Physical Sciences and Mathematics Commons^™

Globec Nep: Satellite-Observed Ocean Climate Variability, Andrew C. Thomas

University of Maine Office of Research Administration: Grant Reports

The PIs will extend in time and expand in scope the satellite data development and satellite-based analyses of ocean climate variability in the Northeast Pacific (NEP), begun during the GLOBEC Pilot Project phase (1997 - 00). The overall scientific problem is to characterize and quantify the dominant modes of variability in the NEP as embodied by satellite measurements of surface transports, temperature and chlorophyll patterns. Our analyses address multiple spatial and temporal scales using merged satellite data products over GLOBEC target study regions in both the California Current (CCS) and the coastal Gulf of Alaska (CGOA).

GLOBEC NEP field studies …

Zwitterionic Self-Assembly Of L-Methionine Nanogratings On The Ag(111) Surface, Andreas Riemann, Agustin Schiffrin, Willi Auwarter, Yan Pennec, Alex Weber-Bargioni, Albano Cossaro, Alberto Morgante, Johannes V. Barth

Physics & Astronomy

The engineering of complex architectures from functional molecules on surfaces provides new pathways to control matter at the nanoscale. In this article, we present a combined study addressing the self-assembly of the amino acid L-methionine on Ag(111). Scanning tunneling microscopy data reveal spontaneous ordering in extended molecular chains oriented along high-symmetry substrate directions. At intermediate coverages, regular biomolecular gratings evolve whose periodicity can be tuned at the nanometer scale by varying the methionine surface concentration. Their characteristics and stability were confirmed by helium atomic scattering. X-ray photoemission spectroscopy and high-resolution scanning tunneling microscopy data reveal that the L-methionine chaining is …

Frequency-Dependent Attenuation Analysis Of Ground-Penetrating Radar Data, John H. Bradford

CGISS Publications and Presentations

In the early 1990s, it was established empirically that, in many materials, ground-penetrating radar (GPR) attenuation is approximately linear with frequency over the bandwidth of a typical pulse. Further, a frequency-independent Q* parameter characterizes the slope of the band-limited attenuation versus frequency curve. Here, I derive the band-limited Q* function from a first-order Taylor expansion of the attenuation coefficient. This approach provides a basis for computing Q* from any arbitrary dielectric permittivity model. For Cole-Cole relaxation, I find good correlation between the first-order Q* approximation and Q* computed from linear fits to the attenuation coefficient …

Size Dependence Of Static And Dynamic Magnetic Properties In Nanoscale Square Permalloy Antidot Arrays, Minghui Yu, Leszek M. Malkinski, Leonard Spinu, Weilie Zhou, Scott L. Whittenburg

Chemistry and Biochemistry Faculty Publications

Permalloy antidot arrays with different square hole sizes ( , , and ) have been fabricated by means of electron-beam lithography and lift-off techniques. The smaller square hole size results in enhanced remanence and reduced coercivity in the antidot array. Multiple resonance modes were clearly observed for the magnetic field applied normal to the array plane, and double uniform resonance modes occurred when the field deviated more than 30° from the normal to the plane. Two distinct dipolar field patterns with different orientations and magnitudes split the uniform resonance into double resonance modes. The double resonance modes show uniaxial in-plane …

Piezomagnetism In Epitaxial Cr2o3 Thin Films And Spintronic Applications, Sarbeswar Sahoo, Christian Binek

Christian Binek Publications

Stress-induced perturbation of the antiferromagnetic long-range order in epitaxially grown Cr2O3 thin films gives rise to pronounced piezomagnetism and a significant reduction of the antiferromagnetic ordering temperature. The temperature dependence of the piezomagnetic moment measured by superconducting quantum interference device magnetometry reveals a power law behaviour with a critical exponent 2B=0.66 in accordance with the Ising anisotropy of a three-dimensional system. The observed shift of the Neel temperature allows estimating the internal lateral stress which is in excellent agreement with an independent estimate based on the elastic properties of Cr2O3 and the lattice mismatch at the interface between the sapphire …

Poster Session, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Identification of potential bacterial sources and levels, Red Duck Creek, Mayfield, Kentucky, Brooke Vorbeck, Travis Martin, and Mike Kemp, Dept of Industrial and Engineering Technology, Murray State University
• Water-quality trend analysis for streams in Kentucky, A.S. Crain and G.R. Martin, USGS, Louisville
• Preliminary Results of a Fecal Microbe Survey in a Eutrophic Lake, Wilgreen Lake, Madison County, Kentucky, W.S. Borowski and M.S. Albright, Depts of Earth Sciences and Geography, EKU
• Preliminary Physical and Chemical Characteristics of an Eutrophic Lake, Wilgreen Lake, Madison County, Kentucky, E.C. Jolly and W.S. Borowski, Dept of Earth Sciences, EKU
• Lethal and …

