Physical Sciences and Mathematics Commons^™

Ultra-Strong Long-Chain Polyamide Elastomers With Programmable Supramolecular Interactions And Oriented Crystalline Microstructures, Lingzhi Song, Tianyu Zhu, Liang Yuan, Jiangjun Zhou, Yaqiong Zhang, Zhongkai Wang, Chuanbing Tang

Faculty Publications

Polyamides are one of the most important polymers. Long-chain aliphatic polyamides could bridge the gap between traditional polyamides and polyethylenes. Here we report an approach to preparing sustainable ultra-strong elastomers from biomass-derived long-chain polyamides by thiol-ene addition copolymerization with diamide diene monomers. The pendant polar hydroxyl and non-polar butyrate groups between amides allow controlled programming of supramolecular hydrogen bonding and facile tuning of crystallization of polymer chains. The presence of thioether groups on the main chain can further induce metal–ligand coordination (cuprous-thioether). Unidirectional step-cycle tensile deformation has been applied to these polyamides and significantly enhances tensile strength to over 210 …

Partially Coherent Sources Generated From The Incoherent Sum Of Fields Containing Random-Width Bessel Functions, Milo W. Hyde Iv

Faculty Publications

Using the criterion for a genuine cross-spectral density function, we demonstrate the realization of an ??-Bessel correlated source, which has only recently been achieved using the source’s coherent-mode representation. In addition, with just a simple change, we create a whole new class of partially coherent sources that have not been realized. We simulate the generation of these sources and compare the results to theoretical predictions to validate our analysis. The partially coherent sources described herein can easily be synthesized using spatial light modulators, and the approach presented in this Letter can be used to design sources for optical trapping, optical …

A Second Galaxy Missing Dark Matter In The Ngc 1052 Group, Pieter Van Dokkum, Shany Danieli, Roberto Abraham, Charlie Conroy, Aaron Romanowsky

Faculty Publications

The ultra-diffuse galaxy NGC1052-DF2 has a very low velocity dispersion, indicating that it has little or no dark matter. Here we report the discovery of a second galaxy in this class, residing in the same group. NGC1052-DF4closely resembles NGC1052-DF2 in terms of its size, surface brightness, and morphology; has a similar distance of Dsbf = 19.9 +/- 2.8 Mpc; and also has a population of luminous globular clusters extending out to >7 kpc from the center of the galaxy. Accurate radial velocities of the diffuse galaxy light and seven of the globular clusters were obtained with the Low Resolution Imaging …

A Second Galaxy Missing Dark Matter In The Ngc 1052, Pieter Van Dokkum, Shany Danieli, Roberto Abraham, Charlie Conroy, Aaron Romanowsky

Faculty Publications

The ultra-diffuse galaxy NGC1052-DF2 has a very low velocity dispersion, indicating that it has little or no dark matter. Here we report the discovery of a second galaxy in this class, residing in the same group. NGC1052-DF4 closely resembles NGC1052-DF2 in terms of its size, surface brightness, and morphology; has a similar distance of Dsbf =  19.9 2.8 Mpc; and also has a population of luminous globular clusters extending out to 7 kpc from the center of the galaxy. Accurate radial velocities of the diffuse galaxy light and seven of the globular clusters were obtained with the Low Resolution …

Stochastic Modeling Reveals How Motor Protein And Filament Properties Affect Intermediate Filament Transport, J. C. Dallon, Cecil Leduc, Sandrine Etienne-Manneville, Stephanie Portet

Faculty Publications

Intermediate filaments are a key component of the cytoskeleton. Their trans- port along microtubules plays an essential role in the control of the shape and structural organization of cells. To identify the key parameters responsible for the control of intermediate filament transport, we generated a model of elastic filament transport by microtubule-associated dynein and kinesin. The model is also applicable to the transport of any elastically-coupled cargoes. We inves- tigate the effect of filament properties such as number of motor binding sites, length, and elasticity on motion of filaments. Additionally, we consider the ef- fect of motor properties, i.e. off …

The Knill Graph Dimension From The Minimum Clique Cover, Kassahun Betre, Evatt Salinger

Faculty Publications

In this paper we prove that the recursive (Knill) dimension of the join of two graphs has a simple formula in terms of the dimensions of the component graphs: dim(G1+G2)=1+dimG1+dimG2. We use this formula to derive an expression for the Knill dimension of a graph from its minimum clique cover. A corollary of the formula is that a graph made of the arbitrary union of complete graphs KN of the same order N will have dimension N−1. We finish by finding lower and upper bounds on the Knill dimension of a graph in terms of its clique number.

