Physical Sciences and Mathematics Commons^™

Land Suitability Analysis For Windfarm Development In Texas, Robert Laszlo Milecz

Electronic Theses and Dissertations

Due to the negative impact on the environment of conventional electric power generation methods, especially coal and oil-fired generating plants, wind power as an alternative for sustainable energy has received more attention in recent years. The purpose of this project was to apply Geographic Information System (GIS), integrated with Multi Criteria Decision Making (MCDM), for identifying suitable areas for wind turbine applications in Texas. Factors taken into consideration included socioeconomic criteria such as distance to highways, proximity to airports and urban areas, localized environmental criteria such as terrain slope and distance to rivers, affected waterbodies, and wildlife management areas. Also …

Decompositions Of The Complete Mixed Graph By Mixed Stars, Chance Culver

Electronic Theses and Dissertations

In the study of mixed graphs, a common question is: What are the necessary and suffcient conditions for the existence of a decomposition of the complete mixed graph into isomorphic copies of a given mixed graph? Since the complete mixed graph has twice as many arcs as edges, then an obvious necessary condition is that the isomorphic copies have twice as many arcs as edges. We will prove necessary and suffcient conditions for the existence of a decomposition of the complete mixed graphs into mixed stars with two edges and four arcs. We also consider some special cases of decompositions …

A Gis-Based Method For Archival And Visualization Of Microstructural Data From Drill Core Samples., Elliott Holmes

Electronic Theses and Dissertations

Core samples obtained from scientific drilling could provide large volumes of direct microstructural and compositional data, but generating results via the traditional treatment of such data is often time-consuming and inefficient. Unifying microstructural data within a spatially referenced Geographic Information System (GIS) environment provides an opportunity to readily locate, visualize, correlate, and explore the available microstructural data. Using 26 core billet samples from the San Andreas Fault Observatory at Depth (SAFOD), this study developed procedures for: 1. A GIS-based approach for spatially referenced visualization and storage of microstructural data from drill core billet samples; and 2. Producing 3D models of …

Marginal Methods And Software For Clustered Data With Cluster- And Group-Size Informativeness., Mary Elizabeth Gregg

Electronic Theses and Dissertations

Clustered data result when observations have some natural organizational association. In such data, cluster size is defined as the number of observations belonging to a cluster. A phenomenon termed informative cluster size (ICS) occurs when observation outcomes vary in a systematic way related to the cluster size. An additional form of informativeness, termed informative within-cluster group size (IWCGS), arises when the distribution of group-defining categorical covariates within clusters similarly carries information related to outcomes. Standard methods for the marginal analysis of clustered data can produce biased estimates and inference when data have informativeness. A reweighting methodology has been developed that …

Search For New Physics Using Lepton Flavor Violating Signatures In Modern Particle Colliders., Atanu Pathak

Electronic Theses and Dissertations

Charged lepton flavor violation is a clear signal of new physics. Such decays are not allowed in the Standard Model but highly anticipated in a large class of new physics models. A direct search for lepton flavor violation in decays of the Higgs boson with the ATLAS detector at the LHC is presented here. The analysis is performed in the H → l tau channel, where the leading lepton (l) can be either an electron or a muon, and the tau lepton decays into an opposite flavored lighter lepton or via the hadronic decay channel. Published results of this search …

Electrochemically-Modulated Surface Plasmon Waves At A Nano-Scale For Investigations And Applications Of Redox Assemblies., Aymen Hasan Qatamin

Electronic Theses and Dissertations

In this thesis, an electrochemically-modulated surface plasmon resonance (EC-SPR) technique was developed for challenging investigations and applications in different redox assemblies. The principle of the technique is based on the nano-scale confined and sensitive interplay between a surface plasmon wave and a redox-active probe featuring an optical transition when undergoing a faradaic redox process. Such faradaic process is electrochemically controlled by modulating the surface electric potential of the SPR platform to create an optical output signal that is substantially immune to the negative impacts of background environment and enabling the identification and quantification minute properties linked to a molecular event …

Utilizing The Public On Public Lands: The Application Of Community Science To Monitor And Model Erosion In National Forests, Jacob L. Hansen

