Physical Sciences and Mathematics Commons^™

Cranial Morphological Distinctiveness Between Ursus Arctos And U. Americanus, Benjamin James Hillesheim

Electronic Theses and Dissertations

Despite being separated by millions of years of evolution, black bears (Ursus americanus) and brown bears (Ursus arctos) can be difficult to distinguish based on skeletal and dental material alone. Complicating matters, some Late Pleistocene U. americanus are significantly larger in size than their modern relatives, obscuring the identification of the two bears. In the past, fossil bears have been identified based on differences in dental morphology or size. This study used geometric morphometrics to look at overall differences in cranial shape and used step-wise discriminant analysis to identify specific characters that distinguish cranial morphology between …

Black Bears (Ursus Americanus) Versus Brown Bears (U. Arctos): Combining Morphometrics And Niche Modeling To Differentiate Species And Predict Distributions Through Time, Theron Michael Kantelis

Electronic Theses and Dissertations

Late Pleistocene American black bears (Ursus americanus) often overlap in size with Pleistocene brown bears (U. arctos), occasionally making them difficult to diagnose. Large U. americanus have previously been distinguished from U. arctos by the length of the upper second molar (M2). However, the teeth of fossil U. americanus sometimes overlap size with U. arctos. As such, there is need for a more accurate tool to distinguish the two species. Here, 2D geometric morphometrics is applied to the occlusal surface of the M2 to further assess the utility of this tooth for distinguishing U. americanus and …

Novel Statistical Approaches For Missing Values In Truncated High-Dimensional Metabolomics Data With A Detection Threshold., Jasmit Sureshkumar Shah

Electronic Theses and Dissertations

Despite considerable advances in high throughput technology over the last decade, new challenges have emerged related to the analysis, interpretation, and integration of high-dimensional data. The arrival of omics datasets has contributed to the rapid improvement of systems biology, which seeks the understanding of complex biological systems. Metabolomics is an emerging omics field, where mass spectrometry technologies generate high dimensional datasets. As advances in this area are progressing, the need for better analysis methods to provide correct and adequate results are required. While in other omics sectors such as genomics or proteomics there has and continues to be critical understanding …

Assessment And Characterization Of Microbial Communities In Salt Affected Soils On Galveston Island, Elaine Fowler

Electronic Theses and Dissertations

After Hurricane Ike in 2008, Galveston Island was flooded with sea water that left the soil and groundwater of the island with elevated sodium concentrations. As part of a long-term study that aims to restore plant life to the island, various soil amelioration techniques are being evaluated. Samples from bedded and non- bedded plots treated with gypsum, mulch, or both were assessed for microbial populations. Samples collected in July and October 2016 were cultured on Tryptic Soy Agar (bacteria enumeration), Pseudomonas Agar, Actinomycete Agar, and Rose Bengal Agar (fungi enumeration). Bacteria populations ranged from 4.07 to 5.12 log CFU/gram and …

Basement And Cover Structural Analysis Along The Eagle River Gorge, Sawatch Range, Colorado, Kaitlin Lee Askelson

Electronic Theses and Dissertations

The Sawatch Range within the Rocky Mountains of central Colorado exposes Paleoproterozoic basement and overlying Paleozoic sedimentary rocks with a complex history of ductile and brittle deformation.

The goal of this study is to conduct analyses of brittle structures that occur in the basement and cover units to determine geometric relationships between the structures, provide a detailed description of structures and refine a geologic history for structures along the basement-cover contact in the northeastern Sawatch Range along the Eagle River canyon and U.S. Highway 24 from Red Cliff to Gilman, Colorado. Paleoproterozoic basement rocks include the Cross Creek granite, diorites, …

Using A Multi Variate Pattern Analysis (Mvpa) Approach To Decode Fmri Responses To Fear And Anxiety., Sajjad Torabian Esfahani

Electronic Theses and Dissertations

This study analyzed fMRI responses to fear and anxiety using a Multi Variate Pattern Analysis (MVPA) approach. Compared to conventional univariate methods which only represent regions of activation, MVPA provides us with more detailed patterns of voxels. We successfully found different patterns for fear and anxiety through separate classification attempts in each subject’s representational space. Further, we transformed all the individual models into a standard space to do group analysis. Results showed that subjects share a more common fear response. Also, the amygdala and hippocampus areas are more important for differentiating fear than anxiety.

