Physical Sciences and Mathematics Commons^™

Improved Secure And Low Computation Authentication Protocol For Wireless Body Area Network With Ecc And 2d Hash Chain, Soohyeon Choi

Electronic Theses and Dissertations

Since technologies have been developing rapidly, Wireless Body Area Network (WBAN) has emerged as a promising technique for healthcare systems. People can monitor patients’ body condition and collect data remotely and continuously by using WBAN with small and compact wearable sensors. These sensors can be located in, on, and around the patient’s body and measure the patient’s health condition. Afterwards sensor nodes send the data via short-range wireless communication techniques to an intermediate node. The WBANs deal with critical health data, therefore, secure communication within the WBAN is important. There are important criteria in designing a security protocol for a …

Quantification Of Climate Variability And Extreme Events In The Great Plains, Angelinah Ntsieng Rasoeu

Electronic Theses and Dissertations

Climate variability and extreme events continue to worsen resulting in significant impacts to society and the environment. Quantifying precipitation variability, streamflow, and extreme events at local scale is crucial for local planning and management due to spatial and temporal precipitation variability which influences streamflow and thus, water resources. This study uses statistical tools to analyze 1895-2019 (125 years) of historical precipitation data to examine how long-term precipitation varies annually, seasonally, and monthly, and create climate classifications. The results show that annual precipitation is increasing linearly over time ranging from 13.2 in (1976) to 43.1 in (2010) and 5 climate classes …

Spatial And Temporal Patterns Of Sympatric Bobcats (Lynx Rufus) And Coyotes (Canis Latrans) In An Agricultural Landscape, Marlin M. Dart

Electronic Theses and Dissertations

Bobcat (Lynx rufus) populations experienced declines in the Midwest during the 20th century due to land conversion for agriculture and over exploitation and were practically nonexistent in areas by the 1970-80s. Populations have been recovering following changes in land-use practices and habitat improvement. Eastern South Dakota was closed to bobcat harvest in 1977 but reopened in 2012 to select counties. Bobcats are elusive, have large home ranges, and occur at low densities, making monitoring their populations difficult. Camera trapping is an effective tool for monitoring elusive carnivores but can be burdened by low detection rates. Researchers often employ …

Therapeutic Immunoglobulin G Surface Mobility Promotes Antibody-Dependent Cellular Phagocytosis By Arp2/3 And Syk Mediated Rearrangement Of Fcγ Receptors, Seongwan Jo

Electronic Theses and Dissertations

Therapeutic antibodies are rapidly growing class of drugs for treating cancers and immunological disorders by targeting specific antigens or blocking certain pathway to inhibit the tumor growth. In cancer immunotherapy, it was found that Fcγ receptor (FcγR) in immune cells play an important role in antibody dependent cell toxicity against tumor cells. Therefore, understanding FcγR activation mechanism, which requires ligation with immunoglobulin (IgG), is crucial to enhance potency of therapeutic antibodies. One crucial immune responses triggered upon FcγR ligation with IgG is phagocytosis which indicates clearing targets by engulfment. It is known that FcγRs form microclusters which gets rearranged during …

Development Of A Probabilistic Multi-Class Model Selection Algorithm For High-Dimensional And Complex Data, Madeline Anne Ausdemore

Electronic Theses and Dissertations

The development of quantifiable measures of uncertainty in forensic conclusions has resulted in the debut of several ad-hoc methods for approximating the weight of evidence (WoE). In particular, forensic researchers have attempted to use similarity measures, or scores, to approximate the weight of evidence characterized by highdimensional and complex data. Score-based methods have been proposed to approximate theWoE for numerous evidence types (e.g., fingerprints, handwriting, inks, voice analysis). In general, scorebased methods consider the score as a projection onto the real line. For example, the score-based likelihood ratio evaluates and compares the likelihoods of a score calculated between two objects …

Lightweight Encryption Based Security Package For Wireless Body Area Network, Sangwon Shin

Electronic Theses and Dissertations

As the demand of individual health monitoring rose, Wireless Body Area Networks (WBAN) are becoming highly distinctive within health applications. Nowadays, WBAN is much easier to access then what it used to be. However, due to WBAN’s limitation, properly sophisticated security protocols do not exist. As WBAN devices deal with sensitive data and could be used as a threat to the owner of the data or their family, securing individual devices is highly important. Despite the importance in securing data, existing WBAN security methods are focused on providing light weight security methods. This led to most security methods for WBAN …

