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2017

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Articles 1111 - 1140 of 12521

Full-Text Articles in Physical Sciences and Mathematics

Improving Service Level Of Free-Floating Bike Sharing Systems, Aritra Pal Nov 2017

Improving Service Level Of Free-Floating Bike Sharing Systems, Aritra Pal

USF Tampa Graduate Theses and Dissertations

Bike Sharing is a sustainable mode of urban mobility, not only for regular commuters but also for casual users and tourists. Free-floating bike sharing (FFBS) is an innovative bike sharing model, which saves on start-up cost, prevents bike theft, and offers significant opportunities for smart management by tracking bikes in real-time with built-in GPS. Efficient management of a FFBS requires: 1) analyzing its mobility patterns and spatio-temporal imbalance of supply and demand of bikes, 2) developing strategies to mitigate such imbalances, and 3) understanding the causes of a bike getting damaged and developing strategies to minimize them. All of these …


Statistical Analysis And Modeling Of Stomach Cancer Data, Chao Gao Nov 2017

Statistical Analysis And Modeling Of Stomach Cancer Data, Chao Gao

USF Tampa Graduate Theses and Dissertations

The objective of this study is to address some important questions associated with stomach cancer patients using the data from the Surveillance Epidemiology and End Results (SEER) program of the United States. To better understand the behavior of stomach cancer, we first perform parametric analysis for each patient group (white male, white female, African American male, African American female, other male and female) to identify the probability distribution function which can best characterize the behavior of the malignant stomach tumor sizes. We evaluate the effects of patients’ age, gender and race on the malignant stomach tumor sizes by developing quantile …


Ncer Assistance Agreement Annual Progress Report For Grant #83582401 - Assessment Of Stormwater Harvesting Via Manage Aquifer Recharge (Mar) To Develop New Water Supplies In The Arid West: The Salt Lake Valley Example, Ryan Dupont, Joan E. Mclean, Richard C. Peralta, Sarah E. Null, Douglas B. Jackson-Smith Nov 2017

Ncer Assistance Agreement Annual Progress Report For Grant #83582401 - Assessment Of Stormwater Harvesting Via Manage Aquifer Recharge (Mar) To Develop New Water Supplies In The Arid West: The Salt Lake Valley Example, Ryan Dupont, Joan E. Mclean, Richard C. Peralta, Sarah E. Null, Douglas B. Jackson-Smith

Civil and Environmental Engineering Faculty Publications

The aims of the original proposed project remain the same, that is, to test the hypothesis that Managed Aquifer Recharge (MAR) for stormwater harvesting is a technically feasible, socially and environmentally acceptable, economically viable, and legally feasible option for developing new water supplies for arid Western urban ecosystems experiencing increasing population, and climate change pressures on existing water resources. The project is being carried out via three distinct but integrated components that include: 1) Monitoring of existing distributed MAR harvesting schemes involving a growing number of demonstration Green Infrastructure (GI) test sites; 2) Integrated stormwater/vadose zone/groundwater/ ecosystem services modeling; and …


A Brief Overview Of Intelligent Mobility Management For Future Wireless Mobile Networks, Ilsun You, Yuh-Shyan Chen, Sherali Zeadally, Fei Song Nov 2017

A Brief Overview Of Intelligent Mobility Management For Future Wireless Mobile Networks, Ilsun You, Yuh-Shyan Chen, Sherali Zeadally, Fei Song

Information Science Faculty Publications

No abstract provided.


