Physical Sciences and Mathematics Commons^™

Beam Deflection, Matthias Münnich,

Electronic Theses and Dissertations

In order to fully understand the third order nonlinear optical response of materials under high irradiance excitation it is necessary to study the temporal and polarization dependence of nonlinear refraction and absorption. There are several existing approaches such as Z-scan and pump-probe techniques to determine those responses. As part of this work, these approaches will be briefly outlined before presenting beam deflection, applied from photothermal beam deflection, as an alternative experimental technique to determine the nonlinear refraction with its temporal and polarization dynamics. This technique measures the angle of the probe beam deflected via the index gradient of the material …

High Flux Isolated Attosecond Pulse Generation, Yi Wu

Electronic Theses and Dissertations

This thesis outlines the high intensity tabletop attosecond extreme ultraviolet laser source at the Institute for the Frontier of Attosecond Science and Technology Laboratory. First, a unique Ti:Sapphire chirped pulse amplifier laser system that delivers 14 fs pulses with 300 mJ energy at a 10 Hz repetition rate was designed and built. The broadband spectrum extending from 700 nm to 900 nm was obtained by seeding a two stage Ti:Sapphire chirped pulse power amplifier with mJ-level white light pulses from a gas filled hollow core fiber. It is the highest energy level ever achieved by a broadband pulse in a …

Volume Phase Masks In Photo-Thermo-Refractive Glass, Marc Segall

Electronic Theses and Dissertations

In many applications such as beam shaping, mode conversion, and phase encoding it is necessary to alter the spatial phase profile of a beam via a phase mask. Conventional techniques to accomplish this either involve surface relief profiling in thin films such as PMMA or refractive index modulation in bulk photorefractive crystals such as lithium niobate. These materials have been used extensively for the past several decades and perform admirably in low power conditions. However, in high power systems these materials will be destroyed, requiring a new means of producing phase masks. In this dissertation a method for producing robust …

Prediction Of Optical Properties Of Pi-Conjugated Organic Materials For Technological Innovations, Iffat Nayyar

Electronic Theses and Dissertations

Organic π-conjugated solids are promising candidates for new optoelectronic materials. The large body of evidence points at their advantageous properties such as high charge-carrier mobility, large nonlinear polarizability, mechanical flexibility, simple and low cost fabrication and superior luminescence. They can be used as nonlinear optical (NLO) materials with large two-photon absorption (2PA) and as electronic components capable of generating nonlinear neutral (excitonic) and charged (polaronic) excitations. In this work, we investigate the appropriate theoretical methods used for the (a) prediction of 2PA properties for rational design of organic materials with improved NLO properties, and (b) understanding of the essential electronic …

Phase-Locking Stability Of A Quasi-Single-Cycle Pulse, Nathan Bodnar

Electronic Theses and Dissertations

There is increasing interest in the generation of very short laser pulses, even down to attosecond (10-18 s) durations. Laser systems with femtosecond pulse durations are needed for these applications. For many of these applications, positioning of the maximum electric field within the pulse envelope can affect the outcome. The peak of the electric field relative to the peak of the pulse is called the Carrier Envelope Phase (CEP). Controlling the position of the electric field becomes more important when pulse duration approaches single-cycle. This thesis focuses on the stabilization of a quasi-single-cycle laser facility. Improvements to this already-established laser …

External Cavity Mode-Locked Semiconductor Lasers For The Generation Of Ultra-Low Noise Multi-Gigahertz Frequency Combs And Applications In Multi-Heterodyne Detection Of Arbitrary Optical Waveforms, Josue Davila-Rodriguez

Electronic Theses and Dissertations

The construction and characterization of ultra-low noise semiconductor-based mode-locked lasers as frequency comb sources with multi-gigahertz combline-to-combline spacing is studied in this dissertation. Several different systems were built and characterized. The first of these systems includes a novel mode-locking mechanism based on phase modulation and periodic spectral filtering. This mode-locked laser design uses the same intra-cavity elements for both mode-locking and frequency stabilization to an intra-cavity, 1,000 Finesse, Fabry-Pérot Etalon (FPE). On a separate effort, a mode-locked laser based on a Slab-Coupled Optical Waveguide Amplifier (SCOWA) was built. This system generates a pulse-train with residual timing jitter of

