Physical Sciences and Mathematics Commons^™

Study On New Strategy Toward Gold(I/Iii) Redox Catalysis, Shuyao Zhang

USF Tampa Graduate Theses and Dissertations

This dissertation mainly contains three parts: 1) the study of ligand assisted gold oxidative addition toward aryl iodide to achieve the alkene difunctionalization. 2) The selective arylation reaction via electrochemical anode oxidation promoted gold redox chemistry. 3) The π acid reactivity of gold redox chemistry under electrochemistry conditions.

In the first part, the gold-catalyzed intermolecular oxyarylation of alkene is reported. This work employed the oxidative addition of aryl iodide to Me-DalphosAu+ for the formation of Au(III)-Ar intermediate. The better binding ability of alkene over O nucleophiles ensured the success of intermolecular oxyarylation, giving desired products with broad substrate scope and …

Magnetism In Doped And Hybrid Two – Dimensional Transition Metal Dichalcogenides, Nalaka Kapuruge

USF Tampa Graduate Theses and Dissertations

In recent years, spintronics has gained increasing interest due to the possibility of storing and processing information through the manipulation of both the charge and spin of an electron. Dilute magnetic semiconductors are ideal for the fabrication of such devices as they display carrier-mediated ferromagnetism which allows the electronic control of magnetism. Transferring these properties into the two-dimensional (2D) realm is very attractive for both fundamental research and novel applications. The recent discovery of long-range magnetic order in 2D materials has attracted a growing effort in the search for new functional 2D materials that can display ferromagnetic properties at room-temperature. …

Preventing Variadic Function Attacks Through Argument Width Counting, Brennan Ward

USF Tampa Graduate Theses and Dissertations

Format String attacks, first noted in June 2000 [1], are a type of attack in which anadversary has control of the string argument (the format string) passed to a string format function (such as printf). Such control allows the attacker to read and write arbitrary program memory. To prevent these attacks, various methodologies have been proposed, each with their own costs and benefits. I present a novel solution to this problem through argument width counting, ensuring that such format functions cannot access stack memory beyond the space where arguments were placed. Additionally, I show how this approach can be expanded …

Exploring The Vulnerability Of A Neural Tangent Generalization Attack (Ntga) - Generated Unlearnable Cifar-10 Dataset, Gitte Ost

USF Tampa Graduate Theses and Dissertations

Nowadays, a massive amount of data is generated and stored on servers and cloudsfrom various applications daily. Preventing these data from unauthorized use often becomes necessary and critical in various real-world applications. Many researchers have studied this crucial problem and developed different methods for this purpose. Among them, Neural Tangent Generalization Attack (NTGA) is one of the most efficient methods to make a dataset unlearnable, which means that the dataset is not learnable by machine learning/deep learning methods. That is, the NTGA-generated dataset is protected against unauthorized use. In this thesis, we explore the vulnerability of an NTGA-generated unlearnable CIFAR-10 …

Sports And Greenhouse Gas Emissions: Building A Better Framework For Sustainable Sports Operations, Austin Anahory

USF Tampa Graduate Theses and Dissertations

This thesis analyzes the approach to sustainability of American soccer leagues and provides a Greenhouse Gas (GHG) Inventory of the Tampa Bay Rowdies. Sustainability and climate change are rising concerns for most industries, especially the sports industry as it will face many immediate and long term impacts. To address these issues, a sustainability analysis was done of each USL Championship team to assess prominence of sustainability topics from their website. To conduct the GHG inventory, the GHG Protocol was followed and resulted in assessing Scope 1, 2, and 3 of the given soccer team. Assumptions were used to estimate missing …

Measurement In Chemistry, Mathematics, And Physics Education: Student Explanations Of Organic Chemistry Reaction Mechanisms And Instructional Practices In Introductory Courses, Brandon J. Yik

USF Tampa Graduate Theses and Dissertations

The work in this dissertation is presented in two parts. The first part (Chapters 3 and 4) details work relating to students’ explanations of reaction mechanisms in organic chemistry. The second part (Chapters 5 and 6) details work relating to the evaluating the uptake of research-based instructional practices in introductory chemistry, mathematics, and physics courses.

