Physical Sciences and Mathematics Commons^™

Synthesis And Applications Of Imidazolium-Based Ionic Liquids And Their Polymer Derivatives, Woon Su Oh

Doctoral Dissertations

"Imidazolium-based ionic liquids have been increasingly used as green solvents to replace the volatile and relatively toxic organic solvents, in homogeneous and heterogeneous catalysis, materials science, nano materials, lithium ion batteries, and separation technology. Section 1 describes the modulating effect of the imidazolium based room temperature ionic liquids (RTILs) on the critical micelle concentrations (CMC) of surfactants. CMC of sodium dodecyl sulfate (SDS), an anionic surfactant, has been investigated in aqueous solutions of a variety of room temperature ionic liquids (RTILs). CMC values decrease with increasing alkyl chain-length and with fluorinated side chains on the imidazole moiety. In section 2, …

Electrodeposition And Electrochemical Reduction Of Epitaxial Metal Oxide Thin Films And Superlattices, Zhen He

Doctoral Dissertations

"The focus of this dissertation is the electrodeposition and electrochemical reduction of epitaxial metal oxide thin films and superlattices. The electrochemical reduction of metal oxides to metals has been studied for decades as an alternative to pyrometallurgical processes for the metallurgy industry. However, the previous work was conducted on bulk polycrystalline metal oxides. Paper I in this dissertation shows that epitaxial face-centered cubic magnetite (Fe₃O₄) thin films can be electrochemically reduced to epitaxial body-centered cubic iron (Fe) thin films in aqueous solution on single-crystalline Au substrates at room temperature. This technique opens new possibilities to produce special epitaxial metal/metal oxide …

Lifetime Prediction And Confidence Bounds In Accelerated Degradation Testing For Lognormal Response Distributions With An Arrhenius Rate Relationship, Steven Michael Alferink

Doctoral Dissertations

"Determining the lifetime of a product is an important component of quality assurance. Traditional life testing methods are infeasible for products that have been designed to have a very long lifetime because they require a lengthy testing period. An alternative method is accelerated degradation testing, where a response variable determining the usability of the product is measured over time under multiple accelerating stress levels. The resulting data are then used to predict the life distribution of the product under the design stress level. In this dissertation, several methods are proposed and studied for obtaining prediction bounds for the lifetime of …

Sieve Bootstrap Based Prediction Intervals And Unit Root Tests For Time Series, Maduka Rupasinghe

Doctoral Dissertations

"The application of the sieve bootstrap procedure, which resamples residuals obtained by fitting a finite autoregressvie (AR) approximation to empirical time series, to obtaining prediction intervals for integrated, long-memory, and seasonal time series as well as constructing a test for seasonal unit roots, is considered. The advantage of this resampling method is that it does not require knowledge about the underlying process generating a given time series and has been shown to work well for ARMA processes. We extend the application of the sieve bootstrap to ARIMA and FARIMA processes. The asymptotic properties of the sieve bootstrap prediction intervals for …

Small Sample Inference For Exponential Survival Times With Heavy Right-Censoring, Noroharivelo Volaniaina Randrianampy

Doctoral Dissertations

"We develop a saddlepoint-based method and several generalized Bartholomew methods for generating confidence intervals about the rate parameter of an exponential distribution in the presence of heavy random right-censoring. Butler's conditional moment generating function formula is used to derive the relevant moment generating function for the rate parameter score function which provides access to a saddlepoint-based bootstrap method. Moment generating functions also play a key role in the generalized Bartholomew methods we develop. Since heavy censoring is assumed, the possible non-existence of the rate parameter maximum likelihood estimate (MLE) is nonignorable. The overwhelming majority of existing methods condition upon the …

The Effects Of Hydrologic Modifications On Floodplain Forest Tree Recruitment And Growth In The Mississippi River Alluvial Valley, Usa, Hugo Gee

