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Articles 811 - 840 of 4194
Full-Text Articles in Physical Sciences and Mathematics
Modeling Disorder In Proteins Yields Insights Into The Evolution Of Stability And Function, Jonathan Huihui
Modeling Disorder In Proteins Yields Insights Into The Evolution Of Stability And Function, Jonathan Huihui
Electronic Theses and Dissertations
The central dogma of molecular biology dictates that a DNA sequence codes for an RNA sequence, which in turn codes for a sequence of amino acids that comprises a protein. Proteins are responsible with performing myriad functions within living organisms and most proteins require a folded structure in order to perform their function. The protein's structure is the direct link from sequence to function. This is known as the sequence - structure - function paradigm. However, this does not mean that the unfolded state is unimportant. In order to properly model the stability of the folded state, one needs to …
Photoassisted Synthesis Of Complex Polyheterocycles Via Rational Design Of Tailored Photoprecursors, Tina Alanna Holt
Photoassisted Synthesis Of Complex Polyheterocycles Via Rational Design Of Tailored Photoprecursors, Tina Alanna Holt
Electronic Theses and Dissertations
Natural products remain the most common source for drug leads, although diversity-oriented synthesis of unnatural complex molecules is gaining momentum. Our lab has been developing experimentally simple and straightforward approaches to complex molecular architectures via photochemical reactions involving a minimal number of experimental steps. In order to achieve this, photoprecursors were assembled via high yielding reactions. Next, we deployed photoinduced cycloadditions to create complex 3-dimentional structures. Lastly, with this obtained primary photoproduct, post-photochemical transformations were used to further grow its scaffold complexity.
One method to increase scaffold complexity is the [4+2] intramolecular cycloadditions of azaxylylenes, which are developed through standard …
The Design, Development, And Determination Of A Virtual Reality Classroom, Victoria Alexxis Reddington
The Design, Development, And Determination Of A Virtual Reality Classroom, Victoria Alexxis Reddington
Electronic Theses and Dissertations
The COVID-19 pandemic has radically changed the way students learn and engage with their peers and instructors. Likewise, instructors have had to quickly transform their course materials to suit the online classroom format. Results from a survey of students and instructors at the University of Denver revealed that perceived levels of learning and collaboration were lessened with the transition to online learning. Moreover, the sense of presence in an educational atmosphere with other individuals was reported to be significantly stronger in a real physical classroom, as compared to an online classroom. This thesis therefore seeks to provide a new, alternative …
Change Request Prediction And Effort Estimation In An Evolving Software System, Lamees Abdullah Alhazzaa
Change Request Prediction And Effort Estimation In An Evolving Software System, Lamees Abdullah Alhazzaa
Electronic Theses and Dissertations
Prediction of software defects has been the focus of many researchers in empirical software engineering and software maintenance because of its significance in providing quality estimates from the project management perspective for an evolving legacy system. Software Reliability Growth Models (SRGM) have been used to predict future defects in a software release. Modern software engineering databases contain Change Requests (CR), which include both defects and other maintenance requests. Our goal is to use defect prediction methods to help predict CRs in an evolving legacy system.