Electronic Theses and Dissertations

Unpaved forest roads are adversely affecting coldwater streams through excessive erosion and the subsequent sedimentation of adjacent waterways. To help identify areas of concern, Trout Unlimited (TU) in the Southern Appalachian region developed a Community Science initiative to gather data on sediment sources and stream-road crossings. Volunteers were recruited and trained to monitor road and trail conditions and collect and submit data using a Survey123 application on their cell phones. Analysis of the contributed data reveals statistical connections between drainage type and both erosion level and stream sedimentation. The contributed data were also included as a calibration for the lite …

Evaluation Of Groundwater Sodium And Sodium Uptake In Taxodium And Its Hybrids On Galveston Island, Texas, Daniel Morgan

Electronic Theses and Dissertations

In September 2008, Hurricane Ike swept through the Gulf of Mexico striking the Gulf Coast, claiming hundreds of lives and causing billions of dollars in damage. The hurricane left behind elevated sea salt concentrations in the soil and groundwater, preventing the unaided return of live oaks and other species to the island. To determine effective ways to ameliorate the elevated Na⁺ concentrations in the soil, eight treatments were applied to the soil and combinations of three species of plants, live oak (Quercus virginiana), hybrid bald cypress (Taxodium ‘T406’), and yellow hibiscus (Hibiscus hamabo …

(Pseudo)Phase Tuning In The Service Of Synthesis: Technologies For Sustainable Catalysis., Justin Douglas Smith

Electronic Theses and Dissertations

Strategies for manipulation of chemical phases were explored with emphasis on synthetic chemistry applications. Some strategies are fairly divergent from their origin, but all ultimately began from investigations of micellar media. Accordingly, Chapter 1 reviews the historical development of micellar catalytic processes. Chapters 2 and 3 detail development of synthetic methods in micellar solutions of designer surfactant PS-750-M. PS-750-M was designed to create benign micellar solutions which effectively mimic toxic organic solvents; it contains a proline-based linker between its hydrophobic and hydrophilic regions which imparts increased polarity to the micellar core. Chapter 2 details an interfacial nucleophilic substitution of perfluoroarenes …

Water Cluster Motifs In Structurally Similar N-(2-Aminoethyl)-1-Methylimidazole-2-Carboxamide Metal Complexes: Synthesis, Characterization, Thermal And Electrical Properties., Nina Saraei

Electronic Theses and Dissertations

Water is a remarkable molecule and in all of its forms exhibits an amazing collection of properties and functions. Besides its crucial role in life and many technological processes, water displays some unusual and anomalous properties at various interfaces and under different conditions. Although the role of hydrogen-bonding interactions and their fluctuations are well known to determine the properties of water, the main obstacle exists in the complexity of correctly describing the interactions between water molecules. The key to understanding the behavior of water is to collect precise structural data of various H-bonded water networks in diverse environments. In this …

Convolution Inequalities And Applications To Partial Differential Equations., Matthew Reynolds

Electronic Theses and Dissertations

In this dissertation we develop methods for obtaining the existence of mild solutions to certain partial differential equations with initial data in weighted L p spaces and apply them to some examples as well as improve the solutions to some known PDEs studied extensively in the literature. We begin by obtaining a version of a Stein-Weiss integral inequality which we will use to obtain general convolution inequalities in weighted L p spaces using the techniques of interpolation. We will then use these convolution inequalities to make estimates on PDEs that will help us obtain mild solutions as fixed points of …

A Structural Study Of Correlated Materials: Incipient Mott Insulators And Low-Dimensional Systesm., Alaa Alfailakawi

Electronic Theses and Dissertations

Current theories of high-temperature superconductivity suggest that electrons must organize into Cooper pairs in order for a material to exhibit a superconducting phase. Electrons in insulators experience significant repulsive interactions that tend to keep electrons localized at atomic positions. In contrast, electrons in metals are delocalized, interact weakly, and are free to conduct electricity. Therefore, the formation of Cooper pairs should have different mechanisms for metals compared to insulators. This contrast raises the debate about the origin of high-temperature superconductivity in iron-based material, whether it depends on the strong or weak coupling. Many iron-based materials are metallic in the normal …

Linear Methods For Regression With Small Sample Sizes Relative To The Number Of Variables., Rajesh Sikder