Session 2d: Superfund, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Challenges and Opportunities in Working Directly with Affected Superfund Communities in Kentucky, Lisa Gaetke, Nutrition and Food Science, UK
• Selected Chloro-Organic Detoxifications by Poly-Chelate (polyacrylic acid) and Citrate-Based Fenton Reaction at Neutral pH Environment, YongChao Li, L. G. Bachas, and Dibakar Bhattacharyya, Depts of Chemical & Materials Engineering and Chemisty, UK
• Reductive Degradation of Cholorinated Organics by Membrane-Supported Nonoparticles, Jian Xu and Dibakar Bhattacharyya, Dept of Chemical & Materials Engineering, UK

Session 2c: Education/Outreach, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• 5 Stars, 15 Students, and 5000 Trees, A.A. Gumbert and others, Extension Associate for Environmental and Natural Resource Issues, UK
• The Water Pioneers Water Quality Initiative, Stephanie Jenkins, Doug McLaren, Blake Newton, Amanda Abnee, UK
• Local and State Partnership for MS4 Success in Kentucky – Coordinated Communication, Education and Outreach, C.D. McCormick and Shelby Jett, FMSM Engineers, Louisville and Kentucky Transportation Cabinet
• Illicit Discharge Detection and Elimination: A Challenge for Kentucky’s Stormwater Program Cities, B. Tonning, R. Walker, and J. Arnold, Tetra Tech, Lexington

Session 2b: Goundwater, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Kentucky Groundwater-Quality Mapping Service, R.S. Fisher and Bart Davidson, KGS
• Kentucky Groundwater-Quality Data Search Engine, Bart Davidson and R.S. Fisher, KGS
• Water Quality in the Karst Terrane of the Sinking Creek Basin, Kentucky 2004-06, Angela S. Crain, USGS, Louisville
• Salt Movement Through the Vadose Zone of a Karst Soil – First Experiences with a Transfer Function Approach, Ole Wendroth and others, Dept Plant and Soil Sciences, UK

Session 2a: Surface Water, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Development and Application of a New Sediment Fingerprinting Methodology for the Commonwealth of Kentucky, Charles Davis and Jimmy Fox, Dept of Civil Engineering, UK
• Accounting for Construction Stormwater in TMDL Development for Sediment Impaired Streams in Rapidly Growing Residential Areas, Jon Ludwig and John Bekman, Tetra Tech, and David Montali, WVDEP
• Responses of Riparian Plant Diversity to Gradients in Flood Frequency and Severity, Patrick Lawless and Jimmy Fox, Depts of Geography and Civil Engineering, UK

Session 1d: Biology, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Long-Term Assessments and Seasonal Variations of Polychlorinated Biphenyls (PCBs) in Water, Sediments, Floodplain Soils, and Sentinel Fish Species from Big and Little Bayou Creeks, McCracken County, Kentucky, D.J. Price, Dept of Biology, UK
• Characterization of total dissolved solids (TDS) toxicity to Ceriodaphnia dubia associated with effluent discharges from a meat packaging industry, Agus Sofyan and David Price, Dept of Biology, UK
• Wilson Creek Restoration and the Response in Food Web Function and Fish Community Structure, Wesley Daniel and Jeff Jack, Dept of Biology and Center for Environmental Science, U of L

Session 1c: Epscor Projects, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Colloidal Arsenic in Poultry-Litter Amended Soils, Lisa Y. Blue and others, Dept of Chemistry, UK
• Environmental Monitoring and Assessment of Arsenic Metal in Groundwater Samples from Ballard, Carlisle, and Graves Counties, Kentucky, H.B. Fannin and others, Dept of Chemistry, Murray State University
• Environmental Monitoring and Assessment of the Groundwater Quality in Calloway County, Kentucky, Dan Kotter and others, KGS, Henderson, KY
• Land-Use Effects on Water Quality Within Lower Howard Creek Watershed, Southwestern Clark County, Kentucky, S.D. Daugherty and J.S. Dinger, Dept Earth & Environmental Sciences and KGS, UK