The Impact Of Growth Conditions On Cubic Znmgo Ultraviolet Sensors, Ryan Boutwell

Electronic Theses and Dissertations

Cubic Zn1-xMgxO (c-Zn1-xMgxO) thin films have opened the deep ultraviolet (DUV) spectrum to exploration by oxide optoelectronic devices. These extraordinary films are readily wet-etch-able, have inversion symmetric lattices, and are made of common and safe constituents. They also host a number of new exciting experimental and theoretical challenges. Here, the relation between growth conditions of the c-Zn1-xMgxO film and performance of fabricated ultraviolet (UV) sensors is investigated. Plasma-Enhanced Molecular Beam Epitaxy was used to grow Zn1-xMgxO thin films and formation conditions were explored by varying the growth temperature, Mg source flux, oxygen flow rate, and radio-frequency (RF) power coupled into …

Properties Of High Energy Laser Light Transmission Through Large Core Optical Cables, Christopher Kennedy

Electronic Theses and Dissertations

Laser induced damage is of interest in studying the transmission of large amounts of optical energy through step-index, large core multimode fibers. Optical fibers often have to be routed around objects when laser light is being transmitted between two locations which require the fiber to bend into a curve. Depending on how tight the bend is, this can result in transmission losses or even catastrophic damage when the energy density of the laser pulse exceeds the damage threshold of silica glass. The purpose of this study is to: Establish a minimum bend radius that would allow high energy (GW/cm2 ) …

High Energy, High Average Power, Picosecond Laser Systems To Drive Few-Cycle Opcpa, Andreas Vaupel

Electronic Theses and Dissertations

The invention of chirped-pulse amplification (CPA) in 1985 led to a tremendous increase in obtainable laser pulse peak intensities. Since then, several table-top, Ti:sapphire-based CPA systems exceeding the 100 TW-level with more than 10 W average power have been developed and several systems are now commercially available. Over the last decade, the complementary technology of optical parametric chirped-pulse amplification (OPCPA) has improved in its performance to a competitive level. OPCPA allows direct amplification of an almost-octave spanning bandwidth supporting few-cycle pulse durations at center wavelengths ranging from the visible to the mid-IR. The current record in peak power from a …

Mode-Division Multiplexed Transmission In Few-Mode Fibers, Neng Bai

Electronic Theses and Dissertations

As a promising candidate to break the single-mode fiber capacity limit, mode-division multiplexing (MDM) explores the spatial dimension to increase transmission capacity in fiberoptic communication. Two linear impairments, namely loss and multimode interference, present fundamental challenges to implementing MDM. In this dissertation, techniques to resolve these two issues are presented. To de-multiplex signals subject to multimode interference in MDM, Multiple-InputMultiple-Output (MIMO) processing using adaptive frequency-domain equalization (FDE) is proposed and investigated. Both simulations and experiments validate that FDE can reduce the algorithmic complexity significantly in comparison with the conventional time-domain equalization (TDE) while achieving similar performance as TDE. To further …

Mathematical Modeling And Analysis Of Asthma Stability And Severity, Arezoo Hanifi

Electronic Theses and Dissertations

Asthma is one of the most common chronic conditions in the United States. Asthma affects about one in fifteen people. It affects children more than adults and blacks more than whites. People with asthma experience attacks of wheezing, breathlessness, chest tightness, and coughing. Asthma can be fatal and the costs for the disease (direct and indirect) are approximated to be tens of billions of dollars each year.