Quantifying The Impacts Of Land Use, Management And Climate Change On Water Resources In Missouri River Basin, Arun Bawa

Electronic Theses and Dissertations

A location-specific evaluation of hydrological landscape responses concerning past and projected climate and land use land cover (LULC) changes can provide a powerful intellectual basis for developing efficient and profitable agroecosystems, and overcoming uncertain and detrimental consequences of LULC and climate shifts. This dissertation assessed the impacts of land use, management, and climate change on water resources in the Missouri River Basin (MRB) through four specific studies that included: (i) to study the responses of leached nutrient concentrations and soil health to winter rye cover crop (CC) under no-till corn (Zea mays L.)-soybean [Glycine max (L.) Merr.] rotation, (ii) to …

Analysis Of Volatile Organic Compounds: Petroleum Emissions And Microbial Degradation, A K M Ahsan Ahmed

Electronic Theses and Dissertations

Volatile organic compounds (VOCs) are abundant in nature and can occur in various forms in a wide variety of sources. Petroleum is one of the major sources of VOCs. Petroleum being the most widely used energy resources of the world, often released to the environment due to emission and leakage or accidental spillage during exploration, transportation and manufacturing. Once released to the environment, petroleum poses a serious threat to the environment due to some of its toxic organic components. Therefore, the analysis of petroleum is critical to understand its effect on the environment and remediation. This dissertation is focused on …

Assaying Bacillus Amyloliquefaciens Isolates 1ba And 1d3 For Biosurfactant Production And Utilization Of Petroleum Hydrocarbons And Phenolic Acids, Pavan Kulkarni

Electronic Theses and Dissertations

Several Bacillus amyloliquefaciens isolates obtained from wheat residue have been studied as biological agents to control wheat diseases. Notable traits of isolates 1BA and 1D3 include growth with high salt (10% NaCl), at temperatures up to 50°C and over a wide pH range. BIOLOG Gen III plates were used to study and further characterize Bacillus amyloliquefaciens 1BA and 1D3. Both isolates showed tolerance to high salt concentration supporting previous studies. They also grew in the presence of lithium chloride, potassium tellurite, and sodium bromate. Both isolates grew at pH 5, with almost identical carbon source utilization fingerprints. However, D-serine, quinic …

Search For Cpt And Lorentz Invariance Violation In The Muon G-2 Experiment At Fermilab, Meghna Bhattacharya

Electronic Theses and Dissertations

The Muon g-2 experiment at Fermilab (E989) aims to measure the anomalous magnetic moment of the muon, $a_{\mu}= (g-2)/2$, to a groundbreaking precision of $140$ ppb, obtaining a near four-fold increase in precision over the previous experiment, E821, at the Brookhaven National Laboratory (BNL). The value of $a_{\mu}$ from BNL currently differs from the Standard Model prediction by $\sim 3.7$ standard deviations, suggesting the potential for new physics and therefore, motivating a new experiment.Because the theory predicts this number with high precision, testing the g-factor through experiment provides a stringent test of the SM and can suggest physics beyond the …

Constructing And Validating Feature Models Using Relational, Document, And Graph Databases, Hazim Shatnawi

Electronic Theses and Dissertations

Building a software product line (SPL) is a systematic strategy for reusing software within a family of related systems from some application domain. To define an SPL, a domain analyst must identify the common and variable aspects of a family of systems and capture them for later use in construction of specific products. To do so, Feature-Oriented Domain Analysis (FODA) introduced the feature model as an abstraction to represent the common and variable aspects, using a feature diagram to depict the model visually. However, this abstraction is often difficult for developers to use because most tools rely on specialized theories, …

Enhanced Electrochemical And Light-Driven Co2 Reduction By Incoporating Pendant Functionality In The Second-Coordination Sphere Of Molecular Catalysts, Sayontani Sinha Roy

Electronic Theses and Dissertations

With the increase in global population and rapid industrialization, a gigantic amount of greenhouse gases is being released into the atmosphere each year. The catastrophic effect of these accumulated greenhouse gases is driving global climate change and adversely impacting our ecosystem. Popularizing the traditional renewable energy sources (such as solar and wind energy) can mitigate the problem by cutting down anthropogenic CO2 emissions, which is the major contributor to this global problem. However, the intermittent nature of these energy sources is problematic to reliably power society throughout the year. Therefore, converting CO2 to various value-added chemicals with the aid of …

A Valence-Bond Operator Algebra For Quantum Spin Models And Its Applications, Huu Tran Do