Remotely Sensed Heat : Variation And Change In Surface Urban Heat Islands In A Temperate Eco-Region Of The United States., Jeremy Sandifer

Electronic Theses and Dissertations

Urban heat island (UHI) is a term used to describe increased surface and atmospheric temperatures in an urban core relative to surrounding non-urbanized areas. To examine the variability introduced into derived estimates of the surface UHI, this study constructs and compares multiple remotely sensed indicators of the surface UHI for major metropolitan cities of a temperate eco-region of the United States. The Moderate Resolution Imaging Spectroradiometer (MODIS) 8-day, 500-meter product (MOD11A2) is the source data used to calculate six different RS-derived UHI indicators for the year 2002 to 2012. The different SUHI indicators are evaluated using the Spearmans Rho rank-order …

Homogeneous Ligand-Centered Hydrogen Evolution And Hydrogen Oxidation : Exploiting Redox Non-Innocence To Drive Catalysis., Andrew Z. Haddad

Electronic Theses and Dissertations

Hydrogen is a promising carbon-free fuel / energy carrier and is an essential building block for many industrial and agricultural processes. Rising energy demands have ignited interest in the development of carbon-free and carbon neutral energy sources. In this context, hydrogen is an attractive candidate—being energy-dense, carbon-free—and easily accessible through a two-electron reduction of water. Accordingly, many electrochemical homogeneous catalyst systems have been studied, with a focus on understanding the mechanism of hydrogen evolution proceeding through metal-hydride intermediates. However, there has been a renaissance in hydrogen evolution reaction (HER) catalyst design, with many groups implicating ligand redox non-innocence as a …

Functionalized Silica Gel For Adsorption Of Cesium From Solution, Kenneth Marshall Seaton Iii

Electronic Theses and Dissertations

Mesoporous silica gel containing embedded phosphotungstic acid (PTA) was synthesized by sol-gel co-condensation of tetraethyl orthosilicate with PTA in acidic media. The obtained material had high Brunauer-Emmett-Teller Theory (BET) surface area and pore volume. A characteristic band of the Keggin structure of PTA was present in its FT-IR spectrum while its X-ray diffraction patterns were absent. This proved the embedding of PTA on a sub-molecular level and not as a second phase. Acidic sites were determined by neutralization with base in aprotic solvent, followed by titration of the remaining base with an acid. The material demonstrated high adsorption capacity of …

A Distribution Of The First Order Statistic When The Sample Size Is Random, Vincent Z. Forgo Mr

Electronic Theses and Dissertations

Statistical distributions also known as probability distributions are used to model a random experiment. Probability distributions consist of probability density functions (pdf) and cumulative density functions (cdf). Probability distributions are widely used in the area of engineering, actuarial science, computer science, biological science, physics, and other applicable areas of study. Statistics are used to draw conclusions about the population through probability models. Sample statistics such as the minimum, first quartile, median, third quartile, and maximum, referred to as the five-number summary, are examples of order statistics. The minimum and maximum observations are important in extreme value theory. This paper will …

Peeking Into The Other Half Of The Glass : Handling Polarization In Recommender Systems., Mahsa Badami

Electronic Theses and Dissertations

This dissertation is about filtering and discovering information online while using recommender systems. In the first part of our research, we study the phenomenon of polarization and its impact on filtering and discovering information. Polarization is a social phenomenon, with serious consequences, in real-life, particularly on social media. Thus it is important to understand how machine learning algorithms, especially recommender systems, behave in polarized environments. We study polarization within the context of the users' interactions with a space of items and how this affects recommender systems. We first formalize the concept of polarization based on item ratings and then relate …

An Analysis Of The Relationship Between Snowpack And Groundwater Across Utah Watersheds., Samuel Wright

Electronic Theses and Dissertations

This thesis examined what type of relationship existed between snow water equivalence (SWE) volume and groundwater elevation within six sub-watersheds in Utah. Data was gathered on SWE from seventeen SNOTEL sites and groundwater elevation data was gathered from six continuously monitored groundwater wells. This data was gathered for January through May for 2011, 2013, and 2014 in order to represent the water conditions that were above average, below average, and average respectively. Using MLR formulas the total SWE for each sub-watershed was determined for each year/month. Afterwards a correlation analysis was performed to determine if any association existed between SWE …