Evidence Of Subglacial Brine Inflow And Wind-Induced Mixing From High Resolution Temperature Measurements In Lake Bonney, Antarctica, Jade Lawrence Nov 2017

Evidence Of Subglacial Brine Inflow And Wind-Induced Mixing From High Resolution Temperature Measurements In Lake Bonney, Antarctica, Jade Lawrence

LSU Master's Theses

Hypersaline brine beneath Taylor Glacier enters proglacial West Lobe Lake Bonney (WLB) subglacially as well as from Blood Falls, a surface discharge point at the Taylor Glacier terminus. The brine strongly influences the water column of WLB. Because of the extremely high salinities below the chemocline in WLB, density is determined almost entirely by salinity and temperature can be used as a passive tracer. Cold brine intrusions enter WLB at the glacier face and intrude in to the water column at the depth of neutral buoyancy, where they can be identified by anomalously cold temperatures at that depth. This study …


Construction Of Synthetic Signal Pathways In Mammalian Cells Via Induced Protein Proximity, Guihua Zeng Nov 2017

Construction Of Synthetic Signal Pathways In Mammalian Cells Via Induced Protein Proximity, Guihua Zeng

Chemistry and Chemical Biology ETDs

Cell signaling translates extracellular signals into intracellular processes that carry out cellular functions. The introduction of artificial signaling networks using synthetic biology methods has facilitated the investigation of signaling mechanisms and the generation of novel cell functions. Several synthetic biology methods that are based on chemical controls have been developed to provide precise temporal regulation. In my dissertation, we constructed new synthetic biology engineering strategies to control tailored cellular events.

Described in Chapter 2, we developed a new chemical strategy to generate de novo signaling pathways that link a signaling molecule, H2O2, to different downstream cellular …


High Throughput Petrochronology And Sedimentary Provenance Analysis By Automated Phase Mapping And Laicpms, Pieter Vermeesch, Martin Rittner, Ethan Petrou, Jenny Omma, Chris Mattinson, Eduardo Garzanti Nov 2017

High Throughput Petrochronology And Sedimentary Provenance Analysis By Automated Phase Mapping And Laicpms, Pieter Vermeesch, Martin Rittner, Ethan Petrou, Jenny Omma, Chris Mattinson, Eduardo Garzanti

All Faculty Scholarship for the College of the Sciences

The first step in most geochronological studies is to extract dateable minerals from the host rock, which is time consuming, removes textural context, and increases the chance for sample cross contamination. We here present a new method to rapidly perform in situ analyses by coupling a fast scanning electron microscope (SEM) with Energy Dispersive X-ray Spectrometer (EDS) to a Laser Ablation Inductively Coupled Plasma Mass Spectrometer (LAICPMS) instrument. Given a polished hand specimen, a petrographic thin section, or a grain mount, Automated Phase Mapping (APM) by SEM/EDS produces chemical and mineralogical maps from which the X-Y coordinates of the datable …


Reduced Graphene Oxide On Nickel Foam For Supercapacitor Electrodes, Uma Ramabadran, Gillian Ryan, Xuan Zhou, Susan Farhat, Felicia Manciu, Yigang Tong, Ryan Ayler, Graham Garner Nov 2017

Reduced Graphene Oxide On Nickel Foam For Supercapacitor Electrodes, Uma Ramabadran, Gillian Ryan, Xuan Zhou, Susan Farhat, Felicia Manciu, Yigang Tong, Ryan Ayler, Graham Garner

Physics Publications

The focus of this paper is the investigation of reduced graphene oxide (GO)/nickel foam (RGON) samples for use as supercapacitor electrodes. Nickel foam samples were soaked in a GO suspension and dried before being subjected to two different methods to remove oxygen. Atmospheric pressure annealed (APA) samples were treated with a varying number (10–18) of nitrogen plasma jet scans, where sample temperatures did not exceed 280 °C. Furnace annealed (FA) samples were processed in an atmosphere of hydrogen and argon, at temperatures ranging from 600 °C to 900 °C. Environmental Scanning Electron Microscope (ESEM) data indicated that …


Nanopatterns Of Zinc Phthalocyanines, Gold Nanoparticles, And Porphyrins Prepared Using Particle Lithography: Characterization Of Patterning Steps With Scanning Probe Microscopy, Ashley Marie Taylor Nov 2017

Nanopatterns Of Zinc Phthalocyanines, Gold Nanoparticles, And Porphyrins Prepared Using Particle Lithography: Characterization Of Patterning Steps With Scanning Probe Microscopy, Ashley Marie Taylor

