Physical Sciences and Mathematics Commons^™

Absorptive And Refractive Optical Nonlinearities In Organic Molecules And Semiconductors, Davorin Peceli

Electronic Theses and Dissertations

The main purpose of this dissertation to investigate photophysical properties, third order nonlinearity and free carrier absorption and refraction in organic materials and semiconductors. Special emphasis of this dissertation is on characterization techniques of molecules with enhanced intersystem crossing rate and study of different approaches of increasing triplet quantum yield in organic molecules. Both linear and nonlinear characterization methods are described. Linear spectroscopic characterization includes absorption, fluorescence, quantum yield, anisotropy, and singletoxygen generation measurements. Nonlinear characterization, performed by picosecond and femtosecond laser systems (single and double pump-probe and Z-scan measurements), includes measurements of the triplet quantum yields, excited-state absorption, two-photon …

Ytterbium-Doped Fiber-Seeded Thin-Disk Master Oscillator Power Amplifier Laser System, Christina Willis-Ott

Electronic Theses and Dissertations

Lasers which operate at both high average power and energy are in demand for a wide range of applications such as materials processing, directed energy and EUV generation. Presented in this dissertation is a high-power 1 μm ytterbium-based hybrid laser system with temporally tailored pulse shaping capability and up to 62 mJ pulses, with the expectation the system can scale to higher pulse energies. This hybrid system consists of a low power fiber seed and pre-amplifier, and a solid state thin-disk regenerative amplifier. This system has been designed to generate high power temporally tailored pulses on the nanosecond time scale. …

Remediation Of Polychlorinated Biphenyl (Pcb) Contaminated Building Materials Using Non-Metal And Activated Metal Treatment Systems, Tamra Legron-Rodriguez

Electronic Theses and Dissertations

PCBs are recalcitrant compounds of no known natural origin that persist in the environment despite their ban by the United States Environmental Protection Agency in 1979 due to negative health effects. Transport of PCBs from elastic sealants into concrete, brick, and granite structures has resulted in the need for a technology capable of removing these PCBs from the materials. This research investigated the use of a nonmetal treatment system (NMTS) and an activated metal treatment system (AMTS) for the remediation and degradation of PCBs from concrete, brick, and granite affixed with PCB-laden caulking. The adsorption of PCBs onto the components …

Computational Methods For Comparative Non-Coding Rna Analysis: From Structural Motif Identification To Genome-Wide Functional Classification, Cuncong Zhong

Electronic Theses and Dissertations

Recent advances in biological research point out that many ribonucleic acids (RNAs) are transcribed from the genome to perform a variety of cellular functions, rather than merely acting as information carriers for protein synthesis. These RNAs are usually referred to as the non-coding RNAs (ncRNAs). The versatile regulation mechanisms and functionalities of the ncRNAs contribute to the amazing complexity of the biological system. The ncRNAs perform their biological functions by folding into specific structures. In this case, the comparative study of the ncRNA structures is key to the inference of their molecular and cellular functions. We are especially interested in …

Accelerated Life Model With Various Types Of Censored Data, Kathryn Pridemore

Electronic Theses and Dissertations

The Accelerated Life Model is one of the most commonly used tools in the analysis of survival data which are frequently encountered in medical research and reliability studies. In these types of studies we often deal with complicated data sets for which we cannot observe the complete data set in practical situations due to censoring. Such difficulties are particularly apparent by the fact that there is little work in statistical literature on the Accelerated Life Model for complicated types of censored data sets, such as doubly censored data, interval censored data, and partly interval censored data. In this work, we …

Light-Matter Interactions Of Plasmonic Nanostructures, Jennifer Reed

Electronic Theses and Dissertations

Light interaction with matter has long been an area of interest throughout history, spanning many fields of study. In recent decades, the investigation of light-matter interactions with nanostructures has become an intense area of research in the field of photonics. Metallic nanostructures, in particular, are of interest due to the interesting properties that arise when interacting with light. The properties are a result of the excitation of surface plasmons which are the collective oscillation of the conduction electrons in the metal. Since the conduction electrons can be thought of as harmonic oscillators, they are quantized in a similar fashion. Just …

Seeded Propagation Of Tau Fibrils, Paul David Dinkel

Electronic Theses and Dissertations

In various neurodegenerative diseases, including Alzheimer's disease, progressive supranuclear palsy, Pick's disease, and corticobasal degeneration, the deposition of fibrils composed of misfolded tau protein is observed. Recent evidence suggests that tau fibrils transfer between cells and spread throughout the brain, underscoring the significance of fibril propagation.

