phenomena occur when light interacts with a number of different types of materials, such as biological and chemical systems and fabricated nanostructures. As a framework, mesoscale optics unifies the interpretations of the interaction of light with complex media when the outcome depends significantly upon the scale of the interaction. Most importantly, it guides the process of designing an optical sensing technique by focusing on the nature and amount of information that can be extracted from a measurement. Different aspects of mesoscale optics are addressed in this dissertation which led to the solution of a number of problems in …


Peak Power Scaling Of Nanosecond Pulses In Thulium Based Fiber Lasers, Christian Gaida Jan 2013

Peak Power Scaling Of Nanosecond Pulses In Thulium Based Fiber Lasers, Christian Gaida

Electronic Theses and Dissertations

Thulium based fiber lasers represent a promising alternative for pulse energy scaling and high peak power generation with ytterbium based systems at 1µm. Advantages of thulium arise from the operation at longer wavelengths and a large gain bandwidth (1.8-2.1µm). Nonlinear effects, such as self phase modulation, stimulated Raman scattering and stimulated Brillouin scattering generally limit peak power scaling in fiber lasers. The longer wavelength of thulium fiber lasers and large mode field areas can significantly increase the nonlinear thresholds. Compared to 1µm systems, thulium fiber lasers enable single mode guidance for two times larger mode field diameter in step index …


Development Of Laser Spectroscopy For Elemental And Molecular Analysis, Yuan Liu Jan 2013

Development Of Laser Spectroscopy For Elemental And Molecular Analysis, Yuan Liu

Electronic Theses and Dissertations

Laser-Induced Breakdown Spectroscopy (LIBS) and Raman spectroscopy are still growing analytical and sensing spectroscopic techniques. They significantly reduce the time and labor cost in analysis with simplified instrumentation, and lead to minimal or no sample damage. In this dissertation, fundamental studies to improve LIBS analytical performance were performed and its fusion with Raman into one single sensor was explored. On the fundamental side, Thomson scattering was reported for the first time to simultaneously measure the electron density and temperature of laser plasmas from a solid aluminum target at atmospheric pressure. Comparison between electron and excitation temperatures brought insights into the …


Sagebrush Ecosystem Characterization, Monitoring, And Forecasting With Remote Sensing: Quantifying Future Climate And Wildlife Habitat Change, Collin G. Homer Jan 2013

Sagebrush Ecosystem Characterization, Monitoring, And Forecasting With Remote Sensing: Quantifying Future Climate And Wildlife Habitat Change, Collin G. Homer

Electronic Theses and Dissertations

Sagebrush (Artemisia spp.) ecosystems constitute the largest single North American shrub ecosystem and provide vital ecological, hydrological, biological, agricultural, and recreational ecosystem services. Disturbances continue to alter this ecosystem, with climate change possibly representing the greatest future disturbance risk. Improved ways to characterize and monitor gradual change in this ecosystem are vital to its future management. A new remote sensing sagebrush characterization approach was developed in Wyoming which integrates three scales of remote sensing to derive four primary continuous field components (bare ground, herbaceousness, litter, and shrub), and four secondary components (sagebrush, big sagebrush, Wyoming sagebrush, and shrub …


Hjb Equation And Statistical Arbitrage Applied To High Frequency Trading, Yonggi Park Jan 2013

Hjb Equation And Statistical Arbitrage Applied To High Frequency Trading, Yonggi Park

Electronic Theses and Dissertations

In this thesis we investigate some properties of market making and statistical arbitrage applied to High Frequency Trading (HFT). Using the Hamilton-Jacobi-Bellman(HJB) model developed by Guilbaud, Fabien and Pham, Huyen in 2012, we studied how market making works to obtain optimal strategy during limit order and market order. Also we develop the best investment strategy through Moving Average, Exponential Moving Average, Relative Strength Index, Sharpe Ratio.