LSU Doctoral Dissertations

The growth and self-assembly of molecules on surfaces can be directly visualized at the molecular level using studies which combine nanoscale lithography and high-resolution imaging. Nanopatterning provides a unique and practical approach for direct views of surface changes after the key chemical steps of nanopatterning, providing landmarks and baselines for measuring growth in vertical and lateral dimensions. Controlling the arrangement of materials on surfaces at the nanoscale can be achieved using particle lithography. Arrays of well-defined nanostructures can be prepared with reproducible geometries and arrangement. Results for the preparation of nanopatterns produced with particle lithography are presented using high resolution …


Ion-Scale Wave Properties And Enhanced Ion Heating Across The Low-Latitude Boundary Layer During Kelvin-Helmholtz Instability, T. W. Moore, K. Nykyri, A. P. Dimmock Nov 2017

Ion-Scale Wave Properties And Enhanced Ion Heating Across The Low-Latitude Boundary Layer During Kelvin-Helmholtz Instability, T. W. Moore, K. Nykyri, A. P. Dimmock

Publications

In the Earth's magnetosphere, the magnetotail plasma sheet ions are much hotter than in the shocked solar wind. On the dawn sector, the cold-component ions are more abundant and hotter by 30–40% when compared to the dusk sector. Recent statistical studies of the flank magnetopause and magnetosheath have shown that the level of temperature asymmetry of the magnetosheath is unable to account for this, so additional physical mechanisms must be at play, either at the magnetopause or plasma sheet that contributes to this asymmetry. In this study, we perform a statistical analysis on the ion-scale wave properties in the three …


Epitaxial Thin Films Of Dirac Semimetal Antiperovskite Cu3Pdn, C. X. Quintela, N. Campbell, D. F. Shao, J. Irwin, D. T. Harris, L. Lie, T. J. Anderson, N. Reiser, X. Q. Pan, Evgeny Y. Tsymbal, M. S. Rzchowski, C B. Eom Nov 2017

Epitaxial Thin Films Of Dirac Semimetal Antiperovskite Cu3Pdn, C. X. Quintela, N. Campbell, D. F. Shao, J. Irwin, D. T. Harris, L. Lie, T. J. Anderson, N. Reiser, X. Q. Pan, Evgeny Y. Tsymbal, M. S. Rzchowski, C B. Eom

Evgeny Tsymbal Publications

The growth and study of materials showing novel topological states of matter is one of the frontiers in condensed matter physics. Among this class of materials, the nitride antiperovskite Cu3PdN has been proposed as a new three-dimensional Dirac semimetal. However, the experimental realization of Cu3PdN and the consequent study of its electronic properties have been hindered due to the difficulty of synthesizing this material. In this study, we report fabrication and both structural and transport characterization of epitaxial Cu3PdN thin films grown on (001)-oriented SrTiO3 substrates by reactive magnetron sputtering and post-annealed in …


Floodplain Impacts On Water Quality: A Case Study In Southern Louisiana, Emily Delduco Nov 2017

Floodplain Impacts On Water Quality: A Case Study In Southern Louisiana, Emily Delduco

LSU Master's Theses

The quantity and quality of dissolved carbon delivered to coastal margins by rivers is an important component of global carbon cycling. The Atchafalaya River (AR) discharges ~25% of the flow of the Mississippi River (MR) and the total flow of the Red River (RR) into the Gulf of Mexico (GoM) annually while flowing through the largest bottomland swamp in North America. This provides a unique opportunity to study floodplain impacts on dissolved carbon processes in a large river system. The research aimed to: (1) determine DIC and DOC transport and processing by a river swamp basin under varied seasons and …


Evolution And Rationale For United States Department Of Defense Electromagnetic Pulse Protection Standard, George H. Baker Iii Nov 2017

Evolution And Rationale For United States Department Of Defense Electromagnetic Pulse Protection Standard, George H. Baker Iii