Electronic Theses and Dissertations

The Heisenberg Hamiltonian is the prototype model for quantum magnetism. The Hamilto- nian includes exchange couplings between vector spins, which are the intrinsic magnetic moments of localized electrons. The classical energy between any pair of interacting spins can be minimized by aligning them parallel (ferromagnetic case) or antiparallel (antiferromagnetic), depending on the sign of the coupling. But quantum fluctuations play a key role, and a full quantum mechanical treatment of the many-body system is generally required. Finding the exact ground-state energy and wave function of isotropic antiferromagnetic (AFM) systems for an arbitrary spin-S and lattice morphology is still a challenging …

Topics On Applications Of Optimization Theories On Statistical Methodologies, Duc Anh Anh Doan

Electronic Theses and Dissertations

In this dissertation, We show the results of our researches in statistical sampling, functional optimization, and methodology for partially observed Markov process (POMP) models. In statistical sampling, we introduce a p-generalized smoothing method that enables the Langevin-Monte Carlo method to generate a sample from a log concave distribution weakly smoothing potential function. For our optimization research, we introduce an accelerated inexact gradient (AIG) method. Combining the strengths while mitigating the weakness of its parent methods: gradient descent and Nesterov's accelerated gradient, AIG converges with excellent rates for both convex and non-convex optimization problems for smooth objective functions. Furthermore, we also …

Elucidating The Interfacial Interactions Between Biomacromolecules And Functionalized Pamam-Based Materials For Biomedical Applications, Briana L. Simms

Electronic Theses and Dissertations

Polyamidoamine (PAMAM) is a dendrimer structure with a polypeptide backbone architecture. It has been utilized in a wide variety of applications but has found significant utility in biomedical applications. PAMAM has been studied extensively due to its globular structure that is similar to proteins found in the body. The branched architecture and overall size provide a favorable environment for host-guest interactions and allows for the loading of small molecules for therapeutic delivery. Although PAMAM has many benefits for use in the area of therapeutic delivery, a primary area of concern for this molecular architecture is the terminal amines that serve …

Application Of Passive Air Samplers For Atmospheric Research, And Determination Of Metals In Tree Rings And Marine Sapropel By Icp-Ms, Byunggwon Jeon

Electronic Theses and Dissertations

This research focuses on studies of atmospheric mercury (Hg) using passive air samplers (PAS) and studies of trace elements in tree cores and sediment using inductively coupled plasma mass spectrometry (ICP-MS). Mercury is a toxic element that is dispersed globally through the atmosphere. Accurately measuring airborne Hg concentrations aids understanding of the pollutant’s sources, distribution, cycling, and trends. Mercury PAS are designed to capture gaseous elemental mercury (GEM) at a known rate. Compared to active air sampling the low-cost of PAS allows for greater spatial coverage. We used a commercially available Hg PAS (MerPAS®) and observed differences in GEM between …

Dependency-Based Reactive Change Propagation Design Pattern Applied To Environments With High Unpredictability, João Paulo Oliveira Marum

Electronic Theses and Dissertations

Transitional turbulence is a period of chaotic or unreliable variation in the state of a software system that results from changes in the system’s interconnected components. During these periods of instability, an external observer of the system’s state may “see” erroneous results. This is a problem that can affect visual user interfaces such as those in virtual and augmented reality applications and desktop or Web GUIs. In this research, we study two different reactive applications developed in C# on .NET. We reduce the transitional turbulence by augmenting the base applications with a dependency-graph-based event scheduling approach. The first study investigates …

Fostering Coastal Destination Resilience In Maine: Understanding Climate Change Risks And Behaviors, Lydia Horne

Electronic Theses and Dissertations

Tourism is an increasingly important global industry. Coastal and nature-based tourism destinations are especially vulnerable to climate change. Trends in visitation are expected to shift under changing climate conditions, influencing tourist travel behaviors related to destination selection, timing of visits, and activity participation. Tourism suppliers’ adaptation and mitigation behaviors have the potential to alleviate negative shifts in visitation and respond to negative climate change impacts, while also enabling suppliers to take advantage of emerging opportunities. The purpose of this dissertation is to understand how tourism stakeholders, including tourism suppliers (i.e., business owners, managers) and consumers (i.e., visitors), perceive their risk …

Optical Signatures Of Plankton In The Open Ocean: From Individual Cells To Global Patterns, Nils Haentjens