To evaluate learning of organic chemistry reactions, instructors must ask students to construct written explanations of reaction mechanisms. Written assessments should focus on what is happening and why it is happening to promote deeper student understanding. However, for instructors to gain insight into students’ understanding, …

Accelerating Multiparametric Mri For Adaptive Radiotherapy, Shraddha Pandey

USF Tampa Graduate Theses and Dissertations

MR guided Radiotherapy (MRgRT) marks an important paradigm shift in the field of radiotherapy. Superior tissue contrast of MRI offers better visualization of the abnormal lesions, as a result precise radiation dose delivery is possible. In case of online treatment planning, MRgRT offers better control of intratumoral motion and quick adaptation to changes in the gross tumor volume. Nonetheless, the MRgRT process flow does suffer from some challenges that limit its clinical usability. The primary aspects of MRgRT workflow are MRI acquisition, tumor delineation, dose map prediction and administering treatment. It is estimated that the acquisition of MRI takes around …

Social Media Time Series Forecasting And User-Level Activity Prediction With Gradient Boosting, Deep Learning, And Data Augmentation, Fred Mubang

USF Tampa Graduate Theses and Dissertations

In the overall history of technological innovations, social media has only existed for a brief time, however its influence is undeniable. Researchers have found that it can be used to influence elections, spread health misinformation, and aid with financial pump-and-dump schemes. Keeping all this in mind, it is clear that more research is needed to predict the spread of information on social media in order to combat its malicious use.

To that end, in this dissertation, we explore the use of Machine Learning algorithms to perform time series forecasting and user-level activity prediction in social media. We address the different …

Association Between Use Of Remdesivir And Bradycardia, Gibret Umeukeje

USF Tampa Graduate Theses and Dissertations

Remdesivir received the first emergency use authorization from the FDA for the treatment of COVID-19. Multiple adverse drug reactions (ADR) have been reported since its approval in October 2020. Bradycardia, defined by a decrease in heart rate has been reported as an adverse event for patients receiving remdesivir for COVID-19 treatment. The purpose of the research is to systematically investigate the frequency of occurrence of bradycardia in adults receiving remdesivir using clinical data derived from the FDA Adverse Event Reporting System (FAERS) database. Patients receiving remdesivir were compared to those receiving Paxlovid, Regen-Cov, and Dexamethasone for COVID-19 treatment to see …

Adaptive Multi-Scale Place Cell Representations And Replay For Spatial Navigation And Learning In Autonomous Robots, Pablo Scleidorovich

USF Tampa Graduate Theses and Dissertations

Place cells are one of the most widely studied neurons thought to play a vital role in spatial cognition. Extensive studies show that their activity in the rodent hippocampus is highly correlated with the animal’s spatial location, forming “place fields” of smaller sizes near the dorsal pole and larger sizes near the ventral pole. Despite advances, it is yet unclear how this multi-scale representation enables navigation in complex environments.

In this dissertation, we analyze the place cell representation from a computational point of view, evaluating how multi-scale place fields impact navigation in large and cluttered environments. The objectives are to …

Towards High Performing And Reliable Deep Convolutional Neural Network Models For Typically Limited Medical Imaging Datasets, Kaoutar Ben Ahmed

USF Tampa Graduate Theses and Dissertations

Artificial Intelligence (AI) is “The science and engineering of making intelligent machines, especially intelligent computer programs”. Artificial Intelligence has been applied in a wide range of fields including automobiles, space, robotics, and healthcare.

According to recent reports, AI will have a huge impact on increasing the world economy by 2030 and it's expected that the greatest impact will be in the field of healthcare. The global market size of AI in healthcare was estimated at USD 10.4 billion in 2021 and is expected to grow at a high rate from 2022 to 2030 (CAGR of 38.4%). Applications of AI in …

An Enterprise Risk Management Framework To Design Pro-Ethical Ai Solutions, Quintin P. Mcgrath

USF Tampa Graduate Theses and Dissertations

The effective use of Artificial Intelligence (AI) has immediate business benefits for an organization and its stakeholders through efficiency and quality gains, and the potential to explore and implement new business models. However, there are risks of unintended ethical consequences. Enterprise Risk Management (ERM) focuses on managing risk while maximizing business value from exploiting opportunities. Using applied ethics as a basis and the perspective that ethics includes both enabling human flourishing and not violating accepted norms, I argue that greater business value is achieved when an organization simultaneously targets the maximization of benefits and the minimization of harms for the …

