Physical Sciences and Mathematics Commons^™

Investigation Of Cryptotephra In Polar Ice Cores, Meredith Helmick

Electronic Theses and Dissertations

Volcanic ash (tephra) present within polar ice cores greatly supplements our understanding of past volcanism and its impacts on society and the state of the climate system. This thesis investigates the utility and limitations of ice core tephrochronology in answering questions related to volcanic source identification of ice core glaciochemical signals, tephrostratigraphy of an Antarctic ice core, and the timing of major and climate forcing eruptions. This thesis explores the efficacy of SEM-EDS measurements on ultra-fine (µm) volcanic particles for the purpose of geochemically characterizing a non-visible ice-embedded tephra and the subsequent identification of the volcanic source. In combination with …

Regional Scale Generalizations Of Firn Thickness And Snow Accumulation In Southeast Alaska: An Applied Deep Learning Framework, Jonathan Maurer

Electronic Theses and Dissertations

High elevation mountain glaciers are referred to as the “water towers of the world” due to their ability to store water internally and release it later through melt and runoff. Much of the work to understand these complex environments has focused on cold based polar glaciers in high latitude regions, neglecting temperate glaciers and associated snowpack which are more responsive than polar systems to minor climatic changes. Advancements in the availability of open source data, deep learning theory, and computational efficiency has opened up new methods of “data hungry” modeling that may be well suited to the type of complex …

Anthropogenic Effects On Tidal Distortion In A Tidal River, Matthew D. Fischer

Electronic Theses and Dissertations

Tidal rivers are landward portions of estuarine systems constituting the union between coastal, tidally controlled settings and rivers, where fluvial processes dominate. In these reaches, river discharge (mean flow) and tides are the two most important mechanisms in controlling geophysical flows. The processes governing water levels and current amplitudes in tidal rivers are highly nonlinear and modulated by external forcings- thus requiring sophisticated techniques for accurate prediction and forecasting. Physical oceanographers and estuarine physicists tend to limit their study area to the maximum extent of the horizontal tide (salinity intrusion), not the most landward point influenced by tidal water levels. …

Plasma-Assisted Growth And Characterization Of Piezoelectric Aln And Sc(X)Al(1-X)N Films For Microwave Acoustic Sensor Applications, Morton Greenslit

Electronic Theses and Dissertations

The use of surface acoustic wave (SAW) sensors in high temperature harsh environments such as those found in power plants, industrial manufacturing, or aerospace applications allows for monitoring of internal conditions at locations where traditional sensors do not operate or are unreliable. Surface acoustic wave resonator (SAWR) sensors are based on piezoelectric materials and feature a small passive low-profile self-powered design that can operate and wirelessly transmit data to monitor parameters such as temperature, pressure, or strain. SAWR sensors typically consist of a series of metal electrodes fabricated onto a bulk crystal piezoelectric such as langasite (La3Ga5SiO14). However, there are …

Holocene And Last Glacial Period Atmospheric Dynamics And Biogeochemistry Based On South Pole Ice Core Microparticle And Trace Element Records, Aaron Chesler

Electronic Theses and Dissertations

I develop and interpret a record of dust deposition from the South Pole ice core (SPC14) to identify changes in atmospheric variability. The SPC14 core was drilled during 2014 – 2016 and provides a high accumulation (~7 cm w.e.q. per year) record in central Antarctica that reaches a depth of 1751 m (~54 ka). My analysis combines microparticle (dust) concentration, size, and shape metrics using continuous and discrete methodologies and high- and low-resolution multifractional Fe analyses that span the past 54 ka.

Results from my dust shape analysis suggest the common assumption of spherical dust particle shape in incorrect and …

Barriers To And Opportunities For Adoption In Maine’S Aquaculture Industry, Caitlin Cleaver

Electronic Theses and Dissertations

Aquaculture, or the farming of marine species, can diversify coastal economies, but development of this industry is hindered by negative perceptions or regulatory constraints. Commercial fishers are logical adopters of aquaculture, but can also mount opposition to its growth. This dissertation utilized innovation theory to understand fishers’ perceptions of and willingness to adopt aquaculture and drivers of and barriers to scallop aquaculture development in Maine (USA). Through a mail survey, lobster fishers’ perceptions of Maine’s aquaculture industry and their willingness to adopt aquaculture were assessed (Chapter 2). Individuals who were more satisfied with government management of aquaculture held more positive …