Spectrally Uniform Frames And Spectrally Optimal Dual Frames, Saliha Pehlivan Jan 2013

Spectrally Uniform Frames And Spectrally Optimal Dual Frames, Saliha Pehlivan

Electronic Theses and Dissertations

Frames have been useful in signal transmission due to the built in redundancy. In recent years, the erasure problem in data transmission has been the focus of considerable research in the case the error estimate is measured by operator (or matrix) norm. Sample results include the characterization of one-erasure optimal Parseval frames, the connection between two-erasure optimal Parseval frames and equiangular frames, and some characterization of optimal dual frames. If iterations are allowed in the reconstruction process of the signal vector, then spectral radius measurement for the error operators is more appropriate then the operator norm measurement. We obtain a …


Development Of An Efficient Molecular Single-Electron Transport Spectroscopy, Alvar Garrigues Jan 2013

Development Of An Efficient Molecular Single-Electron Transport Spectroscopy, Alvar Garrigues

Electronic Theses and Dissertations

In this thesis I present a complete and detailed guide for the development process and fabrication of efficient single-electron transistors (SETs) and a better single-molecule magnets (SMMs) deposition yield. Starting from a commercial Si/SiO2 wafer I show the steps for the deposition of different layers to fabricate a SET as well as the improvements achieved in those for a completely functional SET device. The development process is based on a combination of optical lithography and e-beam lithography with metal deposition in ultra-high vacuum. The improvements involve a better conductance in the Al gate component, with a controlled formation of the …


Biochemical Characterization Of The Nifb Enzyme And Nifb-Cofactor, Jirair Gevorkyan Jan 2013

Biochemical Characterization Of The Nifb Enzyme And Nifb-Cofactor, Jirair Gevorkyan

Electronic Theses and Dissertations

The Mo-nitrogenase complex is composed of two components, Fe-protein and MoFe-protein. This complex is able to catalyze the reduction of N2 through the MgATP dependent transfer of electrons from the Fe-protein Fe4S4 cluster to the MoFe-protein P-cluster and, subsequently, to the iron-molybdenum cofactor (FeMoco). FeMo-co is a Fe7S9MoC-(R)-homocitrate cluster and has two biosynthetic precursors, NifB-co and L-cluster, of unknown structure and composition. The biosynthesis of FeMo-co is an enigmatic process that minimally requires NifB, NifEN, Fe-protein, MoO4 2- , (R)-homocitrate and S-adenolsylmethionine. A means to isolate the NifB enzyme for characterization has been developed through use of a GST-fusion tag. …


Development Of Novel Redox Sensors And Processes Towards Biological Applications, Jigna Patel Jan 2013

Development Of Novel Redox Sensors And Processes Towards Biological Applications, Jigna Patel

Electronic Theses and Dissertations

Research on the cure and early detection of diseases such as diabetes, Alzheimer's, and Parkinson's is becoming of great interest due to the increasing number of people affected by them every year. An accurate and quick detection of various damaging species is highly critical in treatments of such diseases not only for exploring possible cures but also for early detection. If these diseases are detected during the initial stages than the possibility of curing them is much higher. Motivated by this, many researchers today have developed numerous types of sensing devices that can detect various physiological and biological compounds. However, …


Development Of Thulium Fiber Lasers For High Average Power And High Peak Power Operation, Robert Sims Jan 2013

Development Of Thulium Fiber Lasers For High Average Power And High Peak Power Operation, Robert Sims

Electronic Theses and Dissertations

High power thulium fiber lasers are useful for a number of applications in both continuous-wave and pulsed operating regimes. The use of thulium as a dopant has recently gained interest due to its large bandwidth, possibility of high efficiency, possibility of high power and long wavelength ~1.8 – 2.1 μm. The longer emission wavelength of Tm-doped fiber lasers compared to Yb- and/or Er-doped fiber lasers creates the possibility for higher peak power operation due to the larger nonlinear thresholds and reduced nonlinear phase accumulation. One primary interest in Tm-doped fiber lasers has been to scale to high average powers; however, …


Field Theoretic Lagrangian From Off-Shell Supermultiplet Gauge Quotients, Gregory Katona Jan 2013

Field Theoretic Lagrangian From Off-Shell Supermultiplet Gauge Quotients, Gregory Katona

