Physical Sciences and Mathematics Commons^™

Tree Canopy Effects On Roof-Harvested Rainwater In East Texas, Kimberly Gamez

Electronic Theses and Dissertations

Nine experimental metal roofs with rainwater harvesting systems were constructed and water quality parameters were measured in 2016-2017 in order to evaluate the effects of arboreal overhang on roof-harvested rainwater quality collected in East Texas. Three treatments were evaluated: Rainwater collected from roofs without any overhanging tree vegetation, rainwater collected from roofs under predominantly Southern yellow pine tree cover, and rainwater collected from roofs under predominantly hardwood tree cover. Rainwater was collected from these roofs for one year. The effects of canopy cover on water quality parameters, comparison to drinking water standards, first-flush efficiency, and seasonal effects were evaluated.

Significant …

Early Life History Of Tarpon (Megalops Atlanticus) In South Carolina Estuaries: Assessment Of Juvenile Recruitment And Validity Of Aging And Back-Calculation Methods, Garrett M. Elmo

Electronic Theses and Dissertations

No abstract provided.

Inter-Annual To Inter-Decadal Spatiotemporal Effects Of Storm And Nourishment Events In North Myrtle Beach, South Carolina, Christina Mary Boyce

Electronic Theses and Dissertations

No abstract provided.

Parametric Model Development For Heterogeneous Atmospheric Conditions, Daniel Paul Greenway

Electronic Theses and Dissertations

No abstract provided.

Delineating Of The Utica Shale/Point Pleasant Formation Play System To Determine Influence Of The Precambrian Basement In Northeastern Ohio, Jarrod R. Bridges

Electronic Theses and Dissertations

The Utica Shale/Point Pleasant Formation system has recently become a highly developed unconventional target for oil and natural gas production, leading to an increased desire for knowledge of the controls on deposition of this system. Precambrian basement features have long been known to affect deposition of older strata near these features across Ohio, but the effects of far field tectonics is not fully agreed upon. Precambrian faults and lineaments are known to exist and have been mapped, but are thought to have ceased their influence on deposition by the time of the Knox unconformity during the Cambrian. In the case …

Alkylation Of Benzene On Immobilized Phosphotungstic Acid, Kofi Kankam

Electronic Theses and Dissertations

Linear alkylbenzenes (LAB) are key intermediates in the synthesis of linear alkylbenzene sulfonate surfactants that are used in the manufacture of detergents. Production of LAB with traditional Lewis acids as catalysts, such as hydrofluoric acid, results in the formation of large amounts of toxic wastes and corrosion of industrial equipment. Phosphotungstic acid (PTA) has gained much attention in recent years as a solid catalyst for various alkylation reactions. This research work aims to develop a novel material based on PTA-containing silica gel, which can effectively catalyze LAB synthesis. Sol-gel synthesis of silica gel in the presence of PTA and tetraethyl …

Aerial Mineral And Organic Particulate Deposition In East Texas, Sarah Caton, Sarah Caton

Electronic Theses and Dissertations

This study determined the monthly amount, particle size distribution, and chemical composition of particulate deposition in East Texas over a one-year period. It also recognized the seasonal patterns of this deposition as well as its primary origins as either mineral or organic particulate deposition.

The study recorded the monthly mass of deposition, particle size distribution, and the chemical makeup of deposition throughout a period of twelve months at seven sampling locations. SEM-EDS technology was used in conjunction with PCI programming to measure the sizes of depositional particles throughout this time period and identify their chemical composition.