Limited research has been done in defect prediction using curve-fitting methods evolving software systems, with …
Validation Of A Deployable Proteomic Assay For The Serological Screening Of Sexual Assault Samples, Catherine O'Sullivan Brown
Validation Of A Deployable Proteomic Assay For The Serological Screening Of Sexual Assault Samples, Catherine O'Sullivan Brown
Electronic Theses and Dissertations
Protein mass spectrometry (MS) has emerged as a technique to supplant traditional serological tests for body fluid identification. It was hypothesized that proteomic techniques would surpass the sensitivity and specificity of traditional serological techniques. An automated workflow coupled with protein MS has been developed for the confirmatory identification of five biological fluids. A developmental validation was completed, assessing parameters such as reproducibility, sensitivity, ion suppression, and limit of detection. Implementation was determined through tandem sample processing by MS, traditional serological tests, and standard DNA profiling methods. The MS approach offered superior detection limits while also providing true confirmatory results, producing …
We All Want To Change The World: How Behavioral Insights Can Help Reduce Carbon Emissions, Thomas C. Gifford
We All Want To Change The World: How Behavioral Insights Can Help Reduce Carbon Emissions, Thomas C. Gifford
Electronic Theses and Dissertations
The world is in the midst of an unprecedented environmental crisis driven primarily by human behavior. As the world has globalized, countries have developed, and standards of living have improved, global pollution has skyrocketed and has resulted in a wide range of environmentally destructive outcomes. All paths to environmentally sustainable development involve a dramatic cut in carbon emissions from current day levels. In this thesis, I explore how the omission of behavioral factors from mainstream neoclassical models has contributed to, and can aid in reducing unsustainably high levels of carbon emissions. Throughout the history of economic thought, classical economists such …
Evaluating Nuclear Energy As A Component Of U.S. Energy Innovation Systems, Bryce Jones
Evaluating Nuclear Energy As A Component Of U.S. Energy Innovation Systems, Bryce Jones
Electronic Theses and Dissertations
Nuclear energy is contentious in policy discussions that evaluate its role in the current U.S. clean energy innovation system. OECD nations, on average, have begun to reduce their dependence on nuclear energy. However, the United States has remained invested in its nuclear energy infrastructure and the role that it plays within federal research and development. This thesis examines the Neo-Schumpeterian perspective and the National Innovation System’s approach, the economic history of nuclear energy in the United States, and given insight from these factors, discusses the current role of nuclear energy in the U.S. energy innovation system. The objective is to …
Implementing A Neural Network For Supervised Learning With A Random Configuration Of Layers And Nodes, Kane A. Phillips
Implementing A Neural Network For Supervised Learning With A Random Configuration Of Layers And Nodes, Kane A. Phillips
Electronic Theses and Dissertations
Deep learning has a substantial amount of real-life applications, making it an increasingly popular subset of artificial intelligence over the last decade. These applications come to fruition due to the tireless research and implementation of neural networks. This paper goes into detail on the implementation of supervised learning neural networks utilizing MATLAB, with the purpose being to generate a neural network based on specifications given by a user. Such specifications involve how many layers are in the network, and how many nodes are in each layer. The neural network is then trained based on known sample values of a function …
Statistical Modeling Of Positive Peer Support On Longitudinal Adolescent Substance Use, Kady Rost
Statistical Modeling Of Positive Peer Support On Longitudinal Adolescent Substance Use, Kady Rost
Electronic Theses and Dissertations
To evaluate this study’s research question of ”Does the latent construct of Positive Peer Support (PPS) relate to the construct of Adolescent Substance Use (ASU) over time, controlling for neighborhood safety, race, and sex?”, Structural Equation (SEM) and Latent Growth Curve Modeling (LGCM) were used to investigate trajectories. Secondary longitudinal data from Zimmerman (2014) of 604 students enrolled for four consecutive years in public schools located in Flint, Michigan. In the secondary data resource, students who participated were declared “at risk” by GPA. Significant relationships were found in SEM: Positive Peer Support to Adolescent Substance Use, All Control Variables to …
Deep Learning Methods For Fingerprint-Based Indoor And Outdoor Positioning, Fahad Alhomayani