Silting Dynamics And Metal Contaminants In The Georgetown Inner Harbor, Ezekiel Wil Meyers

Electronic Theses and Dissertations

The Georgetown inner harbor is an abandoned oxbow-like river loop and a vital historic site with a wealth of traditional businesses and heavy local industry located within Winyah Bay. Since the modification of the Sampit River in 1949, chronic rapid silting has plagued the inner harbor. With these substantial amounts of fine-grained material accumulating inside the inner harbor, business operations along the waterfront, navigational and maritime operations, and contamination within the harbor are of major concern. The goals of this study were to (a) understand the silting dynamics inside the inner harbor, (b) identify heavy metals which might be of …

Extraction, Analysis, And Comparison Of Microplastics In Sc Marsh Substrates, Austin G. Sige

Electronic Theses and Dissertations

The global, rapid increase in plastic production is a widespread problem for coastal environments such as marshes that present favorable conditions for plastic retention. This study looked at the microplastic abundance within three previously unstudied South Carolina marshes located in Myrtle Beach, Murrells Inlet, and Waties Island. A comparison between the microplastic types and abundances between locations provided knowledge about the impacts of sediment composition (sand, silt, clay, and organic matter) on microplastic sequestration. This study also produced a novel microplastic extraction methodology for cohesive marsh sediment that used elutriation to effectively break apart aggregates prior to chemical digestion and …

Improving Near Surface Refractivity Estimates In Marine Environments, Sarah Evelyn Wessinger

Electronic Theses and Dissertations

This study utilizes in-situ measurements and numerical weather prediction datasets collected during the Coupled Air-Sea Processes Electromagnetic Ducting Research East field campaign to assess how thermodynamic properties in the marine atmospheric surface layer influence evaporation duct shape and to develop a simple near-surface modified refractivity estimation method. This study utilizes a logarithmic linear parametric model, which describes evaporation ducts via three main parameters: evaporation duct height, evaporation duct curvature, and mixed layer slope. Notably, most studies utilizing this type of model assume the curvature, C0, to be a theoretical value derived assuming neutral atmospheric stability; a thermodynamic regime that is …

Arctic Sea Ice Loss In The Pacific Sector And Its Impacts On Sudden Stratospheric Warming Events, Jiarong Zhang

Electronic Theses and Dissertations

The Arctic sea ice is a critical indicator of climate change. The extent of sea ice coverage over the Arctic Ocean has dramatically declined over the past few decades. The impact has been extensively studied through observations suggesting a linkage between the anomalously warm Arctic surface associated with the Arctic sea ice loss and the mid-latitude surface cooling in the subsequent boreal winter. This linkage could involve the wintertime stratospheric circulation by enhancing the upward planetary wave activity and weakening the polar vortex. With recent advances in climate model, more relevant studies relied on numerical simulations and some suggested that …

Next-Generation Sequencing Shows Increasing Temperatures Affect Stream Fungal Communities, Regan Hodgson

Electronic Theses and Dissertations

Under climate change predictions, surface air temperature is expected to continue to rise and will likely affect functioning of stream ecosystems and microbial communities. Aquatic hyphomycetes are key fungal decomposers of plant litter in headwater streams controlling carbon, energy, and nutrient flows to higher trophic levels. This project addressed the effects of temperature on stream fungal communities in two recently conducted experiments (microcosm and streamside channel studies) using Illumina sequencing. The objectives were to determine (1) if temperature affects community structure of stream fungi based on relative abundances of ITS2 rDNA sequences, (2) if the effects of temperature on aquatic …

Microplastic Accumulation In The Digestive Tract Of Young-Of-Year Atlantic Sharpnose Sharks (Rhizoprionodon Terraenovae) In The Grand Strand, Sc, Andrew Curtis Sitlinger

Electronic Theses and Dissertations

This study focused on the presence and accumulation of microplastic fibers in the digestive tract and livers of young-of-year Atlantic Sharpnose Sharks (Rhizopriondon terraenovae) from two sampling locations along the Grand Strand of South Carolina. R. terraenovae is a small, mesopredatory elasmobranch found abundantly along northwestern Atlantic Ocean coastlines. Thirty specimens of R. terraenovae were collected from May through August of 2020. Microplastics were found in all specimens. A total of 672 plastic particles were identified over the course of the study, with an average of 22.4 ± 10.5 (SD) plastics per specimen. The majority of the plastics were classified …

