Physical Sciences and Mathematics Commons^™

Organocatalyzed Four-Component On-Water Green Synthesis Of Spiroindolinpyranopyrazole, Tanzida Zubair

Theses and Dissertations

Although many synthetic and natural pharmaceuticals and drug-like compounds contain spiro center(s) in their structures, the synthesis of spiro centers is seen to be an exciting and difficult area of research. The synthesis of spiro compounds and their derivatives was carried out using a four-component process that included reagents like hydrazine hydrate, isatin, malononitrile, and an active methylene compound like ethyl acetoacetate. Microwave irradiation was used in a short time range (5 – 30 min) and moderate temperature (80°C), with water as a solvent, and N, N-Diisopropylethylamine (DIPEA) as a catalyst to give high yield of products. Our process complies …

Resistive And Capacitive Behavior In Self-Healing Poly(Ionic Liquid) Copolymers, Jaylan Fraser-Mines

All Theses

This thesis elucidates the origin of molecular events during the damage-repair cycle in a new class of copolymers composed of ionic liquids (ILs) and acrylic-based monomers. In these studies, (1-[(2-methacryloyloxy)ethyl]-3- butylimidazolium bis(trifluoromethyl-sulfonyl)imide) (MEBIm-TFSI) was copolymerized with methyl methacrylate (MMA) and n-butyl acrylate (nBA) to form poly((1-[(2-methacryloyloxy)ethyl]-3- butylimidazolium bis(trifluoromethyl-sulfonyl)imide)-co-methyl methacrylate-co-n butyl acrylate) (p(MEBIm-TFSI/MMA/nBA)) and its mechanical and electrical properties were examined. Following the introduction to this work, Chapter 1 provides an overview of the continuously growing field of ILs and focuses on the structure-property relationships between ILs and their properties as single molecules and monomers in poly(ionic liquid)s (PILs). Chapter 2 …

A Novel Regularized Orthonormalized Partial Least Squares Model For Multi-View Learning, Ce Bian

Mathematics Dissertations

Over the past few years, the size of data dimensions or features has been increasing in various fields of science and engineering, owing to the rapid pace of data collection and the development of more advanced storage methods. However, to handle high-dimensional data, dimensionality reduction is essential before performing classification or regression tasks to eliminate noisy features. There are several numerical methods available for reducing data dimensionality, such as Canonical Correlation Analysis (CCA), Principal Component Analysis (PCA), and Linear Discriminant Analysis (LDA). While these methods offer valuable approaches to data dimensionality reduction, they do come with certain limitations. CCA, for …

Statistical Graph Quality Analysis Of Utah State University Master Of Science Thesis Reports, Ragan Astle

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Graphical software packages have become increasingly popular in our modern world, but there are concerns within the statistical visualization field about the default settings provided by these packages, which can make it challenging to create good quality graphs that align with standard graph principles. In this thesis, we investigate whether the quality of graphs from Utah State University (USU) Plan A Master of Science (MS) thesis reports from the years 1930 to 2019 was affected by the rise of graphical software packages. We collected all data stored on the USU Digital Commons website since November 2021 to determine the specific …

Stressor: An R Package For Benchmarking Machine Learning Models, Samuel A. Haycock

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Many discipline specific researchers need a way to quickly compare the accuracy of their predictive models to other alternatives. However, many of these researchers are not experienced with multiple programming languages. Python has recently been the leader in machine learning functionality, which includes the PyCaret library that allows users to develop high-performing machine learning models with only a few lines of code. The goal of the stressor package is to help users of the R programming language access the advantages of PyCaret without having to learn Python. This allows the user to leverage R’s powerful data analysis workflows, while simultaneously …

Using Natural Language Processing To Quantify The Efficacy Of Language Simplification As A Communication Strategy, Brian Nalley

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

People with communication disorders often experience difficulties being understood by unfamiliar listeners or in noisy environments. A common strategy for effectively communicating in these scenarios is to use simpler and more predictable language. Despite the prevalence of this strategy, there has been little to no research to date focused on the effectiveness of language simplification as a communication strategy. This study seeks to begin filling that gap by using natural language processing to determine whether speakers with early-stage Parkinson’s disease and age-matched neurotypical speakers are able to successfully simplify their language while still maintaining the original message.