Six tau isoforms exist in the adult human brain that can be grouped into 4-repeat (4R) tau and 3-repeat (3R) tau based on the presence or absence of the second of four microtubule binding repeats. We demonstrate in vitro that seeded fibril growth, a prerequisite for the spreading of the tau pathology, is crucially …

The X-Ray And Spectropolarimetric View Of Mass Loss And Transfer In Massive Binary Stars, Jamie Renae Lomax

Electronic Theses and Dissertations

The majority of massive stars are members of binary systems. In order to have a better understanding of their evolutionary pathways, the mass and angular momentum loss from massive binaries needs to be well understood. Self consistent explanations for their behavior need to be valid across many wavelength regimes in order to illuminate key phases of mass loss to completely determine how it affects their evolution. In this dissertation I present the results of X-ray and specropolarimetric studies on one Roche-lobe overflow binary (β Lyr) and two colliding wind binaries (V444 Cyg and WR 140).

In β Lyr a …

Oxide Semiconductors For Organic Opto-Electronic Devices, Ajaya Kanta Sigdel

Electronic Theses and Dissertations

Development of transparent oxide semiconductors (TOS) from Earth-abundant materials is of great interest for cost-effective thin film device applications, such as solar cells, light emitting diodes (LEDs), touch-sensitive displays, electronic paper, and transparent thin film transistors. The need of inexpensive or high performance electrode might be even greater for organic photovoltaic (OPV), with the goal to harvest renewable energy with inexpensive, lightweight, and cost competitive materials. The natural abundance of zinc and the wide bandgap (~3.3 eV) of its oxide make it an ideal candidate.

In this dissertation, I have introduced various concepts on the modulations of various surface, interface …

The Removal Of Pharmaceuticals From Wastewater By Wet-Air Oxidation, Miao Sun

Electronic Theses and Dissertations

The ubiquitous occurrence of pharmaceuticals and personal care products (PPCPs) in aquatic environments has raised concerns about potential adverse effects on aquatic ecology and human health. Certain pharmaceuticals have recently become a major focus of research to better understand the routes and persistence of these compounds once they enter into aquatic system.

In this research, two model compounds were selected to represent pharmaceuticals that have been identified by recent research as being persistent; specifically, these compounds were trimethoprim (TMP, a basic antibiotic) and gemfibrozil (GEM, an acidic lipid regulator). Treatment of synthetic wastewater that contained these drugs was accomplished using …

Numerical Solutions To The Gross-Pitaevskii Equation For Bose-Einstein Condensates, Luigi Galati

Electronic Theses and Dissertations

In this thesis we compare various potential operators for the two-dimensional (2D) Gross-Pitaevskii equation (GPE) for Bose-Einstein condensates. Both the 2D and the 1D models are scaled to get a three parameter model. Smoothness of initial conditions is considered and choice of method (Split-Step Fourier method with Strang Splitting) is justied. Numerical simulations provide graphical evidence of properties of both focusing and nonfocusing cases.

Celestial Paleontology: The Legacy Of Dying Stars, Alexa Hodgson Hart

Electronic Theses and Dissertations

In their death throes, stars dole out their atmospheric material to the interstellar medium in dramatic stellar winds and spectacular explosions. The details of this profound metamorphosis, from star to remnant, play a key role in the next generation of star formation as well as the energetic and chemical evolution of galaxies and the universe as a whole. Dying stars are thought to be the source of all of the nuclei heavier than iron in the universe, as well as more complex molecules, such as carbon chains, which form the backbone of life as we know it.

