Physical Sciences and Mathematics Commons^™

Nonlinear Techniques For Stochastic Systems Of Differential Equations, Tadesse G. Zerihun

USF Tampa Graduate Theses and Dissertations

Two of the most well-known nonlinear methods for investigating nonlinear dynamic processes in sciences and engineering are nonlinear variation of constants parameters and comparison method. Knowing the existence of solution process, these methods provide a very powerful tools for investigating variety of problems, for example, qualitative and quantitative properties of solutions, finding error estimates between solution processes of stochastic system and the corresponding nominal system, and inputs for the designing engineering and industrial problems. The aim of this work is to systematically develop mathematical tools to undertake the mathematical frame-work to investigate a complex nonlinear nonstationary stochastic systems of differential …

Deciphering Deposits: Using Ground Penetrating Radar And Numerical Modeling To Characterize The Emplacement Mechanisms And Associated Energetics Of Scoria Cone Eruption And Construction, Leah Michelle Courtland

USF Tampa Graduate Theses and Dissertations

Our understanding of tephra depositional processes is significantly improved by high-resolution ground-penetrating radar (GPR) data collected at Cerro Negro volcano, Nicaragua. The data reveal three depositional regimes: (1) a near-vent region on the cone itself, where 10 GPR radargrams collected on the western flank show quantifiable differences between facies formed from low energy normal Strombolian and higher energy violent Strombolian processes, indicating imaging of scoria cone deposits may be useful in distinguishing eruptive style in older cones where the proximal to distal tephra blanket has eroded away; (2) a proximal zone in which horizons identified in crosswind profiles collected at …

Hydrogen Storage In Hypercrosslinked Polystyrene And Li-Mg-N-H Complex Hydride, Dervis Emre Demirocak

USF Tampa Graduate Theses and Dissertations

In this dissertation, hydrogen storage enhancement in hypercrosslinked polystyrene, effects of single walled carbon nanotubes (SWCNTs) supported ruthenium (Ru) catalyst on the kinetics and ammonia suppression in the LiNH2-MgH2 complex hydride system and the accuracy of hydrogen storage measurements are investigated in detail.

High surface area physisorption materials are of interest for room temperature hydrogen storage enhancement by spillover. Six different commercially available hypercrosslinked polystyrenes are screened by considering the specific surface area, average pore size, pore volume, and adsorption enthalpy. MN270 is selected mainly due to its high surface area and narrow pores for investigation of the spillover enhancement …

Modeling State Transitions With Automata, Egor Dolzhenko

USF Tampa Graduate Theses and Dissertations

Models based on various types of automata are ubiquitous in modern science. These models allow reasoning about deep theoretical questions and provide a basis for the development of efficient algorithms to solve related computational problems. This work discusses several types of automata used in such models, including cellular automata and mandatory results automata.

The first part of this work is dedicated to cellular automata. These automata form an important class of discrete dynamical systems widely used to model physical, biological, and chemical processes. Here we discuss a way to study the dynamics of one-dimensional cellular automata through the theory of …

A Study Of Permutation Polynomials Over Finite Fields, Neranga Fernando

USF Tampa Graduate Theses and Dissertations

Let p be a prime and q = p^k. The polynomial g_n,q isin F_p[x] defined by the functional equation Sigma_{a isin Fq} (x+a)ⁿ = g_n,q(x^q- x) gives rise to many permutation polynomials over finite fields. We are interested in triples (n,e;q) for which g_n,q is a permutation polynomial of F_q^e. In Chapters 2, 3, and 4 of this dissertation, we present many new families of permutation polynomials in the form of g_n,q. The permutation behavior of g_n,q is becoming increasingly more …

Assessment Of A Modified Double Agar Layer Method To Detect Bacteriophage For Assessing The Potential Of Wastewater Reuse In Rural Bolivia, Sakira N. Hadley

USF Tampa Graduate Theses and Dissertations

Water scarcity is a global concern that impacts many developing countries, forcing people to depend on unclean water sources for domestic, agricultural, and industrial needs. Wastewater is an alternative water source that contains nutrients needed for crop growth. Wastewater reuse for agriculture can cause public health problems because of human exposure to pathogens. Pathogen monitoring is essential to evaluate the compliance of wastewater with established World Health Organization (WHO) and U.S. Environmental Protection Agency (EPA) wastewater reuse guidelines. Indicator organisms are commonly used to detect pathogens in water and wastewater because they are quick and easy to measure, non-pathogenic, and …