Chemical Investigation And Drug Discovery Potential Of Terpenoid Secondary Metabolites From Three Deep-Sea Irish Soft Corals, Joshua Thomas Welsch

USF Tampa Graduate Theses and Dissertations

Secondary metabolites produced primarily by terrestrial plants and animals have provided the basis for treatments and cures of human diseases as far back as historians have been able to probe. However, recent technological advances including the self-contained underwater breathing apparatus, and even further remotely operated vehicles, have allowed researchers a unique opportunity for targeted collection of marine organisms at depths previously thought to possess conditions unsustainable for life as was understood. This has afforded a glimpse into the potential for not only life, but the potential for new biochemical adaptations developed over billions of years that have been evolutionarily developed …

Joint Models For Repeated Measured, Non-Normally Distributed Multilevel Data, Weiwei He

USF Tampa Graduate Theses and Dissertations

Clinical trials have tended to collect both survival information and longitudinal biomarkers, as well as other covariates. In order to better assess the severity of diverse diseases, we need to collect various longitudinal outcomes. Furthermore, longitudinal data could consist of a number of different measurements of varying types. The multilevel item response theory (MLIRT) model has been widely used in several fields such as public health and health sciences for multivariate longitudinal outcomes. Joint models combining the longitudinal and survival processes, as well as the relation between them, have been developed to minimize bias and improve the efficiency of estimates. …

Advanced Analytical Method Development: From Highly-Enrolled Classroom To Data-Intensive Proteomics, Laxmi Sinduri Vuppala

USF Tampa Graduate Theses and Dissertations

In analytical chemistry, method development is key to identifying, separating, and quantifying chemical components of interest systems. The chemical aspects are fundamental to understanding the subject of any analytical system, whether in academic research, industry, or government. These methodologies serve as a bridge between the classroom, where students are taught to be curious and enlightened, and research, where one strives to contribute. The Ph.D. dissertation integrates advanced methodologies in basic and applied research and advanced instrumentation, but the core criteria for validation remain the same. As part of chemical education curriculum development, a large cohort of undergraduates performed two gas …

Functional Morphology And Taphonomy Of Ordovician–Silurian Diploporan Echinoderms, Stephen Ashley Hill

USF Tampa Graduate Theses and Dissertations

Diploporan echinoderms were one of the most speciose groups of stemmed echinoderms during the Ordovician. Despite this widespread abundance, the fossil record of diploporan fauna consists primarily of incomplete specimens, with complete specimens being rare. While the theca, or body, is more commonly preserved, the feeding appendages and the attachment structures (i.e. stems or holdfasts) are seldomly preserved. Insight into these features is highly valuable to the understanding the paleoecology, like the feeding and respiratory strategies, of these enigmatic creatures.

One group of diploporan echinoderms which does have an extensive fossil record, is the Holocystites Fauna, primarily known from the …

Coupling 210Pb And 14C To Constrain Carbon Burial Efficiency Of Blue Carbon Ecosystems, Tynisha R. Martin

USF Tampa Graduate Theses and Dissertations

Blue carbon ecosystems cover a small global area but have the potential to sequester large amounts of organic carbon (OC) from the coastal ocean in the sediment. Organic carbon is continually remineralized and exported in the dissolved form, which is currently only poorly accounted for in blue carbon budgets. Constraining carbon cycling in blue carbon systems is complicated by the range of carbon sources and sinks in the system and high export rates from the system. By coupling 14C and 210Pb chronometers to ascertain the amount of primary production stored within peat, it is possible to study carbon transport through …

Inland Tropical Cyclone Intensity Decay In The Continental United States, Yijie Zhu

USF Tampa Graduate Theses and Dissertations

Tropical cyclone (TC) hazard preparation is mostly focused on coastal cities with less attention typically paid to inland regions. The impact of TCs that propagate far inland is often underestimated and can cause unexpected loss of life and economic loss. This dissertation aims to understand the decay process of TCs during the post-landfall stage by answering three main research questions: (1) What are the general patterns of inland tropical cyclones, including spatial variations, decay rates, and translation speeds? (2) Are there temporal changes in the intensity decay from inland moving hurricanes? (3) How is the hurricane post-landfall dissipation related to …

The Effects Of Temperature And Oxygen Availability On Aerobic Performance In Three Coastal Shark Species; Squalus Acanthias, Carcharhinus Limbatus, And Carcharhinus Leucas, Alyssa M. Andres