High mass Wolf-Rayet …

Multiple Bounding Boxes Algorithm In Collision Detection And Its Performances In Sequential Vs Cuda Parallel Processing, Min Qi

Electronic Theses and Dissertations

The traditional method for detecting collisions in a 2D computer game uses a axisaligned bounding box around each sprite, and checks to determine if the bounding boxes overlap periodically. Using this single bounding box method may result in a large amount of pixel intersection tests, since a sprite may be composed of areas where the pixels are empty and the intersecting bounding box test results in false positives.

Our algorithm analysis shows that the optimal two or three bounding boxes is the best partition we can get for a reasonable time complexity. The results further show significantly diminishing returns for …

Full Newton Step Interior Point Method For Linear Complementarity Problem Over Symmetric Cones, Andrii Berdnikov

Electronic Theses and Dissertations

In this thesis, we present a new Feasible Interior-Point Method (IPM) for Linear Complementarity Problem (LPC) over Symmetric Cones. The advantage of this method lies in that it uses full Newton-steps, thus, avoiding the calculation of the step size at each iteration. By suitable choice of parameters we prove the global convergence of iterates which always stay in the the central path neighborhood. A global convergence of the method is proved and an upper bound for the number of iterations necessary to find ε-approximate solution of the problem is presented.

Computational Fluid Dynamics (Cfd) Modeling Of A Laboratory Scale Coal Gasifier, Kiel S. Schultheiss

Electronic Theses and Dissertations

Furthering gasification technology is an essential part of advancing clean coal technologies. In order to seek insight into the appropriate operations for the formation of synthetic gas (syngas) a numerical simulation was performed to predict the phenomena of coal gasification in a laboratory scale entrained-flow coal gasifier. The mesh for the model was developed with ICEM CFD software and the chemical and physical phenomena were modeled using the fluid flow solver ANSYS FLUENT. Mesh independence was verified. The model was validated with experimental data from several studies performed on a laboratory scale gasifier.

Systematic examination of the model was performed …

Scene Understanding For Real Time Processing Of Queries Over Big Data Streaming Video, Alexander Aved

Electronic Theses and Dissertations

With heightened security concerns across the globe and the increasing need to monitor, preserve and protect infrastructure and public spaces to ensure proper operation, quality assurance and safety, numerous video cameras have been deployed. Accordingly, they also need to be monitored effectively and efficiently. However, relying on human operators to constantly monitor all the video streams is not scalable or cost effective. Humans can become subjective, fatigued, even exhibit bias and it is difficult to maintain high levels of vigilance when capturing, searching and recognizing events that occur infrequently or in isolation. These limitations are addressed in the Live Video …

Discriminative Dictionary Learning With Spatial Constraints, Muhammad Nazar Khan

Electronic Theses and Dissertations

In this thesis, we investigate the use of dictionary learning for discriminative tasks on natural images. Our contributions can be summarized as follows: • We introduce discriminative deviation based learning to achieve principled handling of the reconstruction-discrimination tradeoff that is inherent to discriminative dictionary learning. • Since natural images obey a strong smoothness prior, we show how spatial smoothness constraints can be incorporated into the learning formulation by embedding dictionary learning into Conditional Random Field (CRF) learning. We demonstrate that such smoothness constraints can lead to state-of-the-art performance for pixel-classification tasks. • Finally, we lay down the foundations of super-latent …

Automatically Acquiring A Semantic Network Of Related Concepts, Sean Szumlanski

Electronic Theses and Dissertations

We describe the automatic acquisition of a semantic network in which over 7,500 of the most frequently occurring nouns in the English language are linked to their semantically related concepts in the WordNet noun ontology. Relatedness between nouns is discovered automatically from lexical co-occurrence in Wikipedia texts using a novel adaptation of an information theoretic inspired measure. Our algorithm then capitalizes on salient sense clustering among these semantic associates to automatically disambiguate them to their corresponding WordNet noun senses (i.e., concepts). The resultant concept-to-concept associations, stemming from 7,593 target nouns, with 17,104 distinct senses among them, constitute a large-scale semantic …