Spatial And Temporal Trends Of Snowfall In Central New York - A Lake Effect Dominated Region, Justin Joseph Hartnett

USF Tampa Graduate Theses and Dissertations

Central New York is located in one of the snowiest regions in the United States, with the city of Syracuse, New York the snowiest metropolis in the nation. Snowfall in the region generally begins in mid-November and lasts until late-March. Snow accumulation occurs from a multitude of conditions: frontal systems, mid-latitude cyclones, Nor'easters, and most notably lake-effect storms. Lake effect snowfall (LES) is a difficult parameter to forecast due to the isolated and highly variable nature of the storm. Consequently, studies have attempted to determine changes in snowfall for lake-effect dominated regions. Annual snowfall patterns are of particular concern as …

The Effects Of Fractures On The Occurrence And Distribution Of Arsenic In The Upper Floridan Aquifer During Aquifer Storage And Recovery, William Charles Hutchings

USF Tampa Graduate Theses and Dissertations

ABSTRACT

Aquifer storage and recovery (ASR) is used world-wide to supplement available water supplies by storing surplus water in aquifers and recovering it during periods of drought and increased demand. The use of ASR as an option for increasing available municipal irrigation and fresh water supplies is threatened as a result of the mobilization of arsenic in some aquifers during ASR. Arsenic is liberated from arsenic-bearing sulfide minerals as a result of the mixing of oxidizing injected water with reducing insitu groundwater. Fracture networks can have significant influence on the migration and distribution of arsenic in the Upper Floridan Aquifer …

Design, Synthesis, Processing, And Thermal Analysis Of Nanocomposites With Tunable Properties, Mu Seong Kim

USF Tampa Graduate Theses and Dissertations

Polymer composites containing nanosized fillers have generated explosive interest since the early 1980's. Many recent studies have been conducted incorporating nano-fillers into polymer matrices to design and synthesize materials with tunable mechanical, thermal, and optical properties. Conventional filled polymers, where the reinforcement is on the order of microns, have been replaced by composites with discrete nanosized fillers. Gradually, theories that predicted that composite properties are independent of particle size in the micron range were challenged by nanocomposites. Rather, nanocomposite properties are greatly influenced by the surface area of the. All of this is complicated by the fact that nanoparticles are …

Assessment Of Student Achievement In Introductory Physical Geology: A Three -Year Study On Delivery Method And Term Length, Marianne O'Neal Caldwell

USF Tampa Graduate Theses and Dissertations

Physical Geology is a popular general education course at Hillsborough Community College (HCC) as at many other colleges and universities. Unlike many science courses, most students taking Physical Geology are not majoring in a STEM (Science, Technology, Engineering, and Mathematics) discipline. Typically most students enrolled in Physical Geology are majoring in business, education, or pursuing a general A.A degree for transfer to a four-year university. The class is likely to be one of the few, if not the only, physical science classes that many of these students will take in their academic career. Therefore, this class takes on increased importance, …

Design, Synthesis And Evaluation Of Novel Diazirine Photolabels With Improved Ambient Light Stability And Fluorous-Based Enrichment Capacity, Arun Babu Kumar

USF Tampa Graduate Theses and Dissertations

Photoaffinity labeling is a quintessential technique in studying and analyzing the interaction between a ligand and receptor. Diazirines are one of the important photo-labile moieties used in photoaffinity labeling due to their superior photo labeling characteristics. Herein, we report the investigations we conducted with diazirine photolabels on (a) photochemical aspects leading to enhancement of their ambient light stability and (b) equipping them with fluorous tags to enable fluorous enrichment of labeled proteins. Furthermore, we report a pilot study to develop BACE-1 inhibitors, which have potential to be developed into photoaffinity probes.