Deep Learning Methods For Fingerprint-Based Indoor And Outdoor Positioning, Fahad Alhomayani
Electronic Theses and Dissertations
Outdoor positioning systems based on the Global Navigation Satellite System have several shortcomings that have deemed their use for indoor positioning impractical. Location fingerprinting, which utilizes machine learning, has emerged as a viable method and solution for indoor positioning due to its simple concept and accurate performance. In the past, shallow learning algorithms were traditionally used in location fingerprinting. Recently, the research community started utilizing deep learning methods for fingerprinting after witnessing the great success and superiority these methods have over traditional/shallow machine learning algorithms. The contribution of this dissertation is fourfold:
First, a Convolutional Neural Network (CNN)-based method for …
Observation Of New Particle Formation In The Northern Hemisphere At Altitude From 4 To 20 Km, Mohamed Saad
Observation Of New Particle Formation In The Northern Hemisphere At Altitude From 4 To 20 Km, Mohamed Saad
Electronic Theses and Dissertations
New particle formation (NPF) is investigated using measurements of aerosol size distributions and meteorological variables made in two continents, including USA and Europe. Despite the considerably different aerosol particle abundances among the sites, a common relationship was found between the characteristics of NPF events and the air mass convective and/or advective transport. CO and O3 act as tracers of tropospheric and stratospheric air, respectively, their statistical relationship can be used to quantify air mass characteristics and origins. The mixing ratio values of CO increased within the upper troposphere layer before/during NPF events, which may serve as an indicator of occurring …
Epr Relaxation Of Modified Triphenylmethyl And Nitroxide Radicals, Whylder Moore
Epr Relaxation Of Modified Triphenylmethyl And Nitroxide Radicals, Whylder Moore
Electronic Theses and Dissertations
Trityl and nitroxide radicals are widely used as probes in chemical and biochemical systems. Understanding of factors that impact the electron spin relaxation for these radicals is important for selection of probes and experimental operating conditions. It has been previously reported that 13C isotope enrichment of the central carbon of the trityl yields a highly sensitive micro viscosity probe. It was important to characterize the impact of this substitution on the relaxation processes in fluid solution and immobilized samples.
Electron spin relaxation times for perdeuterated Finland trityl 99% enriched in 13C at the central carbon (13C …
The Ecological Resilience Of A Tropical Montane Pine Forest To Droughts, Fire, And Hurricane Disturbance, Daniel Erland Brugger Swann
The Ecological Resilience Of A Tropical Montane Pine Forest To Droughts, Fire, And Hurricane Disturbance, Daniel Erland Brugger Swann
Electronic Theses and Dissertations
Owing to the geographic isolation and unique climatic conditions which occur in tropical montane forests (TMFs), these systems are highly sensitive to changes in both climate and disturbance. Therefore, as ongoing climate change alters disturbance regimes – potentially facilitating multiple disturbance interactions much greater than that of isolated disturbances – TMFs may be shifted to alternate stable states. However, study of TMF resilience is essentially unknown given the lack of long-term studies in these systems. We address the resiliency of the tropical montane pine forests of the Cordillera Central, Dominican Republic using long-term climate records, remeasured vegetation data, and reconstructed …
Assessing The Variations Of Educational Attainment At National And Subnational Levels Using Hierarchical Linear Models, Bingxin Qi
Electronic Theses and Dissertations
Education is a human right, and equal access to education is not only crucial for an individual’s well-being, but also essential for eradicating poverty, ensuring long-term prosperity for all, transforming the society, and achieving sustainable development. Measuring education development, especially the variations of educational attainment, in a timely and accurate manner can help educators, practitioners, scientists, and policymakers compare and evaluate various education indicators at both subnational and national levels. This research presents an approach that combines multi-source and multidimensional data including population distribution, human settlement, and education data to assess and explore educational attainment trajectories at both national and …
Advancements Toward Sustainable Solar Fuel Production Utilizing Reductive Homogeneous Electro- And Photocatalysis, Hunter Pratt Shirley
Advancements Toward Sustainable Solar Fuel Production Utilizing Reductive Homogeneous Electro- And Photocatalysis, Hunter Pratt Shirley