There is no cure for asthma. However; for most people if asthma is controlled well they can lead normal, active lives. Therefore asthma controllability is a main factor in clinical practice. In order …

Ecology Of Glacial Relict Fishes In South Dakota's Sandhills Region, Eli Felts

Electronic Theses and Dissertations

Native stream fish zoogeography has changed substantially across North America during the last century as habitat degradation, stream fragmentation and introductions of nonnative species have led to numerous extinctions, extirpations and altered distributions. Insufficient information regarding imperiled species often results in reactive, rather than proactive, management, and knowledge of species status and ecology is critical in identifying conservation priorities. South Dakota populations of three dace species (northern redbelly dace Chrosomus eos, finescale dace Chrosomus neogaeus, and pearl dace Margariscus margarita) are relict of Pleistocene Glaciation and are isolated from the northern core of their distribution, but little information exists regarding …

Accelerated Data Delivery Architecture, Michael L. Grecol

Electronic Theses and Dissertations

This paper introduces the Accelerated Data Delivery Architecture (ADDA). ADDA establishes a framework to distribute transactional data and control consistency to achieve fast access to data, distributed scalability and non-blocking concurrency control by using a clean declarative interface. It is designed to be used with web-based business applications. This framework uses a combination of traditional Relational Database Management System (RDBMS) combined with a distributed Not Only SQL (NoSQL) database and a browser-based database. It uses a single physical and conceptual database schema designed for a standard RDBMS driven application. The design allows the architect to assign consistency levels to entities …

Chemometric Applications To A Complex Classification Problem: Forensic Fire Debris Analysis, Erin Waddell

Electronic Theses and Dissertations

Fire debris analysis currently relies on visual pattern recognition of the total ion chromatograms, extracted ion profiles, and target compound chromatograms to identify the presence of an ignitable liquid. This procedure is described in the ASTM International E1618-10 standard method. For large data sets, this methodology can be time consuming and is a subjective method, the accuracy of which is dependent upon the skill and experience of the analyst. This research aimed to develop an automated classification method for large data sets and investigated the use of the total ion spectrum (TIS). The TIS is calculated by taking an average …

Planar Organic Photovoltaic Devices, Feras Alzubi

Electronic Theses and Dissertations

Organic Photovoltaic devices (OPV) are considered to be attractive candidates for clean and renewable energy source because of their potential for low cost of fabrication, easy processing, and their mechanical flexibility. The device efficiency of OPV cells are limited by several factors. Among them are: (i) donor-acceptor interface, (ii) morphology of the materials, (iii) electrode-organic semiconductor (OSC) interface and (iv) device architecture such as active material thickness and electrode separation. Although, the donor-acceptor interface has been studied in detail, the commonly prevalent vertical OPV device structure does not allow a good understanding of the other key issues as the vertical …

Solid Phase Extraction Room Temperature Fluorescence Spectroscopy For The Direct Quantification Of Monohydroxy Metabolites Of Polycyclic Aromatic Hydrocarbons In Urine Samples, Korina Jesusa Calimag

Electronic Theses and Dissertations

Polycyclic aromatic hydrocarbons (PAH) are important environmental pollutants generally formed during incomplete combustion of organic matter containing carbon and hydrogen. Introduced into the human body by adsorption through the skin, ingestion or inhalation, the biotransformation processes of PAH lead to the formation of multiple metabolites. Due to the short elimination lifetime from the body, the quantitative determination of monohydroxy-PAH (OH-PAH) in urine samples provides accurate information on recent exposure to environmental PAH. Urine analysis of OH-PAH with established methodology relies on sample clean-up and pre-concentration followed by chromatographic separation and quantification. Although chromatographic techniques provide reliable results in the analysis …

Modified Pal Interpolation And Sampling Bilevel Signals With Finite Rate Of Innovation, Gayatri Ramesh

Electronic Theses and Dissertations

Sampling and interpolation are two important topics in signal processing. Signal processing is a vast field of study that deals with analysis and operations of signals such as sounds, images, sensor data, telecommunications and so on. It also utilizes many mathematical theories such as approximation theory, analysis and wavelets. This dissertation is divided into two chapters: Modified Pal´ Interpolation and Sampling Bilevel Signals with Finite Rate of Innovation. In the first chapter, we introduce a new interpolation process, the modified Pal interpolation, based on papers by P ´ al, J ´ oo´ and Szabo, and we establish the existence and …

Using Freebase, An Automatically Generated Dictionary, And A Classifier To Identify A Person's Profession In Tweets, Abraham Hall