Simplification was measured …

Constrained Route Optimization With Fleet Considerations For Electrified Heavy-Duty Freight Vehicles, Zarin Subah Shamma

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Almost 75% of traffic-related emissions are caused by heavy-duty freight trucks and significantly impact neighborhoods, schools, and communities around shipping and distribution lines. With poor air quality and respiratory health, many children in at-risk and disadvantaged communities experience high rates of asthma, lower attendance in school, and lower concentration. This research creates to improve the impacts of heavy-duty electric freight by improving the route efficiency (in terms of energy, time, or route distance) of EV trucks. Our software and algorithms are tested in a simulation environment using data from several thousand fleet trucks operating in the Salt Lake City area. …

The Derivation Of Sodium Density In The Mesosphere And Lower Thermosphere From The Na Lidar Photon Counting Profiles, Xiaoqi Xi

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Derivation of Sodium (Na) number density from the Na lidar observations requires the in situ temperature and wind information because the absorption cross-section of the Na atom is a function of these dynamic parameters. The Na number density above ~ 110 km altitude was difficult to derive with the conventional algorithm, however. The standard output of the Na number density that utilizes the lidar-measured wind and temperature information falls short at ~ 110 km altitude and above due to the relatively large measurement uncertainties in the two critical parameters (low signal-to-noise ratio). Therefore, an innovative algorithm that may drive the …

Opening The Black Box: Soil Microbial Communities In Field-Based Plant-Soil Feedback Experiments, Julia Kate Aaronson

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Plant-soil feedback is a process through which plants modify the properties of their associated soils, affecting their growth. PSF can play a key role in regulating plant growth and communities including altering plant invasion, rarity, and abundance. However, our understanding of the soil organisms that drive these plant growth responses is limited. Most studies treat soils as a ‘black box’ and do little to reveal which specific microbes or microbial communities may be responsible. This chapter examines two recent large PSF field experiments conducted in Minnesota, USA, and Jena, Germany. These experiments revealed that plants altered their soils, changing subsequent …

A Mechanistic Examination Of Interspecific Competition Between Wild And Domestic Herbivores, Courtney Check

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Large herbivores, such as mule deer and cattle have similar life histories and likely compete for resources. However, quantifying the extent to which these species compete and the specific resources they compete for has proved challenging. My research examines if cattle influence deer abundance and behavior due to competition for forage, competition for shade, and/or by affecting the predation risk of deer. Using a grid of autonomous trail cameras, I was able to determine if cattle abundance influences local deer abundance in relation to specific resources and habitat features. Using GPS data from collared deer, I was also able to …

The Time-Dependent Ionospheric Model Using A Tec-Driven Servo: An Investigation Of The Capabilities And Limitations, Jenny Rebecca Whiteley

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The ionosphere is a region of the atmosphere with a high density of electrons. These electrons affect the behavior of any electromagnetic wave that passes through the ionosphere. Communication and geolocation systems, such as traditional radio and Global Positioning Systems, depend on emitted electromagnetic signals being picked up by a receiver. The presence of the ionosphere affects the behavior of the signal and the quality of the service. Hence, the interactions between electromagnetic waves and the ionosphere provide a major motivation to understand, research, and successfully model and predict the ionosphere and its physical phenomena. This study focused on determining …

Proxy Voting Coordination Mechanisms: Determining How Agents Should Coordinate In A Continuous Preference Space, Michael D. Hegerhorst

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Illness, injury, and other impediments are common occurrences of everyday life. Such impediments prevent or deter voters from participating in important parts of the voting process, especially deliberation, bargaining, and the voting itself. Without participation, the results of the vote may change. There is a need to provide a system in which voters are still able to participate in important voting processes to ensure their vote is represented. We explore ‘proxy voting,’ a system in which voters are able to select another individual, or proxy, to vote on their behalf. By choosing a good proxy, a voter can still …

Comparing Commonly Used Aquatic Habitat Modeling Methods For Native Fishes, Eryn K. Turney

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Water resources are managed for a variety of human needs, including agriculture, industrial and municipal consumption, hydropower generation, and recreation. There has been a recent push to incorporate habitat needs of aquatic wildlife into water management models alongside these other uses, particularly as competition for limited water resources in a changing climate has reduced instream flow and contributed to declining native fish populations. Habitat models are used to estimate species distributions and differentiate between suitable and unsuitable habitat based on variables important to a given species, but are not usually incorporated into water management models. Because there are many ways …