George H Baker

The United States (US) Department of Defense (DoD) Electromagnetic Pulse (EMP) protection standard offers a solid basis for protecting commercial communication, data, and control facilities. Because of the standard’s shielded barrier and test requirements, it is not surprising that there is a strong temptation within industry and government to dismiss the MIL-STD 188-125 approach in favor of less rigorous protection methods. It is important to understand that US DoD EMP protection standard for fixed facilities, MIL-STD-188-125, reflects an evolution by trial and error that spanned a period of decades beginning with the acquisition of the Minuteman Missile System in the …


Proposal For A Dod Combined Battlefield Electromagnetic Environmental Effects (E3) Initiative, George H. Baker Iii Nov 2017

Proposal For A Dod Combined Battlefield Electromagnetic Environmental Effects (E3) Initiative, George H. Baker Iii

George H Baker

The presentation emphasizes the growing importance of electromagnetic survivability and compatibility. Operation Desert Storm demonstrated the clear military advantage provided by sophisticated electronic weapon and communication systems. In addition, the offensive tactic of taking out the enemy's eyes and ears during the air war paid off, giving our military decisive air superiority. The lessons for the future are clear. High-tech electronics now so dominates the battlefield that the outcome of future conflicts could well be decided by electronics attrition rather than human casualties. Our Desert Storm experience thus accentuates the importance of guaranteeing that our electronic systems will not be …


The Firece Green Fire: Vol. 8 Issue 9, Wofford College Environmental Studies Program Nov 2017

The Firece Green Fire: Vol. 8 Issue 9, Wofford College Environmental Studies Program

The Fierce Green Fire

No abstract provided.


Empirical Modeling Of Planetary Boundary Layer Dynamics Under Multiple Precipitation Scenarios Using A Two-Layer Soil Moisture Approach: An Example From A Semiarid Shrubland, Zulia Mayari Sanchez-Mejia, Shirley A. Papuga Nov 2017

Empirical Modeling Of Planetary Boundary Layer Dynamics Under Multiple Precipitation Scenarios Using A Two-Layer Soil Moisture Approach: An Example From A Semiarid Shrubland, Zulia Mayari Sanchez-Mejia, Shirley A. Papuga

Environmental Science and Geology Faculty Research Publications

In semiarid regions, where water resources are limited and precipitation dynamics are changing, understanding land surface-atmosphere interactions that regulate the coupled soil moistureprecipitation system is key for resource management and planning. We present a modeling approach to study soil moisture and albedo controls on planetary boundary layer height (PBLh). We used Santa Rita Creosote Ameriflux and Tucson Airport atmospheric sounding data to generate empirical relationships between soil moisture, albedo, and PBLh. Empirical relationships showed that ~50% of the variation in PBLh can be explained by soil moisture and albedo with additional knowledge gained by …


Issues Related To Carbon Dioxide Pipeline Transportation Infrastructure In Louisiana, Michael Allen Layne Iii Nov 2017

Issues Related To Carbon Dioxide Pipeline Transportation Infrastructure In Louisiana, Michael Allen Layne Iii

LSU Master's Theses

There is no single solution to mitigate anthropogenic climate change; a multifaceted approach with economic incentives is needed. Carbon dioxide (CO2) enhanced oil recovery (EOR) is one such solution which provides an economic incentive, in the capture and sale of oil, for sequestering CO2 underground. While carbon capture and subsequent geological injection are both mature technologies, there has been little discussion or appreciation for the role of pipelines. The current CO2 pipeline infrastructure will need to significantly expand in order to accommodate increasing EOR production. However, pipeline construction costs, and institutional factors impacting development, may be …


Superconducting Thin Films For The Enhancement Of Superconducting Radio Frequency Accelerator Cavities, Matthew Burton Nov 2017

Superconducting Thin Films For The Enhancement Of Superconducting Radio Frequency Accelerator Cavities, Matthew Burton