Electronic Theses and Dissertations

Recent efforts to classify off-shell representations of supersymmetry without a central charge have focused upon directed, supermultiplet graphs of hypercubic topology known as Adinkras. These encodings of Super Poincare algebras, depict every generator of a chosen supersymmetry as a node-pair transformtion between fermionic bosonic component fields. This research thesis is a culmination of investigating novel diagrammatic sums of gauge-quotients by supersymmetric images of other Adinkras, and the correlated building of field theoretic worldline Lagrangians to accommodate both classical and quantum venues. We find Ref [40], that such gauge quotients do not yield other stand alone or "proper" Adinkras as afore …


Non-Degenerate Two Photon Gain In Bulk Gallium Arsenide, Brendan Turnbull Jan 2013

Non-Degenerate Two Photon Gain In Bulk Gallium Arsenide, Brendan Turnbull

Electronic Theses and Dissertations

The purpose of this thesis is to investigate the nonlinear phenomena known as doubly-stimulated, non-degenerate two-photon emission (ND-2PE) in Gallium Arsenide (GaAs). 2PE refers to the simultaneous emission of two-photons as electrons move from the conduction band in a direct gap semiconductor to the valence band. Following the same path for describing one-photon emission (1PE) we describe 2PE as a product of the irradiance, and the negative of the loss which in this case is two-photon absorption, , the negative coming from the population inversion. We attempt to observe 2PE by using a frequency non-degenerate pump-probe experiment in which a …


Economic Valuation Of Florida Sea Turtles In Face Of Sea Level Rise, Ahmed Hamed Jan 2013

Economic Valuation Of Florida Sea Turtles In Face Of Sea Level Rise, Ahmed Hamed

Electronic Theses and Dissertations

Sea level rise (SLR) is posing a great risk of flooding and inundation to coastal areas in Florida. Some coastal nesting species, including sea turtle species, have experienced diminished habitat from SLR. In an effort to assess the economic and ecosystem service loss to coastal areas with respect to sea turtles Contingent Valuation Method (CVM) and Habitat Equivalency Analysis (HEA) were used. The CVM was used to measure the economic impacts of SLR on sea turtles. Open-ended and dichotomous choice CVM was used to obtain the willingness to pay (WTP) values of Florida residents to implement certain mitigation strategies which …


Magnesium And Acidified Ethanol Based Treatment Systems For The Extraction And Dechlorination Of Polychlorinated Biphenyls From Contaminated Oils, Paints, And Soils, Simone Novaes-Card Jan 2013

Magnesium And Acidified Ethanol Based Treatment Systems For The Extraction And Dechlorination Of Polychlorinated Biphenyls From Contaminated Oils, Paints, And Soils, Simone Novaes-Card

Electronic Theses and Dissertations

Polychlorinated biphenyls (PCBs) are a class of environmentally persistent halogenated organic compounds that were once used as stabilizers to improve the properties of a variety of materials such as lubricants, heat transfer fluids, paints, and caulking materials. PCBs are also capable of migration through processes such as spillage into soils, leaching into groundwater, and volatilization into the atmosphere. Although banned in 1979 over health concerns, PCBs persist in these materials to this day because they are resistant to biotic degradation and natural weathering processes. The wide variety of contaminated materials means that many existing treatment options cannot be used across …


Computational Approach To The Problems Of Electro- And Photo-Catalysis, Sebastian Zuluaga Jan 2013

Computational Approach To The Problems Of Electro- And Photo-Catalysis, Sebastian Zuluaga

Electronic Theses and Dissertations

The main objective of this work is to gain basis for rational design of catalysts used in fuel cells for conversion of chemical energy stored in hydrogen molecules into electric energy, as well as photo-catalysts used for hydrogen production from water under solar irradiation. This objective is achieved by applying the first principles computational approach to reveal relationship among compositions of materials under consideration, their electronic structure and catalytic activity. A major part of the work is focused on electro-catalysts for hydrogen fuel cells. Platinum (Pt) is widely used in the electrodes of fuel cells due to its good catalytic …