The total yearly deposition …

Photoelectrical And Photoelectrochemical Characterization Of The Materials Used In Dye-Sensitized And Perovskite Solar Cells., Pom Lal Kharel

Electronic Theses and Dissertations

Solar energy is one of the most important alternative renewable energy sources to fulfill the increasing demand of energy in the world. Third-generation solar cells like dye-sensitized solar cells, perovskite solar cells, quantum dot solar cells, and organic solar cells are extensively studied to increase their photoconversion efficiency, and ultimately for their large-scale implementation. A dye-sensitized solar cell consists of a photoanode of a mesoporous film of titania sensitized with dye sandwiched with a counter electrode, which is usually a platinum-coated transparent conducting oxide, and a redox couple injected between the photoanode and counter electrode. Doping titania with rare-earth metal …

Design, Synthesis And Application Of Janus Gold Nanoprisms For Directed Self-Assembly., Md. Emtias Chowdhury

Electronic Theses and Dissertations

Colloidal Janus particles that possess more than one type of surface chemistry or functionalities have drawn significant interest due to their enormous potential in bottom-up synthetic strategies for complex superstructures. Moreover, the property of molecular recognition, tunability, and predictability of the DNA-mediated interactions enable a high degree of control over particle assembly to generate highly ordered nanostructures with emergent applications. In this dissertation, we present our works on the synthesis of Janus particles from anisotropic gold nanoprisms, and DNA- mediated assembly of nanoprisms and polymer beads in four major areas: 1) Facet selective asymmetric functionalization of gold nanoprisms for Janus …

Development And Applications Of Condensed Phase Cavity Ring-Down Spectroscopy For Studies Of Electrochemical And Interfacial., Shadi Ahmad Alnaanah

Electronic Theses and Dissertations

This dissertation reports the development of ultra-sensitive platforms based on the laser cavity ring-down spectroscopic (CRDS) technique to enable optical and spectroelectrochemical investigations in the condensed phase of matter at challenging scenarios. Firstly, an electrically-active solid/liquid interface for the evanescent-wave cavity ring-down spectroscopy (EW-CRDS) was developed to specroelectrochemically investigate redox events. By coating the interface of total internal reflection of the EW-CRDS platform with a high quality optically transparent and electrically conductive indium tin oxide thin film (ITO), we demonstrated that sufficiently long ring-down times can be achieved to allow for spectroelectrochemical investigations of redox species at solid/liquid interfaces at …

The Utilization Of Metal-Ligand Cooperativity For Electrocatalytic Reduction And Catalytic Hydration., Steven Cronin

Electronic Theses and Dissertations

Small molecules are building blocks for developing larger materials. These small molecules could be extremely small, such as hydrogen, or larger such as a nitrile, but their impact on the global economy is massive. This dissertation describes a catalyst for three reactions involving small molecules; 1) the hydrogen evolution reaction, 2) the carbon dioxide reduction reaction, 3) nitrile hydration. The catalyst Zn(DMTH) (DMTH = diacetyl-2-(4-methyl-3-thiosemicarbazonate)-3-(2-pyridinehydrazonato)) use “metal-ligand cooperativity” between the Lewis acid Zn(II) metal ion and an uncoordinated Lewis base nitrogen in the ligand framework to activate substrates. The complex has been analyzed via NMR, UV/Vis, single crystal X-ray crystallography, …

Exploring Information For Quantum Machine Learning Models, Michael Telahun

Electronic Theses and Dissertations

Quantum computing performs calculations by using physical phenomena and quantum mechanics principles to solve problems. This form of computation theoretically has been shown to provide speed ups to some problems of modern-day processing. With much anticipation the utilization of quantum phenomena in the field of Machine Learning has become apparent. The work here develops models from two software frameworks: TensorFlow Quantum (TFQ) and PennyLane for machine learning purposes. Both developed models utilize an information encoding technique amplitude encoding for preparation of states in a quantum learning model. This thesis explores both the capacity for amplitude encoding to provide enriched state …

Modified-Half-Normal Distribution And Different Methods To Estimate Average Treatment Effect., Jingchao Sun

