Physical Sciences and Mathematics Commons^™

Harnessing The Synergy Of Fe And Co With Carbon Nanofibers For Enhanced Co, Kevin Arizapana, John Schossig, Michael Wildy, Daniel Weber, Akash Gandotra, Sumedha Jayaraman, Wanying Wei, Kai Xu, Lei Yu, Amos M Mugweru, Islam Mantawy, Cheng Zhang, Ping Lu

College of Science & Mathematics Departmental Research

Amid growing concerns about climate change and energy sustainability, the need to create potent catalysts for the sequestration and conversion of CO2 to value-added chemicals is more critical than ever. This work describes the successful synthesis and profound potential of high-performance nanofiber catalysts, integrating earth-abundant iron (Fe) and cobalt (Co) as well as their alloy counterpart, FeCo, achieved through electrospinning and judicious thermal treatments. Systematic characterization using an array of advanced techniques, including SEM, TGA-DSC, ICP-MS, XRF, EDS, FTIR–ATR, XRD, and Raman spectroscopy, confirmed the integration and homogeneous distribution of Fe/Co elements in nanofibers and provided insights into their catalytic …

Two-Photon Absorption And Fluorescence Of Cadmium Sulfide, Jacob Goranson, Gregory J. Taft

Physics Faculty Publications

The two-photon absorption and fluorescence of bulk cadmium sulfide were studied using 50-fs, 800-nm pulses from an unamplified Ti:sapphire laser. The fluorescence spectrum was measured to have a main peak at 522 nm, and the power of the fluorescence was shown to vary quadratically with the 800-nm beam power. This supports the theory that the fluorescence is excited by two-photon absorption and confirms previous work done with longer duration, higher energy excitation pulses. Pump-probe measurements provided additional confirmation of the two-photon absorption. Measured spectral broadening of the wings of the laser spectrum also was observed, which likely is due to …

Residential Metals Abatement Program Investigation Summary Report (Non-Residential Parcels – Indoor Dust) - Gold Hill Lutheran Church (Creativity Factory Preschool), Environmental Resource Management (Erm)

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Final 2024 Residential Metals Abatement Program (Rmap) Whitehall Borrow Submittal #2, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Emoji Use In Social Media Posts: Relationships With Personality Traits And Word Usage, Shelia Kennison, Kameryn Fritz, Maria Andrea Hurtado Morales, Eric Chan-Tin

Computer Science: Faculty Publications and Other Works

Prior research has demonstrated relationships between personality traits of social media users and the language used in their posts. Few studies have examined whether there are relationships between personality traits of users and how they use emojis in their social media posts. Emojis are digital pictographs used to express ideas and emotions. There are thousands of emojis, which depict faces with expressions, objects, animals, and activities. We conducted a study with two samples (n = 76 and n = 245) in which we examined how emoji use on X (formerly Twitter) related to users’ personality traits and language use …

Maximizing Charge Dynamics In Znin2s4/Cn Van Der Waals Heterojunction For Optimal Hydrogen Production From Photoreforming Of Glucose, Jinqiang Zhang, Xinyuan Xu, Lei Shi, Huayang Zhang, Shaobin Wang, Hongqi Sun

Research outputs 2022 to 2026

Biomass photoreforming stands out as a promising avenue for green hydrogen, leveraging solar energy for the generation and transformation of clean and renewable energy resources. The pursuit of efficient photocatalysts is motivated by the unsatisfied hydrogen evolution performance arising from the complex and stubborn structure of biomass. Herein, we loaded 2-dimensional (2D) ZnIn2S4 onto 2D carbon nitride nanosheets, resulting in the formation of Van der Waals (VDW) heterojunctions (ZIS/CN). Band structure and morphology of CN were rationally tailored through precursor engineering to effectively magnify interfacial internal electric field and minimize diffusion pathway within the VDW heterostructure, realizing optimal charge dynamics …

Unusual Catalytic Strategy By Non-Heme Fe(Ii)/2-Oxoglutarate-Dependent Aspartyl Hydroxylase Asph, Anandhu Krishnan, Sodiq Waheed, Ann Varghese, Fathima Hameed Cherilakkudy, Christopher J. Schofield, Tatyana G. Karabencheva-Christova