LSU Doctoral Dissertations

Floodplains forests are productive and diverse ecosystems characterized by frequent riverine flooding. Levees and dams have eliminated or altered riverine flooding which can potentially affect floodplain tree recruitment and growth. Increased light availability from canopy disturbances may increase photosynthesis given sufficient soil moisture, but information on the combined effect of canopy disturbances and hydrologic modifications on tree recruitment and growth is lacking. I used dendrochronological techniques to reconstruct tree recruitment, growth (Quercus lyrata, Fraxinus pennsylvanica), and canopy disturbance patterns over a 90-year period at several floodplains in the Mississippi River Alluvial Valley, USA: an unleveed site below dams and two …

Poverty Shelf, New Zealand From The Holocene To Present: Stratigraphic Development And Event Layer Preservation In Response To Sediment Supply, Tectonics And Climate, Lila Eve Rose Pierce

Dissertations, Theses, and Masters Projects

The small, high sediment yield Waipaoa River is located on the tectonically active, mountainous Poverty Margin on the east coast of the North Island, New Zealand. In contrast to sedimentary sequences on passive margin shelves, active margins, such as the Poverty Margin, can preserve continuous records of changing geological and environmental conditions at the land-sea interface during rapid sea-level rise. Two subsiding mid-shelf basins on the Poverty Shelf contain thick transgressive sequences which provide a record of evolving river, climate, landscape, and oceanographic conditions since the Last Glacial Maximum (LGM). This dissertation investigates the stratigraphic development of Poverty Shelf, including …

A Study Of Vertical Patterns And Mechanisms Of Along-Channel Estuarine Circulation, Qubin. Qin

Dissertations, Theses, and Masters Projects

The classical theory of estuarine dynamics has been challenged by a number of recent studies regarding the important contributions of tidal, lateral, and Coriolis effects to the subtidal dynamics at leading order. Although the classical theory excluded these processes, Hansen and Rattray’ ( R65) b subtidal circulation. However, the success of the predictive skill is not well understood. In this thesis, a perturbation approach is introduced to derive a “ ” (GS) of subtidal along-channel velocity profile for estuarine circulation incorporating the effects of tidal and lateral processes, which allows us to evaluate the possible circulation patterns, the underlying mechanisms, …

The Consequences Of Shoreline Development For Near-Shore Communities In Chesapeake Bay, Usa: A Before-After Control-Impact Study, Theresa M. Davenport

Dissertations, Theses, and Masters Projects

Hardened shorelines and their construction introduce stressors to a system by altering near-shore habitats. They can reduce biodiversity and abundance of benthic infauna and marsh-edge nekton and epifauna. In this study, I investigated the impacts of shoreline development on near-shore communities using a temporal and spatial approach, by use of a before-after control-impact (BACI) study design at four sub-estuaries within Chesapeake Bay that represent three different types of shoreline change. The BACI study was used to examine infaunal density, biomass, and diversity for two size classes of infauna (3-mm: larger species and adults, 500-!m: smaller species and juveniles), as well …

Transport And Fate Of Sediment On The Waipaoa River Continental Shelf: Implications For The Formation And Reworking Of Flood Deposits, Julia M. Moriarty

Dissertations, Theses, and Masters Projects

As part of a large interdisciplinary study, particulate fluxes in the Waipaoa River sedimentary system in New Zealand have been studied from the terrestrial headlands of the catchment to the oceanic basin over timescales spanning storm events, seasons, and the Holocene. Here, we complement prior efforts by evaluating the formation and reworking of riverine deposits during episodic flood and wave events, and considering their role in accumulation patterns created over longer timescales on the Waipaoa shelf. Using a numerical hydrodynamic and sediment transport model, sediment fluxes and deposition were analyzed from January 2010 through February 2011.