Multiplexed Paper Microfluidics For Titration And Detection Of Ingredients In Beverages, Manas Ranjan Gartia, Alisha Prasad

Faculty Publications

Food safety and access to systematic approaches for ensuring detection of food hazards is an important issue in most developing countries. With the arrival of paper-based analytical devices (mu PADs) as a promising, rapid, easy-to-use, and low-cost analytical tool, we demonstrated a simple microfluidic-based titration study for the analysis of packaged fruit juices. Similar, to the titration experiments using traditional glassware in chemistry laboratories, in this study the titration experiments were developed using paper microfluidics for the analysis of several analytes such as pH, vitamin C, sugars, and preservatives present in the packaged fruit juices. The allergen found commonly in …

Bioassay-Guided Isolation And Structure Elucidation Of Fungicidal And Herbicidal Compounds From Ambrosia Salsola (Asteraceae), Frank R. Fronczek

Faculty Publications

The discovery of potent natural and ecofriendly pesticides is one of the focuses of the agrochemical industry, and plant species are a source of many potentially active compounds. We describe the bioassay-guided isolation of antifungal and phytotoxic compounds from the ethyl acetate extract of Ambrosia salsola twigs and leaves. With this methodology, we isolated and identified twelve compounds (four chalcones, six flavonols and two pseudoguaianolide sesquiterpene lactones). Three new chalcones were elucidated as (S)-beta-Hydroxy-2,3,4,6'-tetrahydroxy-5-methoxydihydrochalcone (salsolol A), (S)-beta-Hydroxy-2',4,4',6'-tetrahydroxy-3-methoxydihydrochalcone (salsolol B), and (R)-alpha, (R)-beta-Dihydroxy-2,3,4,4,6'-pentahydroxydihydrochalcone (salsolol C) together with nine known compounds: balanochalcone, six quercetin derivatives, confertin, and neoambrosin. Chemical structures were determined …

Erratum: “The Sluggs Survey: A Catalog Of Globular Cluster Radial Velocities” (2017, Aj, 153, 114), Duncan Forbes, Adebusola Alabi, Jean Brodie, Aaron Romanowsky, Jay Strader, Caroline Foster, Christopher Usher, Lee Spitler, Sabine Bellstedt, Nicola Pastorello, Sreeja Kartha, Zach Jennings, Alexa Villaume, Asher Wasserman, Vincenzo Pota

Faculty Publications

We would like to point out to the reader that the catalog of globular cluster (GC) radial velocities (listed in Table 5) still contains some multiple entries. In such cases GCs were observed more than once and are recorded in Table 5 with a unique GC ID, along with their coordinates and radial velocity measurement. If the reader wishes to exclude, or average, multiple measurements then GCs within one spatial pixel (i.e., 0.119 arcsec) in R.A. and decl. can be identified. This would include two dozen GCs in the galaxies NGC 720, 1407, 2768, 3608, 4365, 4459, 4474, and 4697. …

Two-Pebbling And Odd-Two-Pebbling Are Not Equivalent, Charles A. Cusack, Airat Bekmetjev, Mark Powers

Faculty Publications

Let G be a connected graph. A configuration of pebbles assigns a nonnegative integer number of pebbles to each vertex of G. A move consists of removing two pebbles from one vertex and placing one pebble on an adjacent vertex. A configuration is solvable if any vertex can get at least one pebble through a sequence of moves. The pebbling number of G, denoted π(G), is the smallest integer such that any configuration of π(G) pebbles on G is solvable. A graph has the two-pebbling property if after placing more than 2π(G) -- q pebbles on G …

Structure And Magnetism Of Nifemngaxsn1-X (X=0, 0.25, 0.5, 0.75, 1.00) Heusler Compounds, Jace Waybright, Lee Halbritter, Bishnu Dahal, Hanyang Qian, Yung Huh, Pavel Lukashev, Parashu Kharel