Michigan Tech Publications, Part 2

Biocatalytic C-H oxidation reactions are of important synthetic utility, provide a sustainable route for selective synthesis of important organic molecules, and are an integral part of fundamental cell processes. The multidomain non-heme Fe(ii)/2-oxoglutarate (2OG) dependent oxygenase AspH catalyzes stereoselective (3R)-hydroxylation of aspartyl- and asparaginyl-residues. Unusually, compared to other 2OG hydroxylases, crystallography has shown that AspH lacks the carboxylate residue of the characteristic two-His-one-Asp/Glu Fe-binding triad. Instead, AspH has a water molecule that coordinates Fe(ii) in the coordination position usually occupied by the Asp/Glu carboxylate. Molecular dynamics (MD) and quantum mechanics/molecular mechanics (QM/MM) studies reveal that the iron coordinating water is …

Multi-Agent System For Portfolio Profit Optimization For Future Stock Trading, Usha Devi, Mohan R

Karbala International Journal of Modern Science

Stock trading highly contributes to the economic growth of the country. The stock trading objective is to earn profits with buy/sell/hold decisions on the set of stocks in the portfolio. The portfolio optimization problem is finding the decision sequence that leads to higher profit and lower risk. Portfolio optimization is challenging due to complex price history patterns and an uncertain environment. Incorrect decisions in stock trading lead to massive losses. The proposed Multi-Agent System for Portfolio Profit Optimization (MASPPO) aims to optimize trading profit and reduce risk with accurate predictions. The proposed model integrates the Fuzzy c-means with the Deep …

Emoji Use In Social Media Posts: Relationships With Personality Traits And Word Usage, Shelia Kennison, Kameryn Fritz, Maria Andrea Hurtado Morales, Eric Chan-Tin

Computer Science: Faculty Publications and Other Works

Prior research has demonstrated relationships between personality traits of social media users and the language used in their posts. Few studies have examined whether there are relationships between personality traits of users and how they use emojis in their social media posts. Emojis are digital pictographs used to express ideas and emotions. There are thousands of emojis, which depict faces with expressions, objects, animals, and activities. We conducted a study with two samples (n = 76 and n = 245) in which we examined how emoji use on X (formerly Twitter) related to users’ personality traits and language use …

Flavors And Frailties Of Globalization, Nikhilesh Dholakia, Deniz Atik

Markets, Globalization & Development Review

No abstract provided.

Protein And Polysaccharide-Based Optical Materials For Biomedical Applications., Gianna Riviello, Brendan Connor, Jake Mcbrearty, Gianna Rodriguez, Xiao Hu

College of Science & Mathematics Departmental Research

Recent advances in biomedical research, particularly in optical applications, have sparked a transformative movement towards replacing synthetic polymers with more biocompatible and sustainable alternatives. Most often made from plastics or glass, these materials ignite immune responses from the body, and their production is based on environmentally harsh oil-based processes. Biopolymers, including both polysaccharides and proteins, have emerged as a potential candidate for optical biomaterials due to their inherent biocompatibility, biodegradability, and sustainability, derived from their existence in nature and being recognized by the immune system. Current extraction and fabrication methods for these biomaterials, including thermal drawing, extrusion and printing, mold …

Modeling Thermosyphon And Heat Pipe Performance For Mold Cooling Applications, Dwaipayan Sarkar

Electronic Thesis and Dissertation Repository

Thermosyphons are enhanced heat transfer devices that can continuously transfer very large amounts of heat rapidly over long distances with small temperature differences. The high heat transfer rate is achieved through simultaneous boiling and condensation of the working fluid and the continuous heat transfer is achieved through recirculation of the working fluid in its liquid and vapor phase. A potentially important application of the thermosyphons has been towards reducing the cycle times of the mold cooling processes which would provide economic incentives to the automotive industry.

Different operational and geometrical parameters such as the input heating power, fill ratio (FR), …

Blood Cell Image Segmentation And Classification: A Systematic Review, Muhammad Shahzad, Farman Ali, Syed Hamad Shirazi, Assad Rasheed, Awais Ahmad, Babar Shah, Daehan Kwak

All Works

Background Blood diseases such as leukemia, anemia, lymphoma, and thalassemia are hematological disorders that relate to abnormalities in the morphology and concentration of blood elements, specifically white blood cells (WBC) and red blood cells (RBC). Accurate and efficient diagnosis of these conditions significantly depends on the expertise of hematologists and pathologists. To assist the pathologist in the diagnostic process, there has been growing interest in utilizing computer-aided diagnostic (CAD) techniques, particularly those using medical image processing and machine learning algorithms. Previous surveys in this domain have been narrowly focused, often only addressing specific areas like segmentation or classification but lacking …

Developing A Remote Gamma-Ray Spectra Collection System (Rgscs) By Coupling A High Purity Germanium (Hpge) Detector With A Cosmicguard Background Reduction Device, Zaijing Sun, Krishnakumar Divakar Nangeelil, Haven Searcy