Electronic Theses and Dissertations

This dissertation consists of three projects related to Modified-Half-Normal distribution and causal inference. In my first project, a new distribution called Modified-Half-Normal distribution was introduced. I explored a few of its distributional properties, the procedures for generating random samples based on Bayesian approaches, and the parameter estimation based on the method of moments. The second project deals with the problem of selection bias of average treatment effect (ATE) if we use the observational data. I combined the propensity score based inverse probability of treatment weighting (IPTW) method and the directed acyclic graph (DAG) to solve this problem. The third project …

Aspects Of Causal Inference., John A. Craycroft

Electronic Theses and Dissertations

Observational studies differ from experimental studies in that assignment of subjects to treatments is not randomized but rather occurs due to natural mechanisms, which are usually hidden from researchers. Yet objectives of the two studies are frequently the same: identify the causal – rather than merely associational – relationship between some treatment or exposure and an outcome. The statistical issues that arise in properly analyzing observational data for this goal are numerous and fascinating, and these issues are encompassed in the domain of causal inference. The research presented in this dissertation explores several distinct aspects of causal inference. This dissertation …

Computational Behavioral Analytics: Estimating Psychological Traits In Foreign Languages., Kristopher Wayne Reese

Electronic Theses and Dissertations

The rise of technology proliferating into the workplace has increased the threat of loss of intellectual property, classified, and proprietary information for companies, governments, and academics. This can cause economic damage to the creators of new IP, companies, and whole economies. This technology proliferation has also assisted terror groups and lone wolf actors in pushing their message to a larger audience or finding similar tribal groups that share common, sometimes flawed, beliefs across various social media platforms. These types of challenges have created numerous studies in psycholinguistics, as well as commercial tools, that look to assist in identifying potential threats …

Statistical Approaches Of Gene Set Analysis With Quantitative Trait Loci For High-Throughput Genomic Studies., Samarendra Das

Electronic Theses and Dissertations

Recently, gene set analysis has become the first choice for gaining insights into the underlying complex biology of diseases through high-throughput genomic studies, such as Microarrays, bulk RNA-Sequencing, single cell RNA-Sequencing, etc. It also reduces the complexity of statistical analysis and enhances the explanatory power of the obtained results. Further, the statistical structure and steps common to these approaches have not yet been comprehensively discussed, which limits their utility. Hence, a comprehensive overview of the available gene set analysis approaches used for different high-throughput genomic studies is provided. The analysis of gene sets is usually carried out based on …

Stratigraphy, Petrology, Diagenesis, Paleontology, And Depositional Environments Of The Harrisburg Member Of The Kaibab Formation In Northern Arizona And Southern Utah, Zachery T. Case

Electronic Theses and Dissertations

The Kaibab Formation has two members, the Fossil Mountain Member below and the Harrisburg Member above. They were deposited in shallow-marine shelf to restricted coastal settings. Stratigraphically above are the Rock Canyon Conglomerate and the Moenkopi Formation; consisting of the Timpoweap and Lower Red members; which are the only members present in the study area. The Rock Canyon Conglomerate was deposited in depressions and as a regolith. The Timpoweap and Lower Red members were deposited in shallow marine to tidal environments.

Nine stratigraphic units were identified in the Harrisburg Member. Units one, two, three, five, six, seven, and nine are …

The Persistence Of Acid Mine Drainage At An East Texas Coal Mine, Sarah Zagurski

Electronic Theses and Dissertations

The objective of this study was to estimate the time it will take for acid forming materials (pyrite) to be weathered to a state of equilibrium and thus cease to produce acid in ground and surface waters within Oak Hill Mine. This was accomplished using an ex-situ kinetic leaching study incorporating a humidity cell in a controlled laboratory setting. Leaching was conducted on soil cores obtained from the vadose zone at Oak Hill Mine and the humidity cell was used to accelerate oxidation of the pyrite within the cores.