Electronic Theses and Dissertations
Molecular CO2 and H+ reductive catalysts, whether they be electro- or photocatalytic, have been shown to be possible routes of harnessing solar energy in a clean, renewable manner. There are few electrocatalysts operating at reasonable overpotentials to prove useful in artificial photosynthetic systems, and there are a number of environmental factors within these systems that have yet to be evaluated. Photo-driven catalysis is rare, difficult to control, and rarely provides high-value CO2 reduction products. I report herein an exceptionally low overpotential H+ reduction catalyst, a method of modulating electrocatalysts in-situ to improve performance, a first-of-its-kind mononuclear proton reduction photocatalyst, a …
Stratigraphy And Geochemistry Of Paleocene-Aged Bauxites From North Mississippi, Timothy Brendan Clark
Stratigraphy And Geochemistry Of Paleocene-Aged Bauxites From North Mississippi, Timothy Brendan Clark
Electronic Theses and Dissertations
Bauxite is a heavily-mined aluminum ore that forms through the relative depletion of silica to aluminum. In North Mississippi, bauxite occurring within the Upper Midway and Lower Wilcox groups has been the subject of study for over a century. Despite the abundance and duration of research, controversy surrounds the subjects of bauxite genesis and economic value. The last detailed study of North Mississippi bauxite was in the 1980’s, so the goal of this project is to apply newly available technologies and modern hypotheses on bauxite formation to refine and obtain new data. Fieldwork observations yielded pisoliths, horizonation, and possible rhizoliths, …
Dynamics For Discretized Gravity In The Causal Set Approach, Benjamin Pilgrim
Dynamics For Discretized Gravity In The Causal Set Approach, Benjamin Pilgrim
Electronic Theses and Dissertations
Causal set theory is an approach to quantum gravity which replaces the continuous spacetime manifold with a discrete set of points and a partial order. In this work, I will focus on causal sets embeddable in two-dimensional manifolds, and define an action based on chains which in the continuum limit replicates the Einstein-Hilbert action; furthermore, I will propose a variational principle based on this action and numerically show it can distinguish nonflat manifoldlike causal sets from the most common type of nonmanifoldlike causal sets. I will then supplement this action with a boundary term similar to the Gibbons-Hawking-York boundary term …
Lstm-Based Model For Human Brain Decisions Using Eeg Signals Analysis, Lorela Bano
Lstm-Based Model For Human Brain Decisions Using Eeg Signals Analysis, Lorela Bano
Electronic Theses and Dissertations
As machine learning models become more sophisticated, and biometric data becomes more readily available through new non-invasive technologies, it becomes increasingly possible to gain access to interesting biometric data that could revolutionize Human Computer Interaction. In this research, we propose a framework to assess and quantify human preference (like or dislike) on presenting various external visual stimuli. Our framework relies on an Long Short-Term Memory (LSTM) Recurrent Neural Network (RNN) based model and on electroencephalogram (EEG) signals analysis to predict Like or Dislike preference of human subjects when presented with various marketing images.
Arnold Transformations As Applied To Data Encryption, Haley N. Anderson
Arnold Transformations As Applied To Data Encryption, Haley N. Anderson
Electronic Theses and Dissertations
As our world becomes increasingly digital, data security becomes key. Data must be encrypted such that it can be easily encrypted only by the intended recipient. Arnold Transformations are a useful tool in this because of its unpredictable periodicity. Our goal is to outline a method for choosing an Arnold Transformation that is both secure and easy to implement. We find the necessary and sufficient condition that a key matrix has periodicity. The chosen key matrix has a random structure, and it has a periodicity that is sufficiently high. We apply this method to several image and data string examples …
A Speciation Modeling Study Of Heavy Metal Adsorption To Plastic In Municipal Wastewater Treatment Plant Units, Kaitlyn Hague
A Speciation Modeling Study Of Heavy Metal Adsorption To Plastic In Municipal Wastewater Treatment Plant Units, Kaitlyn Hague
Electronic Theses and Dissertations
Microplastics are an emerging concern due to their harmful effect to organisms and their ability to facilitate transport of contaminants including heavy metals. Microplastics can enter the environment through wastewater treatment plants, landfill leachate, and littering. Once in the environment microplastics can be distributed throughout rivers, the ocean, and lakes. In order to understand the adsorption of heavy metals to microplastics a geochemical modeling study was completed using Visual Minteq. Lab tests were completed to better understand what constituents are available in wastewater at four different locations: influent, clarifiers, digesters, and effluent. These constituents were then used to observe how …