Health Physics & Diagnostic Sciences Faculty Research

Despite being widely used for high-resolution spectral analysis and quantifying low activity in natural samples, the operations and data analysis of High Purity Germanium (HPGe) gamma-ray detectors are seldom fully automated due to the excessive costs associated with commercially available automatic sample changing systems. This paper introduces the design and implementation of a cost-effective, customized remote gamma-ray spectra collection system centered around the HPGe detector coupled to a cosmic-ray veto background reduction device. The HPGe detector system, equipped with a Lynx DSA, is seamlessly integrated with an economically viable automatic sample changer. This sample vial changer is controlled by a …

Analysis Of The Impact Of Water Treatment By Liming Sedimentation And Dredging On The Content Of Heavy Metals In Fish Intended For Consumption, Asfie Maidie, Ismail Fahmy Almadi, Muchlis Efendi, Rekha Yusdha Nilawardhani, Komsanah Sukarti, Henny Pagoray

Journal of Sustainable Mining

The present study sought to determine the presence of metals and arsenic, a metalloid, among the fish of a coal mine reservoir, where the water was treated regularly through liming sedimentation combined with dredging, and the fish living in an adjoining river. The potential hazard of metals in fish as human food was analyzed. Except for selenium (an important metal to the human body), which was higher among the river fish than in the reservoir fish (P < 0.01), there were no particular patterns of other studied metals found in either habitat (P > 0.05), and apparently not related to the fish family that consumed by local people. Measurements of bioaccumulation factor (BAF) yielded scattered values from …

Probing Central Spin Decoherence Dynamics Of Electronic Point Defects In Diamond And Silicon, Ethan Que Williams

Dartmouth College Ph.D Dissertations

Electron spins of point defects in diamond and silicon can exhibit long coherence times, making them attractive platforms for the physical implementation of qubits for quantum sensing and quantum computing. To realize these technologies, it is essential to understand the mechanisms that limit their coherence. Decoherence of these systems is well described by the central spin model, wherein the central electron spin weakly interacts with numerous electron and nuclear spins in its environment. The dynamics of the resultant dephasing can be probed with pulse electron paramagnetic resonance (pEPR) experiments.

Using a 2.5 GHz pEPR spectrometer built in-house, we performed multi-pulse …

Geothermal Play Fairway Analysis, Part 2: Gis Methodology, Jacob Deangelo, John W. Shervais, Jonathan M. Glen, Dennis Nielson, Sabodh Garg, Patrick F. Dobson, Erika Gasperikova, Eric Sonnenthal, Lee M. Liberty, Drew L. Siler, James P. Evans

Geosciences Faculty Publications and Presentations

Play Fairway Analysis (PFA) in geothermal exploration originates from a systematic methodology developed within the petroleum industry and is based on a geologic, geophysical, and hydrologic framework of identified geothermal systems. We tailored this methodology to study the geothermal resource potential of the Snake River Plain and surrounding region, but it can be adapted to other geothermal resource settings. We adapted the PFA approach to geothermal resource exploration by cataloging the critical elements controlling exploitable hydrothermal systems, establishing risk matrices that evaluate these elements in terms of both probability of success and level of knowledge, and building a code-based ‘processing …

Chronostratigraphy Of Miocene Strata In The Berkeley Hills (California Coast Ranges, Usa) And The Arrival Of The San Andreas Transform Boundary, Stacey H. Gerasimov, Eben B. Hodgin, James L. Crowley, Nicholas L. Swanson-Hysell

Geosciences Faculty Publications and Presentations

Miocene strata of the Claremont, Orinda, and Moraga formations of the Berkeley Hills (California Coast Ranges, USA) record sedimentation and volcanism during the passage of the Mendocino triple junction and early evolution of the San Andreas fault system. Detrital zircon laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) age spectra indicate a change in sedimentary provenance between the marine Claremont formation (Monterey Group) and the terrestrial Orinda and Moraga Formations associated with uplift of Franciscan Complex lithologies. A sandstone from the Claremont formation produced a detrital zircon chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS) maximum depositional age of 13.298 ± 0.046 Ma, …

Geotechnical Characterisation Of Coal Spoil Piles Using High-Resolution Optical And Multispectral Data: A Machine Learning Approach, Sureka Thiruchittampalam, Bikram Pratap Banerjee, Nancy F. Glenn, Simit Raval