A version of the …

Microzooplankton Community Structure And Grazing Impact Along The Western Antarctic Peninsula, Lori M. Price

Dissertations, Theses, and Masters Projects

Microzooplankton (zooplankton 20 – 200 μm) are an integral part of aquatic food webs as they can be significant grazers of phytoplankton and bacteria, remineralizers of nutrients, and prey for higher trophic levels. The importance of microzooplankton in many pelagic ecosystems has been established, yet compared to larger zooplankton, microzooplankton are understudied in the Southern Ocean. I quantified microzooplankton community composition and grazing rates along the Western Antarctic Peninsula (WAP) as part of the Palmer Antarctica Long-Term Ecological Research project (PAL LTER). This region is experiencing rapid warming, causing declines in sea ice and changes in the marine food web. …

Effects Of Life History And Physical Variables On Winter Distribution Of Blue Crabs In Chesapeake Bay, Gabrielle G. Saluta

Dissertations, Theses, and Masters Projects

No abstract provided.

Would Predatory Drillhole Frequency On Chione Spp. Increase Under The Suggested Climate Change Scenario? Comparing Pleistocene And Modern Rhodolith Beds, Carlos E. Cintra-Buenrostro

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

The analysis of predatory drillholes allow paleontologists to reconstruct trophic relationships of ancient systems. To evaluate the potential effects of climate and sea level change on predation frequency by gastropods on bivalves, species of the genus Chione from the Gulf of California were selected because they are a commercially exploited resource - at least locally - and abundant in both modern and Pleistocene (sea level high stand of oxygen substage 5e) samples from rhodolith beds. The present study focused to answer a practical question: would predation on Chione spp. increase under the suggested climate - warming - change scenario? A …

Differences In Immune Defense Evasion Of Selected Inbred Lines Of Heterorhabditis Bacteriophora In Two White Grub Species, Ruisheng An, Marcio Voss, Ganpati B. Jagdale, Parwinder Grewal

School of Earth, Environmental, and Marine Sciences Faculty Publications and Presentations

We determined virulence of seven Heterorhabditis bacteriophora strain GPS11 inbred lines possessing superior infective juvenile longevity, and heat and ultra violet radiation tolerance against white grubs Popillia japonica and Cyclocephala borealis. At 1 and 2 weeks after treatment, inbred line A2 was significantly more virulent towards P. japonica compared to the parent strain GPS11 and inbred lines A7, A8, A12 and A21; and line A2 caused significantly higher C. borealis mortality than lines A6 and A12. Penetration, encapsulation and survival of two inbred lines, A2 and A12, that showed the highest and lowest virulence against both grub species were then …

Analysis And Synthesis Of Metadata Goals For Scientific Data, Craig Willis, Jane Greenberg, Hollie C. White

Faculty Scholarship

The proliferation of discipline-specific metadata schemes contributes to artificial barriers that can impede interdisciplinary and transdisciplinary research. The authors considered this problem by examining the domains, objectives, and architectures of nine metadata schemes used to document scientific data in the physical, life, and social sciences. They used a mixed-methods content analysis and Greenberg’s (2005) metadata objectives, principles, domains, and architectural layout (MODAL) framework, and derived 22 metadata-related goals from textual content describing each metadata scheme. Relationships are identified between the domains (e.g., scientific discipline and type of data) and the categories of scheme objectives. For each strong correlation …

The Hyperboloid Model Of Hyperbolic Geometry, Zachery S. Lane Solheim

EWU Masters Thesis Collection

"The main goal of this thesis is to introduce and develop the hyperboloid model of Hyperbolic Geometry. In order to do that, some time is spent on Neutral Geometry as well as Euclidean Geometry; these are used to build several models of Hyperbolic Geometry. At this point the hyperboloid model is introduced, related to the other models visited, and developed using some concepts from physics as aids. After the development of the hyperboloid model, Fuchsian groups are briefly discussed and the more familiar models of Hyperbolic Geometry are further investigated"--Document.