Distribution And Soil Characteristics Associated With The Neches River Rose-Mallow (Hibiscus Dasycalyx), Morgan E. Langlinais

Electronic Theses and Dissertations

The Neches River rose-mallow, Hibiscus dasycalyx, is a rare herbaceous perennial endemic to East Texas. The threatened, obligate wetland species is currently at risk of being lost in the wild due to habitat loss, encroachment of nonnative and native plant species, and hybridization with two other Hibiscus congeners, Hibiscus laevis and Hibiscus moscheutos. Known locations of each of the three Hibiscus species were used to measure select soil characteristics and habitat variables associated with each of the rose-mallows. H. dasycalyx was concluded to be associated with more fertile soils and slightly more canopy coverage than H. laevis and …

Fossil Mammals From Hickory Tree Cave, Sullivan County, Tennessee, Alexis Rivera

Electronic Theses and Dissertations

Hickory Tree Cave, also known as Big Spring Cave, is located in the southern Appalachians and is known for fossils that are considered to be Quaternary in age. Fossil mammals were identified and assigned to the lowest taxonomical level possible. Most remains are fragmented or digested and it seems likely that various taphonomic processes are responsible for the resulting assemblage. The site lacks the extreme boreal component of Pleistocene cave faunas in the region (e.g. Baker Bluff Cave), with most reported taxa inhabiting Appalachian deciduous forest environments in North America today. While the presence of tapir (Tapirus sp.) …

Folic Acid – Carbon Dots – Doxorubicin Nanoparticles As Cancer Theranostic, Michael Tetteh

Electronic Theses and Dissertations

This work focused on engineering bi-functionalized nanoparticles (NPs) based on carbon dots (CDs) to improve early cancer detection and treatment. Therefore, using folic acid (FA) as a targeting agent, the CDs were prepared to deliver high concentrations (HC) of doxorubicin (DOX) and gemcitabine (GEM) covalently and non-covalently to cancer cells. The prepared FA-CDs-DOX/GEM-HC NPs were characterized using ultraviolet-visible spectroscopy, fluorescence spectroscopy, and Fourier transform infrared spectroscopy. Assessment of the drug loading capacity (DLC) and drug loading efficiency (DLE) indicated that the non-covalent NPs have low DLC but high DLE compared to the relatively low DLE and high DLC of covalent …

Nitrogen-Doped And Phosphorus-Doped Epoxy-Sealed Carbon Fiber Ultramicroelectrodes As Electrochemical Sensors For Detection Of Hydrogen Peroxide, Emmanuel Peprah-Yamoah

Electronic Theses and Dissertations

Ultramicroelectrodes (UMEs) are useful as probes for evaluating electroactive species in confined spaces (e.g., inside living cells) and for measuring fast electrochemical reactions. However, UME applications often require modification of the electrode surface to improve selectivity and sensitivity towards target analytes. Previous research in our group demonstrated that a simple soft nitriding method introduces surface nitrogen (N)-containing groups on carbon fiber (CF), leading to improved electroreduction of hydrogen peroxide (H₂O₂) on CF-UMEs. However, sensitivity for H₂O₂ detection using N-CF-UMEs was low compared to that for other modified UMEs. As an alternative to N-CF-UMEs, …

Weak Gravitational Lensing Analysis In Two Superclusters Of Galaxies, Sarah B. Rice

Electronic Theses and Dissertations

Observations of the Universe on very large scales have shown it to be filled with galaxy clusters and superclusters connected by walls and filaments of galaxies, with vast areas mostly devoid of luminous matter separating them. It is widely accepted that the amount of luminous matter does not provide the mass needed to hold galaxies and galaxy clusters together, and the nature of the missing "dark matter" is one of the most prominent astrophysical mysteries today. Since dark matter interacts with luminous matter gravitationally, it stands to reason that dark matter might organize itself in a similar manner to luminous …

Bayesian Methods For Graphical Models With Neighborhood Selection., Sagnik Bhadury