Dissertations, Theses, and Masters Projects

Bulk niobium (Nb) superconducting radio frequency (SRF) cavities are currently the preferred method for acceleration of charged particles at accelerating facilities around the world. However, bulk Nb cavities have poor thermal conductance, impose material and design restrictions on other components of a particle accelerator, have low reproducibility and are approaching the fundamental material-dependent accelerating field limit of approximately 50MV/m. Since the SRF phenomena occurs at surfaces within a shallow depth of ~1 µm, a proposed solution to this problem has been to utilize thin film technology to deposit superconducting thin films on the interior of cavities to engineer the active …


Proposed Method For Measuring The Let Of Radiotherapeutic Particle Beams, Stephen D. Bello Nov 2017

Proposed Method For Measuring The Let Of Radiotherapeutic Particle Beams, Stephen D. Bello

Physics & Astronomy ETDs

The Bragg peak geometry of the depth dose distributions for hadrons allows for precise and effective dose delivery to tumors while sparing neighboring healthy tissue. Further, compared against other forms of radiotherapeutic treatments, such as electron beam therapy (EBT) or photons (x and \(\gamma\)-rays), hadrons create denser ionization events along the particle track, which induces irreparable damage to DNA, and thus are more effective at inactivating cancerous cells. The measurement of radiation's ability to inactivate cellular reproduction is the relative biological effectiveness (RBE). A quality related to the RBE that is a measurable physical property is the linear energy transfer …


Discovery Of Very-High-Energy Emission From Rgb J2243+203 And Derivation Of Its Redshift Upper Limit, P. T. Reynolds, Et Al Nov 2017

Discovery Of Very-High-Energy Emission From Rgb J2243+203 And Derivation Of Its Redshift Upper Limit, P. T. Reynolds, Et Al

Physical Sciences Publications

Very-high-energy (VHE; > 100 GeV) gamma-ray emission from the blazar RGB J2243+203 was discovered with the VERITAS Cherenkov telescope array, during the period between 2014 December 21 and 24. The VERITAS energy spectrum from this source can be fitted by a power law with a photon index of 4.6 ± 0.5, and a flux normalization at 0.15 TeV of . The integrated Fermi-LAT flux from 1 to 100 GeV during the VERITAS detection is , which is an order of magnitude larger than the four-year-averaged flux in the same energy range reported in the 3FGL catalog, (). The detection with …


The Cosm Aggregate, Georgia Southern University Nov 2017

The Cosm Aggregate, Georgia Southern University

COSM Aggregate (2017)

No abstract provided.


The Effects Of Joule Heating On Electric-Driven Microfluidic Flow, Alexander P. Spitzer Nov 2017

The Effects Of Joule Heating On Electric-Driven Microfluidic Flow, Alexander P. Spitzer

Journal of the South Carolina Academy of Science

This study sought out to more clearly understand the relationship between Joule heating and fluid flow in microfluidic environments, and more specifically, under what circumstances would the fluid flow in the device possibly hinder an experiment being run on it. It had been previous theorised that an electric field may produce turbulence and even vortices within the fluid, which this study attempted to reproduce. Several variables were tested, namely insulating and conducting fluids, higher and lower AC voltages, Newtonian vs. non-Newtonian fluids, and higher and lower DC voltages. A correlation between these variables and turbulent flow was found, with more …


Bikemate: Bike Riding Behavior Monitoring With Smartphones, Weixi Gu, Zimu Zhou, Yuxun Zhou, Han Zou, Yunxin Liu, Costas J. Spanos, Lin Zhang Nov 2017

Bikemate: Bike Riding Behavior Monitoring With Smartphones, Weixi Gu, Zimu Zhou, Yuxun Zhou, Han Zou, Yunxin Liu, Costas J. Spanos, Lin Zhang