An in-situ field study was also conducted that monitored groundwater conditions …

A Synthesis Program: Reducing Uncertainties Of The Terrestrial Biosphere Carbon Cycle At Various Spatio Temporal Scales, Xinyuan Wei

Electronic Theses and Dissertations

The terrestrial biosphere plays an important role in the global carbon cycle, and disturbance fire and climate extreme drought have strong direct and indirect impacts on the carbon fluxes. In addition, the lateral dissolved organic carbon (DOC) flux from soils to inland waters represents an important component of the terrestrial biosphere carbon cycle.

Fires play an important role in the terrestrial biosphere carbon cycle, not only through direct carbon release but also contributing to a potential long-term storage as pyrogenic carbon (PyC). PyC is formed through fires, and because it may resist further biological and chemical degradation, is more stable …

Airborne Hyperspectral Data Application In Stress Detection Of Blueberry Fields And Ash Trees, Catherine Chan

Electronic Theses and Dissertations

Water management and irrigation practices are persistent challenges for many agricultural systems. Changing seasonal and weather patterns impose a greater need for understanding crop deficiencies and excesses (e.g. water, sunlight, nutrients) for optimal growth while allocating proper resources for prompt response. The wild blueberry industry is at heightened susceptibility due to its unique growing conditions and uncultivated nature. Early detection of stress in agricultural fields can prompt management responses to mitigate detrimental conditions including drought and disease. Remote sensing has provided timely and reliable information covering large spatial extents, while novel applications in hyperspectral data and imaging spectroscopy have shown …

Variations In The Southern Hemisphere Westerlies Over The Last 23,000 Years From Lake Records In The Falkland Islands, Meghan M. Spoth

Electronic Theses and Dissertations

The Southern Hemisphere Westerlies (SHW) are an important driver of climate in the mid-latitudes of the Southern Hemisphere. Abrupt latitudinal migration of this coupled atmospheric-oceanic system is thought to be linked to the onset of the Termination at the end of the last ice age and to subsequent climatic variation through the late-glacial period and Holocene. However, the timing and spatial extent of these shifts, as well as variations in wind intensity, are poorly constrained, hindering our understanding of abrupt climate change in the Southern Hemisphere. In addition, future changes in the position and intensity of the SHW are a …

Biophysical And Stable Isotopic Profiles Of The Salmon Louse Lepeophtheirus Salmonis (Krøyer, 1837), Emma Taccardi

Electronic Theses and Dissertations

The salmon louse Lepeophtheirus salmonis is a parasitic copepod that infects wild and farmed salmonids throughout the northern hemisphere. L. salmonis represents the largest economic hurdle of the Atlantic salmon (Salmo salar) industry, with an estimated annual cost of nearly $1 billion globally due to production losses and anti-parasitic control measures. Salmon farming in Maine has existed for decades and is a critical economic driver, yet the region is underrepresented in global sea lice research. The aim of this work was to examine parasites in the context of animal trophic transfer and characterize physiological condition by quantifying the …

Bicknell's Thrush Habitat Use On Commercial Forests In Maine, Usa, Kaitlyn Wilson

Electronic Theses and Dissertations

Forest reliant species may be significantly impacted by forest management practices. Understanding these impacts, and whether they are positive or negative, requires a species- specific understanding of habitat use. Bicknell’s thrush (Catharus bicknelli) is a range-restricted habitat specialist occurring in balsam fir (Abies balsamea) dominated montane forests that have been recently disturbed and are undergoing successional growth. While research investigating this species’ habitat use has been conducted throughout much of its breeding range, knowledge of Bicknell’s thrush habitat use in Maine is lacking. Greater understanding of habitat use in Maine would improve the ability of forest managers to promote conservation …

Investigations On The Helix-Coil Transition Inside Nanotubes, Dylan Suvlu

Electronic Theses and Dissertations

Proteins are the workhorses of biology and are essential to life as we know it. A protein’s function in the cell is intimately related to its three-dimensional structure. Thus, understanding structure formation in proteins has been an essential goal in molecular biology. Experiments indicate proteins start acquiring structure inside the ribosome—the cellular manufacturing plant of proteins—and the process is particularly important for membrane proteins. Therefore, the ribosome appears to play an active role in facilitating protein structure acquisition. However, how and when the ribosome accomplishes this task remains poorly understood. To better understand this process, we conducted molecular dynamics computer …