Electronic Theses and Dissertations

In data sets where there are a small number of observations but a large number of variables observed for each observation, ordinary least squares estimation cannot be used for regression models. There are many alternative including stepwise regression, penalized methods such as ridge regression and the LASSO, and methods based on derived inputs such as principal components regression and partial least squares regression. In this thesis, these five methods are described. K-fold cross validation is also discussed as a way for determining regularization parameters for each method. The performance of these methods in estimation and prediction is also examined through …

Paleoenvironmental Reconstruction Of Quaternary Saltville, Virginia, Using Ostracode Autecology, Austin Gause

Electronic Theses and Dissertations

The Saltville valley in southwestern Virginia is home to Quaternary localities containing paleontological and archaeological remains. Historically the valley has been mined for salt and the small lakes, ponds and springs along the valley floor have a brackish signature. A preliminary report on the site’s ostracode fauna suggested that the site’s water was not always saline. This study analyzed modern and Quaternary ostracodes to understand the valley’s hydrologic and chemical evolution. Sediments contained primarily freshwater species, including the environmentally sensitive Candona crogmaniana. The presence of Pelocypris tuberculatum and a new Fabaeformiscandona species throughout a vertical section spanning the latest Pleistocene …

A Comprehensive Study Of The Short-Term Variability Of The Migrating Diurnal Tide In The Mesosphere And Lower Thermosphere., Lokupatabendige Ashan Shivantha Vitharana

Electronic Theses and Dissertations

Our ability to understand and predict space weather has become vital due to its significant societal impacts on communication, transportation, and national defense. One of the most exciting discoveries in the last decade has been the realization that tropospheric weather can strongly influence space weather. It is now recognized that the atmospheric waves (gravity waves, atmospheric tides, and planetary waves) play a key role in coupling the lower and upper atmosphere. The focus of this dissertation is to study atmospheric tides. While the climatology of tides has been extensively studied, little is known about the tidal weather (tidal variability

Extratropical Cyclones And Associated Climate Impacts In The Northeastern United States, Julia Simonson

Electronic Theses and Dissertations

There is growing concern that some aspects of severe weather could become more frequent and extreme across the northeastern United States (USNE) as a consequence of climate change. Extratropical cyclones and frontal systems are a common factor in a variety of severe weather hazards in the region. This dissertation examines three types of meteorological events impacting the USNE – ice storms, heavy rainfall, and high-wind events. The first research topic utilizes the Weather Research and Forecasting (WRF) model in a case study of the December 2013 New England ice storm. In this analysis, a series of tests are conducted to …

Studies Of Quaternary Depositional Systems Of The Coastal Plain And Inner Continental Shelf Along The Georgia Bight: South Carolina And Georgia, U.S.A., Joshua H. Long

Electronic Theses and Dissertations

The Quaternary stratigraphy of the continental shelf offshore of South Carolina consists of stratigraphic units deposited in coastal plain, shallow marine, and shelfal environments bound by composite erosional surfaces that developed in response to numerous glacioeustatic cycles and overprinted by regional uplift. These units are commonly distributed laterally rather than stacked vertically, a function of the long-term, low shelf gradient and the resulting lack of accommodation. This study integrates high-resolution geological and geophysical data sets acquired offshore and onshore with existing data onshore into a comprehensive conceptual model describing the Quaternary geologic evolution of the coastal plain and continental shelf …

Chemostratigraphy Of Carbonate Gravity Flows Of The Wolfcamp Formation In Crockett County, Midland Basin, Texas, Alex Blizzard, Julie Bloxson

Electronic Theses and Dissertations

Sediment gravity flows into deep-water environments are important stratigraphic traps in lithologically diverse reservoirs generating multiple plays for hydrocarbon exploration. These highly heterogeneous deposits can be studied by utilizing chemostratigraphy and higher-order sequence stratigraphy; being an accurate method for reservoir characterization. Studying these gravity flows along a carbonate platform’s slope can further expand an understanding of the stratigraphy that is filling adjacent basins. The application of elemental analyses can support in identifying mineralogy that impact reservoir quality, especially when conventional testing cannot be applied.