USF Tampa Graduate Theses and Dissertations

Anthropogenically driven climate changes are altering marine habitats globally. Rising sea surface temperatures and coastal eutrophication, arising from global warming and coastal nutrient loading, have resulted in progressive ocean deoxygenation. This may restrict available habitat of marine organisms as studies suggest that the balance between metabolic oxygen demand and environmental supply plays an important role in limiting viable habitat and species fitness. As ectothermic predators, with temperature-dependent metabolism and high metabolic demands, coastal shark species may be susceptible to shifts in ocean temperature and oxygen. Such environmental changes may alter metabolic performance and ultimately success and survival within shark habitat. …

Nano-Optical Imaging Of 2d Materials In The Quantum Regime, Hana Nazari Hrim

USF Tampa Graduate Theses and Dissertations

Chemical vapor deposition (CVD) growth of atomically thin 2D materials, such as transition metal dichalcogenides (TMDs), is a complex process that has not been completely understood. Large-scale growth of monolayer TMDs often leads to polycrystalline films with heterogeneous morphological and optical properties. Previous optical studies of 2D materials by far-field photoluminescence (PL) provided insights into CVD growth mechanisms of simple crystals, which were, however, limited in spatial resolution due to the diffraction limit. Here we performed correlated morphological and tip-enhanced PL (TEPL) imaging of CVD-grown polycrystalline monolayer molybdenum diselenide (MoSe2) flakes with heterogeneous optical response. We observed nanoscale spatial variations …

A Protein-Based Therapeutic Combination For The Treatment Of Hard-To-Heal Wounds, Graham L. Strauss

USF Tampa Graduate Theses and Dissertations

Chronic wounds present many clinical challenges in relation to the successful treatment and closure of the damaged tissue. Most current treatment methods focused on one or two aspects to drive wound closure, while most chronic wounds are multifactorial environments with many of those dependencies relying on the termination of one another to effectively gain tissue construction, closure, and full skin thickness and composition. Natural wound healing processes allude to potential biologics that can impede the chronic breakdown of tissue, while restoring deposition of new tissue, and effectively leading to a healed wound. Proteases secreted by the body’s immune system lay …

Zooplankton Biodiversity In The Northeast Gulf Of Mexico And On The West Florida Shelf From 2005 - 2014, Megan Ferguson

USF Tampa Graduate Theses and Dissertations

Zooplankton abundance and biodiversity was measured in the northeast Gulf of Mexico (NEGoM) and on the West Florida Shelf. Bongo net samples were collected between May 2005 to September 2009 through the SEAMAP program, and between July 2010 to August 2014 through the C-IMAGE program. Calanoid copepods were the most abundant zooplankton group in most of the samples collected, but ostracods, larvaceans, and chaetognaths were also abundant. Shannon and Inverse Simpson indices were calculated for all zooplankton samples and generally showed similar trends, but only Shannon indices were used for statistical analyses. In the winter and spring there were significant …

Large Area Projection Sintering Of Semicrystalline Polymers And Part Analysis Of The Printed Specimens, Taranjot Kaur

USF Tampa Graduate Theses and Dissertations

As the requirements posed to products have increased in recent years. The trend towards individualized serial products steps up the need for respective manufacturing techniques to be more and more flexible. Conventional techniques of serial production, such as injection molding, are unable to fully meet the requirements of this trend. Additive manufacturing techniques generate components directly from a CAD data set while requiring no specific mold, producing minimal waste, and reaching satisfactory geometric accuracy. This is how, as opposed to conventional techniques, they comply with these increased demands to processing technology. Over the last two decades, the research community has …

Ocean Eddies And Frontal Zones In The Gulf Of Mexico And Straits Of Florida, Yingjun Zhang

USF Tampa Graduate Theses and Dissertations

Ocean eddies and fronts in the Gulf of Mexico (GoM) and the Straits of Florida (SoF) play important roles in ocean physics, biology, and ecology. These two ubiquitous physical features have been studied worldwide for decades, yet many questions remain unanswered or poorly studied for the GoM and SoF. This study aims to improve the understanding of ocean eddies and frontal zones in the GoM and SoF using satellite remote sensing, in situ observations and model outputs, as well as state-of-the-art algorithms, with the following objectives: 1) analyze the three-dimensional (3-D) statistical characteristics and thermohaline structure of mesoscale eddies in …