Geosciences Faculty Publications and Presentations

Geotechnical characterisation of spoil piles has traditionally relied on the expertise of field specialists, which can be both hazardous and time-consuming. Although unmanned aerial vehicles (UAV) show promise as a remote sensing tool in various applications; accurately segmenting and classifying very high-resolution remote sensing images of heterogeneous terrains, such as mining spoil piles with irregular morphologies, presents significant challenges. The proposed method adopts a robust approach that combines morphology-based segmentation, as well as spectral, textural, structural, and statistical feature extraction techniques to overcome the difficulties associated with spoil pile characterisation. Additionally, it incorporates minimum redundancy maximum relevance (mRMR) based feature …

Fuzzy Ideas Explain Fechner Law And Help Detect Relation Between Objects In Video, Olga Kosheleva, Vladik Kreinovich, Ahnaf Farhan

Departmental Technical Reports (CS)

How to find relation between objects in a video? If two objects are closely related -- e.g., a computer and it mouse -- then they almost always appear together, and thus, their numbers of occurrences are close. However, simply computing the differences between numbers of occurrences is not a good idea: objects with 100 and 110 occurrences are most probably related, but objects with 1 and 5 occurrences probably not, although 5 − 1 is smaller than 110 − 100. A natural idea is, instead, to compute the difference between re-scaled numbers of occurrences, for an appropriate nonlinear re-scaling. In …

There Is Still Plenty Of Room At The Bottom: Feynman's Vision Of Quantum Computing 65 Years Later, Alexis Lupo, Vladik Kreinovich, Victor L. Timchenko, Yuriy P. Kondratenko

Departmental Technical Reports (CS)

In 1959, Nobelist Richard Feynman gave a talk titled "There's plenty of room at the bottom", in which he emphasized that, to drastically speed up computations, we need to make computer components much smaller -- all the way to the size of molecules, atoms, and even elementary particles. At this level, physics is no longer described by deterministic Newton's mechanics, it is described by probabilistic quantum laws. Because of this, computer designers started thinking how to design a reliable computer based on non-deterministic elements -- and this thinking eventually led to the modern ideas and algorithms of quantum computing. So, …

From Quantifying And Propagating Uncertainty To Quantifying And Propagating Both Uncertainty And Reliability: Practice-Motivated Approach To Measurement Planning And Data Processing, Niklas R. Winnewisser, Vladik Kreinovich, Olga Kosheleva

Departmental Technical Reports (CS)

When we process data, it is important to take into account that data comes with uncertainty. There exist techniques for quantifying uncertainty and propagating this uncertainty through the data processing algorithms. However, most of these techniques do not take into account that in real world, measuring instruments are not 100% reliable -- they sometimes malfunction and produce values which are far off from the measured values of the corresponding quantities. How can we take into account both uncertainty and reliability? In this paper, we consider several possible scenarios, and we show, for each scenario, what is the natural way to …

Brief Communication: Recent Estimates Of Glacier Mass Loss For Western North America From Laser Altimetry, Brian Menounos, Caitlyn Forentine, Alex A. Gardner, Andrew G. Fountain

Geology Faculty Publications and Presentations

Glaciers in western North American outside of Alaska are often overlooked in global studies because their potential to contribute to changes in sea level is small. Nonetheless, these glaciers represent important sources of freshwater, especially during times of drought. Differencing recent ICESat-2 data from a digital elevation model derived from a combination of synthetic aperture radar data (TerraSAR-X/TanDEM-X), we find that over the period 2013–2020, glaciers in western North America lost mass at a rate of 12:3+3:5 Gt yr^-1. This rate is comparable to the rate of mass loss (11:71:0 Gt yr1) for the period 2018– 2022 calculated …

Lake Whatcom Monitoring Project 2022/2023 Report, Angela Strecker, Joan Pickens, Carmen Archambault, Emily Flarry, Kathryn Queen, Robert Mitchell, Robin Matthews, Geoffrey B. Matthews

Lake Whatcom Annual Reports

This report describes the results from the 2022/2023 Lake Whatcom monitoring program conducted by the Institute for Watershed Studies at Western Washington University (https://diatom.cenv.wwu.edu/).

The major objectives of the 2022/2023 Lake Whatcom monitoring program were to continue long-term baseline water quality monitoring in Lake Whatcom and its major tributaries; collect storm runoff water quality data from representative streams in the watershed; and continue collection of hydrologic data from Austin and Smith Creeks.