Understanding The Magnetic Properties Of Ii-Vi Semiconductor Nanocrystals, Alex Khammang

Electronic Theses and Dissertations

Semiconductor nanocrystals (NC) are well known for their unique size tunable optical properties making them suitable candidates for devices such as light emitting diodes (LEDs), solar cells, and cellular labels. II-VI semiconductors in the bulk form behave diamagnetically, but can inherit paramagnetic (PM) or ferromagnetic (FM) properties at the nanoscale. Reports suggest that the emergence of weak PM or FM behavior in undoped NCs are attributed to the increased surface to volume ratio compared for NCs. Traditionally, these NCs only obtain magnetic properties after doping with certain transition metals, such as Co, Mn, or Fe. Many mechanisms have been proposed …

Sulfur And Trace Metal Cycling At Convergent Margins, Jesse B. Walters

Electronic Theses and Dissertations

Subduction zones are the site of long-term chemical exchange between Earth’s surface and interior geochemical reservoirs. Subducting slabs are progressively depleted in volatiles and other mobile elements through dehydration and melting reactions. These elements are then introduced to the mantle wedge and volcanic arc. One consequence of this cycle is that volcanic arcs produce the most oxidized magmas on Earth. Sulfur, which exhibits a range in valence states from S^2- to S⁶⁺, is one of the few elements in the subducting slab capable of oxidizing the arc and mantle wedge. Sulfides in the slab may also act …

Fostering Climate Change Resilience: A Socio-Ecological Forest Systems Approach, Alyssa R. Soucy

Electronic Theses and Dissertations

As climate change continues to impact socio-ecological systems, those that rely on natural resources are highly sensitive to climatic changes. Maine’s forest industry provides for the economic and social well-being of many residents and is especially vulnerable to climate change impacts. Changes in growing season length and timing, forest health threats imposed by insects and pathogens, extreme weather events, shifting forest composition, and changes in natural disturbance severity and frequency have already begun, and are projected to continue, to impact forest systems in the Northeastern U.S. While climate change presents a threat to forest systems, opportunities also arise due to …

Isolation, Structure Elucidation, And Synthesis Of Natural Products From Marine Cyanobacteria, Keren Solomon

Electronic Theses and Dissertations

This thesis describes the isolation, structure elucidation, and synthesis of natural products from marine cyanobacteria. A crude extract from a cyanobacterium collected in Curacao showed selective affinity for the dopamine D₅ receptor in a screen against a panel of CNS receptors. Due to the high similarity of the D₅ and D₁ receptor, to date there are no known ligands that differentiate them. Attempts to purify the compound responsible for this affinity led to the isolation of the known compound caylobolide A. A second extract from a cyanobacterium collected in Panama underwent bioassay-guided fractionation and yielded the novel …

20th And 21st Century Sea-Level Variability In Winyah Bay, Sc, Madison Schemery Fink

Electronic Theses and Dissertations

No abstract provided.

The Influence Of Environmental Variables On The Height Growth Of Loblolly Pine (Pinus Taeda) In The Western Gulf, Osakpamwan Edo-Iyasere

Electronic Theses and Dissertations

Understanding the effects of environmental factors on stand growth is important in optimizing forest management plans. This study investigated the effects of soil and climate factors on the height growth (site index) of loblolly pine (Pinus Taeda L.) using data collected from permanent plots established in intensively-managed plantations across East Texas and Western Louisiana. The Chapman-Richards model was selected as the base model to describe the height-age relationships and important soil and climate variables were incorporated into the models as model parameter coefficient adjustors. Our results showed that the most important factors for predicting site index were nitrogen …