Research Collection School Of Computing and Information Systems

Detecting dangerous riding behaviors is of great importance to improve bicycling safety. Existing bike safety precautionary measures rely on dedicated infrastructures that incur high installation costs. In this work, we propose BikeMate, a ubiquitous bicycling behavior monitoring system with smartphones. BikeMate invokes smartphone sensors to infer dangerous riding behaviors including lane weaving, standing pedalling and wrong-way riding. For easy adoption, BikeMate leverages transfer learning to reduce the overhead of training models for different users, and applies crowdsourcing to infer legal riding directions without prior knowledge. Experiments with 12 participants show that BikeMate achieves an overall accuracy of 86.8% for lane …


Interactions Between Amyloid-Beta And Microglial Cells, Lisa Gouwens Nov 2017

Interactions Between Amyloid-Beta And Microglial Cells, Lisa Gouwens

Dissertations

Alzheimer’s disease (AD), the most common cause of dementia, is a neurodegenerative condition characterized by loss of memory and intellectual abilities. Intracellular plaques of aggregated amyloid-beta (Ab) protein are a well-known pathology associated with AD. Although symptoms usually appear late in life, the accumulation of Ab begins decades earlier and causes activation of microglia, the brain’s immune cells. The ensuing inflammation contributes significantly to neurodegeneration. Determination of the particular form of Ab that causes the most damage in the brain is one of the major questions in the AD field. My research focused on the interactions of microglia with monomers, …


Exploiting Power For Smartphone Security And Privacy, Qing Yang Nov 2017

Exploiting Power For Smartphone Security And Privacy, Qing Yang

Dissertations, Theses, and Masters Projects

Power consumption has become a key issue for smartphone security and privacy protection. In this dissertation, we propose to exploit power for smartphone security, as well as to optimize energy consumption for smartphone privacy. First, we show that public USB charging stations pose a significant privacy risk to smartphone users. We present a side-channel attack that allows a charging station to identify which webpages are loaded while the smartphone is charging. to evaluate this side-channel, we collected power traces of Alexa top 50 websites on multiple smartphones under several conditions, including: varied battery charging level, browser cache enabled/disabled, taps/no taps …


First Direct Constraints On Fierz Interference In Free-Neutron Β Decay, Kevin P. Hickerson, Xiaohui Sun, Yelena Bagdasarova, David Bravo-Berguño, Leah J. Broussard, Peter Brown, Richard Carr, Scott Currie, Xinjian Ding, Bradley W. Filippone, Alejandro García, Peter Geltenbort, J. Todd Hoagland, A. T. Holley, Ran Hong, Takeyasu M. Ito, Andreas Knecht, Chao-Yu Liu, Jiang-Lai Liu, Mark Makela, Russell R. Mammei, J. W. Martin, Dan Melconian, Michael P. Mendenhall, Spencer D. Moore, Christopher L. Morris, Robert W. Pattie, A. Pérez Galván, Ruediger Picker, Margaret L. Pitt, Bradley R. Plaster, John C. Ramsey, Roger H. Rios, A. Saunders, Susan J. Seestrom, Eduard I. Sharapov, Walter E. Sondheim, Erdinch Tatar, R. Bruce Vogelaar, Brittney Vorndick, Christopher Wrede, Andrew R. Young, B. A. Zeck Nov 2017

First Direct Constraints On Fierz Interference In Free-Neutron Β Decay, Kevin P. Hickerson, Xiaohui Sun, Yelena Bagdasarova, David Bravo-Berguño, Leah J. Broussard, Peter Brown, Richard Carr, Scott Currie, Xinjian Ding, Bradley W. Filippone, Alejandro García, Peter Geltenbort, J. Todd Hoagland, A. T. Holley, Ran Hong, Takeyasu M. Ito, Andreas Knecht, Chao-Yu Liu, Jiang-Lai Liu, Mark Makela, Russell R. Mammei, J. W. Martin, Dan Melconian, Michael P. Mendenhall, Spencer D. Moore, Christopher L. Morris, Robert W. Pattie, A. Pérez Galván, Ruediger Picker, Margaret L. Pitt, Bradley R. Plaster, John C. Ramsey, Roger H. Rios, A. Saunders, Susan J. Seestrom, Eduard I. Sharapov, Walter E. Sondheim, Erdinch Tatar, R. Bruce Vogelaar, Brittney Vorndick, Christopher Wrede, Andrew R. Young, B. A. Zeck

Robert W. Pattie Jr.