Electronic Theses and Dissertations

Marine plankton ecosystems play a major role on Earth, having implications for the global carbon cycle and the food-web structures. Ocean color satellites and networks of autonomous platforms equipped with optical sensors are the primary tools used to study phytoplankton dynamics. They provide long term records while offering a synoptic view of our oceans, enabling to study impact of climate variability on planktonic ecosystems. Interpretation of these observations rely heavily on optical theory and how light propagating through the water is affected by particles who absorb and scatter light (e.g. phytoplankton, sediments). However, the complexity of the optical properties of …

Atom Transfer Radical Processes: From Catalyst Design To Polymer Synthesis, Characterization, And Application, Michael Novak

Electronic Theses and Dissertations

Due to the toxicity of heavy metals and their prevalence in the environment there exists a need to develop highly active transition metal catalysts ultimately reducing the amount needed for chemical transformations. Additionally, there is interest in the scientific community for creating new materials that can remove these pollutants from industrial wastewater prior to its release into the environment. The work presented here focuses on the reduction and removal of heavy metals from industrial hazardous waste by designing novel highly active catalysts and developing polymeric adsorbents.

Highly active catalyst complexes consisting of novel hybrid ligands, 2-(dimethylamino)ethyl-bis-[2-(pyridylmethyl)amine] (M1-T2), and bis[2-(dimethylamino)ethyl]-2-(pyridylmethyl)amine (M2-T1), …

Fluoride Removal With Augmented Bentonite In Drinking Water And Community Perceptions In Arusha, Tanzania, Kara Okular

Electronic Theses and Dissertations

High fluoride concentrations in drinking water affect millions of people around the world. The World Health Organization recommended a fluoride concentration in drinking water of ≤ 1.5 mg/L; fluoride above this concentration can cause long-term dental and skeletal fluorosis. Fluoride imparts no taste to water; therefore, people do not realize that they are ingesting high fluoridated water. Researchers sought to develop a material to remove fluoride from drinking water through sorption. Aluminum was used to form a double ionic layer on the bentonite clay surface. Once mixed in contaminated water, a coagulant, ferric sulfate, was used to separate the bentonite …

Functionalized Materials From Atom Transfer Radical Processes, Sean Fischer

Electronic Theses and Dissertations

This work is focused on the synthesis, characterization, and application of functionalized materials prepared from atom transfer radical processes. Atom transfer radical processes encompass both atom transfer radical addition (ATRA) and polymerization (ATRP) reactions, both of which are catalyzed by ppm amounts of copper complexes. The synthetic efforts of ATRA include increasing adduct selectivity through optimization of reaction conditions to generate small molecules in high to moderate yields. ATRA provides retention of the halogen moiety, which is an attractive functional group that can be further modified with other transformations. Specifically, the copper-catalyzed azide-alkyne [3+2] cycloaddition (CuAAC) allows for the realization …

Live Cell Super-Resolution Microscopy Quanitifies An Interaction Between Influenza Hemagglutinin And Phosphatidylinositol 4,5-Bisphosphate, Jaqulin N. Wallace

Electronic Theses and Dissertations

Influenza virus, colloquially known as the flu, is an acute respiratory disease that infects several millions of individuals each year in the U.S. and kills tens of thousands of those infected. Yearly viral vaccines are widely available, however, due to the virus’s high mutation rate, their efficacy varies greatly. Due to the variability in vaccine efficiency against seasonal influenza, and the potential for even more pathogenic versions of influenza to emerge at any time, there is a high demand for a universal treatment option.

Influenza virus hijacks a variety of host cell components in order to replicate. The glycoprotein hemagglutinin …

An Intramolecular Method For The Formation Of Glycosidic Bonds, Sudeera Nadeeshani Kamburugamuwa Kamburugamuwe Loku Acharige

Electronic Theses and Dissertations

The improved understanding of carbohydrate functions in biological systems has increased the demand for well-characterized and pure carbohydrates in biomedical research. Chemical synthesis is the most feasible method to satisfy the scientific demand despite the inherent challenges of the glycosylation reaction. Therefore, it is essential to investigate novel methods for the formation of glycosidic bonds. In this work, an intramolecular method was developed using a thio-methylene-silyl linker to tether a glycosyl donor and acceptor. The glycosylation conditions resulted in the formation of both anomeric isomers with a preference for the inversion pathway, which is inconsistent with an entirely intermolecular glycosylation …

Accurate Quantitation Of Hexavalent Chromium For Reference Standard Certification And Quality Control Testing Using Speciated Isotope Dilution Mass Spectrometry, James E. Henderson