Elucidating The Sources Supplying Aerosol Iron, Zinc, And Cadmium To The Surface Of The North Pacific Ocean With Stable Isotopes, Zach B. Bunnell

USF Tampa Graduate Theses and Dissertations

Transition metals, such as iron (Fe), zinc (Zn) and cadmium (Cd), are found at just trace amounts within the global oceans yet are vital for many biological functions of phytoplankton. As a result, these metals influence the ocean’s efficacy for carbon sequestration. Atmospheric dust is the primary input of Fe to various surface waters and may also supply Zn and Cd to oligotrophic surface waters. Here, I present Fe, Zn, and Cd isotope data from the US North Pacific GEOTRACES Section GP15 (Alaska-Tahiti) from the low-dust season (Sept. – Nov. 2018). Using this data and aerosol enrichment factors, I show …

Assessing The Human-Health Risk Of Exposure To Pathogens From Beach Sands, Javier Federico Gallard-Góngora

USF Tampa Graduate Theses and Dissertations

Fecal contamination at recreational beaches impacts the health of beachgoers, through the introduction of disease-causing microorganisms, and the well-being of communities dependent on income from recreational beach activities. Beach ecosystems are also impacted by sewage through the introduction of nutrients that can cause abnormal increases in autochthonous microorganisms which can impact the population of larger organisms in the ecosystem. Fecal contamination is introduced into sand via untreated sewage, direct deposition of human feces into sand, runoff, and deposition of animal feces into sand. The introduction of fecal contamination into sand exposes individuals to pathogens (disease causing microorganisms) which can result …

Interdisciplinary Communication By Plausible Analogies: The Case Of Buddhism And Artificial Intelligence, Michael Cooper

USF Tampa Graduate Theses and Dissertations

Communicating interdisciplinary information is difficult, even when two fields are ostensibly discussing the same topic. In this work, I’ll discuss the capacity for analogical reasoning to provide a framework for developing novel judgments utilizing similarities in separate domains. I argue that analogies are best modeled after Paul Bartha’s By Parallel Reasoning, and that they can be used to create a Toulmin-style warrant that expresses a generalization. I argue that these comparisons provide insights into interdisciplinary research. In order to demonstrate this concept, I will demonstrate that fruitful comparisons can be made between Buddhism and Artificial Intelligence research.

An Integrated Approach For Dynamic Process Modeling And Optimization Of Wastewater Treatment Facilities, Komal Rathore

USF Tampa Graduate Theses and Dissertations

The subareas of process systems engineering including process modeling, simulation, and optimization are becoming progressively substantial for understanding processes, making decisions, improving efficiency, and complying with stricter environmental and safety legislation. Additionally, the availability of user-friendly flowsheet simulators and computational resources with the current trend of data collection and analysis has allowed for a more accurate representation of complex processes such as wastewater treatment systems. Despite all the progress in the areas of process modeling and simulation, the first-principle mechanistic models for wastewater treatment processes are at best employed during the design stage, and therefore, not used optimally for day-to-day …

Boundary Behavior Of Analytic Functions And Approximation Theory, Spyros Pasias

USF Tampa Graduate Theses and Dissertations

In this Thesis we deal with problems regarding boundary behavior of analytic functions and approximation theory. We will begin by characterizing the set in which Blaschke products fail to have radial limits but have unrestricted limits on its complement. We will then proceed and solve several cases of an open problem posed in \cite{Da}. The goal of the problem is to unify two known theorems to create a stronger theorem; in particular we want to find necessary and sufficient conditions on sets $E_1\subset E_2$ of the unit circle such that there exists a bounded analytic function that fails to have …

Multiple Solar Receivers Arrangement For High-Temperature Power Generation And Applications, Diego Jesus Guillen Perez

USF Tampa Graduate Theses and Dissertations

This dissertation presents an investigation of the specification and operation of multiple central solar receivers (CSR) sharing a heliostat field and an analysis of the receiver's thermal performance. A heliostat field was modeled in which different parts of the field aimed at different external or cavity receivers located on the same tower. Optical and thermal performance are analyzed, including the receivers' heat flux, solar thermal efficiency, and annual energy output. Some of the contributions of this research are:

1. Propose a novel configuration for a CSP power generation system using two receivers in a single central tower suitable …