Development Of Recyclable Gold Nanoparticles For Routine Benchtop Catalysis In Organic Transformations., Shengzong Liang

Electronic Theses and Dissertations

Homogeneous gold catalysis is a popular research area due to its high efficiency. Various gold catalysts have been utilized in organic synthesis and their reaction mechanisms are also well understood. However, most gold catalysis suffers from high catalyst loading or catalyst decay problems. In addition, homogeneous gold catalysts are not recyclable. These disadvantages have limited their application in large-scale synthesis and also caused a serious waste of this precious metal. A solution for these problems is to use a recyclable heterogeneous gold catalyst. So in this study, with the aim of making gold chemistry greener we successfully used heterogeneous gold …

Application Of Symplectic Integration On A Dynamical System, William Frazier

Electronic Theses and Dissertations

Molecular Dynamics (MD) is the numerical simulation of a large system of interacting molecules, and one of the key components of a MD simulation is the numerical estimation of the solutions to a system of nonlinear differential equations. Such systems are very sensitive to discretization and round-off error, and correspondingly, standard techniques such as Runge-Kutta methods can lead to poor results. However, MD systems are conservative, which means that we can use Hamiltonian mechanics and symplectic transformations (also known as canonical transformations) in analyzing and approximating solutions. This is standard in MD applications, leading to numerical techniques known as symplectic …

Inventory Optimization Using A Simpy Simulation Model, Lauren Holden

Electronic Theses and Dissertations

Existing multi-echelon inventory optimization models and formulas were studied to get an understanding of how safety stock levels are determined. Because of the restrictive distribution assumptions of the existing safety stock formula, which are not necessarily realistic in practice, a method to analyze the performance of this formula in a more realistic setting was desired. A SimPy simulation model was designed and implemented for a simple two-stage supply chain as a way to test the performance of the safety stock formula. This implementation produced results which led to the conclusion that the safety stock formula tends to underestimate the level …

Synthesis And Fundamental Property Studies Of Energy Material Under High Pressure., Meysam Akhtar

Electronic Theses and Dissertations

Recently, high-pressure science and technology has flourished and rapidly advanced to impact a wide domain of materials and physical sciences. One of the most substantial technological developments is the integration of samples at ultrahigh pressure with a wide range of in-situ probing techniques. Applications of extreme pressure have significantly enriched our understanding of the electronic, phonon, and doping effects on the newly emerged two-dimensional (2D) materials. Under high pressure, materials’ atomic volume radically decreases, and electronic density rises, which will lead to extraordinary chemical reaction kinetic and mechanisms. The promising capability of high pressure combine with the significance of novel …

The Tuscaloosa Marine Shale: Geologic History, Depositional Analysis, And Exploration Potential, Jessica D. Pair

Electronic Theses and Dissertations

The Tuscaloosa Marine Shale (TMS) was deposited across southern Louisiana and Mississippi during the Upper Cretaceous. The study focuses on a core region containing vast deposits of Cretaceous-aged sediments that have economic importance for oil and gas exploration. This region has been conventionally drilled for decades, focusing on the recovery of the Cretaceous hydrocarbons. Explorers within this region had traditionally targeted the massive sand units of the Lower and Upper Tuscaloosa Group while neglecting the middle Tuscaloosa Marine Shale unit. With the onset of unconventional drilling technology, new explorers to the region have begun to delineate the Tuscaloosa Marine Shale’s …

Delineation Of Karst Geohazards Along Rm 652 Through The Use Of Ground Penetrating Radar: Culberson County, Texas, Aaron A. Eaves

Electronic Theses and Dissertations

The Delaware Basin is the western member of the larger Permian Basin, and is located in the Trans-Pecos region of Texas and New Mexico. The Delaware Basin hosts significant evaporite karst geohazards throughout the Gypsum Plain of the Castile Formation, where geohazards of all scales form beneath and immediately adjacent to major infrastructure throughout the region, especially Ranch-to-Market 652, including geohazards ranging from small scale dissolution of road base, to large scale cave and sinkhole development. Gypsum sourced from the Castile and Rustler formations was used to create the road base of this RM652 , which meteoric waters have easily …