This study utilizes five cores containing the Wolfcamp Formation from the southeastern slope of the Central …

Simulated Mine Land Reclamation Impact On Biomass Partitioning And Nutrient Contents In Loblolly Pine, Osarumen Egharevba

Electronic Theses and Dissertations

Forest productivity on reclaimed mine land is hindered by soil compaction. Different techniques have been used to alleviate the effect of compaction to various degrees of success. The Forestry Reclamation Approach (FRA) was developed in the Appalachians and has been used to improve forest productivity on reclaimed mines in this region. The FRA provides a step by step method designed to reduce compaction, control erosion, provide land stabilization and accelerate forest succession. This method had not been evaluated in the Gulf Coastal Plain, where the pan scraper reclamation method is commonly used. However, using pan scrapers increases mine soil compaction …

A Numerical Survey Of Multi-Planet Systems’ Inclination Excitation And Survival Under The Influence Of An Oblate, Tilted Star, Kathleen M T Schultz

Electronic Theses and Dissertations

Among the many exciting and thought-provoking discoveries facilitated by the Kepler telescope, one of the most puzzling is the very large proportion of systems with only a single transiting planet in them, relative to the number of systems with multiple transiting planets. Given that most of these multis are close together and have low mutual inclinations, and that planetary systems tend to form in such a configuration, the next logical step is to guess that at least some of the singles are part of multi-planet systems with large mutual inclinations between planets, excited by some other object’s gravitational perturbations. A …

A Method To Reclaim Multifractal Statistics From Saturated Images, Jeremy Juybari

Electronic Theses and Dissertations

The CompuMAINE lab has developed a patented computational cancer detection method utilizing the 2D Wavelet Transform Modulus Maxima (WTMM) method to help predict disrupted, tumor-associated breast tissue from mammography. The lab has a database of mammograms in which some of the image subregions contain artefacts which are excluded from the analysis, image saturation is one such artefact. To maximize statistical power in our clinical analyses, our goal is therefore to minimize the rejection of image subregions containing artefacts. The goal of this particular project is to explore the effects of image saturation on the resulting multifractal statistics from the 2D …

Using Tandem Mass Spectrometry And Irmpd Spectroscopy To Determine The Intrinsic Reactions Of Uranyl-Containing Ions, Irena Tatosian

Electronic Theses and Dissertations

Developing a comprehensive understanding of the intrinsic reactivity of uranium-containing species remains an important goal, as it may influence future developments in areas ranging from new approaches to nuclear fuel processing to studies of the migration and fate of the element in the environment. At a more fundamental level, such studies contribute to the understanding of the role that 5-f electrons may play in chemical bonding, the so called “f-electron challenge”. Electrospray ionization (ESI) is an effective way to generate gas-phase complexes containing uranium and uranyl ions for subsequent studies of intrinsic structure and reactivity. Studies in the gas-phase are …

N-Terminal Imine Derivatization For Enhanced De Novo Peptide Sequencing: A Study Of The Fragmentation Pattern Generated From Cid Of Peptide-Imines, Khiry L. Patterson

Electronic Theses and Dissertations

In this work, the fragmentation pattern derived from model peptides derivatized to create N-terminal imines (Schiff bases) were evaluated. Collision-induced dissociation of the protonated peptide-imines ([M+H]⁺) generally produced complete series of the sequence informative a_n and b_n ions, now undoubtedly characteristic of the peptide ion species. A novel product ion was also observed, denoted the y^ǂ ion, determined by IRMPD spectroscopy and density functional theory to be generated from the elimination of the N-terminal amino acid residue despite the N-terminal modification. It was concluded the pathway involved a nucleophilic attack by an amide nitrogen and …

Calculating Infinite Series Using Parseval's Identity, James R. Poulin

Electronic Theses and Dissertations

Parseval's identity is an equality from Fourier analysis that relates an infinite series over the integers to an integral over an interval, which can be used to evaluate the exact value of some classes of infinite series. We compute the exact value of the Riemann zeta function at the positive even integers using the identity, and then we use it to compute the exact value of an infinite series whose summand is a rational function summable over the integers.