Windows Security Sandbox Framework, Kyle P. Gwinnup

EWU Masters Thesis Collection

"Software systems are vulnerable to attack in many different ways. Systems can be poorly implemented which could allow an attacker access to the system through legitimate means such as anonymous access to a server or security controls and access lists can be configured incorrectly which would allow an attacker access to the system by exploiting a logic flaw in the systems configuration. These security vulnerabilities can be limited by implementing software systems properly or in a more restrictive manner. Sandboxing an application allows for interception of a processes system call for verification against a defined policy. A system call can …

Geometry Of Partial Differential Equations, Paul Bracken

School of Mathematical and Statistical Sciences Faculty Publications and Presentations

The study of partial differential equations has been the object of much investigation and seen a great many advances recently. This is primarily due to the fact that certain classes of these equations fall under the category of being integrable. These kinds of equations have many useful properties such as the existence of Lax pairs, Backlund transformations, explicit solutions and the existence of a correspondence with geometric manifolds. There have also been many applications of solutions to these equations in the study of solitons and other objects which have seen applications in physics. It is the objective here to study …

Stability Indices For Constrained Self-Adjoint Operators, Todd Kapitula, Keith Promislow

University Faculty Publications and Creative Works

A wide class of problems in the study of the spectral and orbital stability of dispersive waves in Hamiltonian systems can be reduced to understanding the so-called "energy spectrum", that is, the spectrum of the second variation of the Hamiltonian evaluated at the wave shape, which is constrained to act on a closed subspace of the underlying Hilbert space. We present a substantially simplified proof of the negative eigenvalue count for such constrained, self-adjoint operators, and extend the result to include an analysis of the location of the point spectra of the constrained operator relative to that of the unconstrained …

Observation Of A Narrow Structure In 1H(Ykso)X Via Interference With Φ-Meson Production, M. J. Amaryan, G. Gavalian, C. Nepali, M. V. Polyakov, W. J. Briscoe, G. E. Dodge, C. E. Hyde, F. Klein, V. Kuznetsov, I. Strakovsky, J. Zhang

Physics Faculty Publications

We report observation of a narrow peak structure at ~1.54 GeV with a Gaussian width σ = 6 MeV in the missing mass of K_S in the reaction γ+p → pK_SK_L. The observed structure may be due to the interference between a strange (or antistrange) baryon resonance in the pK_L system and the φ(K_SK_L) photoproduction leading to the same final state. The statistical significance of the observed excess of events estimated as the log-likelihood ratio of the resonant signal + background hypothesis and the φ-production-based background-only hypothesis …

3,3-Dimethyl-1,2,3,4-Tetra­Hydro­Cyclo­Penta­[B]Indole-1,2-Dione (Bruceolline E), Jason A. Jordon, Jeanese C. Badenock, Gordon W. Gribble, Jerry P. Jasinski, James A. Golen

Dartmouth Scholarship

The title compound, C13H11NO2, crystallizes with two mol­ecules in the asymmetric unit. The crystal packing is stabilized by N—H⋯O hydrogen bonds, which link the mol­ecules into chains along [10], and weak C—H⋯O inter­actions.

Using Participatory Scenarios To Stimulate Social Learning For Collaborative Sustainable Development, Kris A. Johnson, Genya Dana, Nicholas R. Jordan, Kathy J. Draeger, Anne Kapuscinski

Dartmouth Scholarship

Interdependent human and biophysical systems are highly complex and behave in unpredictable and uncontrollable ways. Social and ecological challenges that emerge from this complexity often defy straightforward solutions, and efforts to address these problems will require not only scientific and technological capabilities but also learning and adaptation. Scenarios are a useful tool for grappling with the uncertainty and complexity of social-ecological challenges because they enable participants to build adaptive capacity through the contemplation of multiple future possibilities. Furthermore, scenarios provide a platform for social learning, which is critical to acting in the face of uncertain, complex, and conflict-laden problems. We …

The Impact Of Sprawl On Transportation Energy Copnsumption And Transportation Carbon Footprint In Large U.S. Cities, Leila Ahmadi