Weakly Labeled Action Recognition And Detection, Waqas Sultani

Electronic Theses and Dissertations

Research in human action recognition strives to develop increasingly generalized methods that are robust to intra-class variability and inter-class ambiguity. Recent years have seen tremendous strides in improving recognition accuracy on ever larger and complex benchmark datasets, comprising realistic actions "in the wild" videos. Unfortunately, the all-encompassing, dense, global representations that bring about such improvements often benefit from the inherent characteristics, specific to datasets and classes, that do not necessarily reflect knowledge about the entity to be recognized. This results in specific models that perform well within datasets but generalize poorly. Furthermore, training of supervised action recognition and detection methods …

Quantification Of Non-Stoichiometry And Impurities In Transparent Yag Ceramics By Laser-Induced Breakdown Spectroscopy (Libs), Sudeep Pandey

Electronic Theses and Dissertations

Transparent ceramics are an important class of optical materials with applications in street-lighting, high-strength windows, electro- and magneto-optical isolators, high-power laser gain media and nuclear radiation detectors. Compared to single-crystal growth, ceramic processing enables size scalability, near net-shape forming and prevents issues associated with dopant segregation and inhomogeneity, such as stress-induced birefringence and wavefront distortions. The fabrication of high optical grade ceramics by route of powder sintering, relies on a controlled set of techniques preventing the formation of scattering centers (pores and secondary phases) and harmful point defects (color centers, charge-carrier trapping sites). This thesis work investigates a novel approach …

Mechanochemical Synthesis Of Fuels From Sustainable Sources Utilizing Solid Catalysts, Jacob Todd

Electronic Theses and Dissertations

Mechanochemistry requires less solvents which results in less waste generation. The question becomes can we apply mechanochemistry to current chemical reactions and reduce the generation of waste. This process can be simple or can be very extensive resulting in the generation of large amounts of waste and very little product. A significant advantage of mechanochemistry is the reduced need for solvents that would be common place for reactions. Mechanochemistry transfers energy to reagents via impacts from milling media. Energy can be transferred to the reagents no matter their state-of-matter. Much of the current studies in mechanochemistry today are done using …

Design And Verification Of A Multi-Terawatt Ti-Sapphire Femtosecond Laser System, Patrick Roumayah

Electronic Theses and Dissertations

Ultrashort pulse lasers are well-established in the scientific community due to the wide range of applications facilitated by their extreme intensities and broad bandwidth capabilities. This thesis will primarily present the design for the Mobile Ultrafast High Energy Laser Facility (MU-HELF) for use in outdoor atmospheric propagation experiments under development at the Laser Plasma Laboratory at UCF. The system is a 100fs 500 mJ Ti-Sapphire Chirped-Pulse Amplification (CPA) laser, operating at 10 Hz. Some background on the generation of very high intensity optical pulses is also presented, alongside an overview of the physics of filamentation. As part of the design …

Charge And Spin Transport In Low-Dimensional Materials, Amin Ahmadi

Electronic Theses and Dissertations

My research has been focused on two main areas. First, electronic transports in chiral carbon nanotubes in the presence of charged adatoms. To study such systems we employed recursive Greens function technique to evaluate the conductance using the Landauer formula. Comparing with the experimental data, we determined the effective amplitude and the range of scattering potentials. In addition, using a similar approach we explained qualitatively an unusual conductance feature in a metallic carbon nanotube. The second part of my study was concerned to the dynamical spin injection and spin currents in low-dimensional materials. We have developed an atomistic model to …

High Performance Liquid Crystals For Displays And Spatial Light Modulators, Fenglin Peng

Electronic Theses and Dissertations

Liquid crystals (LCs) are an amazing class of soft materials which have been widely used in the visible, infrared (IR), millimeter wave, and terahertz spectral regions. Both amplitude modulation (e.g. displays) and phase modulation (e.g. spatial light modulators (SLMs) for adaptive optics and adaptive lens) have been investigated extensively. Thin-film-transistor liquid crystal displays (TFT-LCDs) have become ubiquitous in our daily lives. Its widespread applications span from TVs, monitors, tablets, smartphones, augmented reality, virtual reality, to vehicle displays. LCD shows advantages in 1) high resolution, 2) long lifetime, 3) vivid colors using quantum dots backlight, and 4) high dynamic contrast ratio …