Electronic Theses and Dissertations

The ability to perform accurate, repeatable, and defensible elemental and molecular speciated analysis is immensely significant for measurements that support human health, environmental science, and industry. This is especially true since trivalent chromium [Cr(III)] is necessary for proper nutrition, while hexavalent chromium [Cr(VI)] is extremely toxic, genotoxic, and carcinogenic. The main challenges associated with speciated analysis are related to reactive species that are continuously transformed or converted to other species during sample processing. Accurate determination of Cr(III) and Cr(VI) species require a method that is capable of monitoring and correcting for interconversion, bias, and instrumental error. Traditional quantitative methods, such …

Control Of Corrosion On Ss316l Using Surface Initiated Polymers, Alexander Rupprecht

Electronic Theses and Dissertations

Pitting corrosion is arguably one of the most destructive and dangerous forms of corrosion, resulting in damage to structures, the environment, and public health. In addition, damage caused to structures such as bridges, pipelines, and boats, corrosion also has a profound effect on the biomedical community. Implanted metallic devices (i.e., vascular stents and artificial joints) are prone to pitting corrosion caused by aggressive ions present in extracellular fluid. To provide a corrosion-resistant surface on SS316L, films of poly(styrene), poly(methyl acrylate), and poly(methyl methacrylate) were formed using surface-initiated atom transfer radical polymerization (SI-ATRP). The resulting hydrophobic polymer films had a fractional …

Understanding Biomass Upgrading Through Hydrogenolysis Reactions: Kinetics And Mechanism, Jalal Tavana

Electronic Theses and Dissertations

This dissertation involves several hydrogenolysis reactions but is mainly focused on hydrodechlorination (HDC) of chlorobenzene (PhCl) and hydrodeoxygenation (HDO) of 2-furancarboxylic acid (FCA). Hydrodechlorination of PhCl has been the subject of research for some time. Here, we used a Pd/C catalyst to study this reaction though rigorous kinetics and mechanistic analyses in a CSTR reactor. The H₂/D₂ kinetic isotope effect (KIE) experiment revealed that H₂ is not involved in a rate controlling step. The kinetics data are in agreement with similar systems reported before and follow a first-order dependence on chlorobenzene, half order for hydrogen and …

Species Distribution Modeling For Arid Adapted Habitat Specialists In Zion National Park, Sam Driver, Chris M. Schalk, Daniel Unger, David Kulhavy

Electronic Theses and Dissertations

The Arizona toad (Anaxyrus microscaphus) and Jones’ waxy dogbane (Cycladenia humilis var. jonesii) are habitat specialists with historical ranges in the desert southwest and specifically, Zion National Park (ZION). The machine learning method, MaxEnt, constructed species distribution models (SDMs) in ZION for the two study species at 30 m and 900 m spatial resolutions using climate, topographic, and remotely sensed data. Additionally, 900 m forecasting models were constructed to observe the shifts in suitable habitat for the years 2050 and 2070, based off two representative concentration pathway scenarios. Results indicate promising predictive power for both high …

Petrology Of The Gradational Intrusive Contact Between The Packsaddle Schist And The Town Mountain Granite, Enchanted Rock State Natural Area, Llano Uplift, Central Texas, Travis Galle

Electronic Theses and Dissertations

The Mesoproterozoic intrusive contact between the ~1.1 Ga anorogenic Town Mountain Granite and the ~1.3 Ga Packsaddle Schist is a gradational contact exhumed within the Llano uplift. This contact is exposed along the southeastern margin of the Enchanted Rock batholith in central Texas. Field observations, hand sample and thin section petrography, and handheld X-ray fluorescence analysis of hand samples were used to characterize the gradational nature of this contact at multiple scales. The style of gradation between the Town Mountain Granite and Packsaddle Schist varies throughout the study area, containing both injection and permeation. The complex relationships observed at the …

Approximating Fol Ontologies Using Owl2, Robert W. Powell

Electronic Theses and Dissertations

With the amount of data collected everyday ever expanding, techniques which allow com- puters to semantically understand data are growing in importance. Ontologies are a tool to describe the relationships connecting data so that computers can correctly interpret and combine data from many sources. An ontology about water needs to describe what the term "river" may refer to: An arbitrary river or one usable for navigation; a single tributary or an entire river network; the riverbed or the water itself? Well-designed ontologies can be shared, reused, and extended across multiple applications and facilitate betters integration of different data collections.

Common …