Precision measurements of free-neutron β decay have been used to precisely constrain our understanding of the weak interaction. However, the neutron Fierz interference term bn, which is particularly sensitive to beyond-standard-model tensor currents at the TeV scale, has thus far eluded measurement. Here we report the first direct constraints on this term, finding bn=0.067±0.005stat+0.090−0.061sys, consistent with the standard model. The uncertainty is dominated by absolute energy reconstruction and the linearity of the β spectrometer energy response.


Statistical Modelling, Optimal Strategies And Decisions In Two-Period Economies, Jiang Wu Nov 2017

Statistical Modelling, Optimal Strategies And Decisions In Two-Period Economies, Jiang Wu

Electronic Thesis and Dissertation Repository

Motivated by some real problems, our thesis puts forward two general two-period pricing models and explore optimal buying and selling strategies in two states of the two-period decision, when buyer/seller's decisions in the two periods are uncertain: commodity valuations may or may not be independent, may or may not follow the same distribution, be heavily or just lightly influenced by exogenous economic conditions, and so on. For both the example of buying laptops and the example of selling houses, the connections between each example and the two-envelope paradox encourage us to explore optimal strategies based on the works of McDonnell …


Coordination And Organometallic Chemistry Of Novel Gallium Complexes: Synthesis, Reactivity And Spectroscopy, Jeremy L. Bourque Nov 2017

Coordination And Organometallic Chemistry Of Novel Gallium Complexes: Synthesis, Reactivity And Spectroscopy, Jeremy L. Bourque

Electronic Thesis and Dissertation Repository

The work described in this thesis incorporates three main themes: the synthesis and reactivity of new coordination and organometallic gallium compounds, and the chemical state determination of molecular gallium complexes using XPS and XAS. The coordination chemistry of low valent gallium cations was explored using macrocyclic ethers as ligands. The experimental oxidation number, or chemical state, of newly synthesized low valent gallium cationic complexes was compared to known compounds to allow for the assessment of the electronic environment at gallium. The organometallic chemistry of gallium was examined using donor ligands to stabilize monomeric organogallium(III) compounds, demonstrating the ability to substitute …


Development, Energy, And Climate Change Policy: Enabling Sustainable Development Through Access To Energy, Robert J. Brecha Nov 2017

Development, Energy, And Climate Change Policy: Enabling Sustainable Development Through Access To Energy, Robert J. Brecha

Biennial Conference: The Social Practice of Human Rights

Human rights, human development, and climate change clearly overlap in many ways. Development, as quantified by the Human Development Index (HDI), for example, has historically been strongly correlated with energy consumption. This fact is recognized in Sustainable Development Goal (SDG) 7, to “ensure access to affordable, reliable, sustainable and modern energy for all.” Currently the world is in the midst of a large wave of human migration, much of it involuntary and due to stymied development opportunities as well as political upheaval. Climate change will become, or already is, an exacerbating factor in migration dynamics.

A pertinent question is how …


Gamma-Radiation Induced Corrosion Of Alloy 800, Mojtaba Momeni Nov 2017

Gamma-Radiation Induced Corrosion Of Alloy 800, Mojtaba Momeni

Electronic Thesis and Dissertation Repository

This thesis presents a newly developed mechanism and predictive model for the corrosion of Alloy 800. The Fe-Cr-Ni Alloy (Incoloy 800) is mainly used for steam generator (SG) tubing in CANDU and PWR reactors and is a candidate material for the proposed Canadian Supercritical Water Reactor (SCWR) in which it will be exposed to extreme conditions of high radiation flux and large temperature gradients. The influence of gamma radiation and water chemistry conditions on the corrosion behaviour of Alloy 800 are studied in this work. Ionizing radiation creates reducing (•eaq, •H, •O2-) and oxidizing …