Detecting Semantic Method Clones In Java Code Using Method Ioe-Behavior, Rochelle Elva

Electronic Theses and Dissertations

The determination of semantic equivalence is an undecidable problem; however, this dissertation shows that a reasonable approximation can be obtained using a combination of static and dynamic analysis. This study investigates the detection of functional duplicates, referred to as semantic method clones (SMCs), in Java code. My algorithm extends the input-output notion of observable behavior, used in related work [1, 2], to include the effects of the method. The latter property refers to the persistent changes to the heap, brought about by the execution of the method. To differentiate this from the typical input-output behavior used by other researchers, I …

Hydromorphology Of The Econlockhatchee River, John Baker

Electronic Theses and Dissertations

Climate change and human activities alter the hydrologic systems and exerted global scale impacts on our environment with significant implications for water resources. Climate change can be characterized by the change of precipitation and temperature, and both precipitation pattern change and global warming are associated with the increase in frequency of flooding or drought and low flows. With increasing water demand from domestic, agricultural, commercial, and industrial sectors, humans are increasingly becoming a significant component of the hydrologic cycle. Human activities have transformed hydrologic processes at spatial scales ranging from local to global. Human activities affecting watershed hydrology include land …

Wavelength Scale Resonant Structures For Integrated Photonic Applications, Matthew Weed

Electronic Theses and Dissertations

An approach to integrated frequency-comb filtering is presented, building from a background in photonic crystal cavity design and fabrication. Previous work in the development of quantum information processing devices through integrated photonic crystals consists of photonic band gap engineering and methods of on-chip photon transfer. This work leads directly to research into coupled-resonator optical waveguides which stands as a basis for the primary line of investigation. These coupled cavity systems offer the designer slow light propagation which increases photon lifetime, reduces size limitations toward on-chip integration, and offers enhanced light-matter interaction. A unique resonant structure explained by various numerical models …

Sparse Ridge Fusion For Linear Regression, Nozad Mahmood

Electronic Theses and Dissertations

For a linear regression, the traditional technique deals with a case where the number of observations n more than the number of predictor variables p (n > p). In the case n < p, the classical method fails to estimate the coefficients. A solution of the problem is the case of correlated predictors is provided in this thesis. A new regularization and variable selection is proposed under the name of Sparse Ridge Fusion (SRF). In the case of highly correlated predictor, the simulated examples and a real data show that the SRF always outperforms the lasso, eleastic net, and the S-Lasso, and the results show that the SRF selects more predictor variables than the sample size n while the maximum selected variables by lasso is n size.

Optically Induced Forces In Scanning Probe Microscopy, Dana Kohlgraf-Owens

Electronic Theses and Dissertations

The focus of this dissertation is the study of measuring light not by energy transfer as is done with a standard photodetector such as a photographic film or charged coupled device, but rather by the forces which the light exerts on matter. In this manner we are able to replace or complement standard photodetector-based light detection techniques. One key attribute of force detection is that it permits the measurement of light over a very large range of frequencies including those which are difficult to access with standard photodetectors, such as the far IR and THz. The dissertation addresses the specific …

Evaluating The Use Of Autonomous Recording Units To Monitor Yellow Rails, Nelson's Sparrows, And Le Conte's Sparrows, Anna Marie Sidie-Slettedahl

Electronic Theses and Dissertations

Population status and habitat use of yellow rails (Coturnicops noveboracensis) (YERA), Nelson’s sparrows (Ammodramus nelsoni) (NESP), and Le Conte’s sparrows (Ammodramus leconteii) (LCSP) are poorly known, so systematic surveys of these elusive species are needed to inform conservation planning and guide management. A standardized protocol for monitoring secretive marsh birds exists (Conway 2009, 2011); however, these species call at night and may be missed during early-morning marsh bird surveys. I tested the effectiveness of autonomous recording units (ARUs) to survey these species by analyzing recorded vocalizations using bioacoustics software. I deployed 22 ARUs at 54 sites in northern Minnesota and …