3-Trifluoromethyl-3-phenyldiazirine offers good selectivity and protection against pseudolabeling but …

A Geochemical Analysis Of Fulgurites: From The Inner Glass To The Outer Crust, Michael L. Joseph

USF Tampa Graduate Theses and Dissertations

Cloud-to-ground lightning strikes produce natural glasses on the surface of the Earth, called fulgurites. These natural glasses are tubular in shape with a central void surrounded by an inner glass, and the inner glass is surrounded by an outer crust or toasted region. Previous studies report different kinds of melts existing in several different types of fulgurites; however, little to no chemical data has been collected that tracks chemical variations from the inner glass to the outer crust of a fulgurite. This study uses microprobe and laser ablation inductively coupled plasma mass spectrometer analytical techniques to collect transects of chemical …

Sediment Transport And Distribution Over Continental Shelves: A Glimpse At Two Different River-Influenced Systems, The Cariaco Basin And The Amazon Shelf., Laura Lorenzoni

USF Tampa Graduate Theses and Dissertations

The aim of this dissertation was to understand lithogenic suspended sediment transport mechanisms and distribution in two river-influenced margins: The Cariaco Basin, Venezuela, and the Amazon Shelf, Brazil. Lithogenic sediment input in the Cariaco Basin is controlled by small mountainous rivers (SMR), while in the Amazon Shelf it is dominated by the Amazon River, the largest river in the world in terms of freshwater discharge (~20% of global riverine discharge). Optical transmissometer measurements were coupled with particulate organic matter (POM) observations to understand changes in the geochemical composition of suspended sediment and spatial/temporal distributions over the two regions of interest. …

N-Acyl Ciprofloxacins: Synthesis, Antibacterial Activity And Effects On Molecular Loading Of Poly(Vinyl Benzoate) Nanoparticles, Ryan Cormier

USF Tampa Graduate Theses and Dissertations

Bacterial infections are becoming progressively more difficult to treat due to antibiotic resistance and the decreasing rate at which new antibiotics are brought to market. The Turos laboratory has attempted to tackle this problem for the last 15 years with the discovery of N-thiolated β-lactams leading to the design of polyacrylate nanoparticles to deliver these and other drugs. Chapter 1 discusses many reported instances of utilizing different types of polymeric nanoparticles to deliver antibiotics. Poly(lactic-co-glycolic acid) (PLGA), poly(alkyl cyanoacrylate) (PACA), poly(styrene-co-butylacrylate), and chitosan are the main polymers used to make nanoparticles. Chapter 2 describes the synthesis, antibacterial activity, and mechanism …

Production Of Bioactive Secondary Metabolites By Florida Harmful Bloom Dinoflagellates Karenia Brevis And Pyrodinium Bahamense, Cheska Burleson

USF Tampa Graduate Theses and Dissertations

Despite the critical role algae serve as primary producers, increases or accumulation of certain algae may result in Harmful Algal Blooms (HABs). Algal toxins from these blooms contribute significantly to incidences of food borne illness, and evidence suggests HABs are expanding in frequency and distribution. Mitigation of these HABs without knowledge of the ecological purpose and biochemical regulation of their toxins is highly unlikely. The production, function, and potential of secondary metabolites produced by the dinoflagellates Karenia brevis and Pyrodinium bahamense, were investigated.

Brevetoxins were demonstrated by two different methods to localize within the cytosol of Karenia brevis. …

Investigation Of Stress Changes At Mount St. Helens, Washington, And Receiver Functions At The Katmai Volcanic Group, Alaska, With An Additional Section On The Assessment Of Spreadsheet-Based Modules., Heather L. Lehto

USF Tampa Graduate Theses and Dissertations

Forecasting eruptions using volcano seismology is a subject that affects the lives and property of millions of people around the world. However, there is still much to learn about the inner workings of volcanoes and how this relates to the chance of eruption. This dissertation attempts to increase the breadth of knowledge aimed at helping to understand when a volcano is likely to erupt and how large that eruption might be. Chapters 2 and 3 focus on a technique that uses changes in the local stress field beneath a volcano to determine the source of these changes and help forecast …

A Study Of The Eastern Oyster, Crassostrea Virginica, In Tampa Bay: Effects Of Perkinsus Marinus On Reproduction And Condition, Bridgit Melora Mccrickard

USF Tampa Graduate Theses and Dissertations

Abstract

Five sites in Tampa Bay, Florida, were sampled monthly from February 2006 to January 2007. These sites were located at the mouth of the Alafia River, in an inlet of Cross Bayou, on the easement of Gandy Bridge, near mangrove in Manatee County, and an inlet of Salt Creek, off Bayboro Harbor. Standard methods were used to determine shell height and Condition Index (CI). Intensity and prevalence of Perkinsus marinus were analyzed using Ray's Thioglycollate medium test, while Haplosporidium nelsoni was studied by histological examination. Histological methods were also used to determine sex ratios, reproductive phases, and egg diameters. …