An Efficiently Excited Eu3+ Luminescent Site Formed In Eu,O-Codoped Gan, Takenori Iwaya, Shuhei Ichikawa, Volkmar Dierolf, Brandon Mitchell, Hayley Austin, Dolf Timmerman, Jun Tatebayashi, Yasufumi Fujiwara

Physics & Engineering Faculty Publications

For the development of III-nitride-semiconductor-based monolithic micro-light-emitting diode (LED) displays, Eu,O-codoped GaN (GaN:Eu,O) is a promising material candidate for the red LEDs. The luminescence efficiency of Eu-related emission strongly depends on the local atomic structure of Eu ions. Our previous research has revealed that post-growth thermal annealing is an effective method for reconfiguring luminescent sites, leading to a significant increase in light output. We observed the preferential formation of a site with a peak at similar to 2.004 eV by the annealing process. In this study, we demonstrate that it is a previously unidentified independent site (OMVPE-X) using combined excitation-emission …

Examining Sustainable Overseas Investment Information-Sharing Model For Automobile Enterprises: A Multi-Modal Weight Network Approach, Yuan Cheng, Xiaofang Chen, Changbo Lin, Sheqing Ma, Jie Feng

Research Collection School Of Accountancy

In an era of globalization, automotive companies are increasingly looking to make overseas investments to expand their production capacity and explore foreign markets. However, the outcomes of such investments are often influenced by a myriad of factors, including policy changes, social dynamics, and market conditions. To address the need for a comprehensive overseas investment information-sharing model, this research proposes an innovative approach based on a multi-modal weight network. This model aims to provide users with a global perspective on overseas investment opportunities, encompassing policy insights, and market dynamics. It integrates data from various sources, offering multi-dimensional information on investment regions, …

Residual Optical Absorption From Native Defects In Cdsip2 Crystals, Timothy D. Gustafson, Nancy C. Giles, Elizabeth M. Scherrer, Kevin T. Zawilski, Peter G. Schunemann, Kent L. Averett, Jonathan E. Slagle, Larry E. Halliburton

Faculty Publications

CdSiP₂ crystals are used in optical parametric oscillators to produce tunable output in the mid-infrared. As expected, the performance of the OPOs is adversely affected by residual optical absorption from native defects that are unintentionally present in the crystals. Electron paramagnetic resonance (EPR) identifies these native defects. Singly ionized silicon vacancies (V^-_Si) are responsible for broad optical absorption bands peaking near 800, 1033, and 1907 nm. A fourth absorption band, peaking near 630 nm, does not involve silicon vacancies. Exposure to 1064 nm light when the temperature of the CdSiP₂ crystal is near 80K converts …

Predictive Algorithm For Surgery Recommendation In Thoracolumbar Burst Fractures Without Neurological Deficits, Charlotte Dandurand, Nader Fallah, Cumhur F. Öner, Richard J. Bransford, Klaus Schnake, Alex R. Vaccaro, Lorin M. Benneker, Emiliano Vialle, Gregory D. Schroeder, Shanmuganathan Rajasekaran, Mohammad El-Skarkawi, Rishi M. Kanna, Mohamed Aly, Martin Holas, Jose A. Canseco, Sander Muijs, Eugen Cezar Popescu, Jin Wee Tee, Gaston Camino-Willhuber, Andrei Fernandes Joaquim, Ory Keynan, Harvinder Singh Chhabra, Sebastian Bigdon, Ulrich Spiegel, Marcel F. Dvorak

Department of Orthopaedic Surgery Faculty Papers

STUDY DESIGN: Predictive algorithm via decision tree.

OBJECTIVES: Artificial intelligence (AI) remain an emerging field and have not previously been used to guide therapeutic decision making in thoracolumbar burst fractures. Building such models may reduce the variability in treatment recommendations. The goal of this study was to build a mathematical prediction rule based upon radiographic variables to guide treatment decisions.

METHODS: Twenty-two surgeons from the AO Knowledge Forum Trauma reviewed 183 cases from the Spine TL A3/A4 prospective study (classification, degree of certainty of posterior ligamentous complex (PLC) injury, use of M1 modifier, degree of comminution, treatment recommendation). Reviewers' regions …

Usability-Driven Security Enhancements In Person-To-Person Communication, Tarun Kumar Yadav

Theses and Dissertations

In the contemporary digital landscape, ensuring secure communication amid widespread data exchange is imperative. This dissertation focuses on enhancing the security and privacy of end-to-end encryption (E2EE) applications while maintaining or improving usability. The dissertation first investigates and proposes improvements in two areas of existing E2EE applications: countering man-in-the-middle and impersonation attacks through automated key verification and studying user perceptions of cryptographic deniability. Insights from privacy-conscious users reveal concerns about the lack of E2EE support, app siloing, and data accessibility by client apps. To address these issues, we propose an innovative user-controlled encryption system, enabling encryption before data reaches the …

02-26-2024 Orsp Newsletter, Liz Williamson

ORSP Newsletter

No abstract provided.