Faculty Publications

The crystal structure and magnetic properties of NiFeMnGa_xSn_1-x (x = 0, 0.25, 0.50, 0.75 and 1.00) Heusler compounds have been investigated experimentally and theoretically. The computational results suggest that NiFeMnGa_0.75Sn_0.25 is nearly half-metallic with a spin polarization P of 87%. The bulk samples prepared using arc-melting and annealing exhibit a high degree of Y-type order. All the investigated samples show ferromagnetic spin order with the Curie temperatures ranging from 284 K for NiFeMnGa to 408 K for NiFeMnSn. The intermediate composition NiFeMnGa_0.75Sn_0.25, which is predicted to be nearly half metallic, …

36% Reduction In Fuel Resupply Using A Hybrid Generator & Battery System For An Austere Location, David J. Chester [*], Torrey J. Wagner, Douglas S. Dudis

Faculty Publications

The DOD energy policy is to increase energy security resiliency, and mitigate costs in the use and management of energy^[1] Forward operating bases (FOBs) are remote, austere base camps that support an operationally defined mission with a limited or no ability to draw from an energy grid and have historically relied on diesel-powered generators for the primary production of energy.^[2] Generators are sized to meet a theoretical peak demand, but steady state loads are far below this peak, resulting in under-loaded generators.^[3] Under-loaded diesel generators decrease efficiency and increase the need for maintenance, affecting the lifespan of …

Development And Validation Of A New Method To Diagnose Apical Hypertrophic Cardiomyopathy By Gated Single-Photon Emission Computed Tomography Myocardial Perfusion Imaging, Yanli Zhou, Dianfu Li, Haipeng Tang, Yi Xu, Cheng Wang, Zhixin Jiang, Fang Xu, Zhongqiang Zhao, Chunxiang Li, Shaojie Tang, Lijun Tang, Weihua Zhou

Faculty Publications

Aim The aim of this study is to develop and validate a new method to diagnose apical hypertrophic cardiomyopathy (AHCM) by the integral quantitative analysis of myocardial perfusion and wall thickening from gated single-photon emission computed tomography (SPECT) myocardial perfusion imaging (MPI).

Patients and methods Twenty-two consecutive patients, who showed T wave inversion of at least 3 mm in precordial leads and sinus rhythm in ECG, were enrolled. All the patients underwent cardiac magnetic resonance (CMR), gated rest SPECT MPI and echocardiography. According to CMR diagnostic results, 13 patients were categorized as in the AHCM group and the remaining nine …

Shaping The Far-Zone Intensity, Degree Of Polarization, Angle Of Polarization, And Ellipticity Angle Using Vector Schell-Model Sources, Milo W. Hyde Iv

Faculty Publications

This paper presents a method to control both the shape and polarization of a beam in the far field using a vector Schell-model source. Given a desired far-zone beam shape and polarization, and applying Fourier and statistical optics theory, we derive the requisite second-order moments of said source, discuss what aspects of the far-zone beam can be controlled, and develop a step-by-step procedure for synthesizing the required random vector field instances. We validate this approach with Monte-Carlo wave-optics simulations. The results are found to be in very good agreement with the desired far-zone beam characteristics. The beam-shaping technique developed in …

A Theoretical Model Of Underground Dipole Antennas For Communications In Internet Of Underground Things, Abdul Salam, Mehmet C. Vuran, Xin Dong, Christos Argyropoulos, Suat Irmak

Faculty Publications

The realization of Internet of Underground Things (IOUT) relies on the establishment of reliable communication links, where the antenna becomes a major design component due to the significant impacts of soil. In this paper, a theoretical model is developed to capture the impacts of change of soil moisture on the return loss, resonant frequency, and bandwidth of a buried dipole antenna. Experiments are conducted in silty clay loam, sandy, and silt loam soil, to characterize the effects of soil, in an indoor testbed and field testbeds. It is shown that at subsurface burial depths (0.1-0.4m), change in soil moisture impacts …

Observation Of The Decay D0 → K− Π + E + E −, J.P. Lees, P. Poireau, V. Tisserand, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu. G. Kolomensky, M. Fritsch, H. Koch, T. Schroeder, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, V. B. Golubev, Milind Purohit, Et. Al.