Earth & Environmental Sciences Dissertations

Today, climate change and energy shortage are major concerns among scientists, politicians, and economists. For decades in the U.S., emphasis has been placed on improving energy efficiency through technological advances. However, most of these technologies are in the initial phases of development, while energy consumption continues to increase at a rapid pace. In order to solve this dilemma, there is a need to develop a faster and more effective approach for controlling the rates of energy consumption and demand. Transportation consumes more energy than other energy-dependent activities, such as those in the industrial, residential, and commercial sectors of the economy. …

On-Road Measurement Of Nox And Co₂ Emissions From Biodiesel Produced From Different Feedstocks, Natchanok Pala-En

Earth & Environmental Sciences Dissertations

Biodiesel has generated increased interest in the US and elsewhere recently as an alternative to petroleum-derived diesel. Because it can be produced from domestic feedstocks such as soybeans, canola oil, and even recycled cooking oil, biodiesel can help reduce dependence on foreign petroleum. Due to its high oxygen content, biodiesel typically burns more completely than petroleum diesel, and thus has lower emissions of hydrocarbons (HC), carbon monoxide (CO), and particulate matter (PM). However, biodiesel may increase or decrease nitrogen oxide (NOx) and carbon dioxide (CO₂) emissions, depending on engine type, test cycle, and biodiesel feedstock. Therefore, the purpose of this …

Evaluating The Demand For Soft Skills In Software Development, Faheem Ahmed, Luiz Fernando Capretz, Piers Campbell

Electrical and Computer Engineering Publications

An analysis of 500 advertisements for IT positions focuses on the soft skills mentioned in the ads, revealing which soft skills are in high demand for software development and which ones are neglected despite their importance.

Alternatives To Mixture Model Analysis Of Correlated Binomial Data, N. Rao Chaganty, Roy Sabo, Yihao Deng

Mathematics & Statistics Faculty Publications

While univariate instances of binomial data are readily handled with generalized linear models, cases of multivariate or repeated measure binomial data are complicated by the possibility of correlated responses. Likelihood-based estimation can be applied by using mixture distribution models, though this approach can present computational challenges. The logistic transformation can be used to bypass these concerns and allow for alternative estimating procedures. One popular alternative is the generalized estimating equation (GEE) method, though systematic errors can lead to infeasible correlation estimates or nonconvergence problems. Our approach is the coupling of quasileast squares (QLSs) method with a rarely used matrix factorization, …

Wavelet Collocation Method And Multilevel Augmentation Method For Hammerstein Equations, Hideaki Kaneko, Khomsan Neamprem, Boriboon Novaprateep

Mathematics & Statistics Faculty Publications

No abstract provided.

Beefmoves: Dissemination, Diversity, And Dynamics Of English Borrowings In A German Hip Hop Forum, Matt Garley, Julia Hockenmaier

Publications and Research

We investigate how novel English-derived words (anglicisms) are used in a German-language Internet hip hop forum, and what factors contribute to their uptake.

On Primitivity And Dimension Of Finite Semifields And Their Planes, Linlin Chen

Mathematics Dissertations

The study of semifields was originated by L.E. Dickson in 1905 and was greatly developed in the 1960s by Albert, Knuth, Walker, Kleinfeld among others. Two problems of interest in this area are the primitivity of semifields and the dimension of semifields.For the first problem, we provide an equivalent condition for the right (or left) primitivity of finite semifields and with this result, we find that the classical Knuth binary semifields of order 2^{15}, 2^{17} and 2^{19} are all right and left primitive; the Albert semifields of order 2^i, where i=7, 9, 11, 13 are all primitive. Also we prove …

Resolutions And Tor Algebra Structures For Trivariate Monomial Ideals, Jared Lafayette Painter

Mathematics Dissertations

In this manuscript we explore properties of minimal free resolutions and their relationship to the Tor-algebra structure for trivariate monomial ideals. We begin with an in-depth analysis of minimal free resolutions of S = R / I, where R = k[x; y; z] is a polynomial ring over a field k, and I is a monomial ideal that is primary to the homogeneous maximal ideal m of R. We will de ne a special form of the minimal free resolution of S, and then determine when we get nonzero elements from I as entries in the matrices of the resolution. …