A Hydrologic Study Of Climate Variability In Arid Region, Abdullah Alzaydani
A Hydrologic Study Of Climate Variability In Arid Region, Abdullah Alzaydani
Electronic Theses and Dissertations
Climate variability is an important subject to study. It is the change of climate over a long time, which could have a positive or negative impact on humans, soil, and wildlife. Many environments, such as arid environment could be affected by climate variability. The research goal is studying and examining climate variability in arid environment. The research includes three different studies. The first study includes reviewing and understanding of climate variability over extended time through existing studies in arid environments. In addition, this study includes knowledge about climate negative or positive impact on the environment. This study will be reviewing …
Understanding Patterns And Functional Impacts Of An Invasive Tree And Its Biological Control In A Riparian System, Annie L. Henry
Understanding Patterns And Functional Impacts Of An Invasive Tree And Its Biological Control In A Riparian System, Annie L. Henry
Electronic Theses and Dissertations
Invasive species have become an inextricable part of the landscape, particularly in riparian plant communities, and removal is often a key component of restoration programs. Biological control (biocontrol) is a method of removal that is often both efficient and effective. However, the impact of biocontrol on target species and indirect effects from invasive species removal can be hard to predict. While monitoring the impact of invasive species removal usually involves some species-based assessment such as changes in diversity, historically dominant species or native species, these strategies do not typically provide insight into the mechanisms underlying plant community response to removal. …
Use Of Research Tradition And Design In Program Evaluation: An Explanatory Mixed Methods Study Of Practitioners’ Methodological Choices, Margaret Schultz Patel
Use Of Research Tradition And Design In Program Evaluation: An Explanatory Mixed Methods Study Of Practitioners’ Methodological Choices, Margaret Schultz Patel
Electronic Theses and Dissertations
The goal of this explanatory sequential mixed method study was to assess whether there were observable trends, associations, or group differences in evaluation methodology by settings and content area in published evaluations from the past ten years (quantitative), to illuminate how evaluation practitioners selected these methodologies (qualitative), and assess how emergent findings from each phase fit together or helped contextualize each other. In this study, methodology was operationalized as research tradition and method was operationalized as research design. For phase one (quantitative), a systematized ten-year review of five peer-reviewed evaluation journals was conducted and coded by journal, research tradition, research …
Polyester-Pamam “Janus-Type” Linear-Dendritic Blockopolymers (Ldbcs) As Next Generation Biomaterials, Indika Chandrasiri
Polyester-Pamam “Janus-Type” Linear-Dendritic Blockopolymers (Ldbcs) As Next Generation Biomaterials, Indika Chandrasiri
Electronic Theses and Dissertations
Nanomedicine is defined as the application of knowledge and tools of nanotechnology for disease treatment, diagnosis, monitoring, delivery, and sensing. Rapid advances in polymer chemistry and nanotechnology have led to an extensive development of polymeric-based therapeutic systems for nanomedical applications. Compared to traditional molecular-based therapies, polymers facilitate a higher level of versatility and functionality, such as simultaneous imaging and delivery. In particular, amphiphilic diblock copolymers and their self-assemblies have shown apparent success in nanomedicine owing to their ability to provide narrow molar mass distributions and highly ordered nanoscale multimolecular aggregates, including micelles and vesicles. However, engineering these polymeric materials to …
A Spectroscopic And Quantum Chemical Investigation Into The Noncovalent Interactions And Charge Accommodation Of Biomolecules And Their Building Blocks In Various Environments, Ashley Elizabeth Williams
A Spectroscopic And Quantum Chemical Investigation Into The Noncovalent Interactions And Charge Accommodation Of Biomolecules And Their Building Blocks In Various Environments, Ashley Elizabeth Williams
Electronic Theses and Dissertations