Faculty Publications

We report the observation of the rare charm decay D⁰ → K−πþeþe−, based on 468 fb−1 of eþe− annihilation data collected at or close to the center-of-mass energy of the ϒð4SÞ resonance with the BABAR detector at the SLAC National Accelerator Laboratory. We find the branching fraction in the invariant mass range 0.675 < m(e⁺e⁻) < 0.875 GeV=c² of the electron-positron pair to be B(D⁰ → K−π⁺e⁺e⁻) = (4.0 ± 0.5 ± 0.2 ± 0.1) × 10⁻⁶, where the first uncertainty is statistical, the second …

Search For A Stable Six-Quark State At Babar, J. P. Lees, V. Poireau, V. Tisserand, E. Grauges, A. Palano, G. Eigen, D. N. Brown, Yu G. Kolomensky, M. Fritsch, H. Koch, T. Schroeder, C. Hearty, T. S. Mattison, J. A. Mckenna, R. Y. So, V. E. Blinov, A. R. Buzykaev, V. P. Druzhinin, V. B. Golubev, Milind Purohit

Faculty Publications

Recent investigations have suggested that the six-quark combination uuddss could be a deeply bound state (S) that has eluded detection so far, and a potential dark matter candidate. We report the first search for a stable, doubly strange six-quark state in ϒ → SΛ¯ Λ¯ decays based on a sample of 90 × 10⁶ϒ(2S) and 110 × 10⁶ϒ(3S) decays collected by the BABAR experiment. No signal is observed, and 90% confidence level limits on the combined ϒ(2S; 3S) → SΛ¯ Λ¯ branching fraction in the range (1.2–1.4) × 10⁻⁷ are derived for m …

Soil Macroinvertebrate Presence Alters Microbial Community Composition And Activity In The Rhizosphere, Natalie Bray, Jenny Kao-Kniffin, Serita D. Frey, Timothy Fahey, Kyle Wickings

Faculty Publications

Soil Macroinvertebrate Presence Alters Microbial Community Composition and Activity in the Rhizosphere

Large Fatty Acid-Derived Aβ42 Oligomers Form Ring-Like Assemblies, Wenhui Xu, Dexter N. Dean, Kelli A. Stockmal, Sarah E. Morgan, Ulrich H.E. Hansmann, Vijayaraghavan Rangachari

Faculty Publications

As the primary toxic species in the etiology of Alzheimer disease (AD) are low molecular weight oligomers of Aβ, it is crucial to understand the structure of Aβ oligomers for gaining molecular insights into AD pathology. We have earlier demonstrated that in the presence of fatty acids, Aβ42 peptides assemble as 12-24mer oligomers. These Large Fatty Acid-derived Oligomers (LFAOs) exist predominantly as 12mers at low and as 24mers at high concentrations. The 12mers are more neurotoxic than the 24mers and undergo self-replication, while the latter propagate to morphologically distinct fibrils with succinct pathological consequences. In order to glean into their …

Realization Of A Type-Ii Nodal-Line Semimetal In Mg3bi2, Weiwei Xie

Faculty Publications

Nodal-line semimetals (NLSs) represent a new type of topological semimetallic phase beyond Weyl and Dirac semimetals in the sense that they host closed loops or open curves of band degeneracies in the Brillouin zone. Parallel to the classification of type-I and type-II Weyl semimetals, there are two types of NLSs. The type-I NLS phase has been proposed and realized in many compounds, whereas the exotic type-II NLS phase that strongly violates Lorentz symmetry has remained elusive. First-principles calculations show that Mg3Bi2 is a material candidate for the type-II NLS. The band crossing is close to the Fermi level and exhibits …

Toxoplasma Gondii Igg Associations With Sleepwake Problems, Sleep Duration And Timing, Celine C. Corona, Ma Zhang, Abhishek Wadhawan, Melanie L. Daue, Maureen W. Groer, Aline Dagang, Christopher A. Lowry, Kathleen A. Ryan, Andrew J. Hoisington, John W. Stiller, Dietmar Fuchs, Braxton D. Mitchell, Teodor T. Postolache