Session 1b: Student Research Projects, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Experimental Study of the Impact of Upland Sediment Supply upon Cohesive Streambank Erosion Part I: Fluid Turbulence, Brian Belcher and Jimmy Fox, Dept of Civil Engineering, UK
• Toward Using a Three-Dimensional Numerical Model for Simulating Hydrodynamics Near a Dam for Constructing the Rating Curve, Z.S. Shao and S.A. Yost, Dept of Civil Engineering, UK
• Property Taxation and Forest Fragmentation in Kentucky Watersheds, Scott Brodbeck and Tamara Cushing, Dept of Forestry, UK
• Solute and Particle Tracer Movement Under Various Flow Conditions in a Karst Groundwater Basin, Inner Bluegrass Region, Kentucky, J.W. Ward and others, Dept Earth and …

Session 1a: Microbial Source Tracking, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• Detecting Multiple Source Origins from Fecal Bacteria Antibiotic Resistance Patterns, Sloane Ritchey and M.S. Coyne, Environmental Research Institute, EKU and Dept of Plant and Soil Sciences, UK
• Microbial Source Tracking; Limits and Application, Steve Evans, Third Rock Consultants, Lexington
• Triplett Creek Focus Study, Brian Reeder and April Haight, Institute for Regional Analysis and Public Policy, Morehead State University

Proceedings Of 2007 Kentucky Water Resources Annual Symposium, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

This conference was planned and conducted as part of the state water resources research annual program with the support and collaboration of the Department of the Interior, U.S. Geological Survey and the University of Kentucky Research Foundation, under Grant Agreement Number 06HQGR0087.

The views and conclusions contained in this document and presented at the symposium are those of the abstract authors and presenters and should not be interpreted as necessarily representing the official policies, either expressed or implied, of the U.S. Government or other symposium organizers and sponsors.

Assessing Bottom Gear Impact In The Wgom Closure Area: A Multifaceted Approach, Mashkoor A. Malik, Larry A. Mayer

Center for Coastal and Ocean Mapping

Mashkoor Malik presented the results of a UNH Center for Coastal and Ocean Mapping (CCOM) study of the seafloor of the WGOMCA.

Objectives The objectives for the CCOM study were to:

• Construct a bathymetric map of Jeffrey’s Ledge to serve as a framework for subsequent studies.

• Test the potential use of multibeam sonar to monitor fishing gear impacts.

• Determine if it is possible to observe closure impacts with multibeam sonar.

On Comparing The Clustering Of Regression Models Method With K-Means Clustering, Li-Xuan Qin, Steven G. Self

Memorial Sloan-Kettering Cancer Center, Dept. of Epidemiology & Biostatistics Working Paper Series

Gene clustering is a common question addressed with microarray data. Previous methods, such as K-means clustering and hierarchical clustering, base gene clustering directly on the observed measurements. A new model-based clustering method, the clustering of regression models (CORM) method, bases the clustering of genes on their relationship to covariates. It explicitly models different sources of variations and bases gene clustering solely on the systematic variation. Both being partitional clustering, CORM is closely related to K-means clustering. In this paper, we discuss the relationship between the two clustering methods in terms of both model formulation and implications on other important aspects …

Soccer Robot Toy Within An Educational Environment, Peter James Vial, G. Serafini, I. Raad

Faculty of Informatics - Papers (Archive)

Many autonomous robotic systems exist which are operated using battery powered subsystems. These systems typically suffer from short battery life, due in some part to the weight of the battery required to power them and the need for regular battery changes or recharges. This makes continuous operation difficult, which is desired for an embedded Internet system. A novel solution proposed here is to use a power cage in lieu of a battery, and limit the area the robot can traverse to the dimension of the cage. A prototype of such a system has been designed and successfully tested. The goal …

Resonances And Threshold Effects In Low-Energy Electron Collisions With Methyl Halides, Gordon A. Gallup, Ilya I. Fabrikant

Gordon Gallup Publications

Cross sections for elastic and inelastic electron collisions with CH₃X(X =Cl,Br, I) molecules are calculated. For the lowest partial wave, the resonance R-matrix theory, and for the higher partial waves, the theory of scattering by dipolar plus polarization potential, are used. It is shown that the rotationally elastic scattering amplitude for a polar molecule in the fixed-nuclei approximation is logarithmically divergent for the forward direction, and a closure formula is derived to speed up the convergence at small angles. In treating the nuclear motion, only C-X stretch vibrations are taken into account. The dipole moment …