As optical measurements have grown increasingly more precise with the rage of the technological revolution, the computer’s ability has matched in computing speed to produce accurate quantum chemical predictions of systems ranging from the atomic to multi-molecular levels. Application of spectroscopy in the investigation of the structure and function of biomolecules and their building blocks has a rich literature background, with applications among cancer research, charge transfer and energy storage, and drug design and delivery. The focus of this dissertation is thus a quantum chemical and/or spectroscopic investigation of a series of biomolecules which include the vibrational band positions of …
On Domination And Bondage Numbers Of Some Classes Of Graphs, Andrew Pham
On Domination And Bondage Numbers Of Some Classes Of Graphs, Andrew Pham
Electronic Theses and Dissertations
Given a simple finite graph G=(V,E), a vertex subset D ? V(G) is said to be a dominating set of G if every vertex v ? V(G)-D is adjacent to a vertex in D. The domination number of G, denoted ?(G), is the minimum cardinality among all dominating sets of G. In a network, the domination number determines the minimum number of sites required to dominate the entire network at a minimum cost. The bondage number of a graph G is the minimum cardinality among all edge sets B such that ?(G-B) > ?(G). The bondage number may serve as a …
Evaluating Canola Genotypes For Growth And Yield Under Different Environmental Conditions In South Dakota, Unius Arinaitwe
Evaluating Canola Genotypes For Growth And Yield Under Different Environmental Conditions In South Dakota, Unius Arinaitwe
Electronic Theses and Dissertations
Canola (Brassica napus L) and carinata (Brassica carinata A. Braun) are potential oilseed crops for diversifying cropping systems and expanding into marginal lands impacted by saline and sodic soils in South Dakota (SD). However, genotypes that are high yielding, with high agronomic adaptability and stability over diverse environments, and salt tolerant have not been selected. One field experiment was conducted at two environments (Brookings - eastern SD and Pierre - western SD) from 2019 to 2020 to evaluate genotypes for growth and yield stability. Three greenhouse experiments were conducted to evaluate genotypes for salt tolerance in …
Laboratory Measurements Of Bed Shear Stress In Open Channel Flow And Soil Erosion Rate In Cohesive Soils, Gunnar Schurmann Kern
Laboratory Measurements Of Bed Shear Stress In Open Channel Flow And Soil Erosion Rate In Cohesive Soils, Gunnar Schurmann Kern
Electronic Theses and Dissertations
The relationship between soil erosion rate and bed shear stress is an important problem in sediment transport and scour. However, reliable measurements of the soil erosion function are challenging, both in the field and in the laboratory. The objective of this study is to investigate an experimental setup for conducting bed shear stress and soil erosion rate measurements using an open channel flume with a rough bed. These experiments were performed in an A-8 Hydraulic Channel with a fixed gravel bed. The flow discharge was kept constant at 0.158 ft.3/s, and bed shear stress was varied by changing the channel …
Comparison Of Software Packages For Detecting Differentially Expressed Genes From Single-Sample Rna-Seq Data, Rong Zhou
Electronic Theses and Dissertations
RNA-sequencing (RNA-seq) has rapidly become the tool in many genome-wide transcriptomic studies. It provides a way to understand the RNA environment of cells in different physiological or pathological states to determine how cells respond to these changes. RNA-seq provides quantitative information about the abundance of different RNA species present in a given sample. If the difference or change observed in the read counts or expression level between two experimental conditions is statistically significant, the gene is declared as differentially expressed. A large number of methods for detecting differentially expressed genes (DEGs) with RNA-seq have been developed, such as the methods …
Effects Of Predator Management And Parasitism On Over-Water Nesting Diving Duck Production In Southwestern Manitoba, Trenton E. Rohrer
Effects Of Predator Management And Parasitism On Over-Water Nesting Diving Duck Production In Southwestern Manitoba, Trenton E. Rohrer
Electronic Theses and Dissertations
Nest survival of upland nesting waterfowl (e.g., mallard [Anas platyrhynchos], blue-winged teal [Anas discors]) has been studied extensively in the Prairie Pothole Region (PPR) of North America. Conversely, over-water nesting diving ducks’ nest survival is poorly understood, likely because over-water nests are more challenging to find, may be less concentrated, and searching for these nests is physically demanding. Nest depredation is considered a leading cause of duck nest failure and is considered a limiting factor on upland nesting waterfowl production in the PPR. Similar factors limiting upland nesting duck production may limit over-water nesting duck productivity, but studies of this …