Volatile Cycling And Metasomatism In Flat-Slab Subduction Zones Of The Central Andes, Coleman Hiett

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Flat-slab subduction, where an oceanic plate subducts horizontally below a continental margin for hundreds of kilometers, is an enigmatic but prevalent tectonic configuration in which chemical cycling and alteration of the continental plate is poorly constrained. Geochemical investigations in regions of modern and ancient flat-slab subduction in the Central Andes afford an opportunity to study this process. Certain elements naturally occur with varying number of neutrons in their nuclei (isotopes), and measurements of isotope ratios within geologic materials inform on chemical sources and geologic processes. This research leverages stable isotope analyses and other geochemical tools to investigate volatiles and other …

Large Eddy Simulation By Using Wang’S Liutex-Based Subgrid Model, Vishwa Shah

Mathematics Dissertations

Turbulent flows and vortex structures in fluid dynamics have been captivating researchers for decades, owing to their intrinsic complexity and significance in various industrial and natural processes. Despite their fundamental importance, the definition and identification of vortices in turbulent flows continue to pose challenges, and to date, no universally accepted approach exists. This pursuit dates to the pioneering work of Hermann von Helmholtz in the 19th century, when the concept of vortices was first introduced. In 2019, Liu et al. introduced a novel physical quantity termed "Liutex" in scalar, vector, and tensor forms, providing a promising avenue for understanding and …

Analyzing The Adoption, Cropping Rotation, And Impact Of Winter Cover Crops In The Mississippi Alluvial Plain (Map) Region Through Remote Sensing Technologies, Zobaer Ahmed

Graduate Theses and Dissertations

This dissertation explores the application of remote sensing technologies in conservation agriculture, specifically focusing on identifying and mapping winter cover crops and assessing voluntary cover crop adoption and cropping patterns in the Arkansas portion of the Mississippi Alluvial Plain (MAP). In the first chapter, a systematic review using the PRISMA methodology examines the last 30 years of thematic research, development, and trends in remote sensing applied to conservation agriculture from a global perspective. The review uncovers a growing interest in remote sensing-based research in conservation agriculture and emphasizes the necessity for further studies dedicated to conservation practices. Among the 68 …

Evaluation Of Biochar Rate And Hemp Cultivar For The Phytoremediation Of Heavy-Metal-Contaminated Soil From The Tar Creek Superfund Site, Dietrich Thurston

Graduate Theses and Dissertations

Soil contamination by cadmium (Cd), lead (Pb), and zinc (Zn) at the Tar Creek Superfund site in Northeast Oklahoma remains a threat to the environment and local ecosystem. Phytoremediation by industrial hemp (Cannabis sativa L.) and the use of biochar (BC) have been independently shown to be effective methods to remediate heavy-metal-contaminated soils. The objective of this greenhouse study was to evaluate the effects of industrial hemp cultivar (‘Carmagnola’ and ‘Jinma’), BC rate (0, 2, 5, and 10% by volume), soil contamination level (low, medium, and high), and their interactions on above- and belowground (AG and BG, respectively) plant dry …

Constraining High Temperature Deformation And Metamorphism In The Southern Wet Mountains, Colorado, Usa: Implications For The Regional Extent Of The Picuris Orogeny, Sarah Morse

Graduate Theses and Dissertations

The Wet Mountains of Colorado are underlain by exhumed Proterozoic metamorphic rock that lies north of the recently identified 1.46 to 1.40 Ga Picuris orogen in northern New Mexico. The Picuris orogen is inferred to have formed in response to a Mesoproterozoic (ca. 1.49-1.40 Ga) contractional to transpressional event extrapolated to be regional in extent. It has been proposed that the Picuris orogen composes the westernmost tectonic segment of the Pinware-Baraboo-Picuris orogen that formed along an evolving convergent margin that becomes younger from northeast to southwest. This study is focused on the record of high temperature deformation, metamorphism, and plutonism …

Comparing Predictive Performance Of Garch And Stochastic Volatility Models, Swapnaneel Nath