Design And Synthesis Of Protein-Protein Interaction Inhibitor Scaffolds, David B. Badger

USF Tampa Graduate Theses and Dissertations

Many currently relevant diseases such as cancer arise from altered biological pathways that rely on protein-protein interactions. The proteins involved in these interactions contain certain functional domains that are responsible for the protein's biological activities. These domains consist of secondary structural elements such as α-helices and Β-sheets which are at the heart of the protein's biological activity. Therefore, designing drugs that inhibit protein-protein interactions by binding to these key secondary structural elements should provide an effective treatment for many diseases. Presented in this dissertation are the designs, syntheses, and biological evaluations for both novel α-helix and novel Β-sheet mimics.

The …

Hierarchy Of Supramolecular Synthons In The Of Design Multi-Component Crystals, Padmini Kavuru

USF Tampa Graduate Theses and Dissertations

Most of the biological systems in nature are sustained by molecular self-assemblies which are the finest examples of supramolecular architectures. Non-covalent interactions are key concepts which govern these molecular assemblies. Inspired by these examples crystal engineering emerged as an important tool in supramolecular chemistry which aids in the invention of new molecular structures with desired properties. Understanding of how the molecules interact at the molecular levels enables one to rationally design novel solid forms with modulated physicochemical properties. This feature of crystal engineering has heightened its position in materials chemistry and is currently one of the most well studied fields …

Assessment Of The Oxbow Morphology Of The Caloosahatchee River And Its Evolution Over Time: A Case Study In South Florida, Chloe Delhomme

USF Tampa Graduate Theses and Dissertations

The Caloosahatchee River, located in Southern Florida, was originally a meandering and relatively shallow river. During the 1920s, the Caloosahatchee River was channelized and became the C-43 canal. The channelization has significantly impacted the river ecosystem, particularly the oxbows. The oxbows are the U-shaped water bodies on each side of the river channel, which are the remnant bends of the original river. To understand how anthropogenic influence affects hydrologic systems, the proposed case study was designed to assess the geomorphic changes of the oxbows of the Caloosahatchee River, Florida. Understanding and documenting the evolution of river morphology is becoming increasingly …

On The Automatic Recognition Of Human Activities Using Heterogeneous Wearable Sensors, Oscar David Lara Yejas

USF Tampa Graduate Theses and Dissertations

Delivering accurate and opportune information on people's activities and behaviors has become one of the most important tasks within pervasive computing. Its wide spectrum of potential applications in medical, entertainment, and tactical scenarios, motivates further

research and development of new strategies to improve accuracy, pervasiveness, and eciency.

This dissertation addresses the recognition of human activities (HAR) with wearable sensors in three main regards: In the rst place, physiological signals have been incorporated as a new source of information to improve the recognition accuracy achieved by conventional approaches, which rely on accelerometer signals solely. A new HAR system, Centinela, was born …

A Location-Aware Architecture Supporting Intelligent Real-Time Mobile Applications, Sean J. Barbeau

USF Tampa Graduate Theses and Dissertations

This dissertation presents LAISYC, a modular location-aware architecture for intelligent real-time mobile applications that is fully-implementable by third party mobile app developers and supports high-precision and high-accuracy positioning systems such as GPS. LAISYC significantly improves device battery life, provides location data authenticity, ensures security of location data, and significantly reduces the amount of data transferred between the phone and server. The design, implementation, and evaluation of LAISYC using real mobile phones include the following modules: the GPS Auto-Sleep module saves battery energy when using GPS, maintaining acceptable movement tracking (approximately 89% accuracy) with an approximate average doubling of battery life. …

Citizen Action, Power Relations And Wetland Management In The Tampa Bay Urban Socio-Ecosystem, Cornelius Owusu Adjei

USF Tampa Graduate Theses and Dissertations

Wetlands are vital ecosystems that provide ecological, economic and social benefits to societies. In the Tampa Bay region in West Central Florida, a growing population has put immense pressure on wetlands. The situation has not gone unnoticed in the public domain with concerns raised about the need to formulate policies that would protect them. However, it has been difficult to ascertain the level of citizen involvement in the decision making process.