Movements, Survival, And Sightability Of White-Tailed Deer In Southeastern South Dakota, Trenton J. Haffley

Electronic Theses and Dissertations

To effectively manage white-tailed deer (Odocoileus virginianus) populations, managers need to identify population parameters including but not limited to movements, survival and cause-specific mortality. It also is helpful to examine population size and density. The primary objectives of my study were to document seasonal migration, estimate survival rates for female adult white-tailed deer, and generate a sightability model for deer in southeastern South Dakota. Secondary objectives were to calculate seasonal home ranges and document cause-specific mortality. Forty four adult female white-tailed deer were monitored from February 2009 to January 2011 in Bon Homme and Yankton counties. I documented 38 seasonal …

The Urban Heat Island And Its Influence On Precipitation In Denver, Colorado, Diana Thunen

Electronic Theses and Dissertations

Anthropogenic modification of the climate is an unintended yet serious effect of urbanization and it is happening in every city across the globe in the form of the urban heat island. The purpose of this study was to see if Denver, Colorado exhibits evidence of an urban heat island using meteorological data and if there has been a change in precipitation amounts since the urbanization of the city. It was concluded that Denver, Colorado does have an urban heat island that varies seasonally throughout the year with an average magnitude of 3.57°C during the day and 3.82°C at night. The …

Backscatter And Attenuation Properties Of Mammalian Brain Tissues, Pushpani Vihara Wijekularatne

Electronic Theses and Dissertations

Traumatic Brain Injury (TBI) is a comcategory of brain injuries, which contributes to a substantial number of deaths and permanent disability all over the world. Ultrasound technology plays a major role in tissue characterization due to its low cost and portability that could be used to bridge a wide gap in the TBI diagnostic process. This research addresses the ultrasonic properties of mammalian brain tissues focusing on backscatter and attenuation. Orientation dependence and spatial averaging of data were analyzed using the same method resulting from insertion of tissue sample between a transducer and a reference reflector. Apparent Backscatter Transfer Function …

Synthesis, Characterization And Application Of Pt Complexes With Pincer Ccc-Bis(Nhc) Ligands, Xiaofei Zhang

Electronic Theses and Dissertations

The unique metallation/transmetallation route for the synthesis of CCC-bis(NHC) pincer ligand supported transition metal complexes was extended to Pt. Several platinum complexes were synthesized. The identity of these complexes was confirmed through multiple technologies, including nuclear magnetic resonance spectroscopy, mass spectroscopy, elemental analysis, thermal analysis, and X-ray crystallography. The intriguing photophysical and thermal properties of these complexes are reported. These complexes were believed to be congeners of materials for organic light emitting diodes (OLEDs).

Two Methodologies: How Well Can Universities Predict Retention, Tiffany Lynette Gregory

Electronic Theses and Dissertations

Student retention has been a long standing focus in higher education research with one of the earliest work dating back to 1937. Many researchers have proposed factors that affect a student's decision to depart from the university without successfully completing a degree. It is important to not only research different attributes and characteristics that affect student departure but it is also important to study different statistical methodologies. With the advancement in technology, new methodologies such as the Classification and Regression Tree (CART) have proven to yield significant results in a variety of research fields. As these new statistical methodologies emerge, …

On Binary And Regular Matroids Without Small Minors, Kayla Davis Harville

Electronic Theses and Dissertations

The results of this dissertation consist of excluded-minor results for Binary Matroids and excluded-minor results for Regular Matroids. Structural theorems on the relationship between minors and k-sums of matroids are developed here in order to provide some of these characterizations. Chapter 2 of the dissertation contains excluded-minor results for Binary Matroids. The first main result of this dissertation is a characterization of the internally 4-connected binary matroids with no minor that is isomorphic to the cycle matroid of the prism+e graph. This characterization generalizes results of Mayhew and Royle [18] for binary matroids and results of Dirac [8] and Lovász …