Faculty Publications

Background: Evidence links Toxoplasma gondii (T. gondii), a neurotropic parasite, with schizophrenia, mood disorders and suicidal behavior, all of which are associated and exacerbated by disrupted sleep. Moreover, low-grade immune activation and dopaminergic overstimulation, which are consequences of T. gondii infection, could alter sleep patterns and duration. Methods: Sleep data on 833 Amish participants [mean age (SD) = 44.28 (16.99) years; 59.06% women] were obtained via self-reported questionnaires that assessed sleep problems, duration and timing. T. gondii IgG was measured with ELISA. Data were analyzed using multivariable logistic regressions and linear mixed models, with adjustment for age, sex and family …

Near Earth Space Object Detection Using Parallax As Multi-Hypothesis Test Criterion, Joseph C. Tompkins, Stephen C. Cain, David J. Becker

Faculty Publications

The US Strategic Command (USSTRATCOM) operated Space Surveillance Network (SSN) is tasked with Space Situational Awareness (SSA) for the U.S. military. This system is made up of Electro-Optic sensors, such as the Ground-based Electro-Optical Deep Space Surveillance (GEODSS) and RADAR based sensors, such as the Space Fence Gaps. They remain in the tracking of Resident Space Objects (RSO’s) in Geosynchronous Orbits (GEO), due to limitations of SST and GEODSS system implementation. This research explores a reliable, ground-based technique used to quickly determine an RSO’s altitude from a single or limited set of observations. Implementation of such sensors into the SSN …

Experimental Study: Underwater Propagation Of Super-Gaussian And Multi-Gaussian Schell-Model Partially Coherent Beams With Varying Degrees Of Spatial Coherence, Svetlana Avramov-Zamurovic, Charles L. Nelson, Milo W. Hyde Iv

Faculty Publications

We report on experiments where super-Gaussian and flat-top, multi-Gaussian Schell-model spatially partially coherent beams, with varying degrees of spatial coherence, were propagated underwater. Two scenarios were explored—calm and mechanically agitated water. The main objective of our study was the experimental comparison of the scintillation statistics. For a similar degree of coherence widths, the results show a potentially improved performance of scintillation index for the multi-Gaussian Schell-model beams as compared to the super-Gaussian beams. It should be noted that the presented results pertain only to the given experimental scenarios and further investigation is necessary to determine the scope of the findings.

Substrate-Dependent Photoconductivity Dynamics In A High-Efficiency Hybrid Perovskite Alloy, Ali Moeed Tirmzi, Jeffrey A. Christians, Ryan P. Dwyer, David T. Moore, John A. Marohn

Faculty Publications

Films of (FA_0.79MA_0.16Cs_0.05)_0.97Pb(I_0.84Br_0.16)_2.97 were grown over TiO₂, SnO₂, indium tin oxide (ITO), and NiO. Film conductivity was interrogated by measuring the in-phase and out-of-phase forces acting between the film and a charged microcantilever. We followed the films’ conductivity versus time, frequency, light intensity, and temperature (233−312 K). Perovskite conductivity was high and light-independent over ITO and NiO. Over TiO₂ and SnO₂, the conductivity was low in the dark,increased with light intensity, and persisted for 10’s of seconds after the light …

Deep Sea Biofilms, Historic Shipwreck Preservation And The Deepwater Horizon Spill, Rachel L. Mugge, Melissa L. Brock, Jennifer L. Salerno, Melanie Damour, Robert A. Church, Jason Lee, Leila J. Hamdan

Faculty Publications

Exposure to oil from the Deepwater Horizon spill may have lasting impacts on preservation of historic shipwrecks in the Gulf of Mexico. Submerged steel structures, including shipwrecks, serve as artificial reefs and become hotspots of biodiversity in the deep-sea. Marine biofilms on submerged structures support settlement of micro- and macrobiota and may enhance and protect against corrosion. Disruptions in the local environment, including oil spills, may impact the role that biofilms play in reef preservation. To determine how the Deepwater Horizon spill potentially impacted shipwreck biofilms and the functional roles of the biofilm microbiome, experiments containing carbon steels disks (CSDs) …