This study aimed at investigating whether the perceptions and concerns of citizens drove them to influence local water policy. Questionnaires were used to collect data from residents living in …

A Location-Based Incentive Mechanism For Participatory Sensing Systems With Budget Constraints, Luis Gabriel Jaimes

USF Tampa Graduate Theses and Dissertations

Participatory Sensing (PS) systems rely on the willingness of mobile users to participate in the collection and reporting of data using a variety of sensors either embedded or integrated in their

cellular phones. Users agree to use their cellular phone resources to sense and transmit the data of interest because these data will be used to address a collective problem that otherwise would

be very difficult to assess and solve. However, this new data collection paradigm has not been very successful yet mainly because of the lack of incentives for participation and privacy concerns. Without adequate incentive and privacy guaranteeing …

A Framework For Participatory Sensing Systems, Diego Mendez Chaves

USF Tampa Graduate Theses and Dissertations

Participatory sensing (PS) systems are a new emerging sensing paradigm based on the participation of cellular users in a cooperative way. Due to the spatio-temporal granularity that a PS system can provide, it is now possible to detect and analyze events that occur at different scales, at a low cost. While PS systems present interesting characteristics, they also create new problems. Since the measuring devices are cheaper and they are in the hands of the users, PS systems face several design challenges related to the poor accuracy and high failure rate of the sensors, the possibility of malicious users tampering …

On Algorithmic Fractional Packings Of Hypergraphs, Jill Dizona

USF Tampa Graduate Theses and Dissertations

Let F₀ be a fixed k-uniform hypergraph, and let H be a given k-uniform hypergraph on n vertices. An F₀-packing of H is a family F of edge-disjoint copies of F₀ which are subhypergraphs in H. Let n_F0(H) denote the maximum size |F| of an F₀-packing F of H. It is well-known that computing n_F0(H) is NP-hard for nearly any choice of F₀.

In this thesis, we consider the special case when F₀ is a linear hypergraph, that is, when no two edges …

Surface Mass Transfer In Large Eddy Simulation (Les) Of Langmuir Turbulence, Cigdem Akan

USF Tampa Graduate Theses and Dissertations

Over the past century the study of gas exchange rates between the atmosphere and the ocean has received increased attention because of concern about the fate of greenhouse gases such as CO₂ released into the atmosphere. Of interest is the oceanic uptake of CO₂ in shallow water coastal regions as biological productivity in these regions is on average about three times larger than in the open ocean. It is well-known that in the absence of breaking surface waves, the water side turbulence controls gas transfer of sparingly soluble gases such as CO₂ from the air to the …

On The Design Of Socially-Aware Distributed Systems, Nicolas Kourtellis

USF Tampa Graduate Theses and Dissertations

Social media services and applications enable billions of users to share an unprecedented amount of social information, which is further augmented by location and collocation information from mobile phones, and can be aggregated to provide an accurate digital representation of the social world. This dissertation argues that extracted social knowledge from this wealth of information can be embedded in the design of novel distributed, socially-aware applications and services, consequently improving system response time, availability and resilience to attacks, and reducing system overhead. To support this thesis, two research avenues are explored.

First, this dissertation presents Prometheus, a socially-aware peer-to-peer service …

Wronskian, Grammian And Pfaffian Solutions To Nonlinear Partial Differential Equations, Alrazi Abdeljabbar

USF Tampa Graduate Theses and Dissertations

It is significantly important to search for exact soliton solutions to nonlinear partial differential equations (PDEs) of mathematical physics. Transforming nonlinear PDEs into bilinear forms using the Hirota differential operators enables us to apply the Wronskian and Pfaffian techniques to search for exact solutions for a (3+1)-dimensional generalized Kadomtsev-Petviashvili (KP) equation with not only constant coefficients but also variable coefficients under a certain constraint

(u_t + α ₁(t)u_xxy + 3α ₂(t)u_xu_y)_x +α ₃ (t)u_ty -α ₄(t)u_zz + α ₅(t)(u_x + α ₃(t)u_y) = …

Innovative Desalination Systems Using Low-Grade Heat, Chennan Li

USF Tampa Graduate Theses and Dissertations

Water and energy crises have forced researchers to seek alternative water and energy sources. Seawater desalination can contribute towards meeting the increasing demand for fresh water using alternative energy sources like low-grade heat. Industrial waste heat, geothermal, solar thermal, could help to ease the energy crisis.

Unfortunately, the efficiency of the conventional power cycle becomes

uneconomically low with low-grade heat sources, while, at the same time, seawater desalination requires more energy than a conventional water treatment process. However, heat discarded from low-grade heat power cycles could be used as part of desalination energy sources with seawater being used as coolant …