Assessing The Factors That Alter Ecological Responses Of Cold, Oligotrophic Lakes To Nutrient Subsidies, Benjamin Burpee

Electronic Theses and Dissertations

Arctic and alpine areas experience rapid environmental changes that are altering nutrient delivery to lakes. I review the current state of lake ecosystem subsidization research and summarize Arctic and alpine lake subsidies, their ecological importance, and ways they are changing. I identify current knowledge gaps in Arctic and alpine lake subsidization research and highlight the importance of Arctic and alpine lakes for ecosystem subsidy research. Meltwater from the Greenland Ice Sheet (GrIS) exports sediment and nutrients to lakes, but the ecological effects of this subsidy remain unclear. To assess the effects, four glacially fed (GF) lakes that receive GrIS meltwater …

First-Year Computer Science Students: Pathways And Perceptions In Introductory Computer Science Courses, Christina A. Leblanc

Electronic Theses and Dissertations

This study examined student perceptions and experiences of an introductory Computer Science course at the University of Maine; COS 125: Introduction to Problem Solving Using Computer Programs. It also explored the pathways that students pursue after taking COS 125, depending on their success in the course, and their motivation to persist. Through characterizing student populations and their performance in their first semester in the Computer Science program, they can be placed into one of three categories that explain their path; a “continuer” (passed COS 125 and decided to stay in the major), a “persister” (did not pass COS 125 and …

A Groundwater Flow Model To Aid In Water Resource Management For The Carraipia Basin In The Coastal Semi-Arid Region Of La Guajira State (Colombia), Efren D. Gomez Arevalo

Electronic Theses and Dissertations

About 160,000 inhabitants live in the 1,600 square kilometers Carraipia River Basin located in northeastern Colombia and northwestern Venezuela. Historically, water has been supplied to the inhabitants in this arid coastal region by shallow dug wells. Water supplied by these wells is frequently of poor quality due to high concentrations of total dissolved solids (TDS). Recently, due to the increasing demand for water, numerous deep wells have been drilled in the region to supply water to rural and urban areas from deep aquifers. Colombian agencies seek more quantitative information on groundwater resources, driven by increasingly severe water shortages over the …

Phenolic Phytochemicals And Their Antioxidant Activities In Maine-Grown Asian, American-Hybrid, And European Plums, Hye Weon Hwang

Electronic Theses and Dissertations

Plum fruits of 16 plum cultivars derived from three species, Asian, American-hybrid, and European plums, and one cultivar of an interspecific hybrid between Asian plum and apricot were investigated to identify and quantify two major groups of phenolic phytochemicals, anthocyanins and hydroxycinnamic acids (HCAs) by HPLC–DAD/MS. The plums were harvested from 2014 to 2017. Some cultivars were analyzed through consecutive years to determine year-to-year differences and to evaluate the maturity impacts on the concentration of anthocyanins and HCAs from the partial-ripe stage and tree-ripe stage. Anthocyanins were present in red−purple colored plums, but their profiles varied among cultivars and species. …

Examining The Northern Shrimp Fishery In A Changing Gulf Of Maine, Ashley N. Charleson

Electronic Theses and Dissertations

Northern Shrimp (Pandalus borealis) once supported a key commercial fishery in the State of Maine. Since its closure in 2013, the stock has remained in a particularly vulnerable state following recruitment failure, overfishing, and rising water temperatures. Furthermore, without this source of supplemental income, local fishermen have also experienced financial stress following unstable fishing conditions in other fisheries. The collective goal of this research project was to assess factors impacting the feasibility of reopening and maintaining this vulnerable winter fishery. These goals are addressed over 4 chapters. Chapter two offers insight regarding what is most often omitted from the regulatory …

Delineating Subsurface Karst Potential Using Electrical Resistivity In The Shell Mountain Province, Fort Hood Military Installation, Texas, Annie Robison

Electronic Theses and Dissertations

Fort Hood Military Installation is located within the Lampasas Cut Plain in Bell and Coryell counties, Texas, and is characterized by exposures of Lower Cretaceous Trinity and Fredericksburg Group carbonates. The Shell Mountain Province is an elevated plateau located in western Fort Hood utilized by the military for heavy mechanical (troop and wheeled) maneuver training and hosts significant surficial and subsurface karst. Ongoing karst inventories in western Fort Hood conducted by range managers have documented over 100 individual karst features. Recent studies utilizing LiDAR and remote sensing techniques delineated karst potential in this area and identified over 13,909 discrete depressions. …