The Electronic Band Structure Of Cos2, Ning Wu, Yaroslav B. Losovyj, David Wisbey, Kirill D. Belashchenko, M. Manno, L. Wang, C. Leighton, Peter A. Dowben

Peter Dowben Publications

Angle-resolved and energy-dependent photoemission was used to study the band structure of paramagnetic CoS₂ from high-quality single-crystal samples. A strongly dispersing hybridized Co–S band is identified along the Γ–X line. Fermi level crossings are also analyzed along this line, and the results are interpreted using band structure calculations. The Fermi level crossings are very sensitive to the separation in the S–S dimer, and it is suggested that the half-metallic gap in CoS₂ may be controlled by the bonding– antibonding splitting in this dimer, rather than by exchange splitting on the Co atoms.

The Structure Of The Cos2 (100)-(1 × 1) Surface, Z. X. Yu, M. A. Van Hove, S. Y. Tong, David Wisbey, Yaroslav B. Losovyj, Ning Wu, M. Manno, L. Wang, C. Leighton, Wai-Ning Mei, Peter A. Dowben

Peter Dowben Publications

Quantitative low-energy electron diffraction (LEED) has been used to determine the structure of the cubic CoS₂ (100)-(1 × 1) surface. The clearly favored structural model from the LEED analysis is the 1S-terminated (1 × 1) surface, in which the S–S dimer is intact and the terminal surface layer retains a complete S–Co–S sandwich structure. The surface S atoms move outwards towards the vacuum while the subsurface Co atoms move towards the bulk, by approximately 0.03 and 0.11 Å, respectively. In addition, the S atoms in the third sublayer relax outwards by about 0.12 Å, thus providing an indication of …

Electric Energy Density Of Dielectric Nanocomposites, Jiangyu Li, L. Zhang, Stephen Ducharme

Stephen Ducharme Publications

Dielectric materials with large electric energy density are actively pursued for many applications. The authors analyze the effective permittivity, breakdown strength, and electric energy density of dielectric nanocomposites using an effective medium approximation, modeling the nanocomposite as a three-phase material by the double-inclusion method. The addition of nanoparticles enhances the permittivity but reduces the breakdown strength, making the potential gain in electric energy density small. In addition, the interfacial interaction shifts the “percolation” threshold toward lower volume fraction of nanoparticles. The analysis suggests that the microstructure of nanocomposites must be carefully controlled to maintain high dielectric strength and therefore realize …

The Niemann-Pick Type C2 Protein Loads Isoglobotrihexosylceramide Onto Cd1d Molecules And Contributes To The Thymic Selection Of Nkt Cells, Paul B. Savage, Nicolas Schrantz, Yuval Sagiv, Yang Liu, Albert Bendelac, Luc Teyton

Faculty Publications

The Niemann-Pick type C2 (NPC2) protein is a small, soluble, lysosomal protein important for cholesterol and sphingolipid transport in the lysosome. The immunological phenotype of NPC2-deficient mice was limited to an impaired thymic selection of Valpha 14 natural killer T cells (NKT cells) and a subsequent reduction of NKT cells in the periphery. The remaining NKT cells failed to produce measurable quantities of interferon-gamma in vivo and in vitro after activation with alpha-galactosylceramide. In addition, thymocytes and splenocytes from NPC2-deficient mice were poor presenters of endogenous and exogenous lipids to CD1d-restricted Valpha 14 hybridoma cells. Importantly, we determined that similar …

Analysis And Properties Of Carotenoids In Vivo And In Vitro, Yisi Cao

FIU Electronic Theses and Dissertations

The purpose of this study was to develop a deeper understanding of the nature of carotenoid metabolism in the human and primate retina. We have sought to do this from two perspectives (1) through preparation and study of a carotenoid diketone that is a candidate metabolic product and (2) through measurement of the carotenoid distribution in the retinas of neonatal macaques.

In this thesis we report the synthesis, purification, and characterization of the product using HPLC, UV/Vis, MS, ¹H-NMR. The data obtained are all consistent with the proposed β,β-carotene-3,3'-dione.