Graduate Theses and Dissertations

This paper compares the predictive performance of two commonly used financial models, the Generalized Auto-Regressive Conditional Heteroskedasticity (GARCH) model, and the Stochastic Volatility model. Both techniques are used in the finance literature to model returns on an asset; the main difference between the two is that the former holds volatility as deterministic, whereas the latter treats it as a stochastic component. Three 10-year periods (2006-15, 2008-17, and 2010-19) of returns of the S&P-500 Index are used to train the two models. The parameter estimation is done using Hamiltonian Monte Carlo. Then, using Sequential Monte Carlo updates, returns for 2016, 2018, …

Investigation Of The Flow Field In The Jack Rabbit Ii Mock Urban Environment Field Tests Using A 1:50 Scale Wind Tunnel Model, Paulo Victor De Freitas Lopes

Graduate Theses and Dissertations

Accidental release of toxic chemicals can put workers and nearby populations at significant risk. Consequence assessment of accidents in urban environments is of particular interest. Urban geometries create wind channels between buildings, along with particularly dangerous areas downwind of buildings, where near-stagnant flow is present. Furthermore, recirculation zones can be formed between buildings, trapping high concentrations of toxic gases at ground level, particularly for denser-than-air gases. In 2015, the Department of Homeland Security conducted the Jack Rabbit II Field Test (JR-II) at Dugway Proving Ground, UT. During JR-II, chlorine was released at the center of a Mock Urban Environment (MUE) …

Verification Of Astm Centrifugation Equations For Soil Suction Determination, Esteban Maclein Miranda Pinzon

Graduate Theses and Dissertations

The unit correction constant (B) in the ASTM D6836 standard needs to be evaluated. The B-value was proposed to be 0.00548 instead of 0.00553. This apparent discrepancy led to an investigation comparing the predicted and measured suction values for high air entry (HAE) ceramic disks. A Beckman-Coulter Model J6-MI six-bay centrifuge and a WP4C Dewpoint Potentiameter were used in the testing program. HAE ceramic disks rated with bubbling pressures of 3-bar and 5-bar were used as analogue soil specimens. The HAE ceramic disks were spun in the small-scale centrifuge to apply prescribed suction amounts and then placed in the WP4C …

Runoff Water Quality And Crop Growth As Affected By Wastewater-Derived Struvite, Machaela Morrison

Graduate Theses and Dissertations

Mined phosphate rock, used to produce phosphorus (P) fertilizers, is a finite resource. Struvite (MgNH4PO4 • 6H2O) that has been synthetically produced from a stock solution of known P and nitrogen (N) concentrations has been shown to be an effective, alternative fertilizer-P source for various crops. However, little is known about the runoff-water-quality implications from and the crop response to soil application of struvite created from an actual municipal wastewater source. This study consisted of two objectives: i) to evaluate the effects of soil [i.e., Creldon (Oxyaquic Fragiudalf), Dapue (Fluventic Hapludoll), Roxana (Typic Udifluvent), and Calloway (Aquic Fraglossudalf) series], fertilizer-P …

Circuitry And Semiconductor Studies For Making A Graphene Energy Harvesting Device, Ferdinand Harerimana

Graduate Theses and Dissertations

Freestanding graphene has constantly moving ripples. Due to its extreme flexibility, graphene responds to ambient vibrations and changes its curvature from concave to convex and vice versa. During a ripple inversion 10,000 atoms move together, suggesting the presence of kinetic energy which can be harvested. In this study we present circuitry and semiconductor studies for harvesting energy from graphene vibrations. The goal of the study is to develop a graphene energy harvesting chip which can serve as a battery replacement in low power electronics. In the first study we determined the best circuit for harvesting vibrational low power. To do …

Poly(Ionic Liquid)S For Magnetic, Ionic, And Electrical Stimuli-Responsive Applications, Kayla Ann Foley

Graduate Theses and Dissertations

Poly(ionic liquid)s (PILs) are a fascinating subclass of strong polyelectrolytes formed from polymerizable ionic liquids. As a result of their unique properties and counterion exchangeability, PILs can exhibit conformation structure or material property changes in response to external stimuli such as changes in pH/ionic environment, magnetic fields, and electric potentials. In Chapter 1, a comprehensive review of PILs design as well as their stimuli-responsive behavior is provided. Additional motivation for each dissertation chapter is also discussed. In Chapter 2, magnetically responsive PILs (MPILs) are developed from complexing paramagnetic salts with a random PIL copolymer containing a metal-coordinating co-monomer, acrylamide. A …