Electronic Theses and Dissertations

Algorithms for classifying pre-tagged person entities in tweets into one of eight profession categories are presented. A classifier using a semi-supervised learning algorithm that takes into consideration the local context surrounding the entity in the tweet, hash tag information, and topic signature scores is described. In addition to the classifier, this research investigates two dictionaries containing the professions of persons. These two dictionaries are used in their own classification algorithms which are independent of the classifier. The method for creating the first dictionary dynamically from the web and the algorithm that accesses this dictionary to classify a person into one …

X-Band Rapid-Scan Epr, Deborah Gale Mitchell

Electronic Theses and Dissertations

The advantages of rapid-scan EPR relative to CW and pulse techniques for samples with long longitudinal relaxation time T₁ (N_s⁰ defects in diamond, N@C₆₀, and amorphous hydrogenated silicon), heterogeneous samples (crystalline 1:1 α,γ-bisdiphenylene-β-phenylallyl (BDPA):benzene), lossy samples (aqueous nitroxyl radicals), and transient radicals (5-tert-butoxycarbonyl-5-methyl-1-pyrroline-N-oxide (BMPO)-superoxide adduct) were studied.

For samples with long relaxation times, CW (continuous wave) EPR is challenging due to power saturation and distortions from passage effects. In rapid-scan EPR, the field is swept through resonance in a time that is short relative to T₂. In rapid-scan EPR, the magnetic field is …

Method Development Using Laser Ablation And Solution Icpms And Their Application In Environmental Science And Forensic Provenance Studies, Kaixuan Bu

Electronic Theses and Dissertations

Inductively coupled plasma mass spectrometry (ICPMS) is an analytical technique that can be used to determine multiple elements and isotope ratios in a wide variety of samples. In this work, four projects are described that involve the method development using laser ablation (LA) and solution-based ICPMS and their application in environmental science and forensic (provenance) investigations. In the first project, plutonium (Pu) concentrations and 240Pu/ 239Pu atom ratios were measured in kelp, lichen, aquatic moss, and horse mussel collected on or near Amchitka Island, a former nuclear test in Alaska, and at a background site. The Pu in terrestrial and …

Interaction Of The Cyclonic Winds With The Infrasonic Signal Generated By A Large Maritime Storm, Philip Stephen Blom

Electronic Theses and Dissertations

The collision of counter propagating ocean surface waves of like periods is known to produce an infrasonic signal termed a microbarom. It has been suggested that microbaroms associated with large maritime storms are generated far from the storm center at a location in which the storm swell and background swell have equal period and are counter-propagating. It is shown in this work that the interaction of the atmospheric microbarom signal generated by a large maritime storm with the cyclonic winds of the storm results in a characteristic acoustic signal far from the storm which could potentially be used to estimate …

Smooth And Non-Smooth Traveling Wave Solutions Of Some Generalized Camassa-Holm Equations, Taslima Rehman

Electronic Theses and Dissertations

In this thesis we employ two recent analytical approaches to investigate the possible classes of traveling wave solutions of some members of recently derived integrable family of generalized Camassa-Holm (GCH) equations. In the first part, a novel application of phase-plane analysis is employed to analyze the singular traveling wave equations of four GCH equations, i.e. the possible non-smooth peakon, cuspon and compacton solutions. Two of the GCH equations do no support singular traveling waves. We generalize an existing theorem to establish the existence of peakon solutions of the third GCH equation. This equation is found to also support four segmented, …

Novel Optical Properties Of Metal Nanostructures Based On Surface Plasmons, Haining Wang

Electronic Theses and Dissertations

Surface plasmons have been attracted extensive interests in recent decades due to the novel properties in nanometer sized dimensions. My work focused on the novel optical properties of metal nanostructures based on surface plasmons using theoretical simulation methods. In the first part, we investigated metal nanofilms and nanorods and demonstrated that extremely low scattering efficiency, high absorption efficiency and propagation with long distance could be obtained by different metal nanostructures. With a perforated silver film, we demonstrated that an extremely low scattering cross section with an efficiency of less than 1% can be achieved at tunable wavelengths with tunable widths. …