Vertical Marine Snow Distribution In The Stratified Hypersaline, And Anoxic Orca Basin (Gulf Of Mexico), Arne Diercks, Kai Ziervogel, Ryan Sibert, Samantha B. Joye, Vernon Asper

Faculty Publications

We present a complete description of the depth distribution of marine snow in Orca Basin (Gulf of Mexico), from sea surface through the pycnocline to within 10 m of the seafloor. Orca Basin is an intriguing location for studying marine snow because of its unique geological and hydrographic setting: the deepest ~200 m of the basin are filled with anoxic hypersaline brine. A typical deep ocean profile of marine snow distribution was observed from the sea surface to the pycnocline, namely a surface maximum in total particle number and midwater minimum. However, instead of a nepheloid (particle-rich) layer positioned near …

Exposure Characterization Of Haloacetic Acids In Humans For Exposure And Risk Assessment Applications: An Exploratory Study, Shahid Parvez, Jeffrey L. Ashby, Susana Y. Kimura, Susan D. Richardson

Faculty Publications

Disinfected water is the major source of haloacetic acids (HAAs) in humans, but their inter- and intra-individual variability for exposure and risk assessment applications is under-researched. Thus, we measured HAAs in cross-sectional and longitudinal urine and water specimens from 17 individuals. Five regulated HAAs—mono-, di-, and trichloroacetic acid (MCAA, DCAA, and TCAA) and mono- and dibromoacetic acid (MBAA and DBAA)—and one unregulated HAA—bromochloroacetic acid (BCAA)—were measured. Urinary DCAA, MBAA, DBAA, and BCAA levels were always below the limits of detection (LOD). Measured levels and interindividual variability of urinary MCAA were higher than urinary TCAA. Longitudinal urinary specimens showed MCAA levels …

In Situ Geochemistry Of Middle Ordovician Dolomites Of The Upper Mississippi Valley, Achim D. Herrmann

Faculty Publications

The dolomitization and diagenetic history of Ordovician carbonates of southern Wisconsin is complex. Previous studies attributed dolomitization to various diagenetic factors and environments. In this study, high-resolution, in situ laser ablation inductively coupled mass spectrometry analysis of rare earth element patterns of dolomite was used to assess the diagenetic fluids responsible for dolomitization of the Ordovician Decorah Formation. Integrated geochemical data and petrographic evidence suggest that the dolostones are formed in two different diagenetic realms: shallow burial and hydrothermal. Shallow burial dolomites exhibit three distinct rare earth element patterns. Dolomite from the middle portion of the Guttenberg Member exhibits light …

In Situ Geochemistry Of Middle Ordovician Dolomites Of The Upper Mississippi Valley, Achim D. Herrmann

Faculty Publications

The dolomitization and diagenetic history of Ordovician carbonates of southern Wisconsin is complex. Previous studies attributed dolomitization to various diagenetic factors and environments. In this study, high-resolution, in situ laser ablation inductively coupled mass spectrometry analysis of rare earth element patterns of dolomite was used to assess the diagenetic fluids responsible for dolomitization of the Ordovician Decorah Formation. Integrated geochemical data and petrographic evidence suggest that the dolostones are formed in two different diagenetic realms: shallow burial and hydrothermal. Shallow burial dolomites exhibit three distinct rare earth element patterns. Dolomite from the middle portion of the Guttenberg Member exhibits light …

Surface Coupling Of Octaethylporphyrin With Silicon Tetrachloride, Jayne C. Garno, Phillip C. Chambers, Neepa M. K. Kuruppu Arachchige, Ashley M. Taylor

Faculty Publications

The surface assembly of 2,3,7,8,12,13,17,18-octaethylporphyrin (OEP) using silicon tetrachloride as a coupling agent was investigated using atomic force microscopy (AFM). Nanopatterned films of Si-OEP were prepared by protocols of colloidal lithography to evaluate the morphology, thickness, and molecular orientation for samples prepared on Si(111). The natural self-stacking of porphyrins can pose a challenge for molecular patterning. When making films on surfaces, porphyrins will self-associate to form co-planar configurations of random stacks of molecules. There is a tendency for the flat molecules to orient spontaneously in a side-on arrangement that is mediated by physisorption to the substrate as well as by …