Physical Sciences and Mathematics Commons^™

Use Of Optical Character Recognition In The Invoice Processing System Of The Michigan Medicaid Program, Richard F. Burns

Masters Theses

No abstract provided.

Affects Of Thermal Assimilation And Low Grade Metamorphism On A Xenolith Bearing Basalt Dike In Marquette, Michigan, William E. Coons

Masters Theses

No abstract provided.

Trace Fossils Of The Brassfield Formation, Lower Silurian, In South-Central Ohio And North Central Kentucky, Eugene J. Murray

Masters Theses

No abstract provided.

Spin-Flip Inelastic Scattering In 12C(P,P1)12C Near The 9.14 Mev Doublet, Hsing-Tsuen Chen

Masters Theses

No abstract provided.

Kinetics Of The Thermal Decomposition Of Pyridine, Tesfaye Biftu

Masters Theses

No abstract provided.

Spectroscopic Studies Of The Hydrogen-Chlorine Flame, Gonzalo Pizarro

Masters Theses

No abstract provided.

Synthesis And Analysis Of Dimers Of Alpha-Methylstyrene, Bhadreshkumar J. Mehta

Masters Theses

Introduction

The heat of polymerization ∆Hp, of Alpha-methylstyrene (AMS) has been a source of study for many years. The structure of AMS is shown in Figure 1.

Roberts and Jessup carried out the first quantitative work to determine ∆Hp if AMS.¹ Their data displayed a ∆Hp dependence on the degree of polymerization, DP. Several other reports were also published with new values for ∆Hp and new explanations for the apparent DP dependence.^{2, 3, 4, 5.}

Samples of dimers of AMS have been prepared by various workers.^{6, 7, 8} The reactions were mostly carried out by using sulfuric …

A Simulation Model Of Dietary Competition In The Great Smoky Mountains National Park, John Steven Cherry

Masters Theses

Interactive feeding among a group of vertebrates in the Great Smoky Mountains National Park was simulated. Consumer density, biomass production, consumer consumption rates, and seasonal food habits of adults of each species were calculated using field or literature values.

The consumers included the European wild hog, black bear, raccoon, wild turkey, white-tailed deer, three sciurid species, and several rodents. The sciurids and rodents were considered as two respective canonical groups making a total of seven consumer groups. Literature values of requisite parameters from various studies, primarily in the Southeast, were utilized. These values were allowed to vary randomly.

Simulations were …

Some Pegmatites Near Gwinn, Michigan, Michael J. Moss

Masters Theses

No abstract provided.

A Petrographic And Spectrographic Analysis Of Several Soapstone Artifacts From Tennessee And Soapstone Deposits In North Carolina And South Carolina: In An Attempt To Determine The Source Area Of The Artifacts, Earl Roger Bohanan

Masters Theses

Several soapstone artifacts from Late Archaic-Early Woodland archaeological sites in Tennessee and ten soapstone deposits, two in South Carolina and eight in North Carolina were analyzed by X-ray diffraction, X-ray spectroscopy and petrographically in an attempt to correlate the artifacts and deposits. The data show that two of the deposits, Shelton Mine and Watermellon Branch, exhibit the best correlation with some of the artifacts. However, the evidence isn't conclusive.

Petrographic analysis revealed that the deposits and artifacts consist of one of two distinct mineral assemblages, one consisting of talc, chlorite, and anthophyllite, and a second in which talc, chlorite, and …

Tertiary Welded Tuffs Of The Ryan Spring Area, Needle Range, Beaver County, Utah, Peter Carlyle Rauch

Masters Theses

"The Needle Range of southwestern Utah is composed of Paleozoic sediments overlain by a thick sequence of Tertiary volcanic rocks primarily of the welded tuff class. The area has undergone at least four stages of post-eruptive structural deformation. The most significant stage is that which formed the range by normal Basin and Range type faulting. The faults strike northwest and tilt the volcanic layers northeast.

The volcanic section is composed primarily of the Needles Range Formation (Oligocene) overlain by the Isom Formation and underlain by several flows and ash flows, one of which has been tentatively correlated to the Escalante …

Mechanistic Studies Of Alkylation Of Cobalt(I) By Cyclopropyl Derivatives, Lailing Magdalene Soong

Masters Theses

A second order nucleophilic substitution reaction with retention of configuration is predicted by Ugi and co-workers if electrophiles such as cyclopropyl, cyclobutyl, or cyclopentyl derivatives undergo substitution under conditions where the S_N2 process is faster than the competing S_N1 process.