Income Inequality Measures And Statistical Properties Of Weighted Burr-Type And Related Distributions, Meznah R. Al Buqami

Electronic Theses and Dissertations

In this thesis, tail conditional expectation (TCE) in risk analysis, an important measure for right-tail risk, is presented. This value is generally based on the quantile of the loss distribution. Explicit formulas of several tail conditional expectations and inequality measures for Dagum-type models are derived. In addition, a new class of weighted Burr-III (WBIII) distribution is presented. The statistical properties of this distribution including hazard and reverse hazard functions, moments, coefficient of variation, skewness, and kurtosis, inequality measures, entropy are derived. Also, Fisher information and maximum likelihood estimates of the model parameters are obtained.

Cusum Generalized Variance Charts, Yuxiang Li

Electronic Theses and Dissertations

The commonly recommended charts for monitoring the mean vector are affected by a shit in the covariance matrix. As in the univariate case, a chart for monitoring for a change in the covariance matrix should be examined first before examining the chart used to monitor for a change in the mean vector.

Pressure Poisson Method For The Incompressible Navier-Stokes Equations Using Galerkin Finite Elements, John Cornthwaite

Electronic Theses and Dissertations

In this thesis we examine the Navier-Stokes equations (NSE) with the continuity equation replaced by a pressure Poisson equation (PPE). Appropriate boundary conditions are developed for the PPE, which allow for a fully decoupled numerical scheme to recover the pressure. The variational form of the NSE with PPE is derived and used in the Galerkin Finite Element discretization. The Galerkin finite element method is then used to solve the NSE with PPE. Moderate accuracy is shown.

Revising Common Core Georgia Performance Standards Statistics Lesson Plans To Better Align With Statistical Practice, Rachel Bonilla

Electronic Theses and Dissertations

In this thesis, lesson plans provided by the Georgia Department of Education are revised to give students better exposure and practice working with real-life data. Three learning tasks and a performance task are presented covering a unit lesson on statistical regression. The development of Georgia statistics curriculum standards are reviewed and presented.

Partial Replica Location And Selection For Spatial Datasets, Yun Tian

Electronic Theses and Dissertations

As the size of scientific datasets continues to grow, we will not be able to store enormous datasets on a single grid node, but must distribute them across many grid nodes. The implementation of partial or incomplete replicas, which represent only a subset of a larger dataset, has been an active topic of research. Partial Spatial Replicas extend this functionality to spatial data, allowing us to distribute a spatial dataset in pieces over several locations. We investigate solutions to the partial spatial replica selection problems. First, we describe and develop two designs for an Spatial Replica Location Service (SRLS), which …

Reducing Communication Delay Variability For A Group Of Robots, Goncalo Martins

Electronic Theses and Dissertations

A novel architecture is presented for reducing communication delay variability for a group of robots. This architecture relies on using three components: a microprocessor architecture that allows deterministic real-time tasks; an event-based communication protocol in which nodes transmit in a TDMA fashion, without the need of global clock synchronization techniques; and a novel communication scheme that enables deterministic communications by allowing senders to transmit without regard for the state of the medium or coordination with other senders, and receivers can tease apart messages sent simultaneously with a high probability of success. This approach compared to others, allows simultaneous communications without …

Injection Locking Of Semiconductor Mode-Locked Lasers For Long-Term Stability Of Widely Tunable Frequency Combs, Charles Williams

Electronic Theses and Dissertations

Harmonically mode-locked semiconductor lasers with external ring cavities offer high repetition rate pulse trains while maintaining low optical linewidth via long cavity storage times. Single frequency injection locking generates widely-spaced and tunable frequency combs from these harmonically mode-locked lasers, while stabilizing the optical frequencies. The output is stabilized long-term with the help of a feedback loop utilizing either a novel technique based on Pound-Drever-Hall stabilization or by polarization spectroscopy. Error signals of both techniques are simulated and compared to experimentally obtained signals. Frequency combs spaced by 2.5 GHz and ~10 GHz are generated, with demonstrated optical sidemode suppression of unwanted …