Photon Counting Statistics Of Classical And Quantum Light Sources, Luis Felipe Morales Bultron

Graduate Theses and Dissertations

Multiple sources of light, including coherent light, thermal light, light from a degenerate parametric oscillation and resonance fluorescence from a two level coherently driven atom are considered for the analysis of their wait time statistics. We include the second order normalized correlation function and Mandel's Q parameter for brief discussion. A general framework to analyze the generalized conditional and unconditional wait time distributions is also obtained in order to understand the photo-count statistics of the light sources included in this work. Average and variance of wait times with respect to both unconditional and conditional wait time distribution are also obtained …

A Comparative Study Of Techniques For Non-Monotonic Dependence With Emphasis On Sensitivity To Sample Size, Noise Level And Computational Attributes, Fariha Tasnim

Graduate Theses and Dissertations

Evaluating association between variables is often of interest by many researchers. To serve this purpose, different association measures have been developed. However, type of relation between variables affects the degree of relationship. Hence, detection of the rela- tionship between variables is germane to measuring the correlation coefficient. With that mindset, here we explored six non-monotonic measure of association techniques and com- pared them with three classical approaches. Due to inconsistency in definition and range of different techniques, it is not feasible to compare the correlation estimates as their nature of variability differ. Therefore, we used permutation test based on Monte …

Chemostratigraphic And Paleoclimatic Studies Of Cloverly Formation, Northern Wyoming, U.S.A, Queen Amarachi Kalu

Graduate Theses and Dissertations

The Early – Late Cretaceous transition in Western North America recorded a period of rapid climatic and tectonic change in Earth’s history. Major climate events associated with large igneous province eruptions caused several instances of ocean anoxic events (OAE) and perturbations to the global carbon (C) – cycle. These perturbations to the global C-cycle are observed in the bulk organic C record of both marine and terrestrial deposits and can be used to correlate units across major depositional basins. Major efforts are being made to generate time-constrained palaeontologic and paleoclimate information from the North American Cordilleran foreland basin and C-isotope …

Etching Of Silicon Wafer In Preparation Of Graphene Transfer, Floyd T. Lancaster Iii

Graduate Theses and Dissertations

Following the research done on graphene looking at its unique properties it has been found that graphene can be used as a varying capacitor. What has been observed is that graphene acts almost like a torrential ocean constantly fluctuating. What we use is a silicon wafer with multiple etched layers to create a stable platform on which to capture this energy. In this paper we will discuss the general setup and step-by-step procedures required to create a functioning variable capacitor out of graphene, gold, and Silicon dioxide (SiO2) substrate. Electron Beam Lithography (EBL) is used to create the initial design …

Towards Multi-Modal Explainable Video Understanding, Kashu Yamazaki

Graduate Theses and Dissertations

This thesis presents a novel approach to video understanding by emulating human perceptual processes and creating an explainable and coherent storytelling representation of video content. Central to this approach is the development of a Visual-Linguistic (VL) feature for an interpretable video representation and the creation of a Transformer-in-Transformer (TinT) decoder for modeling intra- and inter-event coherence in a video. Drawing inspiration from the way humans comprehend scenes by breaking them down into visual and non-visual components, the proposed VL feature models a scene through three distinct modalities. These include: (i) a global visual environment, providing a broad contextual understanding of …

Cultural Competence Among Child Life Professionals, Rachel Burger

Graduate Theses and Dissertations

There is an ever-growing need for individuals to work towards cultural competence, especially when those individuals work in healthcare. As healthcare professionals with backgrounds in child development and who provide emotional and psychological support to diverse pediatric patient populations in a variety of different sectors, child life specialists (CLS) and Certified Child Life Specialists (CCLSs) have an even greater need for understanding cultural competence (Thompson, 2009). The purpose of the current study was to examine the cultural competency levels of CCLSs, the type of cultural competence professional development units (PDUs) they participate in, and their perspectives on cultural competence in …