A synthesis of both cis and trans-7-chlorobicyclo [4.1.0] heptane from olefin and dichlorocarbene is described. The compound, bicyclo [4.1.0] heptylpyridine [bis(salicylaldehyde)ethylenediiminato] cobalt(III), which contains an alkylcobalt σ-bond, is obtained from the reaction of pyridine [bis(salicylaldehyde)ethylenediiminato] cobalt(I) and 7-chlorobicyclo [4.1.0] heptane. The great light sensitivity of this compound has prevented its isolation in purity sufficient for nmr …

Reactions Of Tungsten Carbonyl Complexes Containing Diphenylvinylphosphine, George S. Leotsakos

Masters Theses

A new synthetic route for the production of the tungsten carbonyl complex (OC)₅WPPh₂CH₂CH₂PPh₂ has been discovered. It has been found that lithiumdiphenylphosphide reacts with diphenylvinylphosphinepentacarbonyltungsten(0) in tetrahydrofuran to produce upon hydrolysis a good yield of the pentacarbonyl product […]. No evidence for the formation of secondary products was noted nor was there evidence for preferential attack of the carbonyl group by LiPPh₂ to form a carbene complex.

Diphenylvinylphosphinepentacarbonyltungsten(0) (mp 62-64°C), was prepared for the first time by two different methods.

I. Displacement of aniline from anilinepentacarbonyltungsten(0) complex with diphenylvinylphosphine.

II. …

Mechanistic Studies Of Alkylation Of Cobalt(I) By Cyclobutyl Derivatives, Hao Ku

Masters Theses

A study was initiated on the hypothesis, by Ugi and co-workers, that cyclopropyl, cyclobutyl, and cyclopentyl electrophiles might under go nucleophilic substitution reactions with retention of configuration.

The synthesis of benzocyclobutenol and 2-phenylcyclobutyl tosylate is described. The reactions of these tosylates with cobalt(I) "supernucleophiles" gave low yields of products which have not been purified sufficiently for assignment of stereochemistry.

Reaction of cyclopentyl tosylate and phenylethyl tosylate with the "supernucleophiles" cobaloxime(I) and cobalt(salen)(I) is discussed for the advance of future work.

Heavy Metal Contamination In Soil Around A Lead Smelter In Southeast Missouri, David Lewis Butherus

Masters Theses

"In order to determine the extent of possible heavy metal contamination, more than 963 samples of leaf litter and soil were collected from 410 sample stations around the AMAX smelter in southeast Missouri. Dried samples of leaf litter and minus 80 mesh soil fractions were analyzed for cadmium, copper, lead, and zinc by atomic absorption spectrophotometry. Minus 80 mesh soil fractions were also analyzed for sulfur using x-ray fluorescence methods. Ranges of heavy metal concentrations in leaf litter were: cadmium, 0.13 μg/g to 175 μg/g; copper, 4.2 μg/g to 6500 μg/g; lead, 50 μg/g to 130,000 μg/g; and zinc, 26 …

Some Relationships In The Water Quality And Life Forms Of Field Tile Effluents And Downstream Water, Joseph C. Sidwell

Masters Theses

No abstract provided.

The Intramolecular Torsional Potential And Dielectric Properties Of 2,3-Butanedione, Gevert H. Meyer

Masters Theses

Dipole moment measurements have been carried out on 2,3-butanedione in solution, pure liquid, and the vapor phase. A dipole moment of 1.03 ± .01 Debye was observed for dilute solutions of 2,3-butanedione in carbon tetrachloride. Pure liquid samples exhibit an anomalous dipole of 1.56 ± .01 Debye. The following results were obtained for vapor phase measurements: 1.04, 1.07, 1.08, 1.11, and 1.17 ± .01 Debye at 310.15, 350.15, 370.15, 431.70 and 472.10 ± .02°K respectively.

The acetyl torsional potential was characterized from the observed temperature dependence of dipole moment. This torsional mode was described by a two-parameter potential function: V(Ø) …

Zwitterionic Carbonyl Halide Complexes Of Tungsten, Dragoslav Marcovich

Masters Theses

The first carbonyl halide zwitterionic complexes have been synthesized and are of the type cis- (OC)₄XWPPh₂(CH₂)nPPh₂R in which X is Cl, Br, or I, n is 1 or 2, and R is an alkyl group. The complexes were prepared by the reaction […]. The temperature of the reaction must be carefully controlled since the decomposition point of the product is only 10°C higher than that of the reactant.

The zwitterionic complexes are sensitive to light in solution but are insensitive to light in the solid state. Unlike carbonyl halide complexes of the …

A Statistical Approach To The Study Of The Ecosystems Of Seven Ponds In East-Central Illinois, Gregory Lee Orr

Masters Theses

Gross primary productivity, heterotrophic bacterial numbers, and net phytoplankton densities of seven ponds in Coles County, Illinois, were studied in relation to physical, chemical, and biological habitat variables (light intensity and duration, turbidity, water temperature, pH, dissolved oxygen, sulfur, nitrogen, phosphorus, production, bacteria, and phytoplankton). Ten observations were made for each pond (except where otherwise noted) from 17 June through 25 August 1974. Stepwise multiple linear regression analyses of the data were used in order to determine those environmental factors which were important in predicting (i.e., significantly correlated with) bacterial and phytoplankton densities, and production. A multiple linear regression equation …

Studies Of Acetylcholinesterase In Synaptosomes, Syed Abbas Rizvi

Masters Theses

Acetylcholinesterase from rat brain was studied in crude homogenates, partially purified enzyme fractions, and in synaptosomes, to observe modification of the enzyme as a consequence of the modification of the membrane containing it.