Coloring Graphs With Forbidden Minors, Martin Rolek

Electronic Theses and Dissertations

A graph H is a minor of a graph G if H can be obtained from a subgraph of G by contracting edges. My research is motivated by the famous Hadwiger's Conjecture from 1943 which states that every graph with no Kt-minor is (t − 1)-colorable. This conjecture has been proved true for t ≤ 6, but remains open for all t ≥ 7. For t = 7, it is not even yet known if a graph with no K7-minor is 7-colorable. We begin by showing that every graph with no Kt-minor is (2t − 6)- colorable for t = …

Pervasive Secure Content Delivery Networks Implementation, Hector Lugo-Cordero

Electronic Theses and Dissertations

Over the years, communication networks have been shifting their focus from providing connectivity in a client/server model to providing a service or content. This shift has led to topic areas like Service-Oriented Architecture (SOA), Heterogeneous Wireless Mesh Networks, and Ubiquitous Computing. Furthermore, probably the broadest of these areas which embarks all is the Internet of Things (IoT). The IoT is defined as an Internet where all physical entities (e.g., vehicles, appliances, smart phones, smart homes, computers, etc.), which we interact daily are connected and exchanging data among themselves and users. The IoT has become a global goal for companies, researchers, …

Jml Template Generation, Kushal Raghav Poojari

Electronic Theses and Dissertations

The Java Modeling Language (JML) is a behavioral interface specific language designed to specify Java modules (which are Java classes and interfaces). Specifications are used to describe the intended functionality without considering the way it is implemented. In JML, if a user wants to write specifications for a Java file, he or she must undertake several steps. To help automate the process of creating annotations for method specifications, a tool Jmlspec was created. Jmlspec generated a file that refines the source file and has empty placeholders in which one can write specifications. Although Jmlspec worked with older versions of Java, …

Growth And Doping Of Mos2 Thin Films For Electronic And Optoelectronic Applications, Hussain Abouelkhair

Electronic Theses and Dissertations

MoS2 high absorption coefficient, high mobility, mechanical flexibility, and chemical inertness is very promising for many electronic and optoelectronic applications. The growth of high-quality MoS2 by a scalable and doping compatible method is still lacking. Therefore, the suitable dopants for MoS2 are not fully explored yet. This dissertation consists mainly of four main studies. The first study is on the growth of MoS2 thin films by atmospheric pressure chemical vapor deposition. Scanning electron microscope images revealed the growth of microdomes of MoS2 on top of a smooth MoS2 film. These microdomes are very promising as a broadband omnidirectional light trap …

Ichetucknee Springs: Measuring The Effects Of Visitors On Water Quality Parameters Through Continuous Monitoring., Sarah Faraji

Electronic Theses and Dissertations

Ichetucknee Springs System is in north central Florida, under the jurisdiction of the Suwannee River Water Management District (SRWMD). The Ichetucknee River is one of the most pristine spring-fed rivers in Florida and became a state park in 1970. Over 400,000 people visited the Ichetucknee Springs State Park in 2016. From that total, over 130,000 people came during the tubing season alone (Memorial Day to Labor Day). During the tubing season, only 750 visitors per day are allowed to launch from the North Launch, near the Ichetucknee Head Spring. The park enforces visitor usage of the river during these time …

Atomic-Scale Simulation Of Physical And Chemical Processes During Space Weathering And Planet Formation, Abrar Quadery

Electronic Theses and Dissertations

We investigate the mechanisms of space weathering and dust grain collisions, two topics of interests from planetary sciences, using atomic-scale simulations. Space weathering is the change in chemical and physical properties of minerals exposed to solar radiation and micrometeorite bombardment on surfaces of airless planetary bodies like the Moon and asteroids. An understanding of the connection between the surface evolution of the minerals and the underlying thermodynamic and kinetic factors is still missing. We address this issue and determine the time evolution of Frenkel defects in the silicate minerals olivine ((Mg,Fe)$_2$SiO$_4$) and orthopyroxene ((Mg,Fe)SiO$_3$) using molecular dynamics with a pair …