Electronic Theses and Dissertations

Graphical models determine associations between variables through the notion of conditional independence. Gaussian graphical models are a widely used class of such models, where the relationships are formalized by non-null entries of the precision matrix. However, in high-dimensional cases, covariance estimates are typically unstable. Moreover, it is natural to expect only a few significant associations to be present in many realistic applications. This necessitates the injection of sparsity techniques into the estimation method. Classical frequentist methods, like GLASSO, use penalization techniques for this purpose. Fully Bayesian methods, on the contrary, are slow because they require iteratively sampling over a quadratic …

The Role Of Generative Adversarial Networks In Bioimage Analysis And Computational Diagnostics., Ahmed Naglah

Electronic Theses and Dissertations

Computational technologies can contribute to the modeling and simulation of the biological environments and activities towards achieving better interpretations, analysis, and understanding. With the emergence of digital pathology, we can observe an increasing demand for more innovative, effective, and efficient computational models. Under the umbrella of artificial intelligence, deep learning mimics the brain’s way in learn complex relationships through data and experiences. In the field of bioimage analysis, models usually comprise discriminative approaches such as classification and segmentation tasks. In this thesis, we study how we can use generative AI models to improve bioimage analysis tasks using Generative Adversarial Networks …

Opinion Mining Of Bird Preference In Wildlife Parks, Isiwat Adenopo

Electronic Theses and Dissertations

Opinion Mining is becoming the fastest growing area to extract useful and insightful information to support decision making. In the age of social media, user’s opinions and discussions have become a highly valuable source to look for users preferences, likes, and dislikes.

The industry of wildlife parks (or zoos) is a competitive domain that requires careful analysis of visitor’s opinions to understand and cater for their preferences when it comes to wildlife. In this thesis, an opinion mining approach was proposed and applied on textual posts on the social media platform, Twitter, to extract the popularity, polarity (sentiment), and emotions …

Alpha, Beta-Unsaturated Aldehydes: The Underrepresented Markers Of Disease., Saurin Sutaria

Electronic Theses and Dissertations

The peroxidation of unsaturated fatty acids is a widely recognized metabolic process that creates a complex mixture of volatile organic compounds including aldehydes. Elevated levels of reactive oxygen species in cancer cells promote random lipid peroxidation, which leads to an increase in a variety of aldehydes. Many of these volatile aldehydes are exhaled and are of interest as potential markers of disease. Chapter 1 presents a review of reported aldehydes in the exhaled breath of lung cancer patients. alpha,beta-Unsaturated aldehydes, detected primarily when derivatized during exhaled breath preconcentration, are underreported in the reviewed articles. Chapter 1 concludes with our hypothesis …

Performance Enhancement Of Hyperspectral Semantic Segmentation Leveraging Ensemble Networks, Nicholas Soucy

Electronic Theses and Dissertations

Hyperspectral image (HSI) semantic segmentation is a growing field within computer vision, machine learning, and forestry. Due to the separate nature of these communities, research applying deep learning techniques to ground-type semantic segmentation needs improvement, along with working to bring the research and expectations of these three communities together. Semantic segmentation consists of classifying individual pixels within the image based on the features present. Many issues need to be resolved in HSI semantic segmentation including data preprocessing, feature reduction, semantic segmentation techniques, and adversarial training. In this thesis, we tackle these challenges by employing ensemble methods for HSI semantic segmentation. …

Differentiate Metasploit Framework Attacks From Others, Gina Liu Ajero

Electronic Theses and Dissertations

Metasploit Framework is a very popular collection of penetration testing tools. From auxiliaries such as network scanners and mappers to exploits and payloads, Metasploit Framework offers a plethera of apparatuses to implement all the stages of a penetration test. There are two versions: both a free open-source community version and a commercial professional version called Metasploit Pro. The free version, Metasploit Framework, is heavily used by cyber crimininals to carry out illegal activities to gain unauthorized access to targets.

In this paper, I conduct experiments in a virtual environment to discover whether attacks originated from Metasploit Framework are marked with …

Turning Ligands On Their Side: Computational Investigation Into The Binding Of N2o And N2 In Transition Metal Complexes, Cole Donald

Electronic Theses and Dissertations

Common greenhouse gas nitrous oxide (N₂O) is a thermodynamically potent and environmentally benign oxidant, making it a desirable target for metal center activation. Unfortunately, N₂O is a poor ligand for transition metals due to its weak sigma-donating and pi-accepting properties; as a result, few transition metal complexes capable of interacting with N₂O have been found. As the primary source of all nitrogen in organisms, abundant gas dinitrogen (N₂) is a crucially important tiny molecule and an essential part of daily existence. However, due to its inertness, it has limited practical uses in …