There has been no thorough study of the development of …

Evidence For Prehistoric Coseismic Folding Along The Tsaotun Segment Of The Chelungpu Fault Near Nan-Tou, Taiwan, Ashley R. Streig, Charles M. Rubin, Wen-Shan Chen, Long-Shen Lee, Stephen C. Thompson, Chris Madden, Shih-Ting Lu

All Faculty Scholarship for the College of the Sciences

Taiwan's 1999 M_w 7.6 earthquake generated over 85 km surface rupture along the Chelungpu thrust fault. Paleoseismic studies at the Shi‐Jia site near Nantou city, reveal folding as the predominant form of deformation. Stratigraphic relations across the 1999 fold scarp show the style and degree of deformation caused by the penultimate event is similar to observed 1999 deformation. A boring transect across the fold scarp provides additional evidence of an earlier earthquake. Investigations at the Shi‐Jia site revealed three prehistoric events; accelerator mass spectrometry (AMS) radiocarbon ages indicate that the penultimate earthquake occurred between 1160 and 1440 A.D. Paleoseismic …

Strategies For Research About Design: A Multidisciplinary Graduate Workshop, Mary Shaw, Susan Finger, Mark Gross, James Herbsleb

Mary Shaw

We are developing a graduate curriculum and summer workshop on design research intended to prepare graduate students to do research about the nature of design or research about a class of designs, including concepts, models, and methods for that class. We expect our workshop to advance the science of design of softwareintensive systems by creating a open community of design researchers, both in software design and in related disciplines, who are knowledgeable about design and design research methods and who are interested in advancing the field. The curriculum will create a common basis for discussion and identify core material to …

Lifetime Difference And Cp-Violating Phase In The BS0 System, V. M. Abazov, Kenneth A. Bloom, Gregory R. Snow, D0 Collaboration

Kenneth Bloom Publications

From an analysis of the decay B_s⁰ → J/ψφ, we obtain the width difference between the light and heavy mass eigenstates ΔΓ≡(Γ_L - Γ_H ) = 0.17 ± 0.09(stat) ± 0.02(syst) ps^-1 and the CP-violating phase φ_s= -0.79 ± 0.56(stat) _-0.01^+0.14 (syst). Under the hypothesis of no CP violation (φ_{s ≡ 0), we obtain 1/ Γ̅= τ̅Bs⁰ = 1.52 ± 0.08(stat) 0.03^+0.01(syst) ps and ΔΓ 0.12-0.10^+0.08(stat) ± 0.02(syst) ps^-1. The data sample corresponds to an integrated luminosity of about …}

Effects Of Monochloramine And Free Chlorine On Copper Dissolution In Drinking Water, Ryan C. Abington

Opportunities for Undergraduate Research Experience Program (OURE)

The effects of the disinfectant's free chlorine and monochloramine have been studied on thin copper films using the electrochemical quartz crystal microbalance, scanning electron microscopy and x-ray diffraction. It has been found that after twenty-four hours of immersion, the hypochlorite and the monochloramine both convert some of the copper into cuprous oxide. However, after immersion in monochloramine, tiny pinholes in the copper develop on the electrode and the gold substrate is visible underneath. This leads to suggest that while free chlorine may oxidize copper, monochloramine will oxidize copper and can cause pitting in the metal.

20,25-Diazacholesterol As An Oral Contraceptive For Black-Tailed Prairie Dog Population Management, Paul Nash, Carol A. Furcolow, Kimberly S. Bynum, Christi A. Yoder, Lowell A. Miller, John J. Johnston

United States Department of Agriculture Wildlife Services: Staff Publications

Black-tailed prairie dog (Cynomys ludovicionus) colonies can become overcrowded, and the colonies, landscape, and people affected by them may benefit from controlled populations. Contraception is a method that may be useful, particularly where lethal control is inappropriate or illegal. We investigated if oral administration of 20,25-diazacholesterol (DiazaCon®)n, inhibitor of cholesterol and reproductive steroid hormone production, could reduce reproductive success of treated black-tailed prairie dogs in a field trial. Ten treatments of approximately 45-mg DiazaCon per black-tailed prairie dog yielded a 47% reduction of young:adult ratios compared to control sites. Over a 3-month period, desmosterol, a cholesterol precursor used …

Nontraditional Synthesis Of Organometallic Compounds And Allylic Alcohols, Andrew J. Hesse

Undergraduate Honors Thesis Collection

One of the central dogmas of chemistry is the use of convection heating to increase rate and yields of reactions. However, other methods for the impartation of energy do exist. Microwave irradiation uses high power waves to directly excite molecule into higher energy states. This speeds up the kinetics of the reaction and thermodynamically favorable products are formed at a higher rate. This project successfully uses microwave irradiation to perform organometallic syntheses of iron based compounds such as ferrocene and iron diene tricarbonyls. Another alternative method involves using mechanical energy as a substitute for thermal energy. By rapidly colliding reactants …