Sodium dodecyl sulfate decreases the absorbance due to particles in the homogenate. This change in absorbance was proportional to both the concentration of sodium dodecyl sulfate and the concentration of the particles. Further, sodium dodecyl sulfate caused sulfhydryl groups to appear in the crude homogenate and in partially purified enzyme fractions. Synaptosomal preparations did not give such results. At concentrations of sodium dodecyl sulfate sufficient to cause …

Comparative Studies Of The Computational Analysis Of One Dimensional Gas Flow, Johnny Ziebarth

Masters Theses

No abstract provided.

Using Ibm's Information Management System To Implement A Relational Data Base, Melvin Arthur Rushton

Masters Theses

"A relational model of data has been the topic of several papers which deal with the question of the underlying design philosophy of data base systems. E. F. Codd, C. J. Date, and others have discussed the application of relation theory to formatted data, the objectives of such an approach, normalization of relations, and languages for manipulating the model (data sublanguages). Few papers have delt with storage constructs or access techniques for a relational data base. Indeed, it was not necessary that they do so, for the user of such a system is only concerned with the information available in …

Toacs : An Interactive Computer Graphic Display Model Of A Theaterwide On-Line Air Combat Simulation, Herman William Blick

Masters Theses

"On-line interactive graphics is a very effective research tool for examining the concepts, components and design parameters of theater warfare involving multiple aircraft. The aim of the present research is to design an on-line computer system which utilizes interactive graphic displays to develop a dynamic, two-sided mathematical model of theaterwide tactical fighter combat operations. The model, called TOACS, is very useful in simulating and evaluating airborne defense systems and the problems common to this type of simulation — such as the formulation of battle strategy for the commitment and guidance of interceptors against threat aircraft -- as well as those …

Geochemical And Biogeochemical Studies In The Hansonburg Mining District, New Mexico, Alan Nathan Silverman

Masters Theses

"The Hansonburg mining district is in Socorro county in south central New Mexico. A Paleozoic section of thick Pennsylvanian limestone units, thin shale and arkose layers and thick Permian units of sandstone, siltstone and gypsiferous beds interlayered with thin limestone units unconformably overlie a Precambrian basement of granite. The sedimentary rocks are folded with north trends and plunges. Northerly, some easterly and northwesterly trending faults cut the folds. Galena, fluorite, and barite mineralization occurs along some of the northerly faults and as bedded replacements and fissure fillings in the Pennsylvanian Council Spring limestone.

Geological mapping and geochemical soil surveys of …

Fluid Inclusion Geothermometry Of Tri-State Sphalerite, Chi-Sheng Wei

Masters Theses

"Fluid inclusions in successively deposited generations of sphalerite from the Tri-State district have been examined for geothermometry as a function of time. The main stage of vug-filling sphalerite has been studied most intensively and as many as 83 fluid inclusions have been examined in a single crystal. These sphalerite crystals are commonly zoned, and their filling temperatures exhibit a general pattern of declining temperature from their cores outward, from about 135°C down to 90°C. The decline is not a steady one, but rather it is characterized by fluctuations commonly about 15-20°C. Some fluctuations have magnitudes as great as 50-60°C, with …

Distribution-Free Interval Estimation Of The Largest Α-Quantile, William E. Plouff

Masters Theses

No abstract provided.

Spin-Flip In 12C (P,P') 12C Near The 9.14 Mev Doublet, John Ambani Muhanji

Masters Theses

No abstract provided.

Geology Of Klump's Cave, Perry County, Missouri, Ernest L. Kern

Masters Theses

No abstract provided.

Debris Slides And Related Flood Effects In The 4-5 August 1938 Webb Mountain Cloudburst: Some Past And Present Environmental Geomorphic Implications, Carl A. Koch

Masters Theses

On the night of 4-5 August, 1938 a cloudburst occurred over Webb Mountain, Tennessee, that lasted three hours with a rainfall in excess of twelve inches. This sudden deluge caused considerable debris sliding and flooding which resulted in the loss of eight lives and extensive property damage in the narrow valleys below the slide area. Over 100 individual slide scars were identified in the study area, 40 of which occurred in the Matthew Creek watershed.

The debris slide movement is thought to have been initiated by sliding at the head of the scar, with the mass of moving rock, soil …

Debris Slides And Related Flood Effect In The 4-5 August 1938 Webb Mountain Cloudburst: Some Past And Present Environmental Geomorphic Implications, Carl A. Koch

Masters Theses

On the night of 4-5 August, 1938 a cloudburst occurred over Webb Mountain, Tennessee, that lasted three hours with a rainfall of twelve inches. This sudden deluge caused considerable debris sliding and flooding which resulted in the loss of eight lives and extensive property damage in the narrow valleys below the slide area. Over 100 individual slide scars were identified in the area, 40 of which occurred in the Matthew Creek watershed.

The debris slide movement is thought to have been initiated by sliding at the head of the scar, with the mass of moving rock, soil and forest debris …