Identification Of Lung Nodule Using Hierarchical Graph-Based Clustering And Multi-Level Thresholding, Yash Trivedi

Electronic Theses and Dissertations

Lung cancer is the second most commonly diagnosed cancer and the leading cause of cancer deaths worldwide. Compared to standard chest radiography, clinical trials have demonstrated that low-dose CT significantly reduces mortality from lung cancer by 20%. However, segmenting pulmonary nodules remains challenging due to intrinsic noise, low contrast, variable sizes and different shapes of the nodules. Radiologists manually drawing the nodule boundary is a common approach for delineating nodules which is time-consuming, expensive and prone to intra (the difference in repeated measurements by the same observer) and inter (the difference in the measurements between observers) observer variability. Also, most …

Thiophene Substituted 1,3,5-Triazines As Building Blocks For Liquid Crystals, Mojtaba Samiei Alalani

Electronic Theses and Dissertations

Discotic liquid crystals (DLCs), due to their self-organizing and self-healing properties, have been used in organic electronic devices. Generally, DLCs consist of a rigid central aromatic core that is substituted with peripheral flexible chains. Nanosegregation between their conjugated cores and the flexible sidechains often generates π-π columnar stacks that show a high charge carrier mobility. This thesis explores trithiothiphene-1,3,5-triazine based molecules with conjugated but conformationally flexible cores as building blocks for DLCs. Previous work has shown that these C3-symmetric (star-shaped) compounds with alkyl chains directly attached to the three thiophenes are not mesomorph. Studied here are derivatives with thioethers as …

Advanced Substrates For Wearable And Printed Electronics, Sara Mechael

Electronic Theses and Dissertations

This dissertation describes the development of elastomer and paper-based electronics, addressing application-specific challenges in the development of wearable electronics and smart packaging through strategic substrate design.

Chapters 2 and 3 describe the patterned, solution-based metallization of a commercially available, disposable glove to fabricate a wearable strain sensing array. Chapter 2 details the characterization and implementation of this ready-to-wear strain sensing glove. The glove garment acts as a convenient vehicle to carry and easily apply the strain sensing array to the hand joints, while the surface roughness of the glove facilitates the formation of a reticular cracking network in the overlying …

An Empirical Analysis Of Automl Tools And Techniques With Automated Feature Engineering, Kevin Shi

Electronic Theses and Dissertations

Automated machine learning is an approach to automate the creation of machine learning pipelines and models. The ability to automatically create a machine learning pipeline would allow users without machine learning knowledge to create and use machine learning systems. Existing machine learning practitioners can also use these automated approaches to simplify the creation of machine learning systems. As with any tool, effective evaluations of AutoML tools are necessary to ensure users can select the correct tool for their machine learning task.

Current evaluations of automated machine learning are performed on simple general purpose datasets, and these datasets may be unable …

The Life And Death Of Organic Electronics: Controlling Degradation And Regeneration Through Molecular Materials Design, Susanna Vu

Electronic Theses and Dissertations

Next-generation electronics will require conformability and stretchability to expand their integration in daily-life objects to be efficient energy and data storage. However, with the design and development of advanced technology comes the growing problem of electronic waste (e-waste). To tackle this growing challenge and access sustainable technologies, we suggest two routes for the fabrication of new electronics and enhancement of current technology that will reduce waste accumulation by using either degradable materials or regenerative materials. We propose the use of self-immolative polymers (SIPs) and self-healing polymers (SHPs) to control the lifetime and durability of various organic electronics through materials design. …

Stereoselective Synthesis Of Pseudosaccharide Derivative And Bisphosphoramidate Core Of Em2487, Saad Z. Mohammed Ali

Electronic Theses and Dissertations

HIV is among the leading causes of death worldwide resulting in over 1 million deaths annually according to the World Health Organization. Despite advances in the treatment of HIV, eradicating this pathogen remains a top priority in the medical and scientific communities. EM2487 is a natural product produced by Streptomyces sp. Mer-2487 that possesses promising activity against HIV. Specifically, EM2487 is a potent and selective inhibitor of HIV replication in both acutely and chronically infected cells. The observed HIV activity is hypothesized to be the result of targeting the Tat-TAR (trans-activation response